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RESEARCH PAPER · The Journal of Physical Chemistry Letters · 2023

Spacer-Dependent and Pressure-Tuned Structures and Optoelectronic Properties of 2D Hybrid Halide Perovskites

Jesse Ratté, MacGregor F. Macintosh, Lauren DiLoreto, Jingyan Liu, Willa Mihalyi‐Koch, Matthew P. Hautzinger, Ilia A. Guzei, Zhaohui Dong, Song Jin, Yang Song

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Spacer-Dependent and Pressure-Tuned Structures and Optoelectronic Properties of 2D Hybrid Halide PerovskitesOriginalBand gap tailoring with octahedral distortion and bader charge analysis for 2D-Ruddlesden–Popper monolayer tin halide perovskites9Correlating Photophysical Properties with Stereochemical Expression of 6s 2 Lone Pairs in Two‐dimensional Lead Halide Perovskites38Correlating Photophysical Properties with Stereochemical Expression of 6s2 Lone Pairs in Two‐dimensional Lead Halide Perovskites1Photophysical Properties of S = 5/2 Zigzag-1D (2-Bromoethylammonium)3MnBr5 Antiferromagnet2Impact of functional groups in spacer cations on the properties of PEA-based 2D monolayer halide perovskites19Exciton engineering of 2D Ruddlesden–Popper perovskites by synergistically tuning the intra and interlayer structures113The self-healing and robust photostability of (PEA)2PbI4 perovskite via pressure-induced amorphization and recrystallization6Hysteretic Piezochromism in a Lead Iodide-Based Two-Dimensional Inorganic–Organic Hybrid Perovskite12Revealing the Universal Pressure‐Driven Behavior of Hybrid Halide Perovskites and Unique Optical Modifiability in Extremely Soft 2D Tin‐Based System13Pressure-Induced Ultrawidely Tunable and Ultrapure Photoluminescence in 2D Perovskites via Fluorination of Organic Cations11First-principles study on bromide-based 2D hybrid organic-inorganic halide perovskites for perovskite solar cells6Releasing trapped excitons in 2D perovskites via pressure annealing: a cooperative interplay between lattice strain and the electronic structure8Recent progress of structures and photoelectric properties of two-dimensional materials under high pressure0Organic Spacers Modulated Low Dose X‐Ray Detection in Hybrid Halide 2D Perovskites: Unveiling Exciton Dynamics15Pressure-Induced Modulation of Band Characteristics in 2D Hybrid Perovskites7High-pressure research on optoelectronic materials: Insights from in situ characterization methods22Pressure‐Induced Structural and Optoelectronic Modulations in 2D Dion‐Jacobson Hybrid Lead Iodide Perovskites With a Rigid Spacer4Cage Balancing Enhances Optoelectronic and Lasing Performance in Stable Quasi-2D Tin Iodide Perovskites11Pressure-tuned 2D hybrid perovskites: emerging insights and future opportunities1Pressure driven interplay of Rashba, Rashba–Dresselhaus and persistent spin texture in lead-free quasi-2D hybrid perovskites0Chirality-Dependent Modulation of Organic-Inorganic Interaction and Exciton Response in 2D Perovskites under Pressure0

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  1. Band gap tailoring with octahedral distortion and bader charge analysis for 2D-Ruddlesden–Popper monolayer tin halide perovskites

    Materials Science in Semiconductor Processing · 2023-04-14

    Mehreen Javed, Noureddine Amrane, Maamar Benkraouda

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  2. Correlating Photophysical Properties with Stereochemical Expression of 6s 2 Lone Pairs in Two‐dimensional Lead Halide Perovskites

    Angewandte Chemie International Edition · 2023-05-26

    Jiazhen Gu, Yu Tao, Tonghuan Fu, Songhao Guo, Xiao‐Fan Jiang, Yan Guan, Xiaotong Li, Chen Li, Xujie Lü, Yongping Fu

    Read original paper ↗ ·

  3. Correlating Photophysical Properties with Stereochemical Expression of 6s2 Lone Pairs in Two‐dimensional Lead Halide Perovskites

    Angewandte Chemie · 2023-05-26

    Jiazhen Gu, Yu Tao, Tonghuan Fu, Songhao Guo, Xiao‐Fan Jiang, Yan Guan, Xiaotong Li, Chen Li, Xujie Lü, Yongping Fu

    Read original paper ↗ ·

  4. Photophysical Properties of S = 5/2 Zigzag-1D (2-Bromoethylammonium)3MnBr5 Antiferromagnet

    The Journal of Physical Chemistry Letters · 2023-10-18

    Debendra Prasad Panda, Diptikanta Swain, Rajamani Raghunathan, Athinarayanan Sundaresan

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  5. Impact of functional groups in spacer cations on the properties of PEA-based 2D monolayer halide perovskites

    Nano Materials Science · 2024-03-16

    Chenchen Li, Xian Chen, Tan Jin, Tianmin Wu, Jun Chen, Wei Zhuang

    Read original paper ↗ ·

  6. Exciton engineering of 2D Ruddlesden–Popper perovskites by synergistically tuning the intra and interlayer structures

    Nature Communications · 2024-04-08

    Songhao Guo, Willa Mihalyi‐Koch, Yuhong Mao, Xinyu Li, Kejun Bu, Huilong Hong, Matthew P. Hautzinger, Hui Luo, Dong Wang, Jiazhen Gu, Yifan Zhang, Dongzhou Zhang, Qingyang Hu, Yang Ding, Wenge Yang, Yongping Fu, Song Jin, Xujie Lü

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  7. The self-healing and robust photostability of (PEA)2PbI4 perovskite via pressure-induced amorphization and recrystallization

    Optical Materials · 2024-04-30

    Haiyan Wang, Qiaohe Wang, Kun Yang, Hangtian Li, Ao Liu, Yuxin Zhao, Zijiong Li

    Read original paper ↗ ·

  8. Hysteretic Piezochromism in a Lead Iodide-Based Two-Dimensional Inorganic–Organic Hybrid Perovskite

    Journal of the American Chemical Society · 2024-08-09

    Paul Steeger, Mohammad Adnan, Thorsten Deilmann, Xiang Li, Susanne Müller, Katarzyna Skrzyńska, Michael Hanfland, Efim Kolesnikov, Jutta Kösters, Theresa Block, Robert Schmidt, Ilya Kupenko, Carmen Sanchez‐Valle, Gaddam Vijaya Prakash, Steffen Michaelis de Vasconcellos, Rudolf Bratschitsch

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  9. Revealing the Universal Pressure‐Driven Behavior of Hybrid Halide Perovskites and Unique Optical Modifiability in Extremely Soft 2D Tin‐Based System

    Advanced Functional Materials · 2024-09-02

    Lingping Kong, Jue Gong, Ioannis Spanopoulos, Shuai Yan, Zhongyang Li, Zhikai Zhu, Xingyi Liu, Yinning Zhu, Hongliang Dong, Haiyun Shu, Qingyang Hu, Wenge Yang, Ho‐kwang Mao, Mercouri G. Kanatzidis, Gang Liu

    Read original paper ↗ ·

  10. Pressure-Induced Ultrawidely Tunable and Ultrapure Photoluminescence in 2D Perovskites via Fluorination of Organic Cations

    Chemistry of Materials · 2024-09-19

    Wei Wang, Hang Luo, Tieshan Yang, Mengmeng Jiao, Shufang Zhang, Zhigang Li, Chuan‐Lu Yang, Qinfeng Xu, Kai Wang

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  11. First-principles study on bromide-based 2D hybrid organic-inorganic halide perovskites for perovskite solar cells

    Journal of Physics and Chemistry of Solids · 2024-12-06

    Ghazaleh Bagha, Katayoon Samavati, Homam Naffakh-Moosavy, Laleh Farhang Matin

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  12. Releasing trapped excitons in 2D perovskites via pressure annealing: a cooperative interplay between lattice strain and the electronic structure

    Materials Chemistry Frontiers · 2024-12-11

    André L. M. Freitas, Naidel A. M. S. Caturello, Aryane Tofanello, Ulisses Ferreira Kaneko, L. E. Corrêa, R. D. dos Reis, Fábio Furlan Ferreira, Gustavo M. Dalpian, Jose Antonio Souza

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  13. Recent progress of structures and photoelectric properties of two-dimensional materials under high pressure

    Acta Physica Sinica · 2025-01-01

    CHENG Lingying, Huafang Zhang, Yanli Mao

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  14. Organic Spacers Modulated Low Dose X‐Ray Detection in Hybrid Halide 2D Perovskites: Unveiling Exciton Dynamics

    Small · 2025-01-16

    Shivani Choudhary, Joydip Ghosh, Shantanu Pathak, Saurabh Kumar Saini, Naveen Kumar Tailor, Paul J Sellin, Saswata Bhattacharya, Soumitra Satapathi

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  15. Pressure-Induced Modulation of Band Characteristics in 2D Hybrid Perovskites

    ACS Applied Energy Materials · 2025-01-16

    Eti Mahal, Biswarup Pathak

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  16. High-pressure research on optoelectronic materials: Insights from in situ characterization methods

    Matter and Radiation at Extremes · 2025-04-28

    Songhao Guo, Yiqiang Zhan, Xujie Lü

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  17. Pressure‐Induced Structural and Optoelectronic Modulations in 2D Dion‐Jacobson Hybrid Lead Iodide Perovskites With a Rigid Spacer

    Advanced Optical Materials · 2025-06-10

    A. P. K. Kutty, Jesse Ratté, Rongfeng Guan, Jingyan Liu, Sean Tao, Yuktsun Lin, Matthew P. Hautzinger, Willa Mihalyi‐Koch, Song Jin, Yang Song

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  18. Cage Balancing Enhances Optoelectronic and Lasing Performance in Stable Quasi-2D Tin Iodide Perovskites

    Journal of the American Chemical Society · 2025-09-15

    Christopher T. Triggs, Chun-Sheng Jack Wu, Yarong He, Eliana Bernat, Willa Mihalyi‐Koch, Kristel M. Forlano, Ilia A. Guzei, Daniele Cortecchia, Annamaria Petrozza, Song Jin

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  19. Pressure-tuned 2D hybrid perovskites: emerging insights and future opportunities

    Journal of Materials Chemistry A · 2025-10-28

    Aditya Kutty, Yang Song

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  20. Pressure driven interplay of Rashba, Rashba–Dresselhaus and persistent spin texture in lead-free quasi-2D hybrid perovskites

    Journal of Materials Chemistry A · 2026-01-01

    Jagjit Kaur, Sudip Chakraborty

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  21. Chirality-Dependent Modulation of Organic-Inorganic Interaction and Exciton Response in 2D Perovskites under Pressure

    ACS Materials Letters · 2026-06-29

    Mattia Capeccia, Marco Moroni, Francesco Capitani, Boby Joseph, Lorenzo Malavasi, P. Postorino, Elena Stellino

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