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RESEARCH PAPER · Materials Horizons · 2023

Linear optical afterglow and nonlinear optical harmonic generation from chiral tin( iv ) halides: the role of lattice distortions

Xiao Han, Puxin Cheng, Rongchao Shi, Yongshen Zheng, Siming Qi, Jialiang Xu, Xian‐He Bu

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Linear optical afterglow and nonlinear optical harmonic generation from chiral tin( iv ) halides: the role of lattice distortionsOriginalFrom H 12 C 4 N 2 CdI 4 to H 11 C 4 N 2 CdI 3 : a highly polarizable CdNI 3 tetrahedron induced a sharp enhancement of second harmonic generation response and birefringence50Homochiral Chemistry Strategy to Trigger Second-Harmonic Generation and Dual Dielectric Switches231,10-Phenanthroline-5-amine derived N-doped carbon dots for long-lived visible-light-activated room temperature phosphorescence in the matrix and information encryption application18Realizing efficient emission and triple‐mode photoluminescence switching in air‐stable tin(IV)‐based metal halides via antimony doping and rational structural modulation37Achieving Highly Efficient Orange Emission in Tin (IV)‐Based Metal Halides with Outstanding Anti‐Water Stability Through Antimony Doping and Reasonable Structural Modulation27Free Halogen Substitution of Chiral Hybrid Metal Halides for Activating the Linear and Nonlinear Chiroptical Properties140Rational design of enantiomeric lead-free double perovskites by achiral-chiral cation intercalation28Tellurium(IV) Halide Achieving Effective Nonlinear-Optical Activity: The Role of Chiral Ligands and Lattice Distortion17Advancing nonlinear optics: discovery and characterization of new non-centrosymmetric phenazine-based halides6Amine-directed synthesis, valence state control, and optical properties of two new organic–inorganic tin chlorides7Realizing efficient broadband near-infrared emission under blue light excitation in Sb 3+ -doped zero-dimensional organic tin( iv )-based metal halides via coordination structure modulation12Tuning the dimensionality in chiral and racemic organic/tin hybrids with halides2Large‐Scale Room‐Temperature Synthesis of the First Sb 3+ ‐Doped Organic Ge(IV)‐Based Metal Halides with Efficient Yellow Emission for Solid‐State Lighting and Latent Fingerprint Detection24Zero-dimensional halide hybrid bulk glass exhibiting reversible photochromic ultralong phosphorescence150Phase Transition of a Chiral Lead‐Free Hybrid Antimony(III) Halide Crystal2Mixed-Layered Lead Halide Frameworks with High Stability and Efficient Room-Temperature Phosphorescence2Efficient manipulation of photoluminescence by organic cations and Sb doping in hybrid manganese chlorides5Simultaneous achieving color‐tuning long persistent luminescence and phosphorescent quantum yield of 81.05% in 2D organic metal halide perovskite17Chiral Metal‐Free Anti‐Perovskite with Strong Chiroptical Nonlinearity13Chiral Metal‐Free Anti‐Perovskite with Strong Chiroptical Nonlinearity23Dynamic control of halide perovskite structures for tailored ferroelectric and second-order nonlinear optical functionalities39Unraveling Lattice Void Occupancy Engineering for Regulating Optical/Dielectric Responses in Hybrid Crystals2Metal Coordination‐Mediated Organic Room‐Temperature Phosphorescence: Toward High‐Efficiency Ultralong Emission via Nonradiative Channel Constriction3Competitive Chirality Induction in Two‐dimensional Germanium Iodide Perovskites Enabling Highly Anisotropic Nonlinear Optical Response8Competitive Chirality Induction in Two‐dimensional Germanium Iodide Perovskites Enabling Highly Anisotropic Nonlinear Optical Response17Enhanced Photocatalytic Water Splitting via Chiral Cadmium Zinc Sulfide Nanostructures: Spin Polarization Modulation for Efficient Charge Carrier Dynamics4REXCO3 (RE = La, Ce, Y; X = OH, F) with circular alignment of anionic motifs induced extraordinary nonlinear optical effects0Internally and externally induced chiral hybrid metal halide materials for advanced chiroptoelectronic applications23Isomeric organic–inorganic indium bromide single crystals with delayed and dual colour emission0Origin of inverse emission behaviour in strain-engineered zero-dimensional tin halides: all-inorganic vs. hybrid3Second-harmonic generation responses in low-dimensional metal bromides functionalized with l -arginine1Single-component zero-dimensional (BPY) 2 ZrCl 6 :Sb 3+ hybrid perovskite exhibiting excitation-dependent multi-color fluorescence and afterglow for advanced hierarchical anti-counterfeiting0Mechanochemical engineering of chiroptical properties in indium-based chiral metal halides by grinding0Efficient Organic‐Inorganic Sn 4+ ‐Based Halide Phosphorescent Scintillators Enabled by Enhanced Triplet Exciton Utilization and Excited Energy Level Regulation0Efficient Organic‐Inorganic Sn 4+ ‐Based Halide Phosphorescent Scintillators Enabled by Enhanced Triplet Exciton Utilization and Excited Energy Level Regulation10Reversible Circularly Polarized Luminescence Response of Chiral Antimony‐Based Hybrid Halides and Its Applications in Information Anti‐Counterfeiting and CP‐LED0Chiral Lattice Distortion Enables Bright Near-Infrared Circularly Polarized Luminescence in Lead-Free Metal Halides0

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  1. From H 12 C 4 N 2 CdI 4 to H 11 C 4 N 2 CdI 3 : a highly polarizable CdNI 3 tetrahedron induced a sharp enhancement of second harmonic generation response and birefringence

    Chemical Science · 2023-01-01

    Huai‐Yu Wu, Chun‐Li Hu, Miao‐Bin Xu, Qianqian Chen, Nan Ma, Xiao‐Ying Huang, Ke‐Zhao Du, Jin Chen

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  2. Homochiral Chemistry Strategy to Trigger Second-Harmonic Generation and Dual Dielectric Switches

    Inorganic Chemistry · 2023-07-10

    Bowen Deng, Yang Zhu, Kun Ying Ding, Jie Li, Meng‐Meng Lun, Da‐Wei Fu, Zhi‐Xu Zhang

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  3. 1,10-Phenanthroline-5-amine derived N-doped carbon dots for long-lived visible-light-activated room temperature phosphorescence in the matrix and information encryption application

    Journal of Luminescence · 2023-07-19

    Wansong Sun, Wanchao Hu, Bingfeng Shi, Changli Lü

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  4. Realizing efficient emission and triple‐mode photoluminescence switching in air‐stable tin(IV)‐based metal halides via antimony doping and rational structural modulation

    Aggregate · 2023-08-24

    Xuefei He, Hui Hua Peng, Qilin Wei, Zhijie Zhou, G. P. Zhang, Zhentao Du, Jialong Zhao, Bingsuo Zou

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  5. Achieving Highly Efficient Orange Emission in Tin (IV)‐Based Metal Halides with Outstanding Anti‐Water Stability Through Antimony Doping and Reasonable Structural Modulation

    Advanced Optical Materials · 2023-11-07

    Bao Ke, Hui Hua Peng, Qilin Wei, Chengzhi Yang, Xueping Li, Weiguo Huang, Zhentao Du, Jialong Zhao, Bingsuo Zou

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  6. Free Halogen Substitution of Chiral Hybrid Metal Halides for Activating the Linear and Nonlinear Chiroptical Properties

    Journal of the American Chemical Society · 2023-12-01

    Junjie Guan, Yongshen Zheng, Puxin Cheng, Wenqing Han, Xiao Han, Peihan Wang, Mingyang Xin, Rongchao Shi, Jialiang Xu, Xian‐He Bu

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  7. Rational design of enantiomeric lead-free double perovskites by achiral-chiral cation intercalation

    Chem · 2023-12-26

    Tingting Zhu, Xinling Li, Panpan Yu, Zeng‐Kui Zhu, Minjuan Li, Ruiqing Li, Shiguo Han, Huang Ye, Chengmin Ji, Junhua Luo

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  8. Tellurium(IV) Halide Achieving Effective Nonlinear-Optical Activity: The Role of Chiral Ligands and Lattice Distortion

    Inorganic Chemistry · 2023-12-28

    Shufang Yan, Yue Guo, Wenlong Liu, Sheng‐Ping Guo, Jiajing Wu

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  9. Advancing nonlinear optics: discovery and characterization of new non-centrosymmetric phenazine-based halides

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    Yibo Cui, Jindong Cao, Jiawei Lin, Chunxiao Li, Jiyong Yao, Kunjie Liu, An Hou, Zhongnan Guo, Jing Wei Zhao, Quanlin Liu

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  10. Amine-directed synthesis, valence state control, and optical properties of two new organic–inorganic tin chlorides

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    Xuemei Wen, Gangji Yi, Zhizhuan Zhang, Caihong Guo, Hongmei Zeng, Ling Huang, Guohong Zou, Zhien Lin

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  11. Realizing efficient broadband near-infrared emission under blue light excitation in Sb 3+ -doped zero-dimensional organic tin( iv )-based metal halides via coordination structure modulation

    Inorganic Chemistry Frontiers · 2024-01-01

    Bao Ke, Hui Hua Peng, Yongqi Yang, Chengzhi Yang, Shangfei Yao, Arfan Bukhtiar, Qilin Wei, Jialong Zhao, Bingsuo Zou

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  12. Tuning the dimensionality in chiral and racemic organic/tin hybrids with halides

    Dalton Transactions · 2024-01-01

    Louis Caussin, Abdelaziz Jouaiti, Daniel Chartrand, W. G. Skene, Sylvie Ferlay

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  13. Large‐Scale Room‐Temperature Synthesis of the First Sb 3+ ‐Doped Organic Ge(IV)‐Based Metal Halides with Efficient Yellow Emission for Solid‐State Lighting and Latent Fingerprint Detection

    Small Structures · 2024-02-02

    Xuefei He, Qilin Wei, Hui Hua Peng, Yuchen Li, Xiao Lu Wang, Bao Ke, Jialong Zhao, Bingsuo Zou

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  14. Zero-dimensional halide hybrid bulk glass exhibiting reversible photochromic ultralong phosphorescence

    Nature Communications · 2024-06-29

    Fei Nie, Dongpeng Yan

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  15. Phase Transition of a Chiral Lead‐Free Hybrid Antimony(III) Halide Crystal

    European Journal of Inorganic Chemistry · 2024-07-26

    Jun‐Chao Qi, Zhang‐Tian Xia, Xin Shen, Hang Peng, Huiping Chen, Yong‐Ju Bai, Wei‐Qiang Liao

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  16. Mixed-Layered Lead Halide Frameworks with High Stability and Efficient Room-Temperature Phosphorescence

    The Journal of Physical Chemistry Letters · 2024-08-09

    Chen Sun, Dongyang Li, Wenyan Dan, Jinlin Yin, Honghan Fei

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  17. Efficient manipulation of photoluminescence by organic cations and Sb doping in hybrid manganese chlorides

    Journal of Luminescence · 2024-10-11

    Yingjie Mao, Zhichao Zhang, Guojun Zhou, Chen Fang, Yihan Liu, Denghui Xu, Jia Zhao, Aicong Geng, Jun Zhou

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  18. Simultaneous achieving color‐tuning long persistent luminescence and phosphorescent quantum yield of 81.05% in 2D organic metal halide perovskite

    Aggregate · 2024-10-24

    Zheng Wang, Chunsheng Li, Jun‐Ting Mo, Mei Ling Pan

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  19. Chiral Metal‐Free Anti‐Perovskite with Strong Chiroptical Nonlinearity

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  20. Chiral Metal‐Free Anti‐Perovskite with Strong Chiroptical Nonlinearity

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  21. Dynamic control of halide perovskite structures for tailored ferroelectric and second-order nonlinear optical functionalities

    Chemical Society Reviews · 2025-01-01

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  22. Unraveling Lattice Void Occupancy Engineering for Regulating Optical/Dielectric Responses in Hybrid Crystals

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  23. Metal Coordination‐Mediated Organic Room‐Temperature Phosphorescence: Toward High‐Efficiency Ultralong Emission via Nonradiative Channel Constriction

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  24. Competitive Chirality Induction in Two‐dimensional Germanium Iodide Perovskites Enabling Highly Anisotropic Nonlinear Optical Response

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  25. Competitive Chirality Induction in Two‐dimensional Germanium Iodide Perovskites Enabling Highly Anisotropic Nonlinear Optical Response

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  26. Enhanced Photocatalytic Water Splitting via Chiral Cadmium Zinc Sulfide Nanostructures: Spin Polarization Modulation for Efficient Charge Carrier Dynamics

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  27. REXCO3 (RE = La, Ce, Y; X = OH, F) with circular alignment of anionic motifs induced extraordinary nonlinear optical effects

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  28. Internally and externally induced chiral hybrid metal halide materials for advanced chiroptoelectronic applications

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  29. Isomeric organic–inorganic indium bromide single crystals with delayed and dual colour emission

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  30. Origin of inverse emission behaviour in strain-engineered zero-dimensional tin halides: all-inorganic vs. hybrid

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  31. Second-harmonic generation responses in low-dimensional metal bromides functionalized with l -arginine

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  32. Single-component zero-dimensional (BPY) 2 ZrCl 6 :Sb 3+ hybrid perovskite exhibiting excitation-dependent multi-color fluorescence and afterglow for advanced hierarchical anti-counterfeiting

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  33. Mechanochemical engineering of chiroptical properties in indium-based chiral metal halides by grinding

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  34. Efficient Organic‐Inorganic Sn 4+ ‐Based Halide Phosphorescent Scintillators Enabled by Enhanced Triplet Exciton Utilization and Excited Energy Level Regulation

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  35. Efficient Organic‐Inorganic Sn 4+ ‐Based Halide Phosphorescent Scintillators Enabled by Enhanced Triplet Exciton Utilization and Excited Energy Level Regulation

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  37. Chiral Lattice Distortion Enables Bright Near-Infrared Circularly Polarized Luminescence in Lead-Free Metal Halides

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