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RESEARCH PAPER · Chemistry of Materials · 2022

Vacancy Control in TiNb2O7: Implications for Energy Applications

Albert A. Voskanyan, K. Jayanthi, Alexandra Navrotsky

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Vacancy Control in TiNb2O7: Implications for Energy ApplicationsOriginalEnhanced Energy Storage Performance of Zr-Doped TiNb2O7 Nanospheres Prepared by the Hydrolytic Method30Nano-TiNb2O7/CNTs composites with pseudocapacitive behavior for superior lithium-ion storage7Engineering Oxygen Vacancies in IrO x Clusters Supported on Metal–Organic Framework Derived Porous CeO 2 for Enhanced Oxygen Evolution in Acidic Media48Impact of carbon coating processing using sucrose for thick binder-free titanium niobium oxide lithium-ion battery anode2Acidic TiNb2O7 nanospheres supported with CeO2 to enhance NH3-SCR denitrification activity and resistance to H2O and SO2: Synergistic effect of CeO2 and TiNb2O733Synthesis, Thermodynamic Properties, and Ionic Conductivity of Compounds Based on Bismuth Niobates Doped by Rare-Earth Elements (A Review)5Synthesis, Thermodynamic Properties, and Ionic Conductivity of Compounds Based on Bismuth Niobates Doped by Rare-Earth Elements (A Review)0“Fast-Charging” Anode Materials for Lithium-Ion Batteries from Perspective of Ion Diffusion in Crystal Structure336Plasma-Induced Defect Engineering in TiNb2O7 for Boosting Lithium-Ion Diffusion12Synthesis, characterizations, and applications of vacancies-containing materials for energy storage systems28Oxygen vacancy modulated Ti2Nb10O29 anodes for high-rate lithium storage7Direct recycling of anode active material from Li-ion batteries using TiNb2O7 anode4A chronicle of titanium niobium oxide materials for high‐performance lithium‐ion batteries: From laboratory to industry39Exploring Niobium oxide-based materials for fast-charging lithium-ion anodes: Insights from structure to property19Self-supporting carbon-encapsulated TiNb2O7 electrode as anode for improved Li-ion batteries: Experimental and theoretical studies17Capacity-weighted figures-of-merit for battery transport metrics8Synergistic effect of an oxygen-defective TiNb 2 O 7 anode and lithiated polyacrylic acid for high-power lithium-ion storage12Tailored TiNb2O7 Particle Size, Defects, and Crystallinity Accelerate Lithiation12Dual Optimization of Ti2nb10o29 Anode Material Properties Via High Pressure0Nanostructure retention to 1100 °C in soft-templated niobium tungstates using dual-carbon strategy3The joys and jitters of high‐temperature calorimetry19Enhanced specific energy in fast-charging lithium-ion batteries negative electrodes via Ti-O covalency-mediated low potential29Oxygen-Deficient Tunnel-Structured TiNb 2 O 7 for High-Rate, Long-Cycle Lithium Storage, and Subzero-Temperature Performance2Low-valence & large-radius cation doping strategy of TiNb2O7 for ultra-high rate anode material0Oxygen vacancies engineering via Sc3+ doping to boost Li-ion transport and cycling stability in TiNb2O7 anodes5Controllable oxygen vacancy engineering via liquid-phase reduction for high-rate TiNb2O7 anodes in lithium-ion batteries1Deepening on the Intercalation Pseudocapacitive Behavior of Ti 0.33 Nb 0.66 O 2 Rutile as the Anode Material for Lithium‐Ion Batteries1Vacancy Engineering of Anatase TiO 2 for Enhanced Lithium Diffusion0Enhanced performance of TiNb2O7 electrode-based mixed-potential NH3 sensor: Synergy of surface lewis acidity and morphological engineering1Defect-engineered semiconductor nanomaterials for photocatalytic hydrogen evolution: mechanistic insights, design strategies, and future perspectives0Structural Evolution and Chemical Incorporation Pathways in Wadsley-Roth Oxides0

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  1. Enhanced Energy Storage Performance of Zr-Doped TiNb2O7 Nanospheres Prepared by the Hydrolytic Method

    ACS Sustainable Chemistry & Engineering · 2023-03-24

    Mo Xin Yu, Zhenfei Cai, Qi Li, Shuai Wang, Yangzhou Ma, Guangsheng Song, Weidong Yang, Cuié Wen

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  2. Nano-TiNb2O7/CNTs composites with pseudocapacitive behavior for superior lithium-ion storage

    Journal of Solid State Electrochemistry · 2023-05-02

    Hongfei Yin, Lei Lei, Shuo Zhao, Jin Wang, Xiaochao Xian

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  3. Engineering Oxygen Vacancies in IrO x Clusters Supported on Metal–Organic Framework Derived Porous CeO 2 for Enhanced Oxygen Evolution in Acidic Media

    Chemistry of Materials · 2023-05-08

    Wenrui Li, Jianning Lv, Di Liu, Wenjun Cai, Xianchun Chen, Qirui Huang, Lu Wang, Bo Wang

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  4. Impact of carbon coating processing using sucrose for thick binder-free titanium niobium oxide lithium-ion battery anode

    Journal of Electrochemical Science and Engineering · 2023-05-21

    Chen Cai, Patrick M. McCormack, Ziyang Nie, Gary M. Koenig

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  5. Acidic TiNb2O7 nanospheres supported with CeO2 to enhance NH3-SCR denitrification activity and resistance to H2O and SO2: Synergistic effect of CeO2 and TiNb2O7

    Separation and Purification Technology · 2023-06-29

    Haiyu Li, Zhiping Zhang, Yingying Li, Min Wei, Yue Bai, Xiaoyu Niu, Yujun Zhu

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  6. Synthesis, Thermodynamic Properties, and Ionic Conductivity of Compounds Based on Bismuth Niobates Doped by Rare-Earth Elements (A Review)

    Russian Journal of Inorganic Chemistry · 2023-11-01

    Н. И. Мацкевич, Anna Nikolaevna Semerikova, Dmitrii A. Samoshkin, С. В. Станкус, В. П. Зайцев, Vitalii A. Kuznetsov, Andrey Yu. Novikov

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  7. Synthesis, Thermodynamic Properties, and Ionic Conductivity of Compounds Based on Bismuth Niobates Doped by Rare-Earth Elements (A Review)

    Журнал неорганической химии · 2023-11-01

    Н. И. Мацкевич, Anna Nikolaevna Semerikova, Dmitrii A. Samoshkin, С. В. Станкус, В. П. Зайцев, Vitalii A. Kuznetsov, Andrey Yu. Novikov

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  8. “Fast-Charging” Anode Materials for Lithium-Ion Batteries from Perspective of Ion Diffusion in Crystal Structure

    ACS Nano · 2024-01-15

    Rui Wang, Lu Wang, Rui Liu, Xiangye Li, Youzhi Wu, Fen Ran

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  9. Plasma-Induced Defect Engineering in TiNb2O7 for Boosting Lithium-Ion Diffusion

    Energy & Fuels · 2024-01-17

    Shangqi Sun, Liguang Qin, Yalin Sun, Chang Guo

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  10. Synthesis, characterizations, and applications of vacancies-containing materials for energy storage systems

    DeCarbon · 2024-03-01

    Jingjing Wang, Yiguang Zhou, Jun‐Yi Li, Lei Zhao, Ying Zhu, Yamei Wang, Rui Fen Wu, Ying Wang, Daniel John Blackwood, Jun Song Chen

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  11. Oxygen vacancy modulated Ti2Nb10O29 anodes for high-rate lithium storage

    Journal of Electroanalytical Chemistry · 2024-08-31

    Qian Chen, Yutong Zhao, Yao Dai, Runguo Zheng, Yanyan Zhao, Zhiyuan Wang, Hongyu Sun, Yanguo Liu

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  12. Direct recycling of anode active material from Li-ion batteries using TiNb2O7 anode

    Sustainable materials and technologies · 2024-10-09

    Asato Kondo, Taro Fukaya, Ryosuke YAGI, Keigo Hoshina, Yasuhiro Harada, Norio Takami

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  13. A chronicle of titanium niobium oxide materials for high‐performance lithium‐ion batteries: From laboratory to industry

    Carbon Neutralization · 2024-10-21

    Cancan Peng, Suzhe Liang, Ying Yu, Longhao Cao, Chao Yang, Xiaosong Liu, Kunkun Guo, Peter Müller‐Buschbaum, Ya‐Jun Cheng, Changhong Wang

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  14. Exploring Niobium oxide-based materials for fast-charging lithium-ion anodes: Insights from structure to property

    Materials Science and Engineering R Reports · 2024-11-29

    Tongtong Li, Frank Krumeich, Luis K. Ono, Ting Guo, Ryusei Morimoto, Chenfeng Ding, Xu Zhong, Meilin Liu, Yabing Qi

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  15. Self-supporting carbon-encapsulated TiNb2O7 electrode as anode for improved Li-ion batteries: Experimental and theoretical studies

    Electrochimica Acta · 2024-12-03

    Prerna Chaturvedi, Zeyad M. Abdulhamid, Inas Magdy Abdelrahman Taha, Dalaver Hussain Anjum, Samuel S. Mao, Daniel Sunghoi Choi

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  16. Capacity-weighted figures-of-merit for battery transport metrics

    Journal of Materials Chemistry A · 2024-12-18

    CJ Sturgill, Christopher A. Sutton, Julian Schwenzel, Morgan Stefik

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  17. Synergistic effect of an oxygen-defective TiNb 2 O 7 anode and lithiated polyacrylic acid for high-power lithium-ion storage

    Journal of Materials Chemistry A · 2024-12-19

    Doosoo Kim, Siddhartha Nanda, Jong Heon Kim, Robson S. Monteiro, Luanna Silveira Parreira, Hadi Khani

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  18. Tailored TiNb2O7 Particle Size, Defects, and Crystallinity Accelerate Lithiation

    Chemistry of Materials · 2024-12-26

    CJ Sturgill, Iva Milisavljevic, Sean Cade Wechsler, Abdullah Al Muhit, Hans‐Conrad zur Loye, Scott T. Misture, Morgan Stefik

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  19. Dual Optimization of Ti2nb10o29 Anode Material Properties Via High Pressure

    SSRN Electronic Journal · 2025-01-01

    Qi Wang, Yan Lv, Jieming Qin, Benkuan Liang, Mingchen Geng, Ning Hu, Tao Zhou

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  20. Nanostructure retention to 1100 °C in soft-templated niobium tungstates using dual-carbon strategy

    New Journal of Chemistry · 2025-01-01

    Sean Cade Wechsler, Alexander Gregg, Coby S. Collins, Santosh Kiran Balijepalli, Morgan Stefik

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  21. The joys and jitters of high‐temperature calorimetry

    Journal of the American Ceramic Society · 2025-02-17

    Manuel Scharrer, Laura Bonatti, Tullio Salvatore Geraci, Sergey V. Ushakov, Juraj Majzlan, Michael Bustamante, Hiroshi Kojitani, Xiaofeng Guo, Hongwu Xu, Lei Zhang, Kristina I. Lilova, Shmuel Hayun, Tamilarasan Subramani, Alexandra Navrotsky

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  22. Enhanced specific energy in fast-charging lithium-ion batteries negative electrodes via Ti-O covalency-mediated low potential

    Nature Communications · 2025-07-07

    Jun Ge Huang, Yang Qi, Anyi Hu, Zhu Liao, Zhengxi Zhang, Qinfeng Zheng, Zhouhong Ren, Shun Zheng, Yixiao Zhang, Xiaolong Yang, Zhenming Xu, Le Zhang, Daming Zhu, Wen Wen, Xi Liu, Akihiro Orita, Nagahiro Saito, Liguang Wang, Yongyao Xia, Liwei Chen, Jun Biao Lu, Li Yang

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  23. Oxygen-Deficient Tunnel-Structured TiNb 2 O 7 for High-Rate, Long-Cycle Lithium Storage, and Subzero-Temperature Performance

    ACS Sustainable Chemistry & Engineering · 2025-12-18

    Enjie Dong, Xuming Wang, Yangqi Ou, Wei Fang, Lingling Zhang, Geping Yin

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  24. Low-valence & large-radius cation doping strategy of TiNb2O7 for ultra-high rate anode material

    SSRN Electronic Journal · 2026-01-01

    Shuo Han, Mingyan Hu, Zhigang Guo, Hui min Zhang, Yu Xiang, Lin Liu, Jingyi Qiu, Wenfeng Zhang

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  25. Oxygen vacancies engineering via Sc3+ doping to boost Li-ion transport and cycling stability in TiNb2O7 anodes

    Journal of Power Sources · 2026-02-17

    Geng-Hua Li, S. Kishore Babu, Cheng‐Wei Kao, Bor Kae Chang, Qi En Hong, Szu‐Chia Chien, M. K. Srivastava, Damian Kowalski, Weiren Liu

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  26. Controllable oxygen vacancy engineering via liquid-phase reduction for high-rate TiNb2O7 anodes in lithium-ion batteries

    Journal of Electroanalytical Chemistry · 2026-03-31

    Yao Dai, Guangyu Zhou, Hao Wang, Kun Li, Runguo Zheng, Zhiyuan Wang, Hongyu Sun, Yanguo Liu

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  27. Deepening on the Intercalation Pseudocapacitive Behavior of Ti 0.33 Nb 0.66 O 2 Rutile as the Anode Material for Lithium‐Ion Batteries

    ChemElectroChem · 2026-04-20

    Andrés Solana, Ester García-González, Flaviano García‐Alvarado

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  28. Vacancy Engineering of Anatase TiO 2 for Enhanced Lithium Diffusion

    ChemistrySelect · 2026-05-01

    Lei Chen, Yi-Xiang Wang, Rui Wu, Yue Wang, Xiaobin Niu, Jun song Chen

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  29. Enhanced performance of TiNb2O7 electrode-based mixed-potential NH3 sensor: Synergy of surface lewis acidity and morphological engineering

    Sensors and Actuators B Chemical · 2026-05-21

    Xiaoqing Jiang, Feng Qiu, Jie Wang, Chu Cheng, Panhui Yang, Yuan, Tao, 1968-, Jiawen Jian, Xianwang Ye, Jie Zou

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  30. Defect-engineered semiconductor nanomaterials for photocatalytic hydrogen evolution: mechanistic insights, design strategies, and future perspectives

    Materials Technology · 2026-10-03

    Ganesan Subbiah, Yogeesha Pai, Kunal Sharma, Honganur Raju Manjunath, Parin Thakorbhai Patel, T. Aravinda, Jayanta Kumar Nath, Aseel Smerat, Kamakshi Priya K

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  31. Structural Evolution and Chemical Incorporation Pathways in Wadsley-Roth Oxides

    Inorganic Chemistry · 2026-10-10

    R. Jackson Spurling, Marlena Alexander, Michael Richard Koehler, Bernadette R. Cladek, Claudia J. Rawn, Philip D. Rack, Katharine Lynn Page

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