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RESEARCH PAPER · Materials Today Advances · 2022

YInMn blue - 200 Years in the making: New intense inorganic pigments based on chromophores in trigonal bipyramidal coordination

Mas A. Subramanian, Jun Li

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YInMn blue - 200 Years in the making: New intense inorganic pigments based on chromophores in trigonal bipyramidal coordinationOriginalSynthesis and characterization of Fe3+ doped YIn1-yMnyO3 black pigment with high near-infrared reflectance15Cu doped YInO3-ZnO green colored NIR reflective pigments: Synthesis and application in PMMA based cool-roof coatings24Thermochromism and thermal crystal structure evolution of YIn0.9Mn0.1O31Near-infrared reflective coatings based on Ca1-xNdxAl12-xNixO19 blue pigments, prepared by solution combustion synthesis14Composite oxide cooling pigments mitigate the impact of urban heat islands13High resolution characterization of Y(Mn,In) Blue Chromophoric Oxides0Novel Co and Cr Free, High-Temperature (Ni, Mn) Co-Doping (Cufe)Fe4o8 Pigment And its Glazing Application0Synthesis of Novel Colored Pearlescent Pigments of Vanadium Phosphate with Large-Size Platelet Morphology0Pinalites: Optical Properties and Quantum Magnetism of Heteroanionic A3MO5X2 Compounds6Understanding color variation with site distribution in inverse spinel structure via neutron diffraction, magnetism, and optical studies10Cr2+ in Square Planar Coordination: Durable and Intense Magenta Pigments Inspired by Lunar Mineralogy15High-Pressure Route to Irreversible Thermochromic Materials6Exploring the Role and Variability of 3d Transition Metal Complexes in Artistic Coloration through a Bottom-Up Scientific Approach8Cool pigments as an urban heat island mitigation strategy for population health20The CoNb2O6 pigments for brilliant-blue ceramic decoration at high temperatures over 1273 K7Preparation of pigmentary grade bismuth vanadate Bi 4 V 2 O 11 via coprecipitation method1Novel Co and Cr free, high-temperature black ceramic pigment based on (Ni, Mn) co-doping (CuFe)Fe4O812Synthesis of nickel and copper metal complexes for blending in PVC to enhance UV absorption and stability5New solid solutions with the R-type hexaferrite structure, BaFe4-MM’2O11 (M = In, Sc; M’ = Ti, Sn)2New Blue Inorganic Pigments Based on SrMgAl10O170Recent Developments in Materials Science for the Conservation and Restoration of Historic Artifacts35Novel (Ni, Mn) co-doping CuFe5O8 black ceramic pigment with pinning strengthen effect in high-temperature black zirconia ceramic application52Exploring Brannerite-Type Mg1−xMxV2O6 (M = Mn, Cu, Co, or Ni) Oxides: Crystal Structure and Optical Properties2Optical properties and application of blue and purple inorganic pigment powders based on cobalt/nickel doped Sr2MgSi2O74Rational Design of Near-Infrared Reflective Pigments by Adjusting the Ni2+ Coordination Environment11Terahertz Investigation of Cultural Heritage Synthetic Materials: A Case Study of Copper Silicate Pigments5Synthesis of LaPO4 based high near-infrared reflective yellow pigment by rational design Ca/V ratio to regulate bandgap3Recent advance in preparation, applications and color regulation mechanism of cobalt blue pigment3π ‐Extended Viologen‐Based Lyotropic Chromonic Liquid Crystal Reactive Mesogen: Uniaxial Orientation and Photopolymerization for Transmittance and Color Controllable Electrochromic Smart Glass4Intense Yellow/Orange/Red Pigments Based on a Thortveitite-like Structure without Toxic Elements: Zn2–xNixV2O73Effect of mineralizer on the synthesis of (Ni, Mn) co-doping CuFe5O8 pigment and its glazing performance3KMgPO4 as a platform of full-color near-infrared reflective pigments1Fluorescent proteins: A journey from the cell to extreme environments in material science3Designer Color‐Tunable NIR‐Reflective Cool Pigments in the Ternary Vanadate Phenacite‐Inverse Spinel Phase Regime3Elucidating the carbochromism of K 3 [V(O 2 ) 4 ] with ab initio modeling0Solid-state engineered inorganic oxides: From durable pigments to high-performance electrochemical sensors1Divalent Chromophores in Trigonal Bipyramidal Coordination: YIn1– x ( M 0.52+Ti0.5) x O3 (M = Co, Mn, Ni, Fe) Solid Solutions0Construction of Mg–Cr spinel and its green coloration mechanism in industrial solid-waste-based Cr-containing systems0

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  1. Synthesis and characterization of Fe3+ doped YIn1-yMnyO3 black pigment with high near-infrared reflectance

    Ceramics International · 2023-03-08

    Meiqi Zhang, Yijie Yang, Luo Feng, Xiaoqi Sun

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  2. Cu doped YInO3-ZnO green colored NIR reflective pigments: Synthesis and application in PMMA based cool-roof coatings

    Progress in Organic Coatings · 2023-05-31

    Michele Fedel, Andrea Rosati, Marco Bertasini, Stefano Rossi

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  3. Thermochromism and thermal crystal structure evolution of YIn0.9Mn0.1O3

    Japanese Journal of Applied Physics · 2023-12-21

    Masaya Oshita, Hidenobu Murata, Isaac Oda-Bayliss, Wencong Wang, Shunsuke Yagi, Kenta Kimura

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  4. Near-infrared reflective coatings based on Ca1-xNdxAl12-xNixO19 blue pigments, prepared by solution combustion synthesis

    Ceramics International · 2023-12-22

    Iulia Rus, Robert Ianoş, Radu Ioan Lazău, Cornelia Păcurariu, Ionela Moldovan, Anamaria Dabici

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  5. Composite oxide cooling pigments mitigate the impact of urban heat islands

    Journal of Materials Chemistry A · 2024-01-01

    Giriyapura Prabhukumar Darshan, Akshay Arjun, H.B. Premkumar, Elisa Moretti, Alberto Vomiero

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  6. High resolution characterization of Y(Mn,In) Blue Chromophoric Oxides

    BIO Web of Conferences · 2024-01-01

    Isobel Claire Bicket, Milenka Andelic, Soham Mukherjee, Somnath Pal, D. D. Sarma, Carlo U. Segre, Gianluigi A. Botton

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  7. Novel Co and Cr Free, High-Temperature (Ni, Mn) Co-Doping (Cufe)Fe4o8 Pigment And its Glazing Application

    SSRN Electronic Journal · 2024-01-01

    Guo Feng, Tiantian Liu, Jun Mu, Feng Jiang, Zhiqi Guo, Lairong Xiao, Qian Wu, Xiaojun Zhang, Jianmin Liu, Jian Liang

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  8. Synthesis of Novel Colored Pearlescent Pigments of Vanadium Phosphate with Large-Size Platelet Morphology

    SSRN Electronic Journal · 2024-01-01

    Qiuyu Cheng, Yibei Xue, Takuya Hasegawa, Ayahisa Okawa, Kizuku Kushimoto, Junya Kano, Tohru Sekino, Shu Yin

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  9. Pinalites: Optical Properties and Quantum Magnetism of Heteroanionic A3MO5X2 Compounds

    Inorganic Chemistry · 2024-02-21

    Daigorou Hirai

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  10. Understanding color variation with site distribution in inverse spinel structure via neutron diffraction, magnetism, and optical studies

    Progress in Solid State Chemistry · 2024-04-04

    Anjali Verma, Jun Li, Arthur P. Ramirez, Mas A. Subramanian

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  11. Cr2+ in Square Planar Coordination: Durable and Intense Magenta Pigments Inspired by Lunar Mineralogy

    Chemistry of Materials · 2024-04-11

    Anjali Verma, Jun Li, Mas A. Subramanian

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  12. High-Pressure Route to Irreversible Thermochromic Materials

    The Journal of Physical Chemistry C · 2024-06-10

    Masaya Oshita, Hidenobu Murata, Hajime Yamamoto, Shintaro Kobayashi, Shogo Kawaguchi, Isaac Oda-Bayliss, Wencong Wang, Shunsuke Yagi, Kenta Kimura

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  13. Exploring the Role and Variability of 3d Transition Metal Complexes in Artistic Coloration through a Bottom-Up Scientific Approach

    Colorants · 2024-06-13

    Alexandra Sheng Coia, Jackson Ruddick, Olivia Shiqi Kuang, Li‐Qiong Wang

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  14. Cool pigments as an urban heat island mitigation strategy for population health

    Nature Reviews Materials · 2024-07-16

    Joya A. Cooley, Mojgan Sami

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  15. The CoNb2O6 pigments for brilliant-blue ceramic decoration at high temperatures over 1273 K

    Journal of the European Ceramic Society · 2024-09-19

    Chengming Qiu, Yuting Gong, Junfu Liu, Xiaohong Xia, Yun Gao, K. P. Homewood, Binglong Lei

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  16. Preparation of pigmentary grade bismuth vanadate Bi 4 V 2 O 11 via coprecipitation method

    Journal of Asian Ceramic Societies · 2024-10-01

    Wendusu, Moxiye

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  17. Novel Co and Cr free, high-temperature black ceramic pigment based on (Ni, Mn) co-doping (CuFe)Fe4O8

    Journal of the European Ceramic Society · 2024-10-15

    Guo Feng, Tiantian Liu, Feng Jiang, Zhiqi Guo, Lairong Xiao, Qian Wu, Xiaojun Zhang, Qing Chun Hu, Jianmin Liu, Jian Liang

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  18. Synthesis of nickel and copper metal complexes for blending in PVC to enhance UV absorption and stability

    Journal of Coordination Chemistry · 2024-11-01

    Sabha Kahlid, Wasifa Asim, Adnan Majeed, Muhammad Adnan Iqbal, Syeda Kainat Fatima Zaidi, Muhammad Yousif, Bahaa Saleh, Hafiz Tauqeer Ali, Haris Nadeem, Mohammad Tauseef Haider

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  19. New solid solutions with the R-type hexaferrite structure, BaFe4-MM’2O11 (M = In, Sc; M’ = Ti, Sn)

    Progress in Solid State Chemistry · 2024-11-08

    Yuan Bo Huang, Jun Li, Arthur P. Ramirez, Mas A. Subramanian

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  20. New Blue Inorganic Pigments Based on SrMgAl10O17

    Journal of the Japan Society of Colour Material · 2024-11-20

    Kaede ADACHI, Kazuki Yamaguchi, Toshiyuki Masui

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  21. Recent Developments in Materials Science for the Conservation and Restoration of Historic Artifacts

    Applied Sciences · 2024-12-05

    Mihaela Badea Doni, Irina Fierăscu, Radu Claudiu Fierăscu

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  22. Novel (Ni, Mn) co-doping CuFe5O8 black ceramic pigment with pinning strengthen effect in high-temperature black zirconia ceramic application

    Ceramics International · 2024-12-13

    Guo Feng, Tiantian Liu, Feng Jiang, Zhiqi Guo, Lairong Xiao, Qian Wu, Xiaojun Zhang, Qing Chun Hu, Jianmin Liu, Jian Liang

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  23. Exploring Brannerite-Type Mg1−xMxV2O6 (M = Mn, Cu, Co, or Ni) Oxides: Crystal Structure and Optical Properties

    Crystals · 2025-01-16

    Hua-Chien Hsu, Narayanan Lakshminarasimhan, Jun Li, Arthur P. Ramirez, Mas A. Subramanian

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  24. Optical properties and application of blue and purple inorganic pigment powders based on cobalt/nickel doped Sr2MgSi2O7

    Solid State Sciences · 2025-02-22

    Qiuyu Cheng, Zhiwei Wang, Ayahisa Okawa, Takuya Hasegawa, Tohru Sekino, Shu Yin

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  25. Rational Design of Near-Infrared Reflective Pigments by Adjusting the Ni2+ Coordination Environment

    Inorganic Chemistry · 2025-03-07

    Jiawan Wei, Yi Wu, Kangzhen Sun, Pengzhai Li, Qiuli Fang, Yin Zhang

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  26. Terahertz Investigation of Cultural Heritage Synthetic Materials: A Case Study of Copper Silicate Pigments

    Minerals · 2025-05-06

    Candida Moffa, Anna Candida Felici, Massimo Petrarca

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  27. Synthesis of LaPO4 based high near-infrared reflective yellow pigment by rational design Ca/V ratio to regulate bandgap

    Ceramics International · 2025-05-30

    Yi Wu, Jiawan Wei, Qiuli Fang, Pengzhai Li, Kangzhen Sun, Yanan Zhang, Yin Zhang

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  28. Recent advance in preparation, applications and color regulation mechanism of cobalt blue pigment

    Progress in Solid State Chemistry · 2025-06-07

    Hao Yang, Bin Mu, Anjie Zhang, Aiqin Wang

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  29. π ‐Extended Viologen‐Based Lyotropic Chromonic Liquid Crystal Reactive Mesogen: Uniaxial Orientation and Photopolymerization for Transmittance and Color Controllable Electrochromic Smart Glass

    Advanced Materials · 2025-06-20

    Huan Huu Pham, Minwoo Rim, Youngjae Wi, Jaeseok Hyeong, Jahyeon Koo, Kyung Min Lee, Nicholas P. Godman, Michael E. McConney, Luciano De Sio, Kwang‐Un Jeong

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  30. Intense Yellow/Orange/Red Pigments Based on a Thortveitite-like Structure without Toxic Elements: Zn2–xNixV2O7

    Chemistry of Materials · 2025-06-26

    Yi-Chia Lin, Anjali Verma, Jun Li, Arthur P. Ramirez, Mas A. Subramanian

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  31. Effect of mineralizer on the synthesis of (Ni, Mn) co-doping CuFe5O8 pigment and its glazing performance

    Open Ceramics · 2025-07-05

    Guo Feng, Tiantian Liu, Jun Mu, Feng Jiang, Zhiqi Guo, Lairong Xiao, Qian Wu, Xiaojun Zhang, Jianmin Liu, Jian Liang

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  32. KMgPO4 as a platform of full-color near-infrared reflective pigments

    Ceramics International · 2025-07-15

    Jiawan Wei, Yi Wu, Yi Wu, Kangzhen Sun, Pengzhai Li, Qiuli Fang, Xiaodong Wu, Yin Zhang

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  33. Fluorescent proteins: A journey from the cell to extreme environments in material science

    Photochemistry and Photobiology · 2025-07-21

    Bianca Menchicchi, André C. Stiel, Mattia Nieddu, J. P. Fuenzalida‐Werner

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  34. Designer Color‐Tunable NIR‐Reflective Cool Pigments in the Ternary Vanadate Phenacite‐Inverse Spinel Phase Regime

    Advanced Functional Materials · 2025-11-22

    Durga Lalitha Bai Kshatri, Upadhyayula Venkata Varadaraju, Surfarazhussain S. Halkarni, Challapalli Subrahmanyam, Pardha Saradhi Maram

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  35. Elucidating the carbochromism of K 3 [V(O 2 ) 4 ] with ab initio modeling

    Journal of Materials Chemistry A · 2026-01-01

    Jacob S. Hirschi, Zhiwei Mao, Anjali Verma, Mas A. Subramanian, May Nyman, Tim Joachim Zuehlsdorff

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  36. Solid-state engineered inorganic oxides: From durable pigments to high-performance electrochemical sensors

    Progress in Solid State Chemistry · 2026-03-01

    Gopika Meenakumari Gopakumar, Kaylee Berlina Johnson-Jordan, Mas A. Subramanian

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  37. Divalent Chromophores in Trigonal Bipyramidal Coordination: YIn1– x ( M 0.52+Ti0.5) x O3 (M = Co, Mn, Ni, Fe) Solid Solutions

    Chemistry of Materials · 2026-07-22

    Anjali Verma, Jun Li, Chung Yi Hsu, Arthur P. Ramirez, Fanny Rodolakis, D. Haskel, Mas A. Subramanian

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  38. Construction of Mg–Cr spinel and its green coloration mechanism in industrial solid-waste-based Cr-containing systems

    Ceramics International · 2026-09-01

    Jiaqi Wang, Qiong Li, Changcong An, Fenglan Han, Xiaoyan Zhang, Bo Liu

    Read original paper ↗ ·
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