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RESEARCH PAPER · Journal of the American Chemical Society · 2022

Discovery of Salt Hydrates for Thermal Energy Storage

Steven Kiyabu, Patrick Girard, Donald J. Siegel

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Discovery of Salt Hydrates for Thermal Energy StorageOriginalCrystal Structures of CuCl2·2H2O (Eriochalcite) and NiCl2∙6H2O (Nickelbischofite) at Low Temperature: Full Refinement of Hydrogen Atoms Using Non-Spherical Atomic Scattering Factors12Enhanced Thermal Conductivity of Phase Change Microcapsules Based on Boron Nitride/Graphene Oxide Composite Sheets25Computational Discovery of Thermochemical Heat Storage Materials Based on Chalcogenide and Complex Anion Salt Hydrates3Cascade phase change from highly-ordered salt hydrate composite monolith for Li-ion battery low-temperature resistance enhancement2Na2hpo4•12h2o Incorporated Surface and Confined Space of Layered Vermiculite Nanosheets for Enhancing Thermal Property Study of Phase Change Material0Particle-based high-temperature thermochemical energy storage reactors63Magnetically triggered heat release from hydrate salt composite microchannels for low-temperature battery thermal management20Performance enhancement of composite salt hydrate-based thermochemical energy storage unit1Comprehensive review of advanced desalination technologies for solar-powered all-day, all-weather freshwater harvesting systems57The “photons storage pool” effect of long afterglow phosphor for round-the-clock photocatalytic clean energy evolution22Impact of scaling and design on salt hydrate thermochemical energy storage performance11Chaotropic Ions Mediated Polymer Gelation for Thermal Management17Incorporated surfaces and confined spaces of Na2HPO4·12H2O–Layered vermiculite nanosheets for phase change materials with enhanced thermal properties10Stabilization of reactive bed particles for thermochemical energy storage with fiber reinforcement6Extensive Screening and Performance Testing of Nucleating Agents for the Sodium Acetate Trihydrate Phase-Change Material7The Integration of Thermal Energy Storage Within Metal Hydride Systems: A Comprehensive Review30MgCl2•6H2O supported on an NH2-MIL-88(Fe)/MXene hybrid substrate to enhance thermochemical heat storage performance12Finding heterogeneous nucleating agents for ice using a data-driven approach0Structurally Engineered Nanocomposite Sorbent Enables High-Performance Thermochemical Energy Storage for Electric Vehicle Applications0Constructing ZIF-8@cellulose/graphene hybrids derived 3D-porous cross-linked network based binary hydrated salts thermochemical composite for solar–thermal energy storage7Recent Advances in Organic Phase Change Materials for Thermal Energy Storage: A Review on Sustainable Development Applications51Comparative Assessment of Hygroscopic Properties and Thermal Performance of Activated Carbon-Based Physical Adsorbents and Advanced Composite Adsorbents1A review of modification strategies and applications for hydrated salts: Insights from energy storage materials encapsulation technology31MoO 2 /SiC Gradient Aerogel-Based Phase-Change Materials for Coordinating Efficient Solar Thermal Energy Conversion and Storage1Building Enhanced Neural Network Models to Predict Energy Storage Density of Composite Materials for Low-Temperature Thermochemical Energy Storage1Salt hydrate bio-composites for thermal energy storage: A concise review5High Latent‐Heat, Soft yet Robust Crystalline Salogels via Dual‐Network Design and Solvent Engineering10Accelerating electro-thermochemical energy storage via additive manufacturing3Recent Advances in Nano-Engineered Thermochemical Energy Storage Materials: Morphologies, Characteristics, and Performance11Materials for thermochemical energy storage and conversion: attributes for low-temperature applications15Operando Neutron Imaging of Reaction Extent and Particle Swelling Informs Limiting Factors for Salt Hydrate Thermochemical Energy Storage2Thermoplastic Network Formation as a Method for Stabilizing Salt Hydrate Particles0Three Cations, One Site: Structural and Thermal Design of the First Triple Tutton Salts as Thermochemical Heat Storage Materials3Cation‐Engineered Hydration Microenvironments in Magnesium Chloride Composites for Enhanced Low‐Humidity Vapor Adsorption and Thermochemical Heat Storage1Machine learning-driven paradigm shift in thermochemical energy storage4Structurally tailored nanocomposite sorbent enabling high-energy-density thermochemical storage in e-thermal banks for electric vehicle applications2Temperature controlled reversible hydration/dehydration reactions in MgAl-layered double hydroxides for thermochemical energy storage0Thermophysical property targets for sodium acetate trihydrate composites in heat-pump-charged packed-bed thermal energy storage0Thermal impedance in pulsed energy storage systems with phase change materials0Comprehensive overview of phase change materials in electronics, building, and solar applications2Microencapsulated phase-change materials for advanced anti-icing coatings4Influence of Nanostructuring on the Dehydration Mechanism of NiF 2 ·4H 2 O: Structural, Thermal, and Kinetic Studies0Application of Ibuprofen Sodium Dihydrate for Thermochemical Energy Storage0Strategies for enhancing Mg(OH)₂ performance in thermochemical energy storage: From material design to pilot scale0Role of Sodium Acetate Anhydrate in the Nucleation of the Sodium Acetate Trihydrate Phase-Change Material0Lamellar‐Type Crystals of an Amphiphilic Anilinium Chloride Adsorbing and Desorbing Water Vapor Under Mild Conditions0

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  1. Crystal Structures of CuCl2·2H2O (Eriochalcite) and NiCl2∙6H2O (Nickelbischofite) at Low Temperature: Full Refinement of Hydrogen Atoms Using Non-Spherical Atomic Scattering Factors

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  2. Enhanced Thermal Conductivity of Phase Change Microcapsules Based on Boron Nitride/Graphene Oxide Composite Sheets

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  3. Computational Discovery of Thermochemical Heat Storage Materials Based on Chalcogenide and Complex Anion Salt Hydrates

    ACS Applied Engineering Materials · 2023-10-05

    Steven Kiyabu, Donald J. Siegel

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  4. Cascade phase change from highly-ordered salt hydrate composite monolith for Li-ion battery low-temperature resistance enhancement

    Chemical Engineering Journal · 2023-10-07

    Wenjun Wang, Wenjun Wang, Haotian Luo, Kai Wang, Yan Wang, Huadong Wu, Yan Wang, Yan Wang, Miao Wang

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  5. Na2hpo4•12h2o Incorporated Surface and Confined Space of Layered Vermiculite Nanosheets for Enhancing Thermal Property Study of Phase Change Material

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    Yixiu Xin, Di Hu, Jinhong Li, Yixuan Ge, Yunxuan Wang

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  6. Particle-based high-temperature thermochemical energy storage reactors

    Progress in Energy and Combustion Science · 2024-02-08

    Jian Zhao, David Korba, Ashreet Mishra, James F. Klausner, Kelvin Randhir, Nick AuYeung, Like Li

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  7. Magnetically triggered heat release from hydrate salt composite microchannels for low-temperature battery thermal management

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  8. Performance enhancement of composite salt hydrate-based thermochemical energy storage unit

    Energy Sources Part A Recovery Utilization and Environmental Effects · 2024-04-19

    Hongzhi Liu, Hongzhi Liu, Han Liu, Han Liu, Minglu Qu, Katsunori Nagano

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    Renewable and Sustainable Energy Reviews · 2024-05-04

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  10. The “photons storage pool” effect of long afterglow phosphor for round-the-clock photocatalytic clean energy evolution

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  11. Impact of scaling and design on salt hydrate thermochemical energy storage performance

    Applied Thermal Engineering · 2024-06-17

    Bryan Kinzer, Durga Prasad Ghosh, Declan Crowley, Arijit Jatkar, Rohini Bala Chandran

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  12. Chaotropic Ions Mediated Polymer Gelation for Thermal Management

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    Chenxiao Yin, Jingrui Sun, Chang Cui, Ke‐Ke Yang, Ling‐Ying Shi, Yiwen Li

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  13. Incorporated surfaces and confined spaces of Na2HPO4·12H2O–Layered vermiculite nanosheets for phase change materials with enhanced thermal properties

    Applied Surface Science · 2024-08-03

    Yi-Xiu Xin, Di Hu, Jinhong Li, Yixuan Ge, Yun-Xuan Wang

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  14. Stabilization of reactive bed particles for thermochemical energy storage with fiber reinforcement

    Journal of Energy Storage · 2024-09-18

    Alexandr Shkatulov, Elena Averina, Tim Raemaekers, Hartmut Fischer, Olaf C. G. Adan, Henk Huinink

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  15. Extensive Screening and Performance Testing of Nucleating Agents for the Sodium Acetate Trihydrate Phase-Change Material

    Crystal Growth & Design · 2024-09-26

    Jinjie Li, Michael A. Parkes, Christoph G. Salzmann

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  16. The Integration of Thermal Energy Storage Within Metal Hydride Systems: A Comprehensive Review

    Inorganics · 2024-12-03

    Matias Davis Cortina, Manuel Romero de Terreros Aramburu, André Martins Neves, Lourdes Hurtado, Julian Jepsen, Ulrich Ulmer

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  17. MgCl2•6H2O supported on an NH2-MIL-88(Fe)/MXene hybrid substrate to enhance thermochemical heat storage performance

    Journal of Energy Storage · 2024-12-26

    Ata Ur Rehman, Tianyu Zhao, Sining Yun, Qiang Xiao, Weidong Zhu, Fu‐Min Zhang

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  18. Finding heterogeneous nucleating agents for ice using a data-driven approach

    Physical Chemistry Chemical Physics · 2025-01-01

    Zixuan Wang, David E. Oliver, Andrew J. Bissell, Gylen Odling, Colin R. Pulham, Carole A. Morrison

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  19. Structurally Engineered Nanocomposite Sorbent Enables High-Performance Thermochemical Energy Storage for Electric Vehicle Applications

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    Waseem Aftab, Muhammad Khurram, Qiqiu Huang, Dacheng Li, Muhammad Maqbool, Jiatong Jiang, Yongliang Li

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  20. Constructing ZIF-8@cellulose/graphene hybrids derived 3D-porous cross-linked network based binary hydrated salts thermochemical composite for solar–thermal energy storage

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    Xiangyu Yang, Shijie Li, Jin Zhang, Jianguo Zhao, Yisong Yu, Weidong Li

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  21. Recent Advances in Organic Phase Change Materials for Thermal Energy Storage: A Review on Sustainable Development Applications

    International Journal of Thermophysics · 2025-04-28

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  22. Comparative Assessment of Hygroscopic Properties and Thermal Performance of Activated Carbon-Based Physical Adsorbents and Advanced Composite Adsorbents

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  23. A review of modification strategies and applications for hydrated salts: Insights from energy storage materials encapsulation technology

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  24. MoO 2 /SiC Gradient Aerogel-Based Phase-Change Materials for Coordinating Efficient Solar Thermal Energy Conversion and Storage

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  25. Building Enhanced Neural Network Models to Predict Energy Storage Density of Composite Materials for Low-Temperature Thermochemical Energy Storage

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  32. Thermoplastic Network Formation as a Method for Stabilizing Salt Hydrate Particles

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  33. Three Cations, One Site: Structural and Thermal Design of the First Triple Tutton Salts as Thermochemical Heat Storage Materials

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  34. Cation‐Engineered Hydration Microenvironments in Magnesium Chloride Composites for Enhanced Low‐Humidity Vapor Adsorption and Thermochemical Heat Storage

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  35. Machine learning-driven paradigm shift in thermochemical energy storage

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  45. Role of Sodium Acetate Anhydrate in the Nucleation of the Sodium Acetate Trihydrate Phase-Change Material

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