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RESEARCH PAPER · ACS Catalysis · 2022

Synthesis of Narrow-Band-Gap GaN:ZnO Solid Solution for Photocatalytic Overall Water Splitting

Kaiwei Liu, Boyang Zhang, Jifang Zhang, Wenrui Lin, Jiaming Wang, Yao Xu, Yao Xiang, Takashi Hisatomi, Kazunari Domen, Guijun Ma

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Synthesis of Narrow-Band-Gap GaN:ZnO Solid Solution for Photocatalytic Overall Water SplittingOriginalA perspective on two pathways of photocatalytic water splitting and their practical application systems78Recent advances in photocatalyst sheet development and challenges for cost-effective solar hydrogen production57High-responsivity ultraviolet–visible photodetector based on an individual (GaN)1-x(ZnO)x solid solution nanobelt9Research Progress of ZnIn2S4-Based Catalysts for Photocatalytic Overall Water Splitting53Tuning the ZnO/GaN heterojunction for atmospheric NO abatement5The Ni2+-LaNiO3/CdS hollow core–shell heterojunction towards enhanced visible light overall water splitting H2 evolution via HER/OER synergism of Ni2+/Ov74Preparation and characterization of carboxyl functional mesoporous ZnO-SiO2 composites and in vitro sensing of glucose and vancomycin7Light‐promoted Selective Reduction of Nitroarenes to Azoxy‐, Azo‐ and Hydrazo‐compounds Catalyzed by Bismuth Porphyrin Metal Organic Framework15Regulation of d ‐Band Centers in Localized CdS Homojunctions through Facet Control for Improved Photocatalytic Water Splitting87Regulation of d‐Band Centers in Localized CdS Homojunctions through Facet Control for Improved Photocatalytic Water Splitting9Enhanced photoelectrochemical performance of cobalt phosphate modified GaN-ZnO Nanowires/GaN microrods heterostructure photoanode by vacancy defect modulation7Au-Deposited Ce0.5Zr0.5O2 Nanostructures for Photocatalytic H2 Production under Visible Light4Structural, mechanical, electronic and optical properties of Si decorated zinc oxide nanotube photocatalyst for hydrogen evolution via overall water splitting: A DFT study13Efficiency in photocatalytic production of hydrogen: energetic and sustainability implications14Integration of nonlinear two-photon excited fluorescence and photocatalysis boosts overall water splitting performance4Long-wavelength photoresponsive gallium zinc oxynitride for efficient oxygen evolution and Z-scheme water splitting reactions10Nanostructured (oxy)nitrides controllably synthesized by flux-assisted nitridation for promoted photocatalytic water splitting7Research progress on zinc oxide-based heterojunction photocatalysts67Synergistically regulating d-band centers of heterojunction redox sites by ligand effect for photocatalytic H2 evolution32Anisotropic Charge Migration on Perovskite Oxysulfide for Boosting Photocatalytic Overall Water Splitting112Alcoholamine-Grafted Zinc Oxide Enhances CO2 Electroreduction at Elevated Temperatures15ZnO-In2O3 solid solution hollow tube improved CO2 hydrogenation to methanol via the formate route11Recent Advances in Redox-Based Z-Scheme Overall Water Splitting under Visible Light Irradiation16Synthesis of Narrow Band Gap Gallium Zinc Nitride Oxide Solid Solutions for Photocatalytic Water Splitting under Visible Light12Coupling Reliable Interfacial Carrier Migration Channels with Visible-Light Response Antennas in ZnO-Based Heterostructure for Ameliorated Photocatalytic Hydrogen Generation13Ultrathin-Shelled Zn-AgIn5S8/ZnS Quantum Dots with Partially Passivated Trap States for Efficient Hydrogen Production3Visible‐Light Harvesting SrTiO3 Solid Solutions for Photocatalytic Hydrogen Evolution from Water3Insights into Atomic Level π‐Electron Modulations in Supramolecular Carbon Nitride Nanoarchitectonics for Sustainable Green Hydrogen Production37Photothermal catalytic CO2 oxidative dehydrogenation of propane over a dual functional Pt-GaN/SrTiO3 catalyst21A Visible Light-Responsive TiO2 Photocathode Achieved by a Rh Dopant6Synthesis of Highly Active GaN:ZnO Photocatalysts Applicable to Z-Scheme Overall Water Splitting Systems31Surprising Effects of Ti and Al2O3 Coatings on Tribocatalytic Degradation of Organic Dyes by GaN Nanoparticles11Bimetallic Cd0.5Ni0.5PS3 solid solution with asymmetric Cd-S-Ni active centers for accelerating hydrogen evolution6Tailoring band structures and photocatalytic overall water splitting in a two-dimensional GaN/black phosphorus heterojunction: First-principles calculations9Activation of Nonoxide Photocatalyst Sheet Operable under Visible Light Irradiation up to 600 nm by Conductive Bilayer14Tracking Water Splitting Activity by Cocatalyst Identity in SrTiO311Photocatalytic water splitting for large-scale solar-to-chemical energy conversion and storage88Efficient photothermal conversion and Z-scheme charge transfer in narrow-gap semiconductor heterojunction for photothermal-assisted photocatalysis15A Ta 3 N 5 /BN composite for enhanced photocatalytic water splitting1Advances in triple-phase catalysis for energy and environmental applications12Bi Doping Regulating Electronic Structure of Mn2v2o7 for Accelerated Photocatalytic Overall Water Splitting0Engineering GaN-based systems for photocatalysis: strategies and applications4Novel materials and techniques for photocatalytic water splitting developed by Professor Kazunari Domen29Enhanced energy storage and solar hydrogen generation via Mg-VO2@ZnO-MWCNT composites3Boosting Photocatalytic Hydrogen Production over Mn0.4Cd0.6S/CuS p–n Heterojunction under Visible Light Irradiation6Dual-driven charge transport enabled by S-scheme heterojunction and solid solution in CdS@N-NiCoO photocatalysts for enhanced hydrogen evolution14LiNH2-Based Nitridation Synthesis and Structure Analysis of GaN:ZnO Solid Solutions2Design and application of Solid Solution Materials in Heterogeneous Photocatalysis2Rationalize to intensify the charge transfer from rutile to anatase via plasmon electrons induction for photocatalytic H2 evolution3A study on rationally designed GaN:ZnO/NiSe2 composite for photocatalytic hydrogen production under artificial as well as natural solar light4Frontline Autocatalysis Mediates the Water Reaction with Single-Layer ZnO7Emerging Mixed-Anion Semiconductors for Particulate Photocatalytic Water Splitting: Remarkable Structures and Innovative Fabrication Methods7Graphene Derivative-Based Particulate Photocatalysts for Energy Conversion Applications: Current Achievements, Bottlenecks, and Future Outlook53Facile and Universal Strategy to Construct Piezo-Photocatalytic Systems via Building Electron Bridges for Highly Efficient Overall Water Splitting7An investigation into the rationally designed GaN:ZnO/NiTe2 composites for photocatalytic hydrogen generation under both simulated and natural solar light2Facet-oriented surface modification for enhancing photocatalytic hydrogen production on Sm2Ti2O5S2 nanosheets4Materials and systems for large-scale photocatalytic water splitting202Hydrothermally Synthesized Dual-Phase Type-II Heterojunction Nanocomposites: Photocatalysis, Hydrogen Evolution, and Super-Capacitive Energy Applications2Spin‐Orbit Coupling Amplifying Polarization State for Regulating Bulk Charge Vectorial Transfer Dynamics at Spatiotemporal Scale for Towering H 2 Generation1On-Site Growth of a TaON Nanoshell on ZrO2 Particles for Photocatalytic Water Splitting4Synergy of interfacial Zn–O–B bond and surface oxygen vacancy in BNNS/GaZnON for efficient photocatalytic overall water splitting10Photocatalytic conversion of CO2 using various TiO2 modified with Ag and Co dual cocatalysts via an ultrasonic reduction method6Gallium Phosphide–Zinc Sulfide Solid Solutions for Photocatalytic Hydrogen Production1Bridging Scales in Solar‐Driven Water Splitting: Pathways to System Integration26Crystal strain engineering boosting carrier transfer behavior and synergistically activating surface sites of CeO2/MoS2 for H2O chemisorption and its conversion to H21In Situ Construction of Bifunctional Nickel Phthalocyanine‐Based COF on Ga 3+ ‐doped SrTiO 3 for Efficient Overall Water Splitting12Lanthanide Incorporation Orchestrates the Structure–Activity Relationship in Bismuth Oxychloride for Visible-Light-Driven Water Splitting9Electrospun Cd 0.3 Zn 0.7 S/PVDF/PAN nanofibers: Synergistic enhancement of photocatalytic hydrogen evolution via piezoelectric polarization and carbon dot-mediated electronic modulation0Immobilized photocatalyst devices for scalable overall water splitting1Anisotropic surface modification of GaN:ZnO for photocatalytic water splitting0Development of Photocatalytic Heterostructures With Broadband Absorption4Switching of Type–I g-C3N4/FeN4 heterojunction to direct Z-scheme photocatalyst for water splitting through non-metal Boron and Fluorine co-doping: A density functional study0Engineering structural variations in oxynitrides to boost photocatalytic hydrogen evolution: current advances and future directions1GaN NPs modified radial porous ZnO microspheres for low-temperature and high-efficiency detection of triethylamine5Recent Developments in Z‐Scheme Systems for Overall Water Splitting: A Focus on (Oxy)Nitride Photocatalysts2Construction and development of Z-scheme systems for solar-driven water splitting5Effect of Al2O3-Induced in situ ZnO/ZnAl2O4 Heterointerface Tailoring on the Microstructure and Conduction Mechanism of ZnO-based Linear Thermistor Ceramics0In-situ H2/O2 separation in photocatalytic water splitting by hydrogen spillover-driven hydrogen storage on Ru/WO3-MWCNTs2Synthesis of Zinc Germanium Oxynitride Photocatalysts Using Solid Nitrogen Sources0Engineered GaN:ZnO/Carbon nanosphere heterostructure for highly efficient solar hydrogen production1Interface engineering of NiSe-integrated multicomponent cocatalyst for enhanced photocatalytic overall water splitting0Kinetic Insight into Zn Vacancy-Mediated Deactivation of GaN:ZnO Photocatalysts0Next-generation photocatalysts: Overcoming the operational hurdles for sustainable and scalable environmental and energy applications0Advances in Spinel Ferrite Photocatalysts: From Synthesis, Fundamental Mechanisms, and Solar Energy Conversion Applications2Fabrication of Solid‐Solution Thin Films via Liquid‐Metal van der Waals Exfoliation for High Signal‐to‐Noise Ratio Visible‐Light Imaging0Constructing Sn–Co–O solid-solution nanotubes via redox-driven Kirkendall effect to enhance photoelectrocatalysis0

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