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RESEARCH PAPER · Nature Reviews Materials · 2022

System of sequences in multivariate reticular structures

Stefano Canossa, Zhe Ji, Cornelius Gropp, Zichao Rong, Evelyn Ploetz, Stefan Wuttke, Omar M. Yaghi

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System of sequences in multivariate reticular structuresOriginalUnlocking new Topologies in Zr-based Metal–Organic Frameworks by Combining Linker Flexibility and Building Block Disorder3Hydrogen-bonded organic framework-stabilized charge transfer cocrystals for NIR-II photothermal cancer therapy26Reticular framework materials for photocatalytic organic reactions262The Dedication to Beautiful Structures (Dr. Omar Yaghi)0Multivariate Porphyrinic MOFs as Precursors of Nanoalloy Catalysts for Efficient Dehydrogenation of Hydrogen Molecular Carriers0Advances in metal-organic frameworks for efficient separation and purification of natural gas55Systematic Thiol Decoration in a Redox-Active UiO-66-(SH) 2 Metal–Organic Framework: A Case Study under Oxidative and Reductive Conditions25Ultrathin 2D Cerium‐Based Metal–Organic Framework Nanosheet That Boosts Selective Oxidation of Inert C(sp3)H Bond through Multiphoton Excitation33Unlocking New Topologies in Zr-Based Metal–Organic Frameworks by Combining Linker Flexibility and Building Block Disorder40Exploring the Role of Amino Acid-Derived Multivariate Metal–Organic Frameworks as Catalysts in Hemiketalization Reactions9Metal–Organic Framework Based Thermoluminescence Dosimeter21MOF‐Based Electromagnetic Shields Multiscale Design: Nanoscale Chemistry, Microscale Assembly, and Macroscale Manufacturing89Functional dynamics in framework materials23Cooperative and Orthogonal Switching in the Solid State Enabled by Metal‐Organic Framework Confinement Leading to a Thermo‐Photochromic Platform40Cooperative and Orthogonal Switching in the Solid State Enabled by Metal‐Organic Framework Confinement Leading to a Thermo‐Photochromic Platform2Incorporation of Chiral Frustrated Lewis Pair into Metal–Organic Framework with Tailored Microenvironment for Heterogeneous Enantio- and Chemoselective Hydrogenation41Unravelling Ultrafast Li Ion Transport in Functionalized Metal–Organic Framework-Based Battery Electrolytes27Metal–Organic Frameworks for Water Desalination127Multilength Scale Hierarchy in Metal‐Organic Frameworks: Synthesis, Characterization and the Impact on Applications33Exceptionally Stable And Super‐Efficient Electrocatalysts Derived From Semiconducting Metal Phosphonate Frameworks12Recent Advances in Multifunctional Reticular Framework Nanoparticles: A Paradigm Shift in Materials Science Road to a Structured Future47Single-crystal metal-organic frameworks for electronic and opto-electronic devices33Strain‐Induced Heteromorphosis Multi‐Cavity Cages: Tension‐Driven Self‐Expansion Strategy for Controllable Enhancement of Complexity in Supramolecular Assembly12Strain‐Induced Heteromorphosis Multi‐Cavity Cages: Tension‐Driven Self‐Expansion Strategy for Controllable Enhancement of Complexity in Supramolecular Assembly1Conquering Metal–Organic Frameworks by Raman Scattering Techniques32Monitoring water harvesting in metal–organic frameworks, one water molecule at a time23Atomically dispersed Ni active sites on covalent organic frameworks for heterogeneous metallaphotocatalytic C–N cross-coupling27Atomically Dispersed Iron Active Sites on Covalent Organic Frameworks for Artificial Photosynthesis of Hydrogen Peroxide77Linker-Guided Growth of Single-Crystal Covalent Organic Frameworks38Building robust metal-organic frameworks with premade ligands53Sustainable moisture energy184Theoretical and experimental insights into the spatial distribution of functional groups in multivariate flexible metal-organic framework JUK-8(Br)(NO2)0Comparison of Electrical Conductivity and Schottky Behavior of 4‐[2‐(9‐anthryl)vinyl]pyridine Based Two 1D Coordination Polymers of Zn(II) and Cd(II)14Enhanced high-temperature iodine capture through band-edge control in covalent organic frameworks20In silico monitoring of non-reactive gas blistering on crystalline substrates4Theoretical and Experimental Insights into the Spatial Distribution of Functional Groups in a Multivariate Flexible Metal–Organic Framework4The integration of multiple components for multi-responsive dynamic framework materials3Altering electronic states of Cu sites in Covalent organic frameworks for synthesis of formate via CO2 reduction15Adsorption and photocatalytic degradation of Ammonia: Status and challenges27Robust Chiral Metal–Organic Framework Coatings for Self‐Activating and Sustainable Biofouling Mitigation76A pyrene-based hydrogen-bonded framework with excimer induced ratiometric emission for discriminative luminescence detection of metal ions9Surface Chemistry Regulation in Cu4I4-Triazolate Metal–Organic Frameworks for One-Step C3H6 Purification from Quaternary C3 Mixtures38Topology-driven directed synthesis of metal-organic frameworks3One sulfate anion-bridged metal–organic framework for adsorptive separation of C2H2 from C2H4 and CO214Synergistic Catalytic Sites in High‐Entropy Metal Hydroxide Organic Framework for Oxygen Evolution Reaction57Reticular Chemistry for Enhancing Bioentity Stability and Functional Performance34High‐Entropy Zeolitic Imidazolate Frameworks for Dynamic Hydrogen Isotope Separation1High‐Entropy Zeolitic Imidazolate Frameworks for Dynamic Hydrogen Isotope Separation16Unveiling the potential of metal-organic framework-based membranes: Transforming material science for a sustainable future8Using Signal Off-to-On Strategy for Designing Precise and Ultrasensitive Biosensor Towards Tumor Through Protein Variant Detection Based on Biocompatible Bimetallic Mof0Design, regulation, and functionalization of self-assembled DNA crystals7Rational Pore Design in Multivariate Metal‐Organic Frameworks for C 2 H 6 /C 2 H 4 Separation14Supramolecular Chemistry in Metal–Organic Framework Materials36Using signal off-to-on strategy for designing precise and ultrasensitive biosensor towards hepatocellular carcinoma through protein variant detection based on biocompatible bimetallic MOF11State‐of‐the‐Art, Insights, and Perspectives for MOFs‐Nanocomposites and MOF‐Derived (Nano)Materials165Retrospective Review on Reticular Materials: Facts and Figures Over the Last 30 Years22Designing covalent organic frameworks for environmental remediation: Photocatalytic strategies for water treatment4Tailoring Artificial Hydration Microenvironments in Covalent Organic Frameworks for Enhanced Enzymatic Catalysis in Organic Media15Quantum Computing Based Design of Multivariate Porous Materials5Capturing CO2 under Dry and Humid Conditions: When Does the Parent MOF Outperform the MTV MOF?6Strategic engineering of structural complexity in metal–organic frameworks18Multisignal Amplification On–Off–On Strategy via Integrating the Pore Release of Polymetallic MOFs with Perovskite QDs to Induce Dual Photocurrent Polarity Reversals for an Ultrasensitive and Wide-Range Photoelectrochemical Precise Assay1MOFs and COFs for Radionuclide and Nuclear‐Waste Treatment35Pressure-Driven Loading of Large Guests in Metal–Organic Frameworks4Property-guided inverse design of metal-organic frameworks using quantum natural language processing5N-Acetyl-L-cysteine-grafted metal-organic framework for heavy metal removal from hazardous waste1ATP-Responsive ZIF-90 Nanocontainers Encapsulating Natural Antifoulants for Intelligent Marine Coatings0Amorphization and High-Entropy (Ni/Fe/Cu/Zn) Tuning over MIL-88(Co) Enable In Situ Irreversible Transformation of an Active CoOOH Layer toward Super Alkaline OER Efficiency1Constructing an ester-infused covalent organic framework for efficient iodine capture0Mixed Metal Metal-Organic Frameworks0Self-Powered Organic Photoelectrochemical Transistor Detection11Rapid Magnetic Separation Absorbent Integrating Amidoxime Chelators and Antibiofouling MOF Coatings for Efficient Uranium Extraction7Photosystem II-Inspired Ce-MOF for Selectively Coupling Photocatalytic Nitro-to-Azoxy Conversion with Water Oxidation7Synergistic defect and morphology engineering of Mn-doped ZIF-8 for superior ciprofloxacin capture7Site-selective valence isomerism as a unified electronic trigger for magnetism, chirality, and catalysis in Ni–carboxylate MOFs1MOFBuilder: automated end-to-end modeling of MOF dynamics for high-throughput screening1Covalent organic frameworks-enabled interfacial engineering of ammonium dinitramide for enhanced stability and energy release0The Future of Reticular Chemistry: From Structural Discovery to Programmable Matter and Artificial Intelligence1Adsorption Hysteresis Under Control: Tuning Host–Guest Interactions via a Genetic Algorithm2Ultra-stable energetic COF rapid-redox cages toward enhanced energy release0Spatial modulation of photoreactivity in isoreticular metal-organic frameworks: comparative insights into single-component, multivariate, and core-shell systems0Fine-Tuning the Pressure Response and Mechanical Properties of Azobenzene- and Stilbene-Based Zr-Metal–Organic Frameworks through Multivariate Design1Large-Mesopore Covalent Organic Framework Nanoparticles for Small Interfering RNA Delivery toward Cancer Immunotherapy0Ligand π‐Conjugation Area Modulates Hydrogen Evolution Performance in Metal–Organic Frameworks0

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  1. Unlocking new Topologies in Zr-based Metal–Organic Frameworks by Combining Linker Flexibility and Building Block Disorder

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  2. Hydrogen-bonded organic framework-stabilized charge transfer cocrystals for NIR-II photothermal cancer therapy

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  3. Reticular framework materials for photocatalytic organic reactions

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  4. The Dedication to Beautiful Structures (Dr. Omar Yaghi)

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  5. Multivariate Porphyrinic MOFs as Precursors of Nanoalloy Catalysts for Efficient Dehydrogenation of Hydrogen Molecular Carriers

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  6. Advances in metal-organic frameworks for efficient separation and purification of natural gas

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  7. Systematic Thiol Decoration in a Redox-Active UiO-66-(SH) 2 Metal–Organic Framework: A Case Study under Oxidative and Reductive Conditions

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  8. Ultrathin 2D Cerium‐Based Metal–Organic Framework Nanosheet That Boosts Selective Oxidation of Inert C(sp3)H Bond through Multiphoton Excitation

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  9. Unlocking New Topologies in Zr-Based Metal–Organic Frameworks by Combining Linker Flexibility and Building Block Disorder

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  10. Exploring the Role of Amino Acid-Derived Multivariate Metal–Organic Frameworks as Catalysts in Hemiketalization Reactions

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  12. MOF‐Based Electromagnetic Shields Multiscale Design: Nanoscale Chemistry, Microscale Assembly, and Macroscale Manufacturing

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  13. Functional dynamics in framework materials

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  14. Cooperative and Orthogonal Switching in the Solid State Enabled by Metal‐Organic Framework Confinement Leading to a Thermo‐Photochromic Platform

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  15. Cooperative and Orthogonal Switching in the Solid State Enabled by Metal‐Organic Framework Confinement Leading to a Thermo‐Photochromic Platform

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  16. Incorporation of Chiral Frustrated Lewis Pair into Metal–Organic Framework with Tailored Microenvironment for Heterogeneous Enantio- and Chemoselective Hydrogenation

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  17. Unravelling Ultrafast Li Ion Transport in Functionalized Metal–Organic Framework-Based Battery Electrolytes

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  18. Metal–Organic Frameworks for Water Desalination

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  19. Multilength Scale Hierarchy in Metal‐Organic Frameworks: Synthesis, Characterization and the Impact on Applications

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  20. Exceptionally Stable And Super‐Efficient Electrocatalysts Derived From Semiconducting Metal Phosphonate Frameworks

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  21. Recent Advances in Multifunctional Reticular Framework Nanoparticles: A Paradigm Shift in Materials Science Road to a Structured Future

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  22. Single-crystal metal-organic frameworks for electronic and opto-electronic devices

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  26. Monitoring water harvesting in metal–organic frameworks, one water molecule at a time

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  27. Atomically dispersed Ni active sites on covalent organic frameworks for heterogeneous metallaphotocatalytic C–N cross-coupling

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  29. Linker-Guided Growth of Single-Crystal Covalent Organic Frameworks

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  30. Building robust metal-organic frameworks with premade ligands

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  32. Theoretical and experimental insights into the spatial distribution of functional groups in multivariate flexible metal-organic framework JUK-8(Br)(NO2)

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  33. Comparison of Electrical Conductivity and Schottky Behavior of 4‐[2‐(9‐anthryl)vinyl]pyridine Based Two 1D Coordination Polymers of Zn(II) and Cd(II)

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  38. Altering electronic states of Cu sites in Covalent organic frameworks for synthesis of formate via CO2 reduction

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  39. Adsorption and photocatalytic degradation of Ammonia: Status and challenges

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  41. A pyrene-based hydrogen-bonded framework with excimer induced ratiometric emission for discriminative luminescence detection of metal ions

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  43. Topology-driven directed synthesis of metal-organic frameworks

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  44. One sulfate anion-bridged metal–organic framework for adsorptive separation of C2H2 from C2H4 and CO2

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  45. Synergistic Catalytic Sites in High‐Entropy Metal Hydroxide Organic Framework for Oxygen Evolution Reaction

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  47. High‐Entropy Zeolitic Imidazolate Frameworks for Dynamic Hydrogen Isotope Separation

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  48. High‐Entropy Zeolitic Imidazolate Frameworks for Dynamic Hydrogen Isotope Separation

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  49. Unveiling the potential of metal-organic framework-based membranes: Transforming material science for a sustainable future

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  50. Using Signal Off-to-On Strategy for Designing Precise and Ultrasensitive Biosensor Towards Tumor Through Protein Variant Detection Based on Biocompatible Bimetallic Mof

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