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RESEARCH PAPER · Environmental Science & Technology · 2022

Metal-Catalyzed Formation of Organic Pollutants Intermediated by Organic Free Radicals

Shuting Liu, Guorui Liu, Lili Yang, Xiaoyun Liu, Mingxuan Wang, Linjun Qin, Minghui Zheng

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Metal-Catalyzed Formation of Organic Pollutants Intermediated by Organic Free RadicalsOriginalStructural properties of alumina surfaces and their roles in the synthesis of environmentally persistent free radicals (EPFRs)17Occurrence and Formation Mechanism of PCDD/Fs and SCCPs in Chlorinated Paraffin Products7Formation of Pre-PCTA/DT Intermediates from 2-Chlorothiophenol on Silica Clusters: A Quantum Mechanical Study0A state-of-art review on the redox activity of persistent free radicals in biochar86DFT and AIMD insights into heterogeneous dissociation of 2-chlorothiophenol on CuO(111) surface: Impact of H2O and OH10Atmospheric emissions of hexachlorobutadiene in fine particulate matter from industrial sources28Br-to-Cl Transformation Guided the Formation of Polyhalogenated Dibenzo-p-dioxins/Dibenzofurans1Forming derivative solid radicals on pyrolytic carbon via persistent free radicals coordinating heavy metals: Peroxide-free degradation of organic pollutants8Free radical mechanisms of ammonium sulfate as intensively used industrial materials on suppressing organic pollutants6In situ enhanced chlorine oxide radical generation on a novel space-confined photoanode and its application for ammonia oxidation: Structure, performance, and mechanism10Persistent free radicals in natural organic matter activated by iron particles enhanced disinfection byproduct formation14Atmospheric evolution of environmentally persistent free radicals in the rural North China Plain: effects on water solubility and PM 2.5 oxidative potential17Catalytic potential of biochar: enhancing pollution removal through persistent free radicals in biomass pyrolysis — a review9An efficient strategy for BDD electrode drive electro-catalysis triggering active species on lincomycin and antibiotic resistance genes removal: Electron transfer based on calculation modeling10Radical inhibition mechanisms of ammonium sulfate on industrial organic pollutants in copper-catalyzed reactions0Release characteristics of POPs during preheating and sintering processes of ceramsite produced with the contaminated sediment2Persistent free radicals in the environment14Free radical mechanisms of halogen coexistence promoting pollutants formation2Self‐Activated Heterogeneous Fenton Process for Accelerated Degradation of Aromatic Pollutants over Copper Oxide Catalysts4Self‐Activated Heterogeneous Fenton Process for Accelerated Degradation of Aromatic Pollutants over Copper Oxide Catalysts29Oxygen-driven thiol-activated ROS generation by particulate organic matter: Deciphering the role of interface-accelerated organic radical chain reaction10Perspectives on the Presence of Environmentally Persistent Free Radicals (EPFRs) in Ambient Particulate Matters and Their Potential Implications for Health Risk4Insight into catalytic performance of chlorobenzene over phosphate-modified MnCeOx catalysts and suppression mechanism of polychlorinated byproducts3Unlocking efficient electrocatalytic removal of trace emerging contaminants via synchronized pollutant enrichment and electron delivery10Ammonia removal under free radical action in advanced oxidation processes: A review0Unveiling the role of A-Site 3d orbital configuration in spinel ferrites for catalytic ozonation0Persistent free radical-mediated Z-scheme charge transfer in ZnO-ZnS@Biochar: Bypassing redox potential compromise for efficient photocatalytic degradation1Recent Advances in Benign Metal Nanoparticle‐Catalyzed Reduction of Organic Functional Groups0

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  1. Structural properties of alumina surfaces and their roles in the synthesis of environmentally persistent free radicals (EPFRs)

    Nanotechnology Reviews · 2023-01-01

    Mohammednoor Altarawneh, Niveen W. Assaf, Hamed M. Hussain, Bogdan Zygmund Dlugogorski

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  2. Occurrence and Formation Mechanism of PCDD/Fs and SCCPs in Chlorinated Paraffin Products

    Environmental Science & Technology · 2023-10-31

    Yunchen He, Wenbin Liu, Lirong Gao, Zhiyuan Ren, Javid Hussain, Tianqi Jia, Tianao Mao, Jinglin Deng, Xiaotian Xu, Fei Yin

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  3. Formation of Pre-PCTA/DT Intermediates from 2-Chlorothiophenol on Silica Clusters: A Quantum Mechanical Study

    International Journal of Molecular Sciences · 2024-03-20

    Fei Xu, Xiaotong Wang, Ying Li, Yongxia Hu, Ying Zhou, Mohammad Hassan Hadizadeh

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  4. A state-of-art review on the redox activity of persistent free radicals in biochar

    Water Research · 2024-03-24

    Jia Qing Xie, Junaid Latif, Kangjie Yang, Zhiqiang Wang, Lang Zhu, Huiqiang Yang, Jianjun Qin, Zheng Ni, Hanzhong Jia, Xin Wang, Xing Li

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  5. DFT and AIMD insights into heterogeneous dissociation of 2-chlorothiophenol on CuO(111) surface: Impact of H2O and OH

    Chemosphere · 2024-05-03

    Xiaotong Wang, Mohammad Hassan Hadizadeh, Wei Wang, Yongxia Hu, Ying Zhou, Fei Xu, Yanhui Sun, Wenxing Wang

    Read original paper ↗ ·

  6. Atmospheric emissions of hexachlorobutadiene in fine particulate matter from industrial sources

    Nature Communications · 2024-06-04

    Chenyan Zhao, Lili Yang, Yuxiang Sun, Changzhi Chen, Zichun Huang, Qiuting Yang, Jianghui Yun, Ahsan Habib, Guorui Liu, Minghui Zheng, Guibin Jiang

    Read original paper ↗ ·

  7. Br-to-Cl Transformation Guided the Formation of Polyhalogenated Dibenzo-p-dioxins/Dibenzofurans

    Environmental Science & Technology · 2024-08-03

    Congcong Zhang, Xuan Geng, Lingfeng Zhu, Dan Xia, Xiang Li, Yifei Sun

    Read original paper ↗ ·

  8. Forming derivative solid radicals on pyrolytic carbon via persistent free radicals coordinating heavy metals: Peroxide-free degradation of organic pollutants

    Applied Catalysis B: Environmental · 2024-08-12

    Ruyi Xu, Zhonghao Wan, Shishu Zhu, Yuyao Zhang, Jiaxin Huang, Qining Liu, Bin Gao, Shuili Yu

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  9. Free radical mechanisms of ammonium sulfate as intensively used industrial materials on suppressing organic pollutants

    The Science of The Total Environment · 2024-08-22

    Shuting Liu, Guorui Liu, Mingxuan Wang, Linjun Qin, Qingyu Guo, Da Li, Lili Yang, Minghui Zheng

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  10. In situ enhanced chlorine oxide radical generation on a novel space-confined photoanode and its application for ammonia oxidation: Structure, performance, and mechanism

    Chemical Engineering Journal · 2024-08-22

    Ting Su, Yunhe Gong, Xuemin Cui, Xinhong Wang, Ya-Nan Zhang, Hongbin Yu

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  11. Persistent free radicals in natural organic matter activated by iron particles enhanced disinfection byproduct formation

    Water Research · 2024-09-03

    Xinyi Qin, Yitian He, Shuming Liu, Baoyou Shi

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  12. Atmospheric evolution of environmentally persistent free radicals in the rural North China Plain: effects on water solubility and PM 2.5 oxidative potential

    Atmospheric chemistry and physics · 2024-10-02

    Yang Xu, Fobang Liu, Shuqi Yang, Yuling Yang, Yanan Wang, Jingjing Li, Mingyu Zhao, Zhao Wang, Kai Wang, Chi Quan He, Haijie Tong

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  13. Catalytic potential of biochar: enhancing pollution removal through persistent free radicals in biomass pyrolysis — a review

    Biomass Conversion and Biorefinery · 2025-01-02

    Mahmoud Elsafi, Yeek‐Chia Ho, Beh Hoe Guan, Wai Hong Leong, Norhana Mohamed Rashid

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  14. An efficient strategy for BDD electrode drive electro-catalysis triggering active species on lincomycin and antibiotic resistance genes removal: Electron transfer based on calculation modeling

    Journal of Hazardous Materials · 2025-03-15

    Jia Wang, Jia Wang, Yihang Hu, Lu An, Jun Wang, Jun Wang, Fei Wu, Jie Gu, Xiaojuan Wang, James M. Tiedje

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  15. Radical inhibition mechanisms of ammonium sulfate on industrial organic pollutants in copper-catalyzed reactions

    Journal of environmental chemical engineering · 2025-04-02

    Shuting Liu, Guorui Liu, Mingxuan Wang, Linjun Qin, Qingyu Guo, Da Li, Lili Yang, Minghui Zheng

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  16. Release characteristics of POPs during preheating and sintering processes of ceramsite produced with the contaminated sediment

    Journal of Hazardous Materials · 2025-04-05

    Hang Yu, Chu Wang, Chu Wang, Xi Luo, Wenjing Xie, Kanglin Tian, Wenjuan Li, Xiaomei Tang, Xi Yang, Yong Li Liang, Pu Wang

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  17. Persistent free radicals in the environment

    Journal of Hazardous Materials · 2025-04-17

    Linjun Qin, Wuyuxin Zhu, Lili Yang, Minghui Zheng, Guorui Liu

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  18. Free radical mechanisms of halogen coexistence promoting pollutants formation

    Journal of Environmental Sciences · 2025-04-27

    Mingxuan Wang, Shuting Liu, Linjun Qin, Qingyu Guo, Guorui Liu, Dong Cao, Lili Yang, Minghui Zheng

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  19. Self‐Activated Heterogeneous Fenton Process for Accelerated Degradation of Aromatic Pollutants over Copper Oxide Catalysts

    Angewandte Chemie · 2025-05-19

    Mingjie Huang, Hongzhi Liu, Qingqing Huang, Tao Zhou, Xiaohui Wu, Wen‐Wei Li, Han‐Qing Yu

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  20. Self‐Activated Heterogeneous Fenton Process for Accelerated Degradation of Aromatic Pollutants over Copper Oxide Catalysts

    Angewandte Chemie International Edition · 2025-05-19

    Mingjie Huang, Hongzhi Liu, Qingqing Huang, Tao Zhou, Xiaohui Wu, Wen‐Wei Li, Han‐Qing Yu

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  21. Oxygen-driven thiol-activated ROS generation by particulate organic matter: Deciphering the role of interface-accelerated organic radical chain reaction

    Water Research · 2025-06-11

    Yixuan Wang, Chenghao Ge, Yuhong Huang, Wenxiu Qin, Xueyuan Gu, Donald L. Sparks, Dongmei Zhou

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  22. Perspectives on the Presence of Environmentally Persistent Free Radicals (EPFRs) in Ambient Particulate Matters and Their Potential Implications for Health Risk

    Atmosphere · 2025-07-17

    Senlin Lü, Jiakuan Lu, Xudong Wang, Kai Xiao, Jingying Niuhe, Xinchun Liu, Shinichi Yonemochi

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  23. Insight into catalytic performance of chlorobenzene over phosphate-modified MnCeOx catalysts and suppression mechanism of polychlorinated byproducts

    Environmental Chemistry and Ecotoxicology · 2025-12-26

    Runtong Dong, Yunfeng Ma, Yi Liu, Fanxiang Meng, Jiabao Lv, Angjian Wu, Zhongkang Han, Yujue Yang, Bingcheng Lin, Rong Jin, Minghui Zheng, Guorui Liu

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  24. Unlocking efficient electrocatalytic removal of trace emerging contaminants via synchronized pollutant enrichment and electron delivery

    Nature Communications · 2026-01-06

    Yao Pan, Junxi Guo, Yu Han, Xudong Yang, Sai Gong, Dan Shan, Lili Ding, Yingzheng Fan, Min Liu, Jinfeng Wang, Xinkun Ren

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  25. Ammonia removal under free radical action in advanced oxidation processes: A review

    Sustainable Horizons · 2026-02-12

    Kun Xiang, Yifeng Hu, Sakil Mahmud, Zhu Xiong, Jing Bai, Qingyi Zeng

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  26. Unveiling the role of A-Site 3d orbital configuration in spinel ferrites for catalytic ozonation

    Applied Catalysis B: Environmental · 2026-04-30

    Rui Hu, Donghua Xie, Kengqiang Zhong, Man-Fang Cheng, Guo‐Ping Sheng

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  27. Persistent free radical-mediated Z-scheme charge transfer in ZnO-ZnS@Biochar: Bypassing redox potential compromise for efficient photocatalytic degradation

    Journal of environmental chemical engineering · 2026-06-24

    Hao Cai, Tianyuan Guan, Shuo Yang, Changyu Lu, Zhijia Miao, Aifang Gao, Zichuan Ma

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  28. Recent Advances in Benign Metal Nanoparticle‐Catalyzed Reduction of Organic Functional Groups

    ChemistrySelect · 2026-08-31

    Partha Sarathi Bera, Milan Bera, Brindaban C. Ranu

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