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RESEARCH PAPER · ACS Sustainable Chemistry & Engineering · 2022

A Zero-Thermal-Quenching Blue Phosphor for Sustainable and Human-Centric WLED Lighting

Zhihua Leng, Hao Bai, Qing Qing, Hongbo He, Jiayi Hou, Bingying Li, Zuobin Tang, Fang Song, Hongyue Wu

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A Zero-Thermal-Quenching Blue Phosphor for Sustainable and Human-Centric WLED LightingOriginalSeeking new, ultra-narrow-band blue emitting phosphors with high color purity for wide color gamut displays24Novel near-ultraviolet-excited and thermally-stable blue-emitting phosphor for healthy WLED lighting30Zero-thermal-quenching of LiAl5O8: Eu2+, Mn2+ phosphors by energy transfer and defects engineering26A novel red-emitting Na5W3O9F5:Eu3+ phosphor with high color purity for blue-based WLEDs61A broadband yellow-green emitting mixed orthoborate–pyroborate phosphor, Ba 2 Sc 2 B 4 O 11 :Ce 3+ , for white light emitting diodes23A novel narrow-band blue-emitting phosphor with high efficiency and thermal stability for WLEDs and FEDs31Achieving efficient violet-light-excited blue phosphors by nitridation for violet-chip-based full-spectrum lighting47Anti-thermal quenching phosphors based on the new phosphate host Ca 3.6 In 3.6 (PO 4 ) 610Highly-efficient Eu 2+ -activated Sr 8 Si 4 O 12 Cl 8 cyan-emitting phosphors with zero-thermal quenching luminescence for versatile applications16Novel highly efficient Bi 3+ -activated phosphors for warm WLEDs39Single‐Site Occupancy of Eu 2+ in Multiple Cations Enables Efficient Ultra‐Broadband Visible to Near‐Infrared Luminescence83Efficient microwave remediation on naphthalene contaminated soil using a multifunctional bluecoke-based conditioner4Rare-earth and transition metal ion single-/co-doped double-perovskite tantalate phosphors: Validation of suitability for versatile applications55Eu 2+ -Doped Ca 4 Y 3 Si 7 O 15 N 5 Phosphor with High Thermal Stability and Pressure Sensitivity for Dual-Functional Applications in W-LEDs and Pressure Sensors32Novel red-emitting Sr3LaTa3O12:Eu3+ phosphor with high color purity and stability for w-LEDs and visualization of latent fingerprint36Anionic Regulation toward Bi3+ Selective Occupation for Full-Spectrum White Light Emission33Ultra-narrow-band luminescence with spectral width down to 32 nm in bismuth-activated phosphate phosphors with superior thermal stability11Synthesis and optical properties of highly efficient Na3KMg7(PO4)6:Eu2+ blue phosphor for full-spectrum white-light-emitting diodes: The role of Li2CO3 flux29Designing multicolor luminescence in Tb3+/Eu3+-codoped KGd2F7 nanoparticles through energy transfer engineering for warm white light-emitting diode5Enhancement of broad-spectrum orange emission and thermal stability in Rb2-xCsxCaP2O7:0.015Eu2+ phosphors by improving local structural symmetry6Structure and photoluminescence studies of Rb3GdSi2O7: Eu2+ phosphor used for NUV converted white LEDs10Towards efficient blue Eu2+ activated pyrophosphate phosphor for warm white LED applications13Different rare earth ions activated NaBiF4 microcrystals for adjustable multicolor luminescence and white light-emitting diodes4Highly bright broadband cyan-emitting CaLu2HfGaAl3O12:Ce3+ garnet phosphors for high-color-quality white light-emitting diodes15Narrow-Band Deep-Blue Emission and Superior Thermal Stability of Fluoroaluminate Phosphor Based on Tungsten Bronze-Type Mineral Structure5White light emitting devices with high color rendering index and electrically adjustable color temperature11K2CaPO4F:Eu2+,RE3+ for pc-WLEDs: Cationic substitution inducing tunable emission and anti-thermal quenching8Crystal Field Engineering Yields New 3D Layered Solid Solution Phosphors (Ca/Sr)4MgAl2Si3O14:Eu2+ for White-Light-Emitting Diode Full-Spectrum Lighting17A highly Mn 2+ -doped narrowband green phosphor toward wide color-gamut display applications26Tuning Eu 2+ luminescence in Sr 8 CaLu (PO 4 ) 7 via Na + -induced local structure engineering for violet-chip-excitable full-spectrum lighting10Ultra-broadband emission up to 181 nm of VO4-activated yellow phosphor for white light-emitting diodes with high color rendering index5In Situ Glass Crystallization Enables Narrowband Blue Luminescence for Full‐Spectrum Lighting and Transparent Display19A long-term stable zero-thermal-quenching blue-emitting phosphor for sustainable and human-centric lighting22Crystal-Site Engineering of Novel Na3kmg7(Po4)6-X(Bo3)X: Eu2+ Phosphor for Full-Spectrum Lighting0Enhanced narrow green emission via efficient energy transfer from Eu 2+ to Mn 2+ in KAl 4 Ga 7 O 17 for backlit LCD displays9Highly efficient blue-green dual-narrow-emission in RbAl 11 O 17 :Eu 2+ ,Mn 2+ toward wide-color-gamut human-centric backlights7Negative thermal expansion in Sc 2 Mo 3 O 12 :Sm 3+ for white LEDs and unveiling the impact of phase transition on cryogenic luminescence32Photoluminescence Properties of CsZn2B3O7:Eu2+ Broadband Green-emitting Phosphor for White Light-emitting Diodes2Photoluminescence Properties of Li3Cs2Sr2B3P6O24:Eu2+ Narrow-band Blue Phosphor for Wide Color Gamut Backlight Display Applications4Progress of Ce 3+ /Eu 2+ doped phosphors for violet chip based full-spectra lighting42Charge compensation improves energy transfer to realize anti-thermal-quenching and improve the CaMoO4: Sm3+ phosphors optical temperature measurement sensitivity base on the FIR model0Charge compensator adjusts the luminescence intensity of ZnWO4: Sm3+ full spectrum phosphors: A bifunctional phosphors for plant growth lights and FIR thermometers23Zero-thermal-quenching broadband yellow-emitting Bi3+-activated phosphors based on metal to metal charge transfer27Super thermally stable Rb-β-Al2O3:Eu blue phosphor for full-spectra lighting4Charge compensation improves energy transfer to realize anti-thermal-quenching and enhances the CaMoO4: Sm3+ phosphors optical temperature measurement sensitivity base on the FIR model7Crystal-Site Engineering of Novel Na3KMg7(PO4)6–x(BO3)x:Eu2+ Phosphors for Full-Spectrum Lighting10Efficient and tunable white light emitting from Sb3+, Tb3+, and Sm3+ Co-doped Cs2NaInCl6 double perovskite via multiple energy transfer processes65Near pure white light emission of CeO2-Dy2O3 co-doped K2O–MgO–B2O3–P2O5 glasses and glass-ceramics18Effect of ion occupancy and Li+ ion doping on luminescence characteristics of CaLaGaO4:Bi3+ blue phosphor30Effect of Synthesis Conditions on the Photoluminescent Properties of Si-Substituted CaYAlO4:Eu: Sources of Experimental Errors in Solid-State Synthesis1Role of host matrix on NIR emission and ratiometric thermometry properties in Nd3+/Yb3+ co-doped CaGd2(MO4)4 (M = W, Mo) phosphors5Optimizations of luminescent materials for white light emitting diodes toward healthy lighting27Luminescence spectra and site-occupation of Eu3+ centres in lithium antimonate LiSbO3 lattice14Enhancing the cyan light emission of Ba9Lu2Si6O24:Ce phosphors by crystal-site engineering for full spectrum lighting2Acid Post-Treatment Triggered High-Efficiency Blue-Emitting LiNa2Sr8B12O24F6Cl:Eu2+ Phosphors toward Multipurpose LED Applications0Enhanced blue emission of KBaYSi2O7:Bi3+ phosphors through partial substitution of Si4+ with Al3+ and Ge4+ for white light-emitting diodes5Unraveling the Remarkable Influence of Square Antiprism Geometry on Highly Efficient Far‐Red Emission of Eu 3+ in Borotellurate Phosphors for Versatile Utilizations67An efficient violet-excited and cyan-green/near-infrared dual emitting phosphor for full-spectrum lighting14Dual-functional application of Ca2Ta2O7:Bi3+/Eu3+ phosphors in multicolor tunable optical thermometry and WLED11Europium(II)-Doped CsBr Nanocrystals in Glass for Spectrally Stable and Narrow-Band Blue-Light-Emitting Applications4Realization of narrow-band blue emission based on structurally engineering-designed Bi3+-doped phosphors12Realization of blue-red dual-emission via energy transfer in Na3KMg7(PO4)6: Eu2+, Mn2+ phosphor for plant growth application14Designing a high-efficiency broadband cyan phosphor for low-blue full-spectrum LED lighting22Synthesis and tunable luminescence of BaLaGa3O7:Bi3+/Eu3+ phosphors1Customized Cyan Phosphors for Efficient Full‐Spectrum Illumination and Fingerprint Detection22Thermal stable and bright yellow-emitting phosphor Na3+xK1-x(AlSiO4)4:Eu2+ for solid-state lighting2Broadband red emission in disordered Sr2LaGaO5:Eu2+ phosphors7Stability of Phosphors for White LED Excitable by Violet Light3Highly efficient blue-emitting silicate phosphor BaY4Si5O17:Eu2+ with superior thermal stability for full-visible-spectrum white LEDs10Modulation of negative thermal expansion and luminescence anti-thermal quenching properties of Er3+-Yb3+ co-doped Sc2Mo3(1+x)O12 via host matrix engineering8Achieving successful reduction of Eu3 + to Eu2+ in NaYSiO4 lattice towards lighting & display applications by a two-pronged approach6A narrow band blue phosphor NaBa 4 Al 2 B 8 O 18 Cl 3 :Eu 2+ for white light emitting diodes5Application of photoluminescent materials in cultural relics protection0Crystallographic site engineering of a single Bi 3+ -doped single-component Ca 5 Ga 6 O 14 :Bi 3+ phosphor for full-spectrum white light emission and highly sensitive optical thermometry10Narrow-Band Deep-Blue Emitting Basr2(Po4)2: Eu2+ Phosphor with High Thermal Stability for Advanced Anti-Counterfeiting and Wleds0Red emitting SnO2:Eu3+ hierarchical structures for multifunctional applications: Thermal sensing, w-LEDs, latent fingerprint detection and biomedical applications15Research progress on the design and regulation of Eu 2+ /Ce 3+ -activated anti-/zero thermal quenching phosphors9Synthesis and Luminescent Properties of Novel Narrow-Band Green-Emitting Phosphors Na3ysi2o7: Eu2+ for Full-Spectrum Lighting0Violet light excitable organic halides with short ∼ns emissions for multiple optoelectronic applications0Energy transfer mediated single-component white light emission in a novel Bi3+/Eu3+ co-doped Sr2Ga2GeO7 phosphor for white LEDs20Na2YMg2V3O12:Dy3+, Eu3+ wideband absorption phosphors suitable for near ultraviolet excitation4Synergetic Contributions of High Quenching Concentration and Tuned Square Antiprism Geometry Boosting Far‐Red Emission of Eu3+ with Near‐Unit Efficiency33High-efficiency and thermally stable Cr3+-doped BaSiF6 fluoride phosphors for broadband near-infrared LED applications5Color-Tunable Photoluminescence via Site-Selective Occupancy of Bi3+/Eu3+ and Chemical Composition Modulation in Stable K3YSi2O7 toward wLED and Optical Temperature-Sensing Applications19Synthesis and luminescence characteristics of a new Mn4+-Activated Ba6Y2Ti4O17 fluorescent material for plant growth LED9A novel inorganic host matrix for Sm3+ doping targeting at the achievement of high color rendering WLEDs20Enhanced blue emission of Ba3Ga2O6: Bi3+ phosphor co-doped with alkali metal ions10A novel double-perovskite structure Mg2YVO6:Sm3+ phosphor with zero thermal quenching characteristics for w-LEDs and latent fingerprint development18Blue/blue–violet‐emitting phosphate phosphors for full‐spectrum white light‐emitting diodes8MgF2 assisted synthesis of deep-red MgAl2O4:Cr3+ phosphors with improved emission properties for pc-LED applications4Synthesis and multi-color emission properties of novel Na3KMg7(PO4)6: RE3+ (RE = Eu, Dy, Tb) phosphor for white LED and indoor plant growth7Single‐Grain High‐Efficiency Full‐Visible‐Spectrum White Emitters17Single‐Grain High‐Efficiency Full‐Visible‐Spectrum White Emitters3A novel phosphate-based phosphor for multifunctional applications realized by energy transmission and color change4Synthesis and luminescence properties of LiY(WO4)2:Bi3+ broadband yellow-emitting phosphor for high-quality NUV pumped WLEDs2Effect of Ca2+ partial substitution with Mg2+ on luminescence enhancement of Ca3Ga4O9:Bi3+ cyan-emitting phosphors for warm WLEDs4Cation-tunable blue phosphor (Ba,Mg)(Y,Sc)4Si5O17:Eu2+: enhanced quantum yield and thermal stability8Narrow‐band green‐emitting RbSr 4 (BO 3 ) 3 :Eu 2+ phosphor paving the way for high‐performance multipurpose WLED applications3Li+ induced enhancements in Eu3+→Eu2+ reduction and photoluminescence properties of Eu-doped KAlSi2O6 phosphors for WLED applications8Europium(II) Activated Blue–Cyan Aluminosilicate Phosphors with Zero Thermal Quenching3Synthesis and luminescent properties of novel cyan-green-emitting phosphors Na3YSi2O7: Eu2+ for full-spectrum lighting0Eu3+ activated Y2Mg2Ga2Si2O12 deep red phosphor for healthy lighting wLEDs3A superb blue phosphor Na3Ba2Sr(PO4)3:Eu2+ with high quantum yield and zero-thermal-quenching for plant growth LEDs5Efficient broadband reddish-orange emitting Mg2Y2.5Al1.5Si2O12:Ce3+ garnet phosphor opens up new avenues for multifunctional optical applications8Effects of alkaline-earth metal oxides and heat treatment on the structure and cyan-luminescence properties of Bi3+-doped SiO2-MO-Y2O3-ZnO-ZrO2-Ga2O3 (M = Ca, Sr, Ba) glass and Y2Zr2O7 transparent glass-ceramic1High-Performance X-Ray Detection and Optical Information Storage via Dual-Mode Luminescent Modulation in Na3KMg7(PO4)6:Eu2Ba2Y[BO3][Si2O6]:Ce3+ phosphor with high-efficiency blue emission and excellent quantum yield enabled by mixed-dimensional anionic framework engineering7Study on luminescence properties of Eu2+ doped K-β-Al2O3 blue phosphor and its anti-counterfeiting application1Actualizing stable white laser lighting with concurrent high-efficiency, broad-spectrum, orangic-inorangic hybid ZnO-based phosphors2Synthesis and luminescent properties of novel red-emitting K3GdSi2O7: Eu2+ phosphors for warm white leds0Violet excitable, highly efficient single broadband emitting oxyfluoride phosphor and polymer composite for conventional and laser-triggered lighting applications8Tunable energy transfer in Bi3 + and Eu3+ co-doped Sr2Al2SiO7 phosphors: Toward warm WLEDs and hierarchical anti-counterfeiting3A novel deep-blue emitting BaSr2(PO4)2: Eu2+ phosphor with excellent thermostability for advanced anti-counterfeiting and white light-emitting diodes1Synthesis and Host-Sensitized Luminescence in Mg 2 YVO 6 :M 3+ (M = Eu, Er, Sm, Dy, Tm, Bi) Phosphor for Application in Human-Centric Lighting8Spectroscopic and thermal behavior of ca₈ MgLa(PO₄)₇:Eu2+,Mn2+ phosphor powders and polymer composites0Multi-functional application of NaYO2: Bi3+ , Eu3+ phosphors: Self-calibrated thermometer, WLEDs, anti-counterfeiting and latent fingerprint detection4Luminescence properties and applications of a zero-thermal-quenching oxyapatite-type Ba2La3(SiO4)2(PO4)O:Tb3+ phosphors1Luminescence of Eu3+,2+ in LiAl7B4O17: a phosphor with activators occupying structural channels3Highly efficient narrow-band green (La,Gd)ZnAl11O19:Mn2+ phosphor for wide-color-gamut display1Broadband Reflective Cholesteric Liquid Crystals for Low‐Blue Circularly Polarized Light Generation in the Visible Region0Luminescence and temperature sensing properties of novel Pr3+, Ho3+ Co-doped KBaGd(Mo/WO4)3 phosphors8Lanthanide-activated chloride and vanadate phosphors: a review study of structure, luminescence, and applications2Interstitially incorporated Eu2+ and its luminescence characteristics in Li3AlB2O60Heavy-element substitution simultaneously boosts comprehensive photoluminescence performance of Ce3+-activated garnets toward multifunctional optical applications0A Thermally Stable Eu 2+ ‐Doped Glass‐Ceramic for High‐Resolution X‐Ray Imaging and Full‐Spectrum Lighting0Theoretical Study on Narrow-Band White Quantum Dot LEDs Based on Asymmetric F-P Microcavities0Health and environmental consequences of blue light exposure and mitigation strategies: A review0Temperature-sensitive color modulation in Ca7-mSrmMg2(PO4)6: Eu2 + for advanced anti-counterfeiting and WLED applications0The Anti‐Thermal Quenching Phosphor Landscape: Mechanisms, Materials, and Applications0Site engineering of single-phase β-Ca3(PO4)2-type phosphors via cation substitution for multifunctional luminescence0

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  4. A novel red-emitting Na5W3O9F5:Eu3+ phosphor with high color purity for blue-based WLEDs

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  11. Single‐Site Occupancy of Eu 2+ in Multiple Cations Enables Efficient Ultra‐Broadband Visible to Near‐Infrared Luminescence

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  17. Ultra-narrow-band luminescence with spectral width down to 32 nm in bismuth-activated phosphate phosphors with superior thermal stability

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  31. Ultra-broadband emission up to 181 nm of VO4-activated yellow phosphor for white light-emitting diodes with high color rendering index

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  32. In Situ Glass Crystallization Enables Narrowband Blue Luminescence for Full‐Spectrum Lighting and Transparent Display

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  34. Crystal-Site Engineering of Novel Na3kmg7(Po4)6-X(Bo3)X: Eu2+ Phosphor for Full-Spectrum Lighting

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