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RESEARCH PAPER · Nature Synthesis · 2022

Synthesis strategies and design principles for nanosized and hierarchical zeolites

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Synthesis strategies and design principles for nanosized and hierarchical zeolitesOriginalUnique Role of GeO2 as a Noninvasive Promoter of Nano‐Sized Zeolite Crystals14Evolution of Morphology, Fractal Dimensions, and Structure of (Titanium) Aluminosilicate Gel during Synthesis of Zeolites Y and Ti-Y10Epitaxial growth of surface-passivated core-shell ferrierite7Synthesis of PHI-type zeolite harmotome using barium as an inorganic structure-directing agent inspired from natural mineral compositions11Underpinnings of Carbonaceous Deposition among Structurally Diverse Hierarchical Zeolites during Hydrocarbon Upgrading8Hierarchical ZSM-5 zeolite using amino acid as template: Avoiding phase separation and fabricating an ultra-small mesoporous structure32Friedel-Crafts acylation of anisole with acetic anhydride over single- to multiple-layer MWW zeolites: Catalytic behavior and kinetic mechanism19Synthesis of nanosized IM-5 zeolite and its CH4/N2 adsorption and separation23Catalytic transesterification of kapok seed oil by dual metal oxide (Na 2 O-K 2 O; MgO-CaO) impregnated active-natural mordenite under ultrasonic irradiation1Synthesis of Dendritic ZSM-5 Zeolite through Micellar Templating Controlled by the Amphiphilic Organosilane Chain Length23Multinuclear MAS NMR Monitoring of the Effect of Silicate Speciation on the Mechanism of Zeolite BEA Formation: Toward Engineering of Crystal Size and Morphology9Design of an Organic Template for Synthesizing ITR Zeolites under Ge-Free Conditions24Covalent Organic Frameworks for Neuromorphic Devices48Tailoring the pore structure、morphology and acidity of MFI zeolites by the regulation of Si/Al ratio in the synthetic gel17Nanoparticles in Medicine: Current Status in Cancer Treatment71A simple strategy for synthesis of b-axis-oriented MFI zeolite macro-nanosheets24Atomic Imaging of Zeolites and Confined Single Molecules by iDPC-STEM31Magnetic Zeolite: Synthesis and Copper Adsorption Followed by Magnetic Separation from Treated Water17Synthetic Control of the Defect Structure and Hierarchical Extra-Large-/Small-Pore Microporosity in Aluminosilicate Zeolite SWY11Constructing Intrapenetrated Hierarchical Zeolites with Highly Complete Framework via Protozeolite Seeding41Constructing Intrapenetrated Hierarchical Zeolites with Highly Complete Framework via Protozeolite Seeding12Single-crystal metal-organic frameworks for electronic and opto-electronic devices33Zeolitic germanosilicate analogue to pharmacosiderite crystallized in an acidic medium1Recent advances in synthetic strategies and physicochemical modifications of SSZ-13 zeolites: A review14MFI nanosheets: a rising star in zeolite materials27Facile synthesis of hierarchical SAPO-56 zeolite as a highly efficient catalyst for CO2 hydrogenation to methanol15Advances and challenges in designing active site environments in zeolites for Brønsted acid catalysis18Analyzing the charge contributions of metal–organic framework derived nanosized cobalt nitride/carbon composites in asymmetrical supercapacitors14Carbon Capture by Conventional and Nano Zeolite1Cooperative Interplay of Micropores/Mesopores of Hierarchical Zeolite in Chemical Production82Ethanol–based in situ synthesis of organic–inorganic hierarchical ZSM–5 for efficient capture of toluene under humidity environment14The art of controlled nanoscale lattices: A review on the self-assembly of colloidal metal–organic framework particles and their multifaceted architectures43High-silica hierarchical ZSM-5 prepared by conventional alkali treatment: A highly stable MTP catalyst23The Current Understanding of Mechanistic Pathways in Zeolite Crystallization192Mechanochemically Induced OSDA-Free Interzeolite Conversion9Nanoplatelet Mordenite Zeolite with a Controlled Aspect Ratio: Implications for the Alkylation of Benzene with Benzyl Alcohol1Catalytic Consequences of Hierarchical Pore Architectures within MFI and FAU Zeolites for Polyethylene Conversion54A novel method for a nanosized ZSM-5 (MFI) zeolite synthesis in proton form6Solid-conversion synthesis of three-dimensionally ordered mesoporous ZSM-5 catalysts for the methanol-to-propylene reaction5Synthesis of hierarchical ZSM ‐5 using polymer macro template for selective C ‐alkylation of m‐cresol with tert ‐butanol0Reinforcement and reconfiguration of framework Al in P@ZSM-5 zeolite via in-situ phosphating strategy for efficient methanol-to-propylene13Lysine-assisted synthesis of plate-like TS-1 zeolite for 1-hexene epoxidation10Zeolite-based nanoparticles drug delivery systems in modern pharmaceutical research and environmental remediation50γ-aminobutyric acid-assisted fabrication of plate-like ZSM-5 zeolite for efficient propylene production from methanol conversion11Catalytic pyrolysis of polystyrene over rice husk silica-derived traditional and hierarchical green MWW zeolites3A dual growth mode unique for organic crystals relies on mesoscopic liquid precursors11Challenges and solutions to the scale-up of porous materials81Active site requirements for bio-alcohol dehydration: Effect of chemical structure and site proximity5Synthesis of hierarchical ZSM-5 with ultra-small mesopore structure and its catalytic performance during methanol to hydrocarbons12Ultrathin BPH Nanosheets with Exceptional Water Adsorption Properties3Hydrocarbon Biofuels4Zeolite Crystallization Inside Chemically Recyclable Ordered Nanoporous Co 3 O 4 Scaffold: Precise Replication and Accelerated Crystallization5Directional Transport in Hierarchically Aligned ZSM-5 Zeolites with High Catalytic Activity27Brønsted Acid-Triggered Fast Synthesis Pathway of Furfural to Ethyl Levulinate by PtZn Supported on ZSM-5 Nanosheets9ZeoReader: Automated extraction of synthesis steps from zeolite synthesis literature for autonomous experiments5Improvement of rust prevention by inclusion of 2D zeolite and graphene in oil-based soft coating2Synthesis of discrete SSZ-39 zeolite nanosheets by solvent-free seed-assisted route for efficient CO2 capture13Potential pathways for CO 2 utilization in sustainable aviation fuel synthesis48Role of extra-framework aluminum species within MOR zeolites for syngas conversion via OXZEO catalysis7Heteroatom-Induced Fractal Growth for Hierarchical Zeolites7Accelerated synthesis of zeolite Y under ultrasound from transparent mother liquor solutions without organic templates or seed addition0Accelerated synthesis of zeolite Y under ultrasound from transparent mother liquor solutions without organic templates or seed addition0Chemical engineering of zeolites: alleviating transport limitations through hierarchical design and shaping85Defective plane induced fractal TON zeolites for efficient hydroisomerization of long-chain hydrocarbons1Dual-additive engineering of Ti sites and mesoporosity in TS-1 zeolite for enhanced oxidative desulfurization7Innovative applications of nanozeolite: Advancing environmental and agricultural sustainability1Synthesis of nanosized HZSM-5 zeolite under microwave irradiation: effect of the Si/Al ratio on the morphology, textural and acidic properties3Hierarchy design of zeolite mesocrystals20Scalable and Low‐Energy Synthesis of Metal–Organic Frameworks by a Seed‐Mediated Approach0Scalable and Low‐Energy Synthesis of Metal–Organic Frameworks by a Seed‐Mediated Approach13AI-empowered digital design of zeolites: Progress, challenges, and perspectives15Study on the functional ingredient of seed crystals in the synthesis process of TS-10Potassium-modified ZSM-5 zeolite for catalytic coupling methanol with butene to propylene3Zeolite composite prepared by quasi-in situ interzeolite conversion approach4Facile Synthesis of Hierarchical MFI Zeolite Nanosheets for Enhanced Dye Adsorption Performance5Alternating Charge Pairs by the Assembly of Covalent Organic Frameworks into Mobil‐Type Five Zeolite Membranes for Enhanced Xylene Separation8Zeolite–Water Chemistry: Characterization Methods to Unveil Zeolite Structure19Uncertainty-aware optimization of zeolite particle size: Utilizing quantile regression and SHAP analysis13Hydroisomerization of C8 aromatic fraction over micro-mesoporous Pt–Mo catalyst2Engineering Compositional Gradients in Ti-Silicalite-1 Catalysts for Improved Olefins Epoxidation9A Review on the Research Progress of Zeolite Catalysts for Heavy Oil Cracking63Hierarchical Beta aggregates assembled from sheet-like nanocrystals: Synthesis and enhanced catalytic application in acylation and alkylation reactions3Operando Two-Dimensional Solid-State NMR Unveils Dual-Template Collaboration and Competition in SAPO-34 Zeolite Crystallization19Multifunctional zeolites for rechargeable lithium-based batteries: progress and perspectives8Divergent Mechanisms of SSZ-39 Crystallization Using Structurally Similar but Chemically Distinct Organic Structure-Directing Agents11Post-Synthesis Surfactant-Induced Mesoporosity in Zeolite Crystals1Structural stability and catalytic activity assessment of (silanized) Titanosilicate-1 catalysts in liquid-phase oxidative desulfurization reaction0Omnipotent nanosized zeolites: A next-generation nanoplatform for biomedical applications5Operando two-dimensional solid-state NMR unravels SAPO-34 zeolite crystallization mechanism2A nonclassical pathway of β-hematin crystal nucleation enables its suppression by antimalarials4Cationic polyelectrolyte stimulated ultrafast synthesis of hierarchical ZSM-11 zeolite with improved methanol to olefin catalytic performances3Metal-Modified Zeolites for Catalytic Dehydration of Bioethanol to Ethylene: Mechanisms, Preparation, and Performance12Structure-property relationships of zeolite-based porous liquids for CO2 capture4Ultra-fine palladium‑gold alloy nanoclusters anchored on amino-grafted self-pillared pentasil zeolite for efficient dehydrogenation of formic acid11Zeolites: Historical Evolution and Current Relevance1Adjusting seed solution-assisted synthesis of hierarchical ZSM-5 zeolite to facilitate efficient tetralin cracking2Diffusion-enhanced AEL zeotype nanosheet macrostructures with shortened c-axis for superior hydroisomerization of long-chain n-alkanes3Formation of GaN in chabazite by scavenging framework gallium0Recent syntheses of novel zeolites with different pore sizes1Challenging the deactivation resistance of Co/Cu-dendritic ZSM-5 zeolites in methane pyrolysis for clean hydrogen1Granules of SIV, AM-4, and ETS-4 Titanosilicate Sorbents Based on the Products of Processing Ti-Bearing Raw Materials of the Kola Peninsula and Their Sorption Behavior with Respect to 137Cs and 90Sr Radionuclides3Morphology-tunable synthesis of two-dimensional silicoaluminophosphate molecular sieves guided by silanol-rich short-range ordered Si species2A Funnel-Structured 12 × 10-Ring Zeolite Customized for Biomass Catalytic Pyrolysis5Modifiers Regulate Crystal Morphology by Generating Lattice Defects1Constructing hierarchical aluminophosphate-based zeotypes via a neutral phosphorus-compensated dissolution–recrystallization strategy0Controlling crystallization pathways: a universal Na + /K + ion switch for mesostructure engineering of zeolites2Engineering Ga-containing dendritic MFI zeolites as safe-by-design hierarchical and immunomodulatory nanointerfaces0Thermomechanically enhanced solvent-free synthesis of titanium silicalite-1 with ultralow template loading0Challenges and Opportunities in Core–Shell Zeolite Catalysts2Consecutive phase transformations of inorganic-organic assembly in the synthesis of single-walled zeolitic nanotube0ZSM-5 Nanocatalyst from Rice Husk: Synthesis, DFT Analysis, and Au/Pt Modification for Isopropanol Conversion2Honeycomb-like Mordenite Zeolite Monoliths with Hierarchical Porosity for Promoting Direct Air Capture of CO 22Research progress on the regulation of zeolite and mesoporous silica synthesis by inorganic ions0Ethanol-Assisted Synthesis of Nanosized Beta Zeolite with Reduced Template Usage0Gas vortex discovery in butterfly microcavities for constructing ultrasensitive gas sensors5A gold catalyst stabilized in an open-porosity TS-1 zeolite for the direct epoxidation of propylene5Chabazite-supported ZnO and CeO2 nanoparticles with structural stability and enhanced antibacterial action1Continuous Control over Zeolite Porosity via the Post-Synthesis Treatment of the IWV Zeolite0SAPO-18-assisted ultra-low Si/Al ratio Y zeolite conversion to SSZ-13 zeolite for NH3-SCR: A novel and efficient solid waste-based zeolite synthesis pathway0Commercial zeolites drying and recovery in a Vacuum Membrane Dryer (VMDr)0Automated extraction of synthesis recipes from the literature using large language models: Application to zeolite ZSM-50Crystal size engineering of zeolite A for highly efficient CO2 capture and separation0Insights into synthesis of ZSM-23 zeolite nanosheets0Temporal- and Spatial-Resolved Characterization of Zeolite-Based Catalysts0Conventional and Green Synthesis Strategies for ZSM-5 Zeolite: A Short Review0Green structural engineering of 4A zeolite via water-modulated deep eutectic solvents: enhanced ammonium adsorption and mechanistic insights0Temperature-Dependent Microstructural Evolution of Seed-Assisted Low-Template ZSM-5 and Its Catalytic Behavior in Benzene Alkylation with Methanol0Pressureless sintering of FAU zeolite-derived transparent mullite glass-ceramics with enhanced mechanical properties0Beta-type zeolites from Brazilian rice husk waste – Toward sustainable catalysts for pyrolysis of high-density polyethylene0Polyfunctional Zeolite-Based Catalysts for Hydrogen-Free Upgrading of Petroleum Fractions0Ultrathin ZSM-5 zeolite nanocrystals synthesized from purely inorganic precursors0

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  5. Underpinnings of Carbonaceous Deposition among Structurally Diverse Hierarchical Zeolites during Hydrocarbon Upgrading

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  9. Catalytic transesterification of kapok seed oil by dual metal oxide (Na 2 O-K 2 O; MgO-CaO) impregnated active-natural mordenite under ultrasonic irradiation

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  10. Synthesis of Dendritic ZSM-5 Zeolite through Micellar Templating Controlled by the Amphiphilic Organosilane Chain Length

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  47. Challenges and solutions to the scale-up of porous materials

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  48. Active site requirements for bio-alcohol dehydration: Effect of chemical structure and site proximity

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  49. Synthesis of hierarchical ZSM-5 with ultra-small mesopore structure and its catalytic performance during methanol to hydrocarbons

    Journal of Materials Science · 2024-09-01

    Chuyu Jiao, Qirui Jiao, Wei Zhang, Zhuo Ji, Jiajun Zheng, Weijiong Dai, Yan Wang, Meng Pan, Ruifeng Li

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  50. Ultrathin BPH Nanosheets with Exceptional Water Adsorption Properties

    ACS Materials Letters · 2024-09-16

    Edwin B. Clatworthy, Rémy Guillet‐Nicolas, Philippe Boullay, Michaël Badawi, Yann Foucaud, Eddy Dib, Nicolas Barrier, Arnold A. Paecklar, Maxime Debost, Sajjad Ghojavand, Jean‐Pierre Gilson, Izabel C. Medeiros-Costa, Svetlana Mintova

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