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RESEARCH PAPER · Nature Synthesis · 2022

Coherent approach to two-dimensional heterolayered oxychalcogenides using molten hydroxides

Xiuquan Zhou, Christos D. Malliakas, Andrey Andreevich Yakovenko, Brandon Wilfong, Suyin G. Wang, Yu‐Sheng Chen, Lei Yu, Jianguo Wen, Mahalingam Balasubramanian, Hsien‐Hau Wang, Duck Young Chung, Mercouri G. Kanatzidis

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Coherent approach to two-dimensional heterolayered oxychalcogenides using molten hydroxidesOriginalFlux-assisted polytypism in the [Na 2 Cl]GaQ 2 heterolayered salt-inclusion chalcogenide family3Sr(Ag 1− x Li x ) 2 Se 2 and [Sr 3 Se 2 ][(Ag 1− x Li x ) 2 Se 2 ] Tunable Direct Band Gap Semiconductors5Sr(Ag1−xLix)2Se2 and [Sr3Se2][(Ag1−xLix)2Se2] Tunable Direct Band Gap Semiconductors0Advances in Chalcogenide Crystal Growth: Flux and Solution Syntheses, and Approaches for Postsynthetic Modifications13Transformation of K2Sb8Q13 and KSb5Q8 Bulk Crystals to Sb2Q3 (Q = S, Se) Nanofibers by Acid–Base Solution Chemistry7Phase Discovery and Selected Synthesis of Subvalent Niobium Tellurides Using a Polytelluride Flux Strategy3A brief survey of principles of co-deposition method as a convenient procedure for preparation of metallic nanomaterials42Laser‐driven liquid assembly: Metal‐nanocluster‐decorated Ni(OH) 2 /nickel foam for efficient water electrolysis41Exploring Single‐Phase Asymmetric Multiple‐Quantum‐Well Architectures in Chiral Hybrid Perovskites via Kinetically Controlled Self‐Assembly4Mixed-anion chalcogenide-halide semiconductors A 2 BaTaS 4 Cl (A = K, Rb, Cs) and K 2 BaNbS 4 Cl1Ultrathin transition metal oxychalcogenide catalysts for oxygen evolution in acidic media39Synthesis of two-dimensional transition metal phosphorous chalcogenides and their high-entropy alloys31Colloidal Chemistry in Molten Inorganic Salts: Direct Synthesis of III–V Quantum Dots via Dehalosilylation of (Me 3 Si) 3 Pn (Pn = P, As) with Group III Halides9Mixed-Flux Techniques for Rational Synthesis and Structural Control in Silver Chalcogenides3Dimensional Evolution Guides Property Control in the A n Cu 4– n TiS 4 Semiconductor Series6Dimensional Reduction Guides Electronic Structure Evolution in the A n Cu 4– n SnS 4 Semiconductor Series8Evolution from topological Dirac metal to flat-band-induced antiferromagnet in layered KxNi4S2 (0 ≤ x ≤ 1)0Chloride-Activated Addition Reactions for Sulfidation and Oxidation1Charge Ordering and Incommensurate Modulations in the Metamagnetic Layered Manganese Oxysulfide Sr 2 MnO 2 Cu 3.5 S 30Intralayer-Mediated Vertical Assembly of Two-Dimensional Organic Molecular Crystals toward Three-Dimensional Integration0Flux-Assisted Growth and Characterization of Noncentrosymmetric Quaternary Rare-Earth Selenides CsRESiSe 4 (RE = La, Pr, Nd, Sm, Gd, Tb): Crystal Structure, Magnetism, and Theoretical Studies0

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  1. Flux-assisted polytypism in the [Na 2 Cl]GaQ 2 heterolayered salt-inclusion chalcogenide family

    CrystEngComm · 2023-01-01

    Anna A. Berseneva, Vladislav V. Klepov, Hunter B. Tisdale, Hans‐Conrad zur Loye

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  2. Sr(Ag 1− x Li x ) 2 Se 2 and [Sr 3 Se 2 ][(Ag 1− x Li x ) 2 Se 2 ] Tunable Direct Band Gap Semiconductors

    Angewandte Chemie International Edition · 2023-01-27

    Xiuquan Zhou, Brandon Wilfong, Xinglong Chen, Craig C. Laing, Indra Raj Pandey, Ying‐Pin Chen, Yu‐Sheng Chen, Duck Young Chung, Mercouri G. Kanatzidis

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  3. Sr(Ag1−xLix)2Se2 and [Sr3Se2][(Ag1−xLix)2Se2] Tunable Direct Band Gap Semiconductors

    Angewandte Chemie · 2023-01-27

    Xiuquan Zhou, Brandon Wilfong, Xinglong Chen, Craig C. Laing, Indra Raj Pandey, Ying‐Pin Chen, Yu‐Sheng Chen, Duck Young Chung, Mercouri G. Kanatzidis

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  4. Advances in Chalcogenide Crystal Growth: Flux and Solution Syntheses, and Approaches for Postsynthetic Modifications

    Crystal Growth & Design · 2023-07-10

    Anna A. Berseneva, Hans‐Conrad zur Loye

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  5. Transformation of K2Sb8Q13 and KSb5Q8 Bulk Crystals to Sb2Q3 (Q = S, Se) Nanofibers by Acid–Base Solution Chemistry

    Journal of the American Chemical Society · 2023-07-12

    Hyungseok Lee, Byeongjun Yoo, Dawoon Kim, Joonil Cha, Yeo Kyung Kang, Sung‐Pyo Cho, Taeghwan Hyeon, Myung‐Gil Kim, Mercouri G. Kanatzidis, In Jae Chung

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  6. Phase Discovery and Selected Synthesis of Subvalent Niobium Tellurides Using a Polytelluride Flux Strategy

    Inorganic Chemistry · 2023-07-25

    Fan Sun, Haoyu Yue, Danilo Puggioni, Zhongnan Guo, Yutong Li, James M. Rondinelli, Zheng Zhang, Wenxia Yuan, Mercouri G. Kanatzidis

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  7. A brief survey of principles of co-deposition method as a convenient procedure for preparation of metallic nanomaterials

    Journal of Alloys and Compounds · 2024-01-12

    Reza Taheri‐Ledari, Mohammad Mehdi Salehi, Farhad Esmailzadeh, Adibeh Mohammadi, Amir Kashtiaray, Ali Reza Maleki

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  8. Laser‐driven liquid assembly: Metal‐nanocluster‐decorated Ni(OH) 2 /nickel foam for efficient water electrolysis

    SmartMat · 2024-03-22

    Yujeong Jeong, Talshyn Begildayeva, Jayaraman Theerthagiri, Ahreum Min, Cheol Joo Moon, Jangyun Kim, Shreyanka Shankar Naik, Myong Yong Choi

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  9. Exploring Single‐Phase Asymmetric Multiple‐Quantum‐Well Architectures in Chiral Hybrid Perovskites via Kinetically Controlled Self‐Assembly

    Advanced Functional Materials · 2024-07-18

    Huang Ye, Jie Bie, Yifei Wang, Peng Wang, Qianwen Guan, Tingting Zhu, Lina Li, Shuang Chen, Xitao Liu, Junhua Luo

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  10. Mixed-anion chalcogenide-halide semiconductors A 2 BaTaS 4 Cl (A = K, Rb, Cs) and K 2 BaNbS 4 Cl

    Dalton Transactions · 2025-01-01

    Thomas S. Ie, Siddhartha S. Nathan, James M. Rondinelli, Mercouri G. Kanatzidis

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  11. Ultrathin transition metal oxychalcogenide catalysts for oxygen evolution in acidic media

    Nature Synthesis · 2025-01-02

    Wenshuo Xu, Yao Wu, Shibo Xi, Yan Wang, Ye Wang, Yuxuan Ke, Lingtong Ding, Xiao Wang, Jieun Yang, Wenjing Angela Zhang, Kian Ping Loh, Feng Ding, Zheng Liu, Manish Chhowalla

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  12. Synthesis of two-dimensional transition metal phosphorous chalcogenides and their high-entropy alloys

    Nature Synthesis · 2025-02-10

    Haifeng Que, Bixuan Li, Luhao Sun, Peng Zhang, Huaning Jiang, Xingguo Wang, Kunpeng Si, Binyin Gao, Qianqian He, Yangyu Jia, Yahan Yang, Juntian Wei, Yongji Gong

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  13. Colloidal Chemistry in Molten Inorganic Salts: Direct Synthesis of III–V Quantum Dots via Dehalosilylation of (Me 3 Si) 3 Pn (Pn = P, As) with Group III Halides

    Journal of the American Chemical Society · 2025-03-04

    Zirui Zhou, Justin C. Ondry, Yichun Liu, Haoqi Wu, Ahhyun Jeong, Aritrajit Gupta, Yi‐Chen Chen, Jun Hyuk Chang, Richard D. Schaller, Dmitri V. Talapin

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  14. Mixed-Flux Techniques for Rational Synthesis and Structural Control in Silver Chalcogenides

    Journal of the American Chemical Society · 2025-05-21

    Xiuquan Zhou, Luqing Wang, Hengdi Zhao, Venkata Surya Chaitanya Kolluru, Wenqian Xu, Tieyan Chang, Yu‐Sheng Chen, Jianguo Wen, Maria K. Y. Chan, Duck Young Chung, Mercouri G. Kanatzidis

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  15. Dimensional Evolution Guides Property Control in the A n Cu 4– n TiS 4 Semiconductor Series

    Journal of the American Chemical Society · 2025-06-13

    Michael A. Viti, Zhi Li, Zhifu Liu, Chris M. Wolverton, Mercouri G. Kanatzidis

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  16. Dimensional Reduction Guides Electronic Structure Evolution in the A n Cu 4– n SnS 4 Semiconductor Series

    Journal of the American Chemical Society · 2025-08-07

    Michael A. Viti, Zhi Li, Chris M. Wolverton, Mercouri G. Kanatzidis

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  17. Evolution from topological Dirac metal to flat-band-induced antiferromagnet in layered KxNi4S2 (0 ≤ x ≤ 1)

    Matter · 2025-09-11

    Hengdi Zhao, Xiuquan Zhou, Hyowon Park, Tianqi Deng, Brandon Wilfong, Alann P. Au, Samuel E. Pate, Craig M. Brown, Hui Wu, Tushar Bhowmick, Tessa McNamee, Ravhi S. Kumar, Yu‐Sheng Chen, Zhi-Li Xiao, Russell J. Hemley, Weizhao Cai, Shanti Deemyad, Duck Young Chung, Stephan Rosenkranz, Mercouri G. Kanatzidis

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  18. Chloride-Activated Addition Reactions for Sulfidation and Oxidation

    Chemistry of Materials · 2025-11-16

    Haoying Han, Renfei Wei, Yan Wang, Kang Chen, Jun Zhou, Liang Huang

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  19. Charge Ordering and Incommensurate Modulations in the Metamagnetic Layered Manganese Oxysulfide Sr 2 MnO 2 Cu 3.5 S 3

    Journal of the American Chemical Society · 2026-01-16

    Lemuel E. Crentsil, Oliver J. Rutt, David G. Free, Murray David, Robert D. Smyth, Catherine F. Smura, David A. Keen, Andrew Nicholas Fitch, Joke Hadermann, S. J. Clarke

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  20. Intralayer-Mediated Vertical Assembly of Two-Dimensional Organic Molecular Crystals toward Three-Dimensional Integration

    Journal of the American Chemical Society · 2026-03-26

    Qiang Lv, Zhao‐Ji Lv, Tian-Zhe Feng, Ying-Xin Ma, Chao-Fei Xu, B J Wang, Xuedong Wang

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  21. Flux-Assisted Growth and Characterization of Noncentrosymmetric Quaternary Rare-Earth Selenides CsRESiSe 4 (RE = La, Pr, Nd, Sm, Gd, Tb): Crystal Structure, Magnetism, and Theoretical Studies

    Inorganic Chemistry · 2026-06-30

    Gopabandhu Panigrahi, Rachita Panigrahi, P. S. S. Dabare, Hope Eden Catalano, Hans‐Conrad zur Loye

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