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RESEARCH PAPER · Chemistry of Materials · 2022

Optimizing Broadband Emission in 2D Halide Perovskites

Carina Pareja‐Rivera, Julio A. Morán-Muñoz, A. Paulina Gómora‐Figueroa, Vojtěch Jančík, Brenda Cabral Vargas, Joelis Rodríguez-Hernández, Diego Solís-Ibarra

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Optimizing Broadband Emission in 2D Halide PerovskitesOriginalHighlighting Recent Research from Latin America in Chemistry of Materials1Broadband yellow and white emission from large octahedral tilting in (110)-oriented layered perovskites: imidazolium-methylhydrazinium lead halides24Lead-free hybrid indium perovskites with near-unity PLQY and white light emission using an Sb 3+ doping strategy82Revealing the Mechanism of Pressure‐Induced Emission in Layered Silver‐Bismuth Double Perovskites59Revealing the Mechanism of Pressure‐Induced Emission in Layered Silver‐Bismuth Double Perovskites7Two-Dimensional Hybrid Dion–Jacobson Germanium Halide Perovskites59Low-Temperature Solution Synthesis of Stable Cs3Cu2Br5 Single Crystals for Visible Light Communications29Mn2+‐Based Luminescent Metal Halides: Syntheses, Properties, and Applications155Mixed perovskites (2D/3D)-based solar cells: a review on crystallization and surface modification for enhanced efficiency and stability57Regulation of Luminescence Properties of the Ultrathin Two-Dimensional Halide Perovskite Cs2PbIxCl4−x ( x = 0,1,2,3,4) with Ruddlesden-Popper Structure11Chemistry in the Molten State: Opportunities for Designing and Tuning the Emission Properties of Halide Perovskites14Extremely Broad Electroluminescence from a Two-Dimensional Hybrid Perovskite Light-Emitting Diode3Correlated Self-Trapped Excitons and Free Excitons with Intermediate Exciton–Phonon Coupling in 2D Mixed-Halide Perovskites24Lead Halide Hybrids Templated by Two Coordinating Ligands for Enhanced and Stable Self-Trapped Emission8Distinct Excitonic Emissions in 2D (C7H7N2)2PbX4 (X = Cl, Br) under Compression11Br-Substituent Effect on Photoluminescence and Scintillation Properties of (C6h5c2h4nh3)2pbcl4 Perovskite-Type Compounds3Luminescence regulation of Sb3+ in 0D hybrid metal halides by hydrogen bond network for optical anti-counterfeiting49Photoluminescence and Scintillation Characteristics of (Ch3c6h5c2h4nh3)2pbcl4 Single Crystals0Broad-Band Emission Switch in Room Temperature Stable Hybrid Perovskite Polymorphs1Phase Transitions and Dynamics in Mixed Three- and Low-Dimensional Lead Halide Perovskites134Cs2Cd1–xMnxCl4 Nanoplatelets for Thermal Quenching Resistance and Luminescence Tuning10Understanding and Controlling the Photoluminescence Line Shapes of 2D Perovskites with Chiral Methylbenzylammonium-Based Cations25Stimuli‐responsive photoluminescent copper(I) halides for scintillation, anticounterfeiting, and light‐emitting diode applications66Effect of halogen on the luminescence properties of two-dimensional double-perovskite ( C 6 H 16 N 2 ) 2 Ag Bi X 8 ⋅ H 2 O ( X = Cl , Br and I ) with the Dion-Jacobson structure6Halogen Content Tunes the Color Temperature of White Light and Afterglow in Zero-Dimensional Hybrid Indium Halides8Pressure‐Tuning Localized Excitons Toward Enhanced Emission, Photocurrent Enhancement and Piezochromism in Unconventional ACI‐Type 2D Hybrid Perovskites22Pressure‐Tuning Localized Excitons Toward Enhanced Emission, Photocurrent Enhancement and Piezochromism in Unconventional ACI‐Type 2D Hybrid Perovskites7Pressure-controlled free exciton and self-trapped exciton emission in quasi-one-dimensional hybrid lead bromides50Ultra broadband yellow emitting lead-free metal halide perovskite like compounds with near-unity emission quantum yields9Photoluminescence and radioluminescence characteristics of (CH3C6H5C2H4NH3)2PbCl4 single crystals1Controlling Energy Flow in Perovskite Heterostructures Through Dimensionality and Phase Engineering7Divalent Methylhydrazinium─An Ultrasmall Organic Cation for Construction of Hybrid Perovskites4Boosting Self-Trapped Exciton Emission via Interlayer Pillaring in Layered Lead Halide Frameworks1Excitation‐Wavelength‐Dependent Emission of Congruently Melting Iodocuprate Hybrid Materials8Excitation‐Wavelength‐Dependent Emission of Congruently Melting Iodocuprate Hybrid Materials1Direct preparation of PEA 2 PbBr 4 nanoplates with electron-irradiation-induced optical evolution0Dynamic and Underwater X‐ray Imaging Enabled by Instant Ion Exchange of Copper Halide Scintillators6Pressure-induced enhancement of deep-blue photoluminescence in two-dimensional hybrid organic-inorganic perovskites0Halogen Bond‐Driven Reversible Thermochromism in a Two‐Dimensional Hybrid Perovskite0Fluorine-Induced Rigidity and Entropy Effects in Mixed-Halide 2,2-Difluoroethylammonium Cadmium Hybrids0Revisiting the Optical Response of Two-Dimensional Perovskites: Beyond Excitons1Thermally Induced In-Lattice Cation Transformation of 0D Antimony Halides for Improved X-ray Scintillation0Cysteine-Based Hybrid Perovskite Exhibiting Thermally Tunable Dual-Band Photoluminescence0

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  1. Highlighting Recent Research from Latin America in Chemistry of Materials

    Chemistry of Materials · 2022-11-28

    Carlos Toro, Sara E. Skrabalak

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  2. Broadband yellow and white emission from large octahedral tilting in (110)-oriented layered perovskites: imidazolium-methylhydrazinium lead halides

    Journal of Materials Chemistry C · 2023-01-01

    Dawid Drozdowski, Katarzyna Fedoruk, Adam Kabański, Mirosław Mączka, Adam Sieradzki, Anna Gągor

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  3. Lead-free hybrid indium perovskites with near-unity PLQY and white light emission using an Sb 3+ doping strategy

    Inorganic Chemistry Frontiers · 2023-01-01

    Ling-Kun Wu, Renfu Li, Wei‐Yang Wen, Qing-Hua Zou, Heng‐Yun Ye, Jian‐Rong Li

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  4. Revealing the Mechanism of Pressure‐Induced Emission in Layered Silver‐Bismuth Double Perovskites

    Angewandte Chemie International Edition · 2023-02-04

    Long Zhang, Shuoxue Li, Huaiyang Sun, Qiwen Jiang, Yue Wang, Yuanyuan Fang, Ying Shi, Defang Duan, Kai Wang, Hong Yi Jiang, Laizhi Sui, Guorong Wu, Kaijun Yuan, Bo Zou

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  5. Revealing the Mechanism of Pressure‐Induced Emission in Layered Silver‐Bismuth Double Perovskites

    Angewandte Chemie · 2023-02-04

    Long Zhang, Shuoxue Li, Huaiyang Sun, Qiwen Jiang, Yue Wang, Yuanyuan Fang, Ying Shi, Defang Duan, Kai Wang, Hong Yi Jiang, Laizhi Sui, Guorong Wu, Kaijun Yuan, Bo Zou

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  6. Two-Dimensional Hybrid Dion–Jacobson Germanium Halide Perovskites

    Chemistry of Materials · 2023-04-05

    Congcong Chen, Xin Lei Zhao, Ya-Ping Gong, Yang Liu, Zhongwei Chen, Luming Zhang, Jian Chen, Zeyu Deng, Haipeng Lu, Min Luo, Pieremanuele Canepa, Lingling Mao

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  7. Low-Temperature Solution Synthesis of Stable Cs3Cu2Br5 Single Crystals for Visible Light Communications

    ACS Applied Materials & Interfaces · 2023-05-12

    Dehai Liang, Lin Tan, Shirong Lu, Zhe Sun, Huaxin Wang, Wensi Cai, Zhigang Zang

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  8. Mn2+‐Based Luminescent Metal Halides: Syntheses, Properties, and Applications

    Advanced Optical Materials · 2023-05-23

    Dehai Liang, Hongbin Xiao, Wensi Cai, Shirong Lu, Shuangyi Zhao, Zhigang Zang, Lei Xie

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  9. Mixed perovskites (2D/3D)-based solar cells: a review on crystallization and surface modification for enhanced efficiency and stability

    Advanced Composites and Hybrid Materials · 2023-05-24

    Xiaohui Li, Putao Zhang, Shengjun Li, Priyanka S. Wasnik, Junna Ren, Qinglong Jiang, Ben Bin Xu, Vignesh Murugadoss

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  10. Regulation of Luminescence Properties of the Ultrathin Two-Dimensional Halide Perovskite Cs2PbIxCl4−x ( x = 0,1,2,3,4) with Ruddlesden-Popper Structure

    Physical Review Applied · 2023-08-18

    Jun Luo, Biao Liu, Junliang Yang, Meng‐Qiu Cai

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  11. Chemistry in the Molten State: Opportunities for Designing and Tuning the Emission Properties of Halide Perovskites

    Inorganic Chemistry · 2023-08-22

    Feten Hleli, Nicolas Mercier, Maroua Ben Haj Salah, Magali Allain, Nabil Zouari, Florian Massuyeau, Romain Gautier

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  12. Extremely Broad Electroluminescence from a Two-Dimensional Hybrid Perovskite Light-Emitting Diode

    ACS Applied Electronic Materials · 2023-09-25

    Paulina Carmona‐Monroy, Wilson Bernal, Enrique Pérez‐Gutiérrez, María Judith Percino, Diego Solís-Ibarra

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  13. Correlated Self-Trapped Excitons and Free Excitons with Intermediate Exciton–Phonon Coupling in 2D Mixed-Halide Perovskites

    The Journal of Physical Chemistry Letters · 2023-11-01

    Cheng Yang, Qi Wei, Yiyang Gong, Mingzhu Long, Guofu Zhou, Guichuan Xing, Bo Wu

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  14. Lead Halide Hybrids Templated by Two Coordinating Ligands for Enhanced and Stable Self-Trapped Emission

    Inorganic Chemistry · 2023-11-16

    Yukong Li, Jinlin Yin, Honghan Fei

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  15. Distinct Excitonic Emissions in 2D (C7H7N2)2PbX4 (X = Cl, Br) under Compression

    Advanced Science · 2023-11-20

    Hai Zhang, Peijie Zhang, Chenlong Xie, Han Jiang, Bin Xu, Zewei Quan

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  16. Br-Substituent Effect on Photoluminescence and Scintillation Properties of (C6h5c2h4nh3)2pbcl4 Perovskite-Type Compounds

    Journal of Luminescence · 2024-01-01

    Shun Matsuzawa, Kai Okazaki, Daisuke Nakauchi, Naoki Kawano, Takeru Suto, Takumi Kato, Noriaki Kawaguchi, Takayuki Yanagida

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  17. Luminescence regulation of Sb3+ in 0D hybrid metal halides by hydrogen bond network for optical anti-counterfeiting

    Opto-Electronic Advances · 2024-01-01

    Dehai Liang, Saif M. H. Qaid, Xin Yang, Shuangyi Zhao, Binbin Luo, Wensi Cai, Qingkai Qian, Zhigang Zang

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  18. Photoluminescence and Scintillation Characteristics of (Ch3c6h5c2h4nh3)2pbcl4 Single Crystals

    SSRN Electronic Journal · 2024-01-01

    Itsuki Wakabayashi, Keishi Yamabayashi, Daisuke Nakauchi, Kai Okazaki, Naoki Kawano, Takumi Kato, Noriaki Kawaguchi, Takayuki Yanagida

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  19. Broad-Band Emission Switch in Room Temperature Stable Hybrid Perovskite Polymorphs

    Crystal Growth & Design · 2024-02-15

    Clémence Cazals, Nicolas Mercier, Magali Allain, Florian Massuyeau, Romain Gautier

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  20. Phase Transitions and Dynamics in Mixed Three- and Low-Dimensional Lead Halide Perovskites

    Chemical Reviews · 2024-02-29

    Mantas Šimėnas, Anna Gągor, J. Banys, Mirosław Mączka

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  21. Cs2Cd1–xMnxCl4 Nanoplatelets for Thermal Quenching Resistance and Luminescence Tuning

    ACS Applied Nano Materials · 2024-03-30

    Biling Zheng, Bao Ke, Chengzhi Yang, Guolun Zhang, Xiaodong Shen, Weizheng Liang, Xian-Ci Zhong, Bingsuo Zou

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  22. Understanding and Controlling the Photoluminescence Line Shapes of 2D Perovskites with Chiral Methylbenzylammonium-Based Cations

    Chemistry of Materials · 2024-04-16

    Lucas Scalon, Arianne New, Ziyuan Ge, Navendu Mondal, Raquel Dantas Campos, Claudio Quarti, David Beljonne, Ana F. Nogueira, Artem A. Bakulin, Yana Vaynzof

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  23. Stimuli‐responsive photoluminescent copper(I) halides for scintillation, anticounterfeiting, and light‐emitting diode applications

    Aggregate · 2024-05-28

    Dilruba A. Popy, Yashpal Singh, Yauhen V. Tratsiak, Abby M. Cardoza, John Michael Lane, Luis Stand, Mariya Zhuravleva, Neeraj Rai, Bayrammurad Saparov

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  24. Effect of halogen on the luminescence properties of two-dimensional double-perovskite ( C 6 H 16 N 2 ) 2 Ag Bi X 8 ⋅ H 2 O ( X = Cl , Br and I ) with the Dion-Jacobson structure

    Physical Review Applied · 2024-07-25

    Jun Luo, Biao Liu, Junliang Yang, Meng‐Qiu Cai

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  25. Halogen Content Tunes the Color Temperature of White Light and Afterglow in Zero-Dimensional Hybrid Indium Halides

    Chemistry of Materials · 2024-07-25

    Xinluan Song, Sihan Wang, Ye Yang, Yanling Zhou, Xin Huang, Bo Tang, Hongming Liu

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  26. Pressure‐Tuning Localized Excitons Toward Enhanced Emission, Photocurrent Enhancement and Piezochromism in Unconventional ACI‐Type 2D Hybrid Perovskites

    Angewandte Chemie International Edition · 2024-08-07

    Xihan Yu, Yuanyuan Fang, Xuening Sun, Ying Hao Xie, Cailong Liu, Kai Wang, Guanjun Xiao, Bo Zou

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  27. Pressure‐Tuning Localized Excitons Toward Enhanced Emission, Photocurrent Enhancement and Piezochromism in Unconventional ACI‐Type 2D Hybrid Perovskites

    Angewandte Chemie · 2024-08-07

    Xihan Yu, Yuanyuan Fang, Xuening Sun, Ying Hao Xie, Cailong Liu, Kai Wang, Guanjun Xiao, Bo Zou

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  28. Pressure-controlled free exciton and self-trapped exciton emission in quasi-one-dimensional hybrid lead bromides

    Nature Communications · 2024-08-27

    Bin Xu, Yawen Li, Peibin Hong, Peijie Zhang, Han Jiang, Zewen Xiao, Zewei Quan

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  29. Ultra broadband yellow emitting lead-free metal halide perovskite like compounds with near-unity emission quantum yields

    Journal of Materials Chemistry C · 2025-01-01

    Sayed Ali Khan, Noor Zamin Khan, Jahangeer Ahmed, Marcin Runowski, Saad M. Alshehri, Simeon Agathopoulos, Simon J. Teat, Jing Li

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  30. Photoluminescence and radioluminescence characteristics of (CH3C6H5C2H4NH3)2PbCl4 single crystals

    Optical Materials · 2025-05-26

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  31. Controlling Energy Flow in Perovskite Heterostructures Through Dimensionality and Phase Engineering

    Advanced Science · 2025-06-20

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  32. Divalent Methylhydrazinium─An Ultrasmall Organic Cation for Construction of Hybrid Perovskites

    Chemistry of Materials · 2025-07-11

    Mirosław Mączka, Anna Gągor, Dagmara Stefańska, J. Hanuza, E. Kucharska, Jan K. Zaręba

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  33. Boosting Self-Trapped Exciton Emission via Interlayer Pillaring in Layered Lead Halide Frameworks

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  34. Excitation‐Wavelength‐Dependent Emission of Congruently Melting Iodocuprate Hybrid Materials

    Angewandte Chemie International Edition · 2025-08-19

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  35. Excitation‐Wavelength‐Dependent Emission of Congruently Melting Iodocuprate Hybrid Materials

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  36. Direct preparation of PEA 2 PbBr 4 nanoplates with electron-irradiation-induced optical evolution

    Journal of Materials Chemistry C · 2026-01-01

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  37. Dynamic and Underwater X‐ray Imaging Enabled by Instant Ion Exchange of Copper Halide Scintillators

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  38. Pressure-induced enhancement of deep-blue photoluminescence in two-dimensional hybrid organic-inorganic perovskites

    Physical Review Applied · 2026-03-09

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  39. Halogen Bond‐Driven Reversible Thermochromism in a Two‐Dimensional Hybrid Perovskite

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  40. Fluorine-Induced Rigidity and Entropy Effects in Mixed-Halide 2,2-Difluoroethylammonium Cadmium Hybrids

    Inorganic Chemistry · 2026-06-10

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  41. Revisiting the Optical Response of Two-Dimensional Perovskites: Beyond Excitons

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  42. Thermally Induced In-Lattice Cation Transformation of 0D Antimony Halides for Improved X-ray Scintillation

    Inorganic Chemistry · 2026-07-06

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  43. Cysteine-Based Hybrid Perovskite Exhibiting Thermally Tunable Dual-Band Photoluminescence

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