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RESEARCH PAPER · ACS Nano · 2022

Highly Emitting Perovskite Nanocrystals with 2-Year Stability in Water through an Automated Polymer Encapsulation for Bioimaging

Sahitya Kumar Avugadda, Andrea Castelli, Balaji Dhanabalan, Tamara Fernández, Niccolò Silvestri, Cynthia Collantes, Dmitry Baranov, Muhammad Imran, Liberato Manna, Teresa Pellegrino, Milena P. Arciniegas

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Highly Emitting Perovskite Nanocrystals with 2-Year Stability in Water through an Automated Polymer Encapsulation for BioimagingOriginalStable and Recyclable Photocatalysts of CsPbBr3@MSNs Nanocomposites for Photoinduced Electron Transfer RAFT Polymerization47Tuning Phonon Energies in Lanthanide‐doped Potassium Lead Halide Nanocrystals for Enhanced Nonlinearity and Upconversion60Tuning Phonon Energies in Lanthanide‐doped Potassium Lead Halide Nanocrystals for Enhanced Nonlinearity and Upconversion12Biomolecules incorporated in halide perovskite nanocrystals: synthesis, optical properties, and applications15Highly water-stable, luminescent, and monodisperse polymer-coated CsPbBr 3 nanocrystals for imaging in living cells with better sensitivity18Phase engineering of inorganic halide Cs–Pb–Br perovskites for advanced energy conversion19Various approaches to synthesize water-stable halide PeNCs17Stable MAPbBr3@PbBr(OH) composites with high photoluminescence quantum yield: Synthesis, optical properties, formation mechanism, and catalytic application25Perovskite super-particles for commercial displays8Combining π-Conjugation and Cation−π Interaction for Water-Stable and Photoconductive One-Dimensional Hybrid Lead Bromide28Announcing the 2023 ACS Nano Lectureship and ACS Nano Impact Laureates1Advancements in Perovskite Nanocrystal Stability Enhancement: A Comprehensive Review27Multimodal Biofilm Inactivation Using a Photocatalytic Bismuth Perovskite–TiO 2 –Ru(II)polypyridyl-Based Multisite Heterojunction33Water‐Dispersable Silica‐Supported Nanocrystalline Pb‐Free Perovskite Rb 7 Bi 3 Cl 16 @SiO 2 for ATP‐Responsive Bio‐Imaging3Application of Perovskite Nanocrystals as Fluorescent Probes in the Detection of Agriculture- and Food-Related Hazardous Substances16Construction of Tumor Microenvironment‐Responsive Gene Carriers0Aqueous‐Based Inorganic Colloidal Halide Perovskites Customizing Liquid Scintillators46Guidelines for Designing Water‐Stable Hybrid Lead Bromide Perovskites with Broad Emission11Introducing Specific Iodine Ions in Perovskite‐Based Nanocomplex to Cater for Versatile Biomedical Imaging and Tumor Radiotherapy6Exploiting the Photo‐Physical Properties of Metal Halide Perovskite Nanocrystals for Bioimaging19Automated LARP synthesis identifies optimal ligand combinations for perovskite nanocrystal preparation2Designed Polymer Ligands for Perovskite Quantum Dots and Their Block Copolymer Nanocomposites8Highly stable and luminescent formamidinium-based perovskite nanocrystal probe for temperature and mercury sensors and in vitro imaging in live cells19Room temperature synthesis of nanocomposite thin films with embedded Cs 2 AgIn 0.9 Bi 0.1 Cl 6 lead-free double perovskite nanocrystals with long-term water stability, wide range pH tolerance, and high quantum yield3Soft optical materials based on the integration of perovskite nanostructures and block copolymers3Scintillation Properties of CsPbBr3 Nanocrystals Prepared by Ligand-Assisted Reprecipitation and Dual Effect of Polyacrylate Encapsulation toward Scalable Ultrafast Radiation Detectors32Síntesis, estabilización y funcionalización de nanocristales de perovskita de haluros metálicos para su empleo como reveladores y marcadores en histoquímica, cultivos celulares y biosensado0Highly stable fluorescent CsPbBr3 perovskite nanocrystals with reduced in-vitro toxicity for bioimaging and mercury ion detection in cells22Perovskite Nanocrystals: Superior Luminogens for Food Quality Detection Analysis17Encapsulation of Pure Water-Stable Perovskite Nanocrystals (PNCs) into Biological Environment-Stable PNCs for Cell Imaging17Reversible CsPbBr 3 ↔ CsPb 2 Br 5 Transformation via Reverse Micellar Aqueous Solution12Stability of core–shell structure CsPbX3@SiO2 (X = Cl,Br) perovskite quantum dots9Sensing Utilities of Cesium Lead Halide Perovskites and Composites: A Comprehensive Review36Aminoazanium of A-site Cations in Metal-Free Halide Perovskite Single Crystals to Reduce Thermal Expansion for Efficient X-ray Detection11Perovskite nanocrystals (PNCs) served as an emerging optical indicator for food safety and quality assessment: progress, challenges, and opportunities14Stabilization of halide perovskites with silicon compounds for optoelectronic, catalytic, and bioimaging applications40From lab to luminescence: Perovskite-based dimensional integrations pushing LED boundaries24Enhanced Performance of CsPbBr3 Nanocrystals via Dual Passivation8Interplay of Phonon Directionality and Emission Polarization in Two-Dimensional Layered Metal Halide Perovskites17Precise Laser-Modulated Anion Exchange on Ultraflexible Perovskite Films for Multicolor Patterns5Symmetry-Broken Electronic State of CsPbBr3 Cubic Perovskite Nanocrystals4Strategies To Achieve Long-Term Stability in Lead Halide Perovskite Nanocrystals and Its Optoelectronic Applications62Fe3+ Assisted Synthesis of Stable 3D‐in‐2D CsPbBr3/CsPb2Br5 Nanocomposites for Optical Gain Media2Dual-phase Cs4PbBr6/CsPbBr3 perovskite quantum dot borosilicate glass for WLED applications7Water-Stable Perovskite Nanocrystals to Overcome the Photocatalysis–Stability Trade-Off in Aqueous Photo-RAFT Polymerization15Interactions between H2O and lead halide perovskites: Recent progress and applications54Phospholipid micelles-encapsulated perovskite nanocrystals via dual solvent exchange for human hela cervical cancer cells imaging0Amino acid assisted aqueous synthesis of highly stable CsPbBr 3 nanocrystals for cell imaging2Homogenous luminescent perovskite-acrylate based films with self-wrinkling patterned surface for flexible full-color backlight display2Impact of Peptide‐Based Supramolecular Gels on the Passivation and Optical Properties of CsPbBr 3 Nanocrystals for Photocatalytic Dye Degradation in Water8High-performance optoelectronics enabled by solution-based sintering of perovskite nanocrystals0Complex Core–Shell Architectures through Spatially Organized Nano-Assemblies6Noble Metal Coating on Perovskite Microcrystals for Robust and Plasmonic Lasing Applications7Research Progress of Halide Perovskite Nanocrystals in Biomedical Applications: A Review10Synergistic Integration of Halide Perovskite and Rare‐Earth Ions toward Photonics55Spectral regulation of Sn/Br-co-doped perovskite nanocrystalline glass0Metal halide perovskite quantum dots for Biological applications: Properties, advances, and challenges13Aqueous Colloidal Perovskite Quantum Emitters10Advancing perovskite light-emitting diodes: Multifunctional role of polymer, organic, and inorganic ligands in stability and efficiency enhancement10Emerging nanoparticle-based strategies for advanced cancer imaging and diagnosis20Na–Cu-Codoped Halide Perovskite Nanocrystals Encapsulated in Pb(OH)I with Stable Red-Orange Emission: Implications for Optoelectronic Applications2Fully Aqua‐Mediated Ripening of Perovskite Quantum Dots with 98% PLQY and Self‐Assembly into Bioimaging Nanoparticles9Terminal Group‐Determined and Dendrimer‐Encapsulated Perovskite Probes for High‐Contrast Biomedical Imaging2Water‐Influenced Perovskite Materials: Crystal Transition, Stability Regulation, and Applications5Exploring the Photocatalytic Potential of Lead-Free Cs2AgxNa1–xBiCl6 Double Perovskites: Influence of Ag/Na Composition and Nanocrystalline Heterojunction Formation Induced by In Situ Water Interaction4Highly Efficient Noble‐Metal Free Photocatalytic Hydrogen Generation Using Water‐Stable 4,4′‐Vinylenedipyridine‐Based Halide Perovskites2Cs3Bi2Br9 QDs/BiOBr heterojunction photoelectrochemical biosensor with APE1 enzyme-driven bipedal DNA walker signal amplification for miRNA-320d detection9Polymer‐Templated In Situ Growth of Centimeter‐Scale Perovskite Nanocrystal Arrays with Ultrasmall Pixel Size and High Stability2Polymer‐Templated In Situ Growth of Centimeter‐Scale Perovskite Nanocrystal Arrays with Ultrasmall Pixel Size and High Stability1Ultrastable Perovskite Quantum Dots for Enhanced Bioimaging1Beyond Surface Facets and Morphology: Precision Silica Shelling for Enhanced Luminescence and Stability in Halide Perovskite Nanocrystals12Aqueous Solution Printed Low‐Threshold Two‐Photon Pumped Flexible Quasi‐2D Perovskite Amplified Spontaneous Emission Arrays3Recent advances in stable halide perovskite nanocrystals for optoelectronic devices, biological imaging, and X-ray detection12How to Slow Down the Phase Transformation of CsPbBr 3 Nanocrystals in an Aqueous Medium? Playing with Metal-Ion Hydration Energy0Perovskite Nanocrystals, Quantum Dots, and Two-Dimensional Structures: Synthesis, Optoelectronics, Quantum Technologies, and Biomedical Imaging12Perspective on water-induced colloidal CsPbBr 3 metal halide perovskites and their non-perovskite derivatives0Unravelling precursor-memory effects in doped Cs 2 ZnCl 4 -based metal-halide solutions0Water-dispersible perovskite nanocrystals: synthesis strategies, ion sensing applications, and future prospects2基于超表面的手性发光研究进展（特邀）0Effects of Additives on the Mediated Synthesis of CsPbBr 3 Nanocrystals via Soft Colloidal Templates of Block Copolymer Micelles1Ligand Engineering of Ultrasmall CsPbI 3 Quantum Dots via In Situ S N 2 Substitution Enables Bright Rec. 2020 Pure‐Red Perovskite LEDs with Exceptional Current Efficiency5Halide Perovskite Photocatalysts in Action: Integrating Photostability, Solvent Robustness, and Surface Charge Management5Polar Opposites: Ligand-Mediated Polarity Inversion for Perovskite Quantum Dots with Sub-Nanometer Ligand Shells2A Water-Dispersible Perovskite-Magnetic Nanocomposite Platform for Efficient Dual-Modal Fluorescence/MR Imaging2Heavy Halide Nanomaterials as Next-Generation Hosts for Lanthanide Upconversion10Bioengineered Protein Stabilized Perovskite Nanoplates in Polar Solvents1Designing Stable Nanoarchitectonics of Metal Halide Perovskite‐Based Materials for Aqueous Electrocatalysis3Optimizing Interfaces Between Mixed‐Halide Perovskite Nanocrystals and Encapsulants Through Ligand Engineering for Stable White Light‐Emitting Diode Applications4Highly Aqueous Stability of Metal Oxides Encapsulated CsPbBr 3 Nanocrystals via A Generalized Core–Shell Engineering0High-performance amphoteric polymer coated lead-free halide perovskite composites: synthesis and application1Perovskite quantum dots: synthesis, stabilization, and hydrophilic modification for bioanalytical applications0Metal-organic framework induced PbBr2 phase transition constructed stable perovskite quantum dots core-shell structure0Metal Halide Perovskite Quantum Dots for Luminescence Sensing and Imaging1Engineering stability in metal halide perovskites: From fundamental strategies to high-performance sensing applications0Ion‐Ligand Synergistic Strategy Enhancing Optical Performance of Perovskite Nanocrystals for Wide Color Gamut Display0An Undergraduate Laboratory Experiment on Lead-Free Tin-Based Perovskites for Phosphor-Converted Light-Emitting Diodes0Photon-engineered nanoplatforms for biophotonics: A comparative review of upconversion and perovskite nanomaterials0Rotor–stator shear processing for recovery of aggregated perovskite nanocrystal dispersions0Water‑induced Phase Transformation for Fluorescence Enhancement of Perovskite Nanocrystals0Multi-armed star-shaped PEG1000-encapsulated Mn2+:CsPbCl3 perovskite quantum dots for sensitive detection of crystal violet0

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  1. Stable and Recyclable Photocatalysts of CsPbBr3@MSNs Nanocomposites for Photoinduced Electron Transfer RAFT Polymerization

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  2. Tuning Phonon Energies in Lanthanide‐doped Potassium Lead Halide Nanocrystals for Enhanced Nonlinearity and Upconversion

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  4. Biomolecules incorporated in halide perovskite nanocrystals: synthesis, optical properties, and applications

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  8. Stable MAPbBr3@PbBr(OH) composites with high photoluminescence quantum yield: Synthesis, optical properties, formation mechanism, and catalytic application

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  10. Combining π-Conjugation and Cation−π Interaction for Water-Stable and Photoconductive One-Dimensional Hybrid Lead Bromide

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  14. Water‐Dispersable Silica‐Supported Nanocrystalline Pb‐Free Perovskite Rb 7 Bi 3 Cl 16 @SiO 2 for ATP‐Responsive Bio‐Imaging

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  46. Interactions between H2O and lead halide perovskites: Recent progress and applications

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  47. Phospholipid micelles-encapsulated perovskite nanocrystals via dual solvent exchange for human hela cervical cancer cells imaging

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  48. Amino acid assisted aqueous synthesis of highly stable CsPbBr 3 nanocrystals for cell imaging

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  49. Homogenous luminescent perovskite-acrylate based films with self-wrinkling patterned surface for flexible full-color backlight display

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  50. Impact of Peptide‐Based Supramolecular Gels on the Passivation and Optical Properties of CsPbBr 3 Nanocrystals for Photocatalytic Dye Degradation in Water

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