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RESEARCH PAPER · Angewandte Chemie · 2007

Self‐Assembly of Polyoxo Clusters and Extended Frameworks by Controlled Hydrolysis of Low‐Valent Uranium

Grégory Nocton, Fabien Burdet, Jacques Pécaut, Marinella Mazzanti

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Self‐Assembly of Polyoxo Clusters and Extended Frameworks by Controlled Hydrolysis of Low‐Valent UraniumOriginalA Nitrido‐Centered Uranium Azido Cluster Obtained from a Uranium Azide119A Nitrido‐Centered Uranium Azido Cluster Obtained from a Uranium Azide23Mixed Valency in a Uranium Multimetallic Complex58Mixed Valency in a Uranium Multimetallic Complex12Polyimido Uranium(IV) Clusters: Imidometalates with an M7(μ3‐N)6(μ2‐N)6 Core Analogous to the Anderson‐Type Polyoxometalate Motif31Polyimido Uranium(IV) Clusters: Imidometalates with an M7(μ3‐N)6(μ2‐N)6 Core Analogous to the Anderson‐Type Polyoxometalate Motif91,4‐Dicyanobenzene as a Scaffold for the Preparation of Bimetallic Actinide Complexes Exhibiting Metal–Metal Communication54Polyimido Clusters of Neodymium and Uranium, Including a Cluster with an M6(μ3‐N)8 Core35Stable Pentavalent Uranyl Species and Selective Assembly of a Polymetallic Mixed‐Valent Uranyl Complex by Cation–Cation Interactions114Stable Pentavalent Uranyl Species and Selective Assembly of a Polymetallic Mixed‐Valent Uranyl Complex by Cation–Cation Interactions32Tetranuclear Uranium Clusters by Reductive Cleavage of 3,5‐Dimethylpyrazolate20Tetranuclear Uranium Clusters by Reductive Cleavage of 3,5‐Dimethylpyrazolate6Base‐Driven Assembly of Large Uranium Oxo/Hydroxo Clusters78Base‐Driven Assembly of Large Uranium Oxo/Hydroxo Clusters22Three‐Dimensional MOF‐Type Architectures with Tetravalent Uranium Hexanuclear Motifs (U6O8)127Ex‐Situ Kinetic Investigations of the Formation of the Poly‐Oxo Cluster U3827First Evidence of a Water‐Soluble Plutonium(IV) Hexanuclear Cluster37The Key Role of U 28 in the Aqueous Self‐Assembly of Uranyl Peroxide Nanocages49Isolation of a Star‐Shaped Uranium(V/VI) Cluster from the Anaerobic Photochemical Reduction of Uranyl(VI)29Isolation of a Star‐Shaped Uranium(V/VI) Cluster from the Anaerobic Photochemical Reduction of Uranyl(VI)11Coordination of Tetravalent Actinides (An=ThIV, UIV, NpIV, PuIV) with DOTA: From Dimers to Hexamers72One-dimensional chain structures of hexanuclear uranium( iv ) clusters bridged by formate ligands9Solution and Solid State Structural Chemistry of Th(IV) and U(IV) 4-Hydroxybenzoates42Structural Snapshots of Cluster Growth from {U6} to {U38} During the Hydrolysis of UCl439Structural Snapshots of Cluster Growth from {U6} to {U38} During the Hydrolysis of UCl46Extension of the Plutonium Oxide Nanocluster Family to Include {Pu16} and {Pu22}43Mononuclear to Polynuclear UIV Structural Units: Effects of Reaction Conditions on U‐Furoate Phase Formation23Intrinsic Semiconducting Behavior in a Large Mixed‐Valent Uranium(V/VI) Cluster64Intrinsic Semiconducting Behavior in a Large Mixed‐Valent Uranium(V/VI) Cluster4Aqueous Speciation of Tetravalent Actinides in the Presence of Chloride and Nitrate Ligands8

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  1. A Nitrido‐Centered Uranium Azido Cluster Obtained from a Uranium Azide

    Angewandte Chemie International Edition · 2008-03-10

    Grégory Nocton, Jacques Pécaut, Marinella Mazzanti

    Read original paper ↗ ·

  2. A Nitrido‐Centered Uranium Azido Cluster Obtained from a Uranium Azide

    Angewandte Chemie · 2008-03-10

    Grégory Nocton, Jacques Pécaut, Marinella Mazzanti

    Read original paper ↗ ·

  3. Mixed Valency in a Uranium Multimetallic Complex

    Angewandte Chemie International Edition · 2008-03-12

    Eric J. Schelter, Ruilian Wu, Brian L. Scott, Joe D. Thompson, David E. Morris, Jaqueline L. Kiplinger

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  4. Mixed Valency in a Uranium Multimetallic Complex

    Angewandte Chemie · 2008-03-12

    Eric J. Schelter, Ruilian Wu, Brian L. Scott, Joe D. Thompson, David E. Morris, Jaqueline L. Kiplinger

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  5. Polyimido Uranium(IV) Clusters: Imidometalates with an M7(μ3‐N)6(μ2‐N)6 Core Analogous to the Anderson‐Type Polyoxometalate Motif

    Angewandte Chemie International Edition · 2008-06-23

    J.‐C. Berthet, P. Thuéry, M. Ephritikhine

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  6. Polyimido Uranium(IV) Clusters: Imidometalates with an M7(μ3‐N)6(μ2‐N)6 Core Analogous to the Anderson‐Type Polyoxometalate Motif

    Angewandte Chemie · 2008-06-23

    J.‐C. Berthet, P. Thuéry, M. Ephritikhine

    Read original paper ↗ ·

  7. 1,4‐Dicyanobenzene as a Scaffold for the Preparation of Bimetallic Actinide Complexes Exhibiting Metal–Metal Communication

    Chemistry - A European Journal · 2008-08-07

    Eric J. Schelter, Jacqueline M. Veauthier, Christopher R. Graves, Kevin D. John, Brian L. Scott, Joe D. Thompson, Jaime A. Pool, David E. Morris, Jaqueline L. Kiplinger

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  8. Polyimido Clusters of Neodymium and Uranium, Including a Cluster with an M6(μ3‐N)8 Core

    European Journal of Inorganic Chemistry · 2008-11-04

    J.‐C. Berthet, P. Thuéry, M. Ephritikhine

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  9. Stable Pentavalent Uranyl Species and Selective Assembly of a Polymetallic Mixed‐Valent Uranyl Complex by Cation–Cation Interactions

    Angewandte Chemie International Edition · 2009-09-08

    Victor Mougel, Paweł Horeglad, Grégory Nocton, Jacques Pécaut, Marinella Mazzanti

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  10. Stable Pentavalent Uranyl Species and Selective Assembly of a Polymetallic Mixed‐Valent Uranyl Complex by Cation–Cation Interactions

    Angewandte Chemie · 2009-09-08

    Victor Mougel, Paweł Horeglad, Grégory Nocton, Jacques Pécaut, Marinella Mazzanti

    Read original paper ↗ ·

  11. Tetranuclear Uranium Clusters by Reductive Cleavage of 3,5‐Dimethylpyrazolate

    Angewandte Chemie International Edition · 2010-03-02

    Jeffrey D. Rinehart, Stosh A. Kozimor, Jeffrey R. Long

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  12. Tetranuclear Uranium Clusters by Reductive Cleavage of 3,5‐Dimethylpyrazolate

    Angewandte Chemie · 2010-03-02

    Jeffrey D. Rinehart, Stosh A. Kozimor, Jeffrey R. Long

    Read original paper ↗ ·

  13. Base‐Driven Assembly of Large Uranium Oxo/Hydroxo Clusters

    Angewandte Chemie International Edition · 2011-05-12

    Biplab Biswas, Victor Mougel, Jacques Pécaut, Marinella Mazzanti

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  14. Base‐Driven Assembly of Large Uranium Oxo/Hydroxo Clusters

    Angewandte Chemie · 2011-05-12

    Biplab Biswas, Victor Mougel, Jacques Pécaut, Marinella Mazzanti

    Read original paper ↗ ·

  15. Three‐Dimensional MOF‐Type Architectures with Tetravalent Uranium Hexanuclear Motifs (U6O8)

    Chemistry - A European Journal · 2013-01-16

    Clément Falaise, Christophe Volkringer, Jean‐François Vigier, Natacha Henry, A. Beaurain, Thierry Loiseau

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  16. Ex‐Situ Kinetic Investigations of the Formation of the Poly‐Oxo Cluster U38

    Chemistry - A European Journal · 2015-09-29

    Clément Falaise, Christophe Volkringer, Christoph Hennig, Thierry Loiseau

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  17. First Evidence of a Water‐Soluble Plutonium(IV) Hexanuclear Cluster

    European Journal of Inorganic Chemistry · 2016-07-08

    Christelle Tamain, Thomas Dumas, Dominique Guillaumont, Christoph Hennig, Philippe Guilbaud

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  18. The Key Role of U 28 in the Aqueous Self‐Assembly of Uranyl Peroxide Nanocages

    Chemistry - A European Journal · 2016-08-19

    Clément Falaise, May Nyman

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  19. Isolation of a Star‐Shaped Uranium(V/VI) Cluster from the Anaerobic Photochemical Reduction of Uranyl(VI)

    Angewandte Chemie International Edition · 2016-10-14

    Lucile Chatelain, Sarah White, Rosario Scopelliti, Marinella Mazzanti

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  20. Isolation of a Star‐Shaped Uranium(V/VI) Cluster from the Anaerobic Photochemical Reduction of Uranyl(VI)

    Angewandte Chemie · 2016-10-14

    Lucile Chatelain, Sarah White, Rosario Scopelliti, Marinella Mazzanti

    Read original paper ↗ ·

  21. Coordination of Tetravalent Actinides (An=ThIV, UIV, NpIV, PuIV) with DOTA: From Dimers to Hexamers

    Chemistry - A European Journal · 2017-03-10

    Christelle Tamain, Thomas Dumas, Christoph Hennig, Philippe Guilbaud

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  22. One-dimensional chain structures of hexanuclear uranium( iv ) clusters bridged by formate ligands

    RSC Advances · 2018-01-01

    Jie Ling, Huangjie Lu, Yaxing Wang, Kenndra Johnson, Shuao Wang

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  23. Solution and Solid State Structural Chemistry of Th(IV) and U(IV) 4-Hydroxybenzoates

    Inorganic Chemistry · 2018-06-07

    Nicole A. Vanagas, Jennifer N. Wacker, Christopher L. Rom, Elliot N. Glass, Ian Colliard, Yusen Qiao, Jeffery A. Bertke, Edward Van Keuren, Eric J. Schelter, May Nyman, Karah E. Knope

    Read original paper ↗ ·

  24. Structural Snapshots of Cluster Growth from {U6} to {U38} During the Hydrolysis of UCl4

    Angewandte Chemie International Edition · 2019-01-02

    Lucile Chatelain, Radmila Faizova, Farzaneh Fadaei‐Tirani, Jacques Pécaut, Marinella Mazzanti

    Read original paper ↗ ·

  25. Structural Snapshots of Cluster Growth from {U6} to {U38} During the Hydrolysis of UCl4

    Angewandte Chemie · 2019-01-02

    Lucile Chatelain, Radmila Faizova, Farzaneh Fadaei‐Tirani, Jacques Pécaut, Marinella Mazzanti

    Read original paper ↗ ·

  26. Extension of the Plutonium Oxide Nanocluster Family to Include {Pu16} and {Pu22}

    Chemistry - A European Journal · 2019-01-03

    Ginger E. Sigmon, Amy E. Hixon

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  27. Mononuclear to Polynuclear UIV Structural Units: Effects of Reaction Conditions on U‐Furoate Phase Formation

    Chemistry - A European Journal · 2020-01-30

    Nicole A. Vanagas, Robert F. Higgins, Jennifer N. Wacker, Dane Romar C. Asuigui, Evan Warzecha, Stosh A. Kozimor, Sarah L. Stoll, Eric J. Schelter, Jeffery A. Bertke, Karah E. Knope

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  28. Intrinsic Semiconducting Behavior in a Large Mixed‐Valent Uranium(V/VI) Cluster

    Angewandte Chemie International Edition · 2021-02-17

    Mingxing Zhang, Chengyu Liang, Guo‐Dong Cheng, Junchang Chen, Yumin Wang, Yumin Wang, Linwei He, Liwei Cheng, Shicheng Gong, Duo Zhang, Jiong Li, Shu‐Xian Hu, Juan Diwu, Guozhong Wu, Yaxing Wang, Yaxing Wang, Zhifang Chai, Shuao Wang

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  29. Intrinsic Semiconducting Behavior in a Large Mixed‐Valent Uranium(V/VI) Cluster

    Angewandte Chemie · 2021-02-17

    Mingxing Zhang, Chengyu Liang, Guo‐Dong Cheng, Junchang Chen, Yumin Wang, Yumin Wang, Linwei He, Liwei Cheng, Shicheng Gong, Duo Zhang, Jiong Li, Shu‐Xian Hu, Juan Diwu, Guozhong Wu, Yaxing Wang, Yaxing Wang, Zhifang Chai, Shuao Wang

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  30. Aqueous Speciation of Tetravalent Actinides in the Presence of Chloride and Nitrate Ligands

    Inorganic Chemistry · 2022-09-01

    Rameswar Bhattacharjee, Pere Miró

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