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RESEARCH PAPER · Angewandte Chemie · 2007

Reduction of Phenyl Silyl Acetylenes with Lithium: Unexpected Formation of a Dilithium Dibenzopentalenide

Masaichi Saito, Michio Nakamura, Tomoyuki Tajima, Michikazu Yoshioka

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33 direct citing papers in this saved network. Explore the next layer with second-order citations.

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42 direct citing works

Reduction of Phenyl Silyl Acetylenes with Lithium: Unexpected Formation of a Dilithium DibenzopentalenideOriginalTandem SiC and CH Activation for Decamethylhafnocene and Bis(trimethylsilyl)acetylene29Tandem‐Aktivierung von Si‐C‐ und C‐H‐Bindungen bei Decamethylhafnocen und Bis(trimethylsilyl)acetylen12Aromaticity of Group 14 Organometallics: Experimental Aspects200Aromatizität von metallorganischen Verbindungen mit Gruppe‐14‐Elementen: experimentelle Aspekte57New Reactions of a Dibenzo[a,e]pentalene74An Extremely Simple Dibenzopentalene Synthesis from 2‐Bromo‐1‐ethynylbenzenes Using Nickel(0) Complexes: Construction of Its Derivatives with Various Functionalities126Isolation, Structural Characterization, and Synthetic Application of Oxycyclopentadienyl Dianions42Isolation, Structural Characterization, and Synthetic Application of Oxycyclopentadienyl Dianions15Heavy Analogs of Aromatic Compounds1Dinaphthopentalenes: Pentalene Derivatives for Organic Thin‐Film Transistors196Dinaphthopentalenes: Pentalene Derivatives for Organic Thin‐Film Transistors701,4‐Diiodo‐1,3‐dienes: Versatile Reagents in Organic Synthesis29An Indenone Synthesis Involving a New Aminotransfer Reaction and Its Application to Dibenzopentalene Synthesis28Molecular Structure and Electronic State of the Dibenzo[a,e]pentalene Anion Radical22Gold‐Catalyzed Synthesis of Dibenzopentalenes – Evidence for Gold Vinylidenes275C–H activation route to dibenzo[a,e]pentalenes: annulation of arylacetylenes promoted by PdCl2–AgOTf–o-chloranil115Dibenzopentalenes from B(C6F5)3‐Induced Cyclization Reactions of 1,2‐Bis(phenylethynyl)benzenes114Dibenzopentalenes from B(C6F5)3‐Induced Cyclization Reactions of 1,2‐Bis(phenylethynyl)benzenes40Barium Dibenzopentalenide as a Main‐Group Metal η8 Complex: Facile Synthesis from 1,4‐Dilithio‐1,3‐butadienes and Ba[N(SiMe3)2]2, Structural Characterization, and Reaction Chemistry52Barium Dibenzopentalenide as a Main‐Group Metal η8 Complex: Facile Synthesis from 1,4‐Dilithio‐1,3‐butadienes and Ba[N(SiMe3)2]2, Structural Characterization, and Reaction Chemistry19Synthesis, Structure, and Reactivity of Lewis Base Stabilized Plumbacyclopentadienylidenes34The B(C6F5)3 Boron Lewis Acid Route to Arene‐Annulated Pentalenes41Facile Synthesis of Dibenzopentalene Dianions and Their Application as New π‐Extended Ligands19π‐Extended Pentalenes: The Revival of the Old Compound from New Standpoints57Facile Synthesis of Polycyclic Pentalenes with Enhanced Hückel Antiaromaticity99Facile Synthesis of Polycyclic Pentalenes with Enhanced Hückel Antiaromaticity31Reactions of Dilithium Dibenzopentalenides with Cr(CO)3(CH3CN)3: Unexpected Formation of a Cubic Tetramer of an Anionic Hydrodibenzopentalenyl Complex2Synthesis and Structures of Sterically Encumbered Group 14 Monolithio Compounds and Unexpected Differences in Their Reactivity8Electronic Push–Pull Modulation by Peripheral Substituents in Pentaaryl Boroles23Dithieno[a,e]pentalenes: Highly Antiaromatic Yet Stable π‐Electron Systems without Bulky Substituents44Aromatic Metamorphosis of Thiophenes by Means of Desulfurative Dilithiation34Cations and Anions of Dibenzo[a,e]pentalene and Reduction of a Dibenzo[a,e]pentalenophane23Assessing an Elusive 3,4‐Dimethyl‐Chloroborole3

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33 direct citing papers saved.

  1. Tandem SiC and CH Activation for Decamethylhafnocene and Bis(trimethylsilyl)acetylene

    Angewandte Chemie International Edition · 2007-07-06

    Torsten Beweries, V.V. Burlakov, Marc A. Bach, Stephan Peitz, Perdita Arndt, Wolfgang Baumann, Anke Spannenberg, Uwe Rosenthal, Biswarup Pathak, Eluvathingal D. Jemmis

    Read original paper ↗ ·

  2. Tandem‐Aktivierung von Si‐C‐ und C‐H‐Bindungen bei Decamethylhafnocen und Bis(trimethylsilyl)acetylen

    Angewandte Chemie · 2007-07-06

    Torsten Beweries, V.V. Burlakov, Marc A. Bach, Stephan Peitz, Perdita Arndt, Wolfgang Baumann, Anke Spannenberg, Uwe Rosenthal, Biswarup Pathak, Eluvathingal D. Jemmis

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  3. Aromaticity of Group 14 Organometallics: Experimental Aspects

    Angewandte Chemie International Edition · 2007-08-02

    Vladimir Ya. Lee, Akira Sekiguchi

    Read original paper ↗ ·

  4. Aromatizität von metallorganischen Verbindungen mit Gruppe‐14‐Elementen: experimentelle Aspekte

    Angewandte Chemie · 2007-08-02

    Vladimir Ya. Lee, Akira Sekiguchi

    Read original paper ↗ ·

  5. New Reactions of a Dibenzo[a,e]pentalene

    Chemistry - A European Journal · 2008-06-09

    Masaichi Saito, Michio Nakamura, Tomoyuki Tajima

    Read original paper ↗ ·

  6. An Extremely Simple Dibenzopentalene Synthesis from 2‐Bromo‐1‐ethynylbenzenes Using Nickel(0) Complexes: Construction of Its Derivatives with Various Functionalities

    Chemistry - A European Journal · 2009-02-02

    Takeshi Kawase, Akihito Konishi, Yasukazu Hirao, Kouzou Matsumoto, Hiroyuki Kurata, Takashi Kubo

    Read original paper ↗ ·

  7. Isolation, Structural Characterization, and Synthetic Application of Oxycyclopentadienyl Dianions

    Angewandte Chemie International Edition · 2009-09-22

    Lantao Liu, Wen‐Xiong Zhang, Chao Wang, Congyang Wang, Zhenfeng Xi

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  8. Isolation, Structural Characterization, and Synthetic Application of Oxycyclopentadienyl Dianions

    Angewandte Chemie · 2009-09-22

    Lantao Liu, Wen‐Xiong Zhang, Chao Wang, Congyang Wang, Zhenfeng Xi

    Read original paper ↗ ·

  9. Heavy Analogs of Aromatic Compounds

    Unknown journal · 2010-07-21

    Vladimir Ya. Lee, Akira Sekiguchi

    Read original paper ↗ ·

  10. Dinaphthopentalenes: Pentalene Derivatives for Organic Thin‐Film Transistors

    Angewandte Chemie International Edition · 2010-09-10

    Takeshi Kawase, Takeru Fujiwara, Chitoshi Kitamura, Akihito Konishi, Yasukazu Hirao, Kouzou Matsumoto, Hiroyuki Kurata, Takashi Kubo, Shoji Shinamura, Hiroki Mori, Eigo Miyazaki, Kazuo Takimiya

    Read original paper ↗ ·

  11. Dinaphthopentalenes: Pentalene Derivatives for Organic Thin‐Film Transistors

    Angewandte Chemie · 2010-09-10

    Takeshi Kawase, Takeru Fujiwara, Chitoshi Kitamura, Akihito Konishi, Yasukazu Hirao, Kouzou Matsumoto, Hiroyuki Kurata, Takashi Kubo, Shoji Shinamura, Hiroki Mori, Eigo Miyazaki, Kazuo Takimiya

    Read original paper ↗ ·

  12. 1,4‐Diiodo‐1,3‐dienes: Versatile Reagents in Organic Synthesis

    Chemistry - An Asian Journal · 2010-09-17

    Valentine P. Ananikov, Oleg Vladimirovich Khazipov, I. P. Beletskaya

    Read original paper ↗ ·

  13. An Indenone Synthesis Involving a New Aminotransfer Reaction and Its Application to Dibenzopentalene Synthesis

    European Journal of Organic Chemistry · 2011-07-13

    Kenta Katsumoto, Chitoshi Kitamura, Takeshi Kawase

    Read original paper ↗ ·

  14. Molecular Structure and Electronic State of the Dibenzo[a,e]pentalene Anion Radical

    Chemistry - An Asian Journal · 2012-01-13

    Masaichi Saito, Yoko Hashimoto, Tomoyuki Tajima, Kazuya Ishimura, Shigeru Nagase, Mao Minoura

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  15. Gold‐Catalyzed Synthesis of Dibenzopentalenes – Evidence for Gold Vinylidenes

    Advanced Synthesis & Catalysis · 2012-02-23

    A. Stephen K. Hashmi, M. Wieteck, Ingo Braun, Pascal Nösel, Linda S. Jongbloed, Matthias Rudolph, Frank Röminger

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  16. C–H activation route to dibenzo[a,e]pentalenes: annulation of arylacetylenes promoted by PdCl2–AgOTf–o-chloranil

    Chemical Science · 2013-01-01

    Takehisa Maekawa, Yasutomo Segawa, Kenichiro Itami

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  17. Dibenzopentalenes from B(C6F5)3‐Induced Cyclization Reactions of 1,2‐Bis(phenylethynyl)benzenes

    Angewandte Chemie International Edition · 2013-05-06

    Chao Chen, Marcel Harhausen, René Liedtke, Kathrin Bussmann, Aiko Fukazawa, Shigehiro Yamaguchi, Jeffrey L. Petersen, Constantin Gabriel Daniliuc, Roland Fröhlich, Gerald Kehr, Gerhard Erker

    Read original paper ↗ ·

  18. Dibenzopentalenes from B(C6F5)3‐Induced Cyclization Reactions of 1,2‐Bis(phenylethynyl)benzenes

    Angewandte Chemie · 2013-05-06

    Chao Chen, Marcel Harhausen, René Liedtke, Kathrin Bussmann, Aiko Fukazawa, Shigehiro Yamaguchi, Jeffrey L. Petersen, Constantin Gabriel Daniliuc, Roland Fröhlich, Gerald Kehr, Gerhard Erker

    Read original paper ↗ ·

  19. Barium Dibenzopentalenide as a Main‐Group Metal η8 Complex: Facile Synthesis from 1,4‐Dilithio‐1,3‐butadienes and Ba[N(SiMe3)2]2, Structural Characterization, and Reaction Chemistry

    Angewandte Chemie International Edition · 2013-10-01

    Heng Li, Baosheng Wei, Ling Xu, Wen‐Xiong Zhang, Zhenfeng Xi

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  20. Barium Dibenzopentalenide as a Main‐Group Metal η8 Complex: Facile Synthesis from 1,4‐Dilithio‐1,3‐butadienes and Ba[N(SiMe3)2]2, Structural Characterization, and Reaction Chemistry

    Angewandte Chemie · 2013-10-01

    Heng Li, Baosheng Wei, Ling Xu, Wen‐Xiong Zhang, Zhenfeng Xi

    Read original paper ↗ ·

  21. Synthesis, Structure, and Reactivity of Lewis Base Stabilized Plumbacyclopentadienylidenes

    Chemistry - A European Journal · 2013-11-15

    Masaichi Saito, Tomoki Akiba, Misumi Kaneko, Toshiaki Kawamura, Minori Abe, Masahiko Hada, Mao Minoura

    Read original paper ↗ ·

  22. The B(C6F5)3 Boron Lewis Acid Route to Arene‐Annulated Pentalenes

    Chemistry - An Asian Journal · 2014-03-28

    Chao Chen, Marcel Harhausen, Aiko Fukazawa, Shigehiro Yamaguchi, Roland Fröhlich, Constantin Gabriel Daniliuc, Jeffrey L. Petersen, Gerald Kehr, Gerhard Erker

    Read original paper ↗ ·

  23. Facile Synthesis of Dibenzopentalene Dianions and Their Application as New π‐Extended Ligands

    Chemistry - A European Journal · 2014-05-07

    Takuya Kuwabara, Kazuya Ishimura, Takahiro Sasamori, Norihiro Tokitoh, Masaichi Saito

    Read original paper ↗ ·

  24. π‐Extended Pentalenes: The Revival of the Old Compound from New Standpoints

    The Chemical Record · 2015-04-20

    Takeshi Kawase, Jun‐ichi Nishida

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  25. Facile Synthesis of Polycyclic Pentalenes with Enhanced Hückel Antiaromaticity

    Angewandte Chemie International Edition · 2017-01-09

    Hiroya Oshima, Aiko Fukazawa, Shigehiro Yamaguchi

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  26. Facile Synthesis of Polycyclic Pentalenes with Enhanced Hückel Antiaromaticity

    Angewandte Chemie · 2017-01-09

    Hiroya Oshima, Aiko Fukazawa, Shigehiro Yamaguchi

    Read original paper ↗ ·

  27. Reactions of Dilithium Dibenzopentalenides with Cr(CO)3(CH3CN)3: Unexpected Formation of a Cubic Tetramer of an Anionic Hydrodibenzopentalenyl Complex

    ChemPlusChem · 2017-03-14

    Takuya Kuwabara, Nobuaki Kurokawa, Masaichi Saito

    Read original paper ↗ ·

  28. Synthesis and Structures of Sterically Encumbered Group 14 Monolithio Compounds and Unexpected Differences in Their Reactivity

    European Journal of Inorganic Chemistry · 2017-09-06

    Lucian‐Cristian Pop, Nobuaki Kurokawa, Hiroaki Ebata, Katsuya Tomizawa, Tomoyuki Tajima, Masaichi Saito

    Read original paper ↗ ·

  29. Electronic Push–Pull Modulation by Peripheral Substituents in Pentaaryl Boroles

    Chemistry - A European Journal · 2019-03-12

    Tobias Heitkemper, Christian P. Sindlinger

    Read original paper ↗ ·

  30. Dithieno[a,e]pentalenes: Highly Antiaromatic Yet Stable π‐Electron Systems without Bulky Substituents

    Chemistry - A European Journal · 2020-10-20

    Junichi Usuba, Masahiro Hayakawa, Shigehiro Yamaguchi, Aiko Fukazawa

    Read original paper ↗ ·

  31. Aromatic Metamorphosis of Thiophenes by Means of Desulfurative Dilithiation

    Chemistry - A European Journal · 2020-12-22

    Atsushi Kaga, Hirokazu Iida, Shun Tsuchiya, Hayate Saito, Koji Nakano, Hideki Yorimitsu

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  32. Cations and Anions of Dibenzo[a,e]pentalene and Reduction of a Dibenzo[a,e]pentalenophane

    Chemistry - A European Journal · 2021-01-15

    Mathias Hermann, Tobias Böttcher, Marcel Schorpp, Sabine Richert, Daniel Wassy, Ingo Krossing, Birgit Esser

    Read original paper ↗ ·

  33. Assessing an Elusive 3,4‐Dimethyl‐Chloroborole

    European Journal of Inorganic Chemistry · 2022-07-11

    Maxim Golfmann, Christian P. Sindlinger

    Read original paper ↗ ·
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