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RESEARCH PAPER · Chemistry of Materials · 2022

Multiple Anion Chemistry for Ionic Layer Thickness Tailoring in Bi2+2nO2+2nSenX2 (X = Cl, Br) van der Waals Semiconductors with Low Thermal Conductivities

Ruiwen Ji, Meng Lei, Cécile Genevois, Wenda Zhang, Xing Ming, Lunhua He, Mathieu M. B. Allix, Congling Yin, Xiaojun Kuang, Xianran Xing

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Multiple Anion Chemistry for Ionic Layer Thickness Tailoring in Bi2+2nO2+2nSenX2 (X = Cl, Br) van der Waals Semiconductors with Low Thermal ConductivitiesOriginalCrystal structure, phase width, and physical properties of the barium tetrel selenides Ba 6 Si 2− x Ge x Se 12 ( x = 0, 0.5, 1, and 1.5) with ultralow thermal conductivity3Thermoelectric Properties of n-Type Bi4O4SeX2 (X = Cl, Br)4Tightly bound and room-temperature-stable excitons in van der Waals degenerate-semiconductor Bi4O4SeCl2 with high charge-carrier density5Charge-balanced codoping enables exceeding doping limit and ultralow thermal conductivity0Synthesis, crystal and electronic structures of two novel tunnel bismuth oxychlorides Bi18O22Cl8.5(BO3)0.5 and Bi18O22Cl8Se2Thermal transport properties of polycrystalline Bi4SeCl2O4 with various texturizations and densities3Tuning the band gap and structure from wide gap SrBi 3 O 4 Cl 3 to narrow gap Bi 4 O 4 SeCl 2 by aliovalent anion substitution2Post-ball-milling-assisted solid-state synthesis of Bi4O4SeCl2: A low thermal conductivity material1Layered Ordered Multianion Semiconductor Bi18O21.6Se1.8Cl7.2 with Low c-Axial Thermal Conductivity0Investigation of a novel selenium-based hybrid material with semiconducting behavior and enhanced dielectric properties5Mixed-anion thermoelectrics: Advanced tuning of electron and phonon transport10Post-annealing effects on (00l) texture, Cl/Se ratio, and electrical and glass-like thermal transport in Bi₄O₄SeCl₂0Flapping vibrations contributed to heat insulation in Cs2ZnI40Suppressing Second-Order Jahn–Teller Distortion of Bi3+ by Smaller Y3+-Substitution in Bi3O4Cl0Enhancing Quasi‐Two‐Dimensional Electronic Structure in Bi 2 O 2 Se via Chlorine Substitution0

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  1. Crystal structure, phase width, and physical properties of the barium tetrel selenides Ba 6 Si 2− x Ge x Se 12 ( x = 0, 0.5, 1, and 1.5) with ultralow thermal conductivity

    Dalton Transactions · 2023-01-01

    Luke T. Menezes, Abdeljalil Assoud, Holger Kleinke

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  2. Thermoelectric Properties of n-Type Bi4O4SeX2 (X = Cl, Br)

    Materials · 2023-06-12

    Tao Wang, Wanghua Hu, Zhefeng Lou, Zhuokai Xu, Xiaohui Yang, Tian Le, Jialu Wang, Xiao Lin

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  3. Tightly bound and room-temperature-stable excitons in van der Waals degenerate-semiconductor Bi4O4SeCl2 with high charge-carrier density

    Communications Materials · 2023-09-04

    Yueshan Xu, Junjie Wang, Bo Su, Jun Deng, Cao Peng, Chunlong Wu, Qinghua Zhang, Lin Gu, Jianlin Luo, Nan Xu, Jiangang Guo, Zhiguo Chen

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  4. Charge-balanced codoping enables exceeding doping limit and ultralow thermal conductivity

    JUSTC · 2024-01-01

    Long Chen, Chun Wang, Lin Wang, Minghao Wang, Yongchun Zhu, Changzheng Wu

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  5. Synthesis, crystal and electronic structures of two novel tunnel bismuth oxychlorides Bi18O22Cl8.5(BO3)0.5 and Bi18O22Cl8Se

    Journal of Solid State Chemistry · 2024-07-06

    Dmitri O. Charkin, Sergey N. Volkov, Alexey N. Kuznetsov∥, Alexey V. Povolotskiy, Anastasiya P. Chernyatieva, Julia S. Mironova, Sergey M. Aksenov

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  6. Thermal transport properties of polycrystalline Bi4SeCl2O4 with various texturizations and densities

    Materials Today Physics · 2024-12-11

    Linjie Wu, Xinyue Zhang, Changyuan Li, Qingyu Bai, Zhiwei Chen, Yanzhong Pei

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  7. Tuning the band gap and structure from wide gap SrBi 3 O 4 Cl 3 to narrow gap Bi 4 O 4 SeCl 2 by aliovalent anion substitution

    Journal of Materials Chemistry C · 2025-01-01

    T. Robinson, A. Safdar, John W. Still, Ieuan David Seymour, Quinn Gibson

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  8. Post-ball-milling-assisted solid-state synthesis of Bi4O4SeCl2: A low thermal conductivity material

    Results in Physics · 2025-01-26

    Nattharika Theekhasuk, Nuttakrit Somdock, Athorn Vora–ud, Iyarat Ounrit, Pichet Limsuwan, Komsilp Kotmool, Rachsak Sakdanuphab, Aparporn Sakulkalavek

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  9. Layered Ordered Multianion Semiconductor Bi18O21.6Se1.8Cl7.2 with Low c-Axial Thermal Conductivity

    Inorganic Chemistry · 2025-06-30

    Zhijun Tu, Wenju Zhou, Zhenghui Fang, Yizhe Liu, Yuting Yang, Shangjie Tian, Shouguo Wang, Xiaofeng Liu, Peiyang Mu, Tianqi Gao, Bo Sun, Huiyang Gou, Xiao Zhang, Hechang Lei

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  10. Investigation of a novel selenium-based hybrid material with semiconducting behavior and enhanced dielectric properties

    Journal of Alloys and Compounds · 2025-11-01

    Hadir Saadaoui, Hadhemi Ben Attia, Mohammed S.M. Abdelbaky, Santiago García-Granda, Mohamed Dammak

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  11. Mixed-anion thermoelectrics: Advanced tuning of electron and phonon transport

    Applied Physics Reviews · 2025-11-18

    Takayoshi Katase, Naoki Sato, Takao Mori

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  12. Post-annealing effects on (00l) texture, Cl/Se ratio, and electrical and glass-like thermal transport in Bi₄O₄SeCl₂

    Journal of Alloys and Compounds · 2026-04-01

    Nuttakrit Somdock, Nattharika Theekhasuk, Athorn Vora–ud, Pichet Limsuwan, Kittisakchai Naemchanthara, Aparporn Sakulkalavek, Rachsak Sakdanuphab, Yongyut Kaewjumras

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  13. Flapping vibrations contributed to heat insulation in Cs2ZnI4

    National Science Review · 2026-05-01

    Linjie Wu, Pengfei Nan, Long Yang, Z Chen, Changyuan Li, Qingyu Bai, Hongzheng Wang, Sui Ting Tai, Chen Wang, Binghui Ge, Yuehua Chen, Luo Jun, Yanzhong Pei

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  14. Suppressing Second-Order Jahn–Teller Distortion of Bi3+ by Smaller Y3+-Substitution in Bi3O4Cl

    Chemistry of Materials · 2026-09-21

    Kosei Takano, Kanta Ogawa, Takafumi Yamamoto

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  15. Enhancing Quasi‐Two‐Dimensional Electronic Structure in Bi 2 O 2 Se via Chlorine Substitution

    Advanced Science · 2026-09-27

    Yong‐Zhen Jiang, Qi‐Xun Wen, Xiang Xu, Su‐Tao Sun, Feng‐Fan Ren, Zi‐Xuan Zhou, Xing‐Yuan You, Kan Yu‐Cheng, Zheng Zhang, Jie‐Yi Liu, Yuzhou Zhao, Zhengtai Liu, Mao Ye, Shu‐Hua Yao, Jian Zhou, Yuehua Chen, Kaihui Liu, Yu‐Lin Chen, Yang‐Yang Lv, Cheng Chen

    Read original paper ↗ ·
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