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RESEARCH PAPER · Chemistry of Materials · 2022

High-Rate Lithium Cycling and Structure Evolution in Mo 4 O 11

Rebecca C. Vincent, Yunkai Luo, Jessica L. Andrews, Arava Zohar, Yucheng Zhou, Qizhang Yan, Eve M. Mozur, Molleigh B. Preefer, Johanna Nelson Weker, Anthony Kevin Cheetham, Jian Shu Luo, Laurent Pilon, Brent C. Melot, Bruce Dunn, Ram Seshadri

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High-Rate Lithium Cycling and Structure Evolution in Mo 4 O 11OriginalR -Nb 2 O 5 has an ‘idealized’ V 2 O 5 structure and Wadsley–Roth-like structural stability during Li-ion battery cycling13Structure and lithium insertion in oxides of molybdenum18Reversible Electrochemical Lithium Cycling in a Vanadium(IV)- and Niobium(V)-Based Wadsley–Roth Phase7Atomic Mo-NC-sourced robust MoO3/C nanocomposite for high-performance Li-ion storage5Molybdenum Oxide Constructed by {Mo6O21}6– Pentagonal Unit Assembly and Its Redox Properties5Controlling Operating Voltages in Molybdenum Oxide Anodes through Inductive Effects3Microcalorimetry electrothermal impedance spectroscopy (ETIS) informs entropy evolution at individual electrodes of PNb9O25 or TiNb2O7 battery cells7Carbon-Assisted Isothermal Close Space Vapor Transport Growth of Mo 4 O 11 and MoO 2 Micro/Nanostructures by in Situ Formation of the Mo(CO) 6 Transport Agent2The ultralong Mo4O11 nanoribbons: Ultrasonic synthesis and topotactic transformation toward high-performance sodium-ion batteries5Structure and Electrochemical Properties of Bronze Phase Materials Containing Two Transition Metals19New Emerging Fast Charging Microscale Electrode Materials10Bifunctional Mo4O11 Nanosheets-Engineered Co-Ni alloy nanowires enable High-Efficiency seawater electrolysis and Zn-Seawater battery22Transforming nanoscale VO2(B) into a scalable sodium-ion electrode5Emerging Capacitive Materials for On-Chip Electronics Energy Storage Technologies10Unraveling oxygen vacancy formation, dynamics and site distribution in MoO 3-x thin films8Anode Materials for High-Power Lithium-Ion Batteries11Electrocatalytic Conversion of Glucose into Renewable Formic Acid Using “Electron‐Withdrawing” MoO3 Support under Mild Conditions6Amorphizing Iron Molybdate as a High‐Capacity Cathode for Lithium Metal Batteries Enabled by Multiple Insertion Reactions in the Metastable Structure3Controlled synthesis of large-area MoS2/MoO2 heterostructure via one-step, two-stage chemical vapor deposition for electrocatalytic hydrogen evolution reaction2In situ Electrochemical Transformation of MoO 2 /Mo 4 O 11 @Mo for High‐Capacity Aqueous Zinc‐Ion Batteries5Ion-dependent electrochemical behavior in shear-structured tungsten oxides2O-vacancy driven structural tuning and enhanced polaron transport in metal/amorphous MoO3 interfaces1Phase-Specific EELS-Derived Optical Onsets and Photoluminescence in α-MoO3 and Orthorhombic γ-Mo4O110Interfacial depletion-zone engineering in MOF-derived MoO3/Mo4O11/Cu2V2O7 enables efficient photocatalytic elimination of imidacloprid in real water matrices0WO3/MoO3 Nanocomposite Thin Films and Heterostructures: Interfacial Synergy for Smart and Sustainable Technologies0

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  1. R -Nb 2 O 5 has an ‘idealized’ V 2 O 5 structure and Wadsley–Roth-like structural stability during Li-ion battery cycling

    Journal of Materials Chemistry A · 2023-01-01

    Kausturi Parui, Alexander D. Lee, Shornam Gandhi, Megan M. Butala

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  2. Structure and lithium insertion in oxides of molybdenum

    APL Materials · 2023-01-01

    Rebecca C. Vincent, Anthony Kevin Cheetham, Ram Seshadri

    Read original paper ↗ ·

  3. Reversible Electrochemical Lithium Cycling in a Vanadium(IV)- and Niobium(V)-Based Wadsley–Roth Phase

    Chemistry of Materials · 2023-04-18

    Erick A. Lawrence, Matthew A. Davenport, Reshma Devi, Zijian Cai, Maxim Avdeev, Jonathan R. Belnap, Jue Liu, Husain F. Alnaser, Alice Ho, Taylor D. Sparks, Gopalakrishnan Sai Gautam, Jared M. Allred, Huiwen Ji

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  4. Atomic Mo-NC-sourced robust MoO3/C nanocomposite for high-performance Li-ion storage

    Science China Materials · 2023-06-06

    Mei Ling Guo, Liyin Huang, Changkai Zhao, Luman He, Yaqun Wang, Gang Dou, Guoxin Zhang, Xiaoming Sun

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  5. Molybdenum Oxide Constructed by {Mo6O21}6– Pentagonal Unit Assembly and Its Redox Properties

    Inorganic Chemistry · 2023-06-09

    Kosuke Shimoda, Satoshi Ishikawa, Mai Miyasawa, Ken‐ichi Shimizu, Wataru Ueda

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  6. Controlling Operating Voltages in Molybdenum Oxide Anodes through Inductive Effects

    Chemistry of Materials · 2023-06-26

    Arava Zohar, Kira E. Wyckoff, Rebecca C. Vincent, Thomas E. Mates, Ram Seshadri

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  7. Microcalorimetry electrothermal impedance spectroscopy (ETIS) informs entropy evolution at individual electrodes of PNb9O25 or TiNb2O7 battery cells

    Electrochimica Acta · 2023-08-23

    Yucheng Zhou, Yunkai Luo, Ashlea R. Patterson, Sun Woong Baek, Matevž Frajnkovič, Ram Seshadri, Bruce Dunn, Laurent Pilon

    Read original paper ↗ ·

  8. Carbon-Assisted Isothermal Close Space Vapor Transport Growth of Mo 4 O 11 and MoO 2 Micro/Nanostructures by in Situ Formation of the Mo(CO) 6 Transport Agent

    The Journal of Physical Chemistry C · 2023-09-27

    O. de Melo, M. Sánchez, Jorge Ricardo Aguilar-Hernandez, Benito Ortega-Nájera, Guillermo Santana, Leon Hamui, Aline Hernández, Yoandris González, Andreas Peter Ruediger, Gerardo Silverio Contreras-Puente

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  9. The ultralong Mo4O11 nanoribbons: Ultrasonic synthesis and topotactic transformation toward high-performance sodium-ion batteries

    Applied Surface Science · 2023-10-09

    Yu Zhou, Zihua Li, Yong Liu, Hai Wang

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  10. Structure and Electrochemical Properties of Bronze Phase Materials Containing Two Transition Metals

    Chemistry of Materials · 2023-10-12

    Yunkai Luo, Etienne Le Calvez, Yucheng Zhou, Éric Gautron, Éric Quarez, Molleigh B. Preefer, Olivier Crosnier, Johanna Nelson Weker, Laurent Pilon, Thierry Brousse, Bruce Dunn

    Read original paper ↗ ·

  11. New Emerging Fast Charging Microscale Electrode Materials

    Small · 2023-11-28

    Litong Wang, Yunlei Zhong, Huibo Wang, Oleksandr I. Malyi, Feng Wang, Yanyan Zhang, Guo Hong, Yuxin Tang

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  12. Bifunctional Mo4O11 Nanosheets-Engineered Co-Ni alloy nanowires enable High-Efficiency seawater electrolysis and Zn-Seawater battery

    Chemical Engineering Journal · 2024-03-24

    Muhaiminul Islam, Sambedan Jena, Saleem Sidra, Duy Thanh Tran, Do Hwan Kim, Nam Hoon Kim, Joong Hee Lee

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  13. Transforming nanoscale VO2(B) into a scalable sodium-ion electrode

    Nano Research · 2024-05-30

    Yunkai Luo, Swetha Chandrasekaran, Bintao Hu, Randy Chen, Marcus Andre Worsley, Bruce Dunn

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  14. Emerging Capacitive Materials for On-Chip Electronics Energy Storage Technologies

    Batteries · 2024-09-07

    Bukola Jolayemi, Gaëtan Buvat, Pascal Roussel, Christophe Lethien

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  15. Unraveling oxygen vacancy formation, dynamics and site distribution in MoO 3-x thin films

    Materials Chemistry and Physics · 2025-01-01

    Francesco Paparoni, Georghii Tchoudinov, Andrea Di Cicco, Emiliano Fonda, Andrea Zitolo, Zeinab Ebrahimpour, R. Gunnella, N. Lockwood, S.J. Rezvani

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  16. Anode Materials for High-Power Lithium-Ion Batteries

    Annual Review of Materials Research · 2025-03-26

    James Michael Sieffert, Stephanie Bazylevych, Eric McCalla

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  17. Electrocatalytic Conversion of Glucose into Renewable Formic Acid Using “Electron‐Withdrawing” MoO3 Support under Mild Conditions

    ChemSusChem · 2025-03-27

    Chaozheng Zhou, Haozhe Jia, Pengfei Yan, Chenglong Yang, Song Ning Xu, Guangyu An, Baorui Song, Qun Xu

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  18. Amorphizing Iron Molybdate as a High‐Capacity Cathode for Lithium Metal Batteries Enabled by Multiple Insertion Reactions in the Metastable Structure

    Advanced Materials · 2025-07-21

    Xiangjun Pu, Jaehoon Heo, Jaekyun Yoo, Long Chen, Chongrui Dong, Zhongxue Chen, Cao Yuliang, Jiayue Peng, Renjie Li, Yuyang Yi, Kisuk Kang, Zheng‐Long Xu

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  19. Controlled synthesis of large-area MoS2/MoO2 heterostructure via one-step, two-stage chemical vapor deposition for electrocatalytic hydrogen evolution reaction

    Applied Physics Letters · 2025-08-25

    Shiwei Zhang, Zhiwei Zhang, Yulong Hao, Aolin Peng, Jie Zhou, Jin Li, Guolin Hao

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  20. In situ Electrochemical Transformation of MoO 2 /Mo 4 O 11 @Mo for High‐Capacity Aqueous Zinc‐Ion Batteries

    Small · 2025-09-19

    Yinfeng Zhang, Xinlei Ma, Panpan Mi, Zhengbo Chen, Minggang Guo, Xiaohang Yang, Quan Zhou, Xu Zhang

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  21. Ion-dependent electrochemical behavior in shear-structured tungsten oxides

    Solid State Ionics · 2025-12-05

    Vincenzo J. Musicó, Noah P. Holzapfel, M. J. Wang, Wan‐Yu Tsai, Tatiana Proksch, Boris Kozinsky, Nina Balke, Veronica Augustyn

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  22. O-vacancy driven structural tuning and enhanced polaron transport in metal/amorphous MoO3 interfaces

    Surfaces and Interfaces · 2026-05-02

    Benedetta Gianfelici, Francesco Paparoni, Nicola Pinto, Marco Minicucci, R. Gunnella, S. J. Rezvani

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  23. Phase-Specific EELS-Derived Optical Onsets and Photoluminescence in α-MoO3 and Orthorhombic γ-Mo4O11

    The Journal of Physical Chemistry C · 2026-08-11

    Carlos Calvo, Gwladys Steciuk, Sylvie Migot, Jaâfar Ghanbaja, Stéphanie Bruyère, Silvère Barrat, M. Sánchez, Guillermo Santana, Jorge Ricardo Aguilar-Hernandez, O. de Melo

    Read original paper ↗ ·

  24. Interfacial depletion-zone engineering in MOF-derived MoO3/Mo4O11/Cu2V2O7 enables efficient photocatalytic elimination of imidacloprid in real water matrices

    Journal of environmental chemical engineering · 2026-09-01

    Hardy Shuwanto, Chiu-Wen Chen, Cheng‐Di Dong

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  25. WO3/MoO3 Nanocomposite Thin Films and Heterostructures: Interfacial Synergy for Smart and Sustainable Technologies

    Journal of Composites Science · 2026-09-01

    Aleksei Viktorovich Shchegolkov, Aleksei Viktorovich Shchegolkov, Veronica O. Malinkina, I. A. Komarov, В. В. Каминский, A. V. Shchegolkov, A. V. Shchegolkov

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