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RESEARCH PAPER · Accounts of Chemical Research · 2022

NbOx-Based Catalysts for the Activation of C–O and C–C Bonds in the Valorization of Waste Carbon Resources

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NbOx-Based Catalysts for the Activation of C–O and C–C Bonds in the Valorization of Waste Carbon ResourcesOriginalCatalytic Cleavage of C-O Bond In Lignin Model Compound Over Nickel-Based Carbon-Nitrogen Catalyst0Recent advances in supported acid/base ionic liquids as catalysts for biodiesel production27Highly Efficient Oxidation of Propane at Low Temperature over a Pt-Based Catalyst by Optimization Support150The weak interaction between polar aprotic solvent and saline water enables efficient production of furans from lignocellulosic biomass16Catalytic modification of corn straw facilitates the remediation of Cd contaminated water and soil23A review on recent trends in selective hydrodeoxygenation of lignin derived molecules41Direct Conversion of Enzymatic Hydrolysis Lignin to Cycloalkane Fuel with Hydrotalcite-Derived Ni Catalyst0High Performance Pt/Nb2w3o14 Catalyst for Glycerol Valorization to 1,3-Propanediol0Heterolytic dissociation of H2 and bond activation: Spotting new opportunities from a unified view38Thin lamellar Li7La3Zr2O12 solid electrolyte with g-C3N4 as grain boundary modifier for high-performance all-solid-state lithium battery18Boosting Higher Selectivity for Thymol Hydrogenation Reaction over Ni/Ce Catalyst2Specific cleavage of >CH-O-bonds in benzyloxybenzene and poplar lignin over nickel supported on a nitrogen-doped carbon material11Highly selective production of light aromatics from lignin through integrated approach of the torrefaction deoxygenation pretreatment and the dual-catalyst catalytic fast pyrolysis using Nb modified γ-Al2O3 and HZSM-528Pt‐Loaded Nb─W Metal Composite Oxide for Selective Cleavage of Secondary C─O Bonds11Theoretical Insight into the Mediation Mechanism of Water on Favorable Isomerization over Epimerization of Glucose on the Nb2O5 Catalyst6Investigation of the promotion effect of metal oxides on the water-gas shift reaction activity over Pt-MO /CeO2 catalysts for aqueous phase reforming7Engineering the Interface Between Au Nanoparticles and CoO-Ov to Enhance the Catalytic Performance of 5-Hydroxymethylfurfural (HMF) to 2,5-Dimethylfuran (DMF)8Precise activation of C–C bonds for recycling and upcycling of plastics81Attapulgite-based MCM-41 zeolite supported Ni-Nb catalysts for hydrogen production by acetic acid steam reforming27Selective C–C and C–O bond cleavage strategies for the thermochemical upgrading of (hemi)cellulosic biomass44Study on the catalytic hydrodeoxygenation of lignin dimers: Adsorption properties and linkages cleavage6Advances in solar-driven, electro/photoelectrochemical, and microwave-assisted upcycling of waste polyesters15Catalytic Co-Pyrolysis of E-Waste Plastic and Sawdust for the Production of Petrochemical-Grade Hydrocarbons0Heterogeneous catalysis for the environment92Synergistic promotion of oxygen vacancy and Lewis acidity of Nb 2 O 5 on the preferential hydroxymethyl hydrogenolysis of 5-hydroxymethylfurfural catalyzed by single atom Pt4Selective Upcycling of Polyethylene Terephthalate towards High‐valued Oxygenated Chemical Methyl p‐Methyl Benzoate using a Cu/ZrO2 Catalyst94Selective Upcycling of Polyethylene Terephthalate towards High‐valued Oxygenated Chemical Methyl p‐Methyl Benzoate using a Cu/ZrO2 Catalyst5Direct conversion of enzymatic hydrolysis lignin to cycloalkane fuel with hydrotalcite-derived Ni catalyst14Recovery of Kraft lignin from industrial black liquor for a sustainable production of value-added light aromatics by the tandem catalytic pyrolysis40Structural elucidation of Kraft lignin isolated from black liquor by the gradient acid precipitation and highly selective production of light aromatics by tandem catalytic pyrolysis over dual-catalysts18Hydroliquefaction of lignin: Can it generate recycle solvents by itself?4High performance Pt/Nb2W3O14 catalyst for glycerol valorization to 1,3-propanediol9Regulating the oxygen vacancy of M-WOx-MgOy catalysts (M = Ni, Pd, Pt, Ru) for the chemoselective conversion of glucose to diols5Solvent-free selective hydrogenation of nitroaromatics to azoxy compounds over Co single atoms decorated on Nb2O5 nanomeshes91Biomass to green surfactants: Microwave-assisted transglycosylation of wheat bran for alkyl glycosides production14Hydrotreating of Palm Oil into Bio Jet Fuel through a One-Step Process over Nb Doping Pt/AlSiO-Nb Catalyst19A synergistic approach for lignin biofuel production: Integrating non-catalytic solvolysis with catalytic product upgrading11Production of Valuable Aromatics from the Hydrodeoxygenation of Guaiacol and Real Bio-Oil over Ni–Nb/HZSM-5 under Supercritical Ethanol19Unlocking opportunities: Supported metal catalysts for the chemical upcycling of waste plastics26Targeted preparation for hydrocarbons through catalytic hydrodeoxygenation of co-pyrolysis bio-oil using bimetal-loaded Nb2O5 catalyst12Selective Synthesis of Renewable Diesel Fuel Precursors via C–C Condensation of Biomass-Derived Furans Using a Niobium Oxide Nanocatalyst19Catalytic depolymerization and hydrodeoxygenation of lignin to high-density fuel precursors using Ni/Nb2O5 catalyst10Selective direct deoxygenation of m-cresol on Heusler alloy catalysts via precise control of electronic structure: An integrated density function theory and microkinetic modeling study3Enhancing reactive oxygen release-replenishment and Lewis acid acidity by Nb doping in NbmCeOx for simultaneous elimination of NOx and toluene49Theoretical Exploration of the Competitive Mechanism for Hydrodehydration and Decarboxylation of 2,5-Furandicarboxylic Acid by Pt1 and Pt3 Supported on Nb2O50An interesting carrier: the excellent performance of Nb 2 O 5 in biomass hydrodeoxygenation3Hydrodeoxygenation of oleic acid over NiCu bimetallic catalysts supported on Mo-modified niobium phosphate8Self-photosensitized cycloaddition induced synthesis of a high-density fuel with ultra-low freezing point using bulk bio-benzaldehyde and furans4Solvent-Free Hydrodeoxygenation of Eucalyptus Sp. Bio-Oil Over Palladium Supported on Niobium Phosphate for Biofuel Production0Flexible Regulation of Product Distribution in Cyclohexane Cracking Catalyzed by Acid–Base Bifunctional Catalyst13Enhanced conversion of lignin into mono-cycloalkanes via C–C bonds cleavage over multifunctional Pt-Nb/MOR catalyst5Switchable Product Selectivity in Biodiesel Synthesis3Hydrogen Spillover‐Induced Brønsted Acidity Enables Controllable Hydrocracking of Polyolefin Waste to Liquid Fuels32Hydrogen Spillover‐Induced Brønsted Acidity Enables Controllable Hydrocracking of Polyolefin Waste to Liquid Fuels4A Mechanism Insight into the Effect of Water on Preferential Dehydration Rather Than Retro-Aldol Condensation of Fructose over a Nb2O5 Catalyst2Solvent-free upgrading of eucalyptus bio-oil over Pd/NbOPO4 for biofuel production2NbOx-Based Catalysts for Biomass Conversion: Progress in the Past 20 Years18Chemical recycling of waste polyethylene terephthalate over mesoporous niobium phosphate5Transforming plastic waste into clean fuel and chemical: zeolite-catalyzed dechlorination and cracking of plastic-derived oil3Integrating weighted life cycle assessment into multidimensional trade-off analysis for lignocellulosic biofuel and chemical production3D–π–A Triazine-Based Polymers Photoinduced Integrated Ring-Increasing Strategy of Biocyclohexene for Synthesizing High-Strained Cyclobutane Fuel3Solid-mediated surface modification of biomass powders: A solvent-free strategy for green functionalisation of porous materials0Directed pyrolysis behavior and product reconstruction mechanisms in waste tire rubber components via waste chromium slag catalysis4CeNbOx/SSZ-13 catalysts with zeolite-protected active sites for broad-temperature NH3-SCR and enhanced resistance to K-poisoning9Niobium-Enhanced Kinetics of Tantalum Phosphate in Catalytic Glucose Dehydration to 5-Hydroxymethylfurfural2Surface and Interface Properties of Metal Species for Waste Plastic Hydroconversion6Enhanced cleavage of C–C bonds in polycarbonate plastic wastes to obtain valuable phenolics over a potassium-modified triazine-based strong base catalyst0Site-Selective Pt Anchoring on Oxygen Vacancies by Atomic Layer Deposition Promotes Metal–Acid Synergy for Enhanced Guaiacol Hydrodeoxygenation0Solvent dependent bioactivity and spectroscopic characterization of neovestitol from Nigerian propolis using experimental and computational methods0Stepwise hydrogen spillover–engineered synergistic sites enable near-quantitative conversion of waste PET to p-xylene10Solvent-free upcycling of polystyrene to mono-aromatics over a selective Ni/NbOx bifunctional catalyst4Ultrathin 2D Mo-doped niobium oxyphosphate nanosheets with rich oxygen vacancies for room-temperature chemiresistive gas sensors with high performance1Fabrication of MgAl2O4/rGO nanocomposite as a reliable electrocatalyst for OER activity and detection of paracetamol2Single-atom Pt embedded in metastable Nb2O5 synergizes with Nb5 + for carbon-conserving hydrodeoxygenation of fatty acids/esters1Multifunctional Cu/Nb2O5 catalyst enabling atom-efficient tandem synthesis of secondary amines from alcohol and nitrobenzene0A review on selective dealkylation of alkylaromatics: Feedstocks, catalysts, and reaction pathways0Frustrated Lewis Pairs Enable Efficient Polyethylene Oxidative Upcycling0Frustrated Lewis Pairs Enable Efficient Polyethylene Oxidative Upcycling0Insight into the catalytic desorption of CO2-rich amine solution over niobium-modified CeZr solid solution catalyst0

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  3. Highly Efficient Oxidation of Propane at Low Temperature over a Pt-Based Catalyst by Optimization Support

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  4. The weak interaction between polar aprotic solvent and saline water enables efficient production of furans from lignocellulosic biomass

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  5. Catalytic modification of corn straw facilitates the remediation of Cd contaminated water and soil

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  10. Thin lamellar Li7La3Zr2O12 solid electrolyte with g-C3N4 as grain boundary modifier for high-performance all-solid-state lithium battery

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  13. Highly selective production of light aromatics from lignin through integrated approach of the torrefaction deoxygenation pretreatment and the dual-catalyst catalytic fast pyrolysis using Nb modified γ-Al2O3 and HZSM-5

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  15. Theoretical Insight into the Mediation Mechanism of Water on Favorable Isomerization over Epimerization of Glucose on the Nb2O5 Catalyst

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  16. Investigation of the promotion effect of metal oxides on the water-gas shift reaction activity over Pt-MO /CeO2 catalysts for aqueous phase reforming

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  17. Engineering the Interface Between Au Nanoparticles and CoO-Ov to Enhance the Catalytic Performance of 5-Hydroxymethylfurfural (HMF) to 2,5-Dimethylfuran (DMF)

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  19. Attapulgite-based MCM-41 zeolite supported Ni-Nb catalysts for hydrogen production by acetic acid steam reforming

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  47. Hydrodeoxygenation of oleic acid over NiCu bimetallic catalysts supported on Mo-modified niobium phosphate

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  48. Self-photosensitized cycloaddition induced synthesis of a high-density fuel with ultra-low freezing point using bulk bio-benzaldehyde and furans

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    Bo Yang, Junyao Xie, Jiawei Xie, Yuxuan Liang, Xiumei Ma, Huyao Ge, Xueping Wang, Zhaohui Wang, Qiuyu Zhang, Ji‐Jun Zou, Junjian Xie, Junjian Xie

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  49. Solvent-Free Hydrodeoxygenation of Eucalyptus Sp. Bio-Oil Over Palladium Supported on Niobium Phosphate for Biofuel Production

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    Yuri Gontijo Rosa, Henrique S. Oliveira, Vânya Márcia Duarte Pasa

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  50. Flexible Regulation of Product Distribution in Cyclohexane Cracking Catalyzed by Acid–Base Bifunctional Catalyst

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