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RESEARCH PAPER · ACS Earth and Space Chemistry · 2022

A Review of Bismuth(III)-Based Materials for Remediation of Contaminated Sites

Tatiana G. Levitskaia, Nikolla P. Qafoku, Mark Bowden, Robert Matthew Asmussen, Edgar C. Buck, Vicky L. Freedman, Carolyn Isobel Pearce

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A Review of Bismuth(III)-Based Materials for Remediation of Contaminated SitesOriginalWater Defect Stabilizes the Bi3+ Lone-Pair Electronic State Leading to an Unusual Aqueous Hydration Structure11Review of recent developments in iodine wasteform production54Iodine Removal from Carbonate-Containing Alkaline Liquids Using Strong Base Resins, Hybrid Resins, and Silver Precipitation12Microbial involvement in iodine cycle: mechanisms and potential applications6A Comprehensive Review on Non‐Trivalent Bismuth‐Based Materials: Structure, Synthesis, and Strategies for Improving Photocatalytic Performance11225 Ac/ 213 Bi radionuclide generators for the separation of 213 Bi towards clinical demands9Different routes of bismuth mineral transformation during pertechnetate and perrhenate uptake for subsurface remediation2Selective capture of uranium by p-block bismuth-based metal–organic framework42Hollow Bismuth-Based Nanoreactor with Ultrathin Disordered Mesoporous Silica Shell for Superior Radioactive Iodine Decontamination25Control of crystallization pathways in the BiFeO3 - Bi2Fe4O9 system2Designed Nanoarchitectures of a BiOBr/BiOI Nanosheet Heterojunction Anchored on Dendritic Fibrous Nanosilica as Visible-Light Responsive Photocatalysts8Oxygen vacancy-suppression strengthened the internal electric field in ZnIn2S4/BiVO4 S-scheme heterojunction to boost photocatalytic removal of aqueous pollutants28Tailoring glassy carbon electrode surface with FeBiO 3 for electrochemical detection of dinitrophenol isomers1Fabrication of interface with capping-bonding synergy to boost CO2 electroreduction to formate17Control of Crystallization Pathways in the BiFeO 3 –Bi 2 Fe 4 O 9 System7Mechanisms of interaction between bismuth-based materials and contaminants for subsurface remediation5A paradigm shift for evaluating natural attenuation of radioactive iodine in soils and sediments: Species-specific mechanisms and pathways5Hydrogen encapsulation properties of heteroatoms doped fullerenes: A DFT study for potential hydrogen storage application8Bi2S3-based photocatalysts: Properties, synthesis, modification strategies, and mechanistic insights towards environmental sustainability and green energy technologies120Hybrid resins for simultaneous removal of multiple groundwater contaminants5Synthesis of Functional Materials from Basic Bismuth(III) Nitrates1Interfacial mechanisms of uranium removal using bismuth hydroxide-impregnated graphitic carbon nitride4CoNiFe-LDH nanoflowers combined with bismuth-based layered perovskite oxide (Bi₂MoO₆) for vortex-assisted micro-solid phase extraction of lead from food and water samples9Effects of Different Concentrations of Bismuth Molybdate as an Electrocatalyst for Water Splitting and Antibacterial Activity0Donor and Acceptor Characteristics of Group IV and VII Doped BiNbO4: A Hybrid Density Functional Investigation1Hydrothermal synthesis of BiOX and its photocatalytic performance0Polyacrylonitrile-loaded bismuth (Bi) porous carbon materials for efficient adsorption of iodine vapour8Part I: Structural Transformation of Bismuth-Based Materials in Dynamic Aqueous Environments and Implications for Subsurface Contaminant Remediation1Part II: Sediment Interactions with Layered Bismuth Materials and Implications for Subsurface Contaminant Remediation2Dual‐Function Piezo‐Photocatalytic Systems for Sustainable Hydrogen Evolution and Environmental Remediation23Polyvinyl alcohol and polyvinylpyrrolidone composite incorporating bismuth nitrate for gamma ray shielding6The Dual Role of Antimony in Enhancing the Durability of Bismuth‐Based CO 2 Reduction Gas Diffusion Electrodes1Synthesis of Bismuth Trifluoromethanesulfonate0Label-free electrochemical sensing of Hg 2+ using a Bi 2 WO 6 –DNA nanocomposite interface1Dual-Functional Bi 4 V 2 O 11 /CdS/g-C 3 N 4 Heterostructure with Engineered Interfaces for Optimized Environmental Iodine Capture and Solar-to-Hydrogen Conversion4Mechanistic insights into anion intercalation for nanosheet-interlaced Bi-based catalysts0Bismuth-Supported Mesostructured Silica: Ligand-Directed Growth of Nanosheets for Sustainable Catalysis and Iodine Scavenging0Restoring Formate Selectivity: In Situ Raman Study of Deactivated Electrodes for CO 2 Electroreduction0Aurivillius-type layered Bi2MoO6 with surface defects: A robust electrocatalyst for trace vanillin detection3First-principles investigation of ZnCu2Sn(S1-xSex)4 (x = 0.05–0.25) solid solutions for environmental pollutant adsorption: structural optimization and interaction with cement industry pollution (CO2, CO, and SO2)0Bismuth-containing molecular sieves (SABiOs) as catalysts for the oxidative dehydration of glycerol0Structure and Compressional Behavior of Sillen-Type (BiO)2(CO3) Bismutite Carbonate0Phase-specific particle size distributions in Hanford tank waste measured by automated SEM–EDS: A statistical comparison across a waste column0

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  1. Water Defect Stabilizes the Bi3+ Lone-Pair Electronic State Leading to an Unusual Aqueous Hydration Structure

    Inorganic Chemistry · 2022-09-13

    Darren M. Driscoll, Richard C. Shiery, Nicolas D’Annunzio, Daria Boglaienko, Mahalingam Balasubramanian, Tatiana G. Levitskaia, Carolyn Isobel Pearce, Niranjan Govind, David C. Cantu, John L. Fulton

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  2. Review of recent developments in iodine wasteform production

    Frontiers in Chemistry · 2022-12-23

    Robert Matthew Asmussen, Joshua R. Turner, Saehwa Chong, Brian Joseph Riley

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  3. Iodine Removal from Carbonate-Containing Alkaline Liquids Using Strong Base Resins, Hybrid Resins, and Silver Precipitation

    Industrial & Engineering Chemistry Research · 2023-02-08

    Robert Matthew Asmussen, Amy Westesen, Elsa A. Cordova, Alessandra Fujii Yamagata, Philip P. Schonewill, Aryiana C. Moore, Agathe Bourchy, Sarah A. Saslow, Gary Lynn Smith, Brian Joseph Riley, Rodney S. Skeen

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  4. Microbial involvement in iodine cycle: mechanisms and potential applications

    Frontiers in Bioengineering and Biotechnology · 2023-10-30

    Eva Duborská, Hana Vojtková, Michaela Matulová, Martin Šeďa, Peter Matúš

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  5. A Comprehensive Review on Non‐Trivalent Bismuth‐Based Materials: Structure, Synthesis, and Strategies for Improving Photocatalytic Performance

    Solar RRL · 2023-12-12

    Qiaofeng Han, Huiwei Ding, Zhihao Wang

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  6. 225 Ac/ 213 Bi radionuclide generators for the separation of 213 Bi towards clinical demands

    Inorganic Chemistry Frontiers · 2024-01-01

    Hongshan Zhu, Stephan Heinitz, Koen Binnemans, Steven Mullens, Thomas Cardinaels

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  7. Different routes of bismuth mineral transformation during pertechnetate and perrhenate uptake for subsurface remediation

    Environmental Science Water Research & Technology · 2024-01-01

    Daria Boglaienko, Mark Bowden, N. M. Escobedo, Q. M. Collins, Amanda R. Lawter, Tatiana G. Levitskaia, Carolyn Isobel Pearce

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  8. Selective capture of uranium by p-block bismuth-based metal–organic framework

    Desalination · 2024-01-22

    Lin Zhao, Zhihao Pan, Lirong Cai, Shiyong Wang, Bing Heng Lu, Sihao Lv, Yongfu Qiu, Gang Wang

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  9. Hollow Bismuth-Based Nanoreactor with Ultrathin Disordered Mesoporous Silica Shell for Superior Radioactive Iodine Decontamination

    Chem & Bio Engineering · 2024-04-16

    Zhenjiang Tian, Tien‐Shee Chee, Yuxun Hao, Kang Kang, Xiaofan Yang, Chengliang Xiao

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  10. Control of crystallization pathways in the BiFeO3 - Bi2Fe4O9 system

    ChemRxiv · 2024-06-05

    Andrea Kirsch, Guilherme B. Strapasson, Niels Lefeld, Mathias Gogolin, Mark C. Videbæk, Soham Banerjee, Heloisa N. Bordallo, Kirsten M. Ø. Jensen

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  11. Designed Nanoarchitectures of a BiOBr/BiOI Nanosheet Heterojunction Anchored on Dendritic Fibrous Nanosilica as Visible-Light Responsive Photocatalysts

    Inorganic Chemistry · 2024-06-12

    Navarut Paengjun, Vivek Polshettiwar, Makoto Ogawa

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  12. Oxygen vacancy-suppression strengthened the internal electric field in ZnIn2S4/BiVO4 S-scheme heterojunction to boost photocatalytic removal of aqueous pollutants

    Journal of environmental chemical engineering · 2024-07-01

    Yongqin Yue, Jian Zou

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  13. Tailoring glassy carbon electrode surface with FeBiO 3 for electrochemical detection of dinitrophenol isomers

    International Journal of Environmental & Analytical Chemistry · 2024-10-17

    Samia A. Kosa, Amna Nisar Khan, M. Aslam, Abdul Hameed, Muhammad Tahir Soomro

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  14. Fabrication of interface with capping-bonding synergy to boost CO2 electroreduction to formate

    Applied Catalysis B: Environmental · 2024-10-28

    Yunpeng Liu, Lei Gong, Jianglong Liu, Peng Xiao, Baotong Chen, Fei Xie, Caoyu Yang, Zhonghua Wu

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  15. Control of Crystallization Pathways in the BiFeO 3 –Bi 2 Fe 4 O 9 System

    Chemistry of Materials · 2024-12-29

    Andrea Kirsch, Guilherme B. Strapasson, Niels Lefeld, Mathias Gogolin, Mark C. Videbæk, Soham Banerjee, Heloisa N. Bordallo, Kirsten M. Ø. Jensen

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  16. Mechanisms of interaction between bismuth-based materials and contaminants for subsurface remediation

    Journal of Materials Chemistry A · 2025-01-01

    Carolyn Isobel Pearce, Daria Boglaienko, Amanda R. Lawter, Elsa A. Cordova, Kirk J. Cantrell, Mark Bowden, Nabajit Lahiri, Odeta S. Qafoku, Sebastian T. Mergelsberg, Charles T. Resch, Ferdinan Cintron Colon, Vanessa A. Garayburu‐Caruso, Nicolas D’Annunzio, Mahalingam Balasubramanian, Sarah A. Saslow, Nikolla P. Qafoku, Vicky L. Freedman, Tatiana G. Levitskaia

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  17. A paradigm shift for evaluating natural attenuation of radioactive iodine in soils and sediments: Species-specific mechanisms and pathways

    Journal of Environmental Management · 2025-01-13

    Hilary P. Emerson, Nikolla P. Qafoku, Christian D. Johnson, James E. Szecsody, Mariah S. Doughman, Rob D. Mackley, Daniel I. Kaplan

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  18. Hydrogen encapsulation properties of heteroatoms doped fullerenes: A DFT study for potential hydrogen storage application

    Diamond and Related Materials · 2025-01-16

    Idongesit Justina Mbonu, Musa Runde, Destiny E. Charlie, Karwan Wasman Qadir

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  19. Bi2S3-based photocatalysts: Properties, synthesis, modification strategies, and mechanistic insights towards environmental sustainability and green energy technologies

    Coordination Chemistry Reviews · 2025-01-28

    Akshay Chawla, Anita Sudhaik, Sonu Sonu, Rohit Kumar, Pankaj Raizada, Tansir Ahamad, Aftab Aslam Parwaz Khan, Quyet Van Le, Van‐Huy Nguyen, Sourbh Thakur, Pardeep Singh

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  20. Hybrid resins for simultaneous removal of multiple groundwater contaminants

    Journal of environmental chemical engineering · 2025-04-22

    Sarah A. Saslow, Jacqueline R. Hager, Carolyn Isobel Pearce, Tatiana G. Levitskaia, Rachel M. Anguish, Elsa A. Cordova, Kelly L. Rue, Nancy M. Avalos, Mark Bowden, Daria Boglaienko, Nabajit Lahiri, Mark Engelhard, Emily T. Nienhuis, José Marcial, Mariah S. Doughman, Alex J. Kugler, Suraj Venkat Pochampally, Larry Gottlieb, Mark Carlson, Rob D. Mackley

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  21. Synthesis of Functional Materials from Basic Bismuth(III) Nitrates

    Russian Journal of General Chemistry · 2025-05-01

    Evgeniya V. Timakova, Tatiana E. Timakova, Liubov I. Afonina

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  22. Interfacial mechanisms of uranium removal using bismuth hydroxide-impregnated graphitic carbon nitride

    Inorganic Chemistry Communications · 2025-05-13

    Lakshmi Prasanna Lingamdinne, Maheswara Reddy Lebaka, Nadavala Siva Kumar, Mohammad Asif, Gajanan Sampatrao Ghodake, Janardhan Reddy Koduru

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  23. CoNiFe-LDH nanoflowers combined with bismuth-based layered perovskite oxide (Bi₂MoO₆) for vortex-assisted micro-solid phase extraction of lead from food and water samples

    Food Chemistry · 2025-06-18

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  24. Effects of Different Concentrations of Bismuth Molybdate as an Electrocatalyst for Water Splitting and Antibacterial Activity

    Microscopy Research and Technique · 2025-07-07

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  25. Donor and Acceptor Characteristics of Group IV and VII Doped BiNbO4: A Hybrid Density Functional Investigation

    Langmuir · 2025-09-18

    Hongchun Zheng, Song Ling, Bo Kong, Tixian Zeng, Shan Jiang, Wentao Wang

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  26. Hydrothermal synthesis of BiOX and its photocatalytic performance

    Elsevier eBooks · 2025-09-27

    Sidra Subhan, Muhammad Zeeshan, Fazle Subhan, Kifayatullah Khan, Muhammad Yaseen

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  27. Polyacrylonitrile-loaded bismuth (Bi) porous carbon materials for efficient adsorption of iodine vapour

    Applied Surface Science · 2025-10-08

    Chao Zhang, Tianhao Sun, Shuangping Xu, Juncheng Ma, Mingyu Zhang, Yanqing Qu, Hongge Jia, Jingyu Xu, Xing Wang

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  28. Part I: Structural Transformation of Bismuth-Based Materials in Dynamic Aqueous Environments and Implications for Subsurface Contaminant Remediation

    ACS Earth and Space Chemistry · 2025-10-09

    Nancy M. Avalos, Sarah A. Saslow, Elsa A. Cordova, Amanda R. Lawter, Mark Bowden, Odeta S. Qafoku, Charles T. Resch, Nabajit Lahiri, Nicolas D’Annunzio, Daria Boglaienko, Tatiana G. Levitskaia, Carolyn Isobel Pearce, Vicky L. Freedman, Rob D. Mackley

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  29. Part II: Sediment Interactions with Layered Bismuth Materials and Implications for Subsurface Contaminant Remediation

    ACS Earth and Space Chemistry · 2025-10-14

    Amanda R. Lawter, Nikolla P. Qafoku, Elsa A. Cordova, Mark Bowden, Odeta S. Qafoku, Ferdinan Cintron Colon, Nicolas D’Annunzio, Hilary P. Emerson, Daria Boglaienko, Tatiana G. Levitskaia, Carolyn Isobel Pearce, Vicky L. Freedman

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  30. Dual‐Function Piezo‐Photocatalytic Systems for Sustainable Hydrogen Evolution and Environmental Remediation

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  31. Polyvinyl alcohol and polyvinylpyrrolidone composite incorporating bismuth nitrate for gamma ray shielding

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  32. The Dual Role of Antimony in Enhancing the Durability of Bismuth‐Based CO 2 Reduction Gas Diffusion Electrodes

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  33. Synthesis of Bismuth Trifluoromethanesulfonate

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  34. Label-free electrochemical sensing of Hg 2+ using a Bi 2 WO 6 –DNA nanocomposite interface

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  35. Dual-Functional Bi 4 V 2 O 11 /CdS/g-C 3 N 4 Heterostructure with Engineered Interfaces for Optimized Environmental Iodine Capture and Solar-to-Hydrogen Conversion

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  36. Mechanistic insights into anion intercalation for nanosheet-interlaced Bi-based catalysts

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  37. Bismuth-Supported Mesostructured Silica: Ligand-Directed Growth of Nanosheets for Sustainable Catalysis and Iodine Scavenging

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  38. Restoring Formate Selectivity: In Situ Raman Study of Deactivated Electrodes for CO 2 Electroreduction

    The Journal of Physical Chemistry C · 2026-05-31

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  39. Aurivillius-type layered Bi2MoO6 with surface defects: A robust electrocatalyst for trace vanillin detection

    Journal of Alloys and Compounds · 2026-06-01

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  40. First-principles investigation of ZnCu2Sn(S1-xSex)4 (x = 0.05–0.25) solid solutions for environmental pollutant adsorption: structural optimization and interaction with cement industry pollution (CO2, CO, and SO2)

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  41. Bismuth-containing molecular sieves (SABiOs) as catalysts for the oxidative dehydration of glycerol

    Applied Catalysis A General · 2026-06-17

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  42. Structure and Compressional Behavior of Sillen-Type (BiO)2(CO3) Bismutite Carbonate

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  43. Phase-specific particle size distributions in Hanford tank waste measured by automated SEM–EDS: A statistical comparison across a waste column

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