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RESEARCH PAPER · Separation and Purification Technology · 2022

Embedding ZnCdS@ZnIn2S4 into thiazole-modified g-C3N4 by electrostatic self-assembly to build dual Z-scheme heterojunction with spatially separated active centers for photocatalytic H2 evolution and ofloxacin degradation

Linlin Hou, Wei Li, Zhiliang Wu, Qiuming Wei, Huixing Yang, Yangyang Jiang, Teng Wang, Yinzhen Wang, Qinyu He

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Embedding ZnCdS@ZnIn2S4 into thiazole-modified g-C3N4 by electrostatic self-assembly to build dual Z-scheme heterojunction with spatially separated active centers for photocatalytic H2 evolution and ofloxacin degradationOriginalInsights into the function of semi-metallic 1T’ phase ReS2 as cocatalyst decorated g-C3N4 nanotubes for enhanced photocatalytic hydrogen production activity30Energy band engineering of hydroxyethyl group grafted on the edge of 3D g-C3N4 nanotubes for enhanced photocatalytic H2 production53Preparation of ZnFe2O4@TiO2 Novel Core-Shell Photocatalyst by Ultrasonic Method and Its Photocatalytic Degradation Activity32Preparation and catalytic properties of ZnO/ Na0.5Bi0.5TiO3 composites8Enhanced charge separation in dual Z-scheme Au decorated LaFeO3-g-C3N4-BiFeO3 system for efficient H2 production55Magnetically recyclable PbMoO4/BC/Fe3O4 composite for tetracycline removal: fabrication, performance, and mechanism3Latest Progress on Photocatalytic H2 Production by Water Splitting and H2 Production Coupled with Selective Oxidation of Organics over ZnIn2S4-Based Photocatalysts47Rational construction of S-scheme BN/MXene/ZnIn2S4 heterojunction with interface engineering for efficient photocatalytic hydrogen production and chlorophenols degradation95Construction of Multi-Dimensional Cu2se@Amorphous Carbon@Graphene Nanobelt/G-C3n4 Z-Scheme Heterojunctions with Enhanced Photocatalytic Hydrogen Evolution Activity0Construction of Multi-Dimensional Cu2se@Amorphous Carbon@Graphene Nanobelt/G-C3n4 Z-Scheme Heterojunctions with Enhanced Photocatalytic Hydrogen Evolution Activity0Efficient photocatalytic hydrogen evolution: a novel multi-modified carbon nitride based on physical adsorption30Passivating Surface States of Graphitic Carbon Nitride for Improved Photocatalytic Fenton-Like Decontamination0Oxygen-Defect-Mediated ZnCr2O4/ZnIn2S4 Z-Scheme Heterojunction as Photocatalyst for Hydrogen Production and Wastewater Remediation43Studying the role of dual vacancies over g-C3N4/Zn0.3Cd0.7S for photocatalytic CO2 reduction30In-situ growth of C-F@CCS@ZIF8/67–1/1 photocatalysts with internal electric field and interfacial enhancement on cobalt-copper foam surface for simultaneous removal of ciprofloxacin and Cr(VI)70Fluoroquinolones: Fate, effects on the environment and selected removal methods115Current scenario in ternary metal indium sulfides-based heterojunctions for photocatalytic energy and environmental applications: A review384-Methyl-5-vinyl thiazole modified Ni-MOF/g-C3N4/CdS composites for efficient photocatalytic hydrogen evolution without precious metal cocatalysts70Highly Efficient Photocathodic Protection Performance of ZIS@CNNs Composites under Visible Light92D/2D Mn0.5Cd0.5In2S4/g-C3N4 heterojunctions with controllable charge transfer pathways for effective photocatalytic H2 production and antibiotics removal17Passivating surface states of graphitic carbon nitride for improved photocatalytic Fenton-like decontamination11A short review on the photocatalytic degradation of ofloxacin in aqueous media2Construction of biomass carbon decorated TiO2 and g-C3N5 Z-scheme heterojunction photocatalyst for removal of rhodamine B30Defect engineering in 0D/2D TiO2/g-C3N4 heterojunction for boosting photocatalytic degradation of tetracycline in a tetracycline/Cu2+ combined system27Sonophotochemical and photochemical efficiency of thiazole-containing metal phthalocyanines and their gold nanoconjugates7Constructing 3D flower-like S-scheme N–Bi2O2CO3/g-C3N4 heterojunction with enhanced photocatalytic performance21Multi-strategies modulation for photocatalytic hydrogen evolution: Enhanced charge separation by coupling sulfur vacancies and built-in electric field at ohmic interface15One-step preparation of direct Z-scheme NH 2 -UiO-66/BiOCl photocatalyst for antibiotic degradation by electrostatic adsorption6Lattice Defects and Electronic Modulation of Flower‐Like Zn3In2S6 Promote Photocatalytic Degradation of Multiple Antibiotics29In-situ constructing ZnIn2S4@In(OH)3@CdS heterostructure for efficient photocatalytic H2 generation under visible light irradiation23Construction of Ni3S4@ZIS@C3N5 photocatalyst with type II and Z-type heterojunctions by self-assembly for efficient photocatalytic hydrogen evolution48Facile synthesis of NiMn 2 O 4 /ZnMn 2 O 4 heterostructure nanocomposite for visible-light-driven degradation of methylene blue dye25Construction of multi-dimensional Cu2Se@amorphous carbon@graphene nanobelt/g-C3N4 Z-scheme heterojunctions for photocatalytic hydrogen production8Novel hollow core-shell Zn0.5Cd0.5S@ZnIn2S4/MoS2 nanocages with Z-scheme heterojunction for enhanced photocatalysis of hydrogen generation56Design of p–n heterojunction between CoWO4 and Zn-defective Zn0.3Cd0.7S for efficient photocatalytic H2 evolution36Facile fabrication of the Zn0.5Cd0.5S/ZnIn2S4 S-scheme heterojunction for efficient photocatalytic hydrogen production and tetracycline degradation27In-situ growing Ni2P on CdS@g-C3N4 composites for highly efficient synergistically photocatalytic H2 evolution and antibiotic degradation47Ti3C2 MXene flakes assisted Mn0.5Cd0.5S/Ti3C2 MXene/g-C3N4 Z-scheme heterojunction for enhancing photocatalytic hydrogen evolution42P-doped ultrathin g-C3N4/In2S3 S-scheme heterojunction enhances photocatalytic hydrogen production and degradation of ofloxacin24One-step synthesis N, O co-doped ZnIn2S4 for efficient photocatalytic H2 production and Cr(VI) reduction20Anchoring ZnIn2S4 nanosheets on cross-like FeSe2 to construct photothermal-enhanced S-scheme heterojunction for photocatalytic H2 evolution78Review on synthesis and modification of g-C3N4 for photocatalytic H2 production53The morphological research of ZnxCd1-xS based photocatalysts for energy conversion11Breaking Type-I heterojunction limitations: Harnessing an Ohmic-like/S-scheme cascade charge transfer mechanism for enhanced photocatalytic H2 evolution28Construction of a 2D/2D Vs-ZnIn2S4/Zn-TCPP heterojunction for effective charge transfer to enhance photocatalytic hydrogen evolution23Novel 2D/2D/2D heterojunction of ZnIn2S4/g-C3N4/MoS2 for enhanced photocatalytic hydrogen evolution reaction32Incorporating Zn0.3Cd0.7S nanoparticles into CoMoO4 microflowers for photocatalytic H2 production by oxidizing p-chlorobenzyl alcohol4Fabrication of double S-scheme Sr2MgSi2O7:Eu2+,Dy3+/ZnIn2S4/UiO-66-NH2 heterojunctions with photon storage effect for enhanced round-the-clock photocatalysis14Highly efficient dual-functional Zn0.6Cd0.4S photocatalyst for dye removal and Pt co-catalyzed hydrogen evolution3Design of 3D/1D/2D ZnIn2S4/Zn0.2Cd0.8S/Ti3C2 MXene interfacial heterojunction for enhanced photocatalytic hydrogen evolution11In situ growth of ZnCdS nanoparticles on bimetallic Cu/Fe-MOF for efficient visible-light-driven photocatalytic hydrogen production and urea synthesis26Advancements and challenges in g-C 3 N 4 /ZnIn 2 S 4 heterojunction photocatalysts55Biological activities of metallic nanostructures functionalized with hexadeca-substituted copper( ii ) and cobalt( ii ) phthalocyanines3PEC-EC dual-mode biosensing platform for PFOA assay based on competitive binding between HSA and PFOA or hemin22Enhanced photocatalyst performance by promoting carrier separation: CuNi2S4-ZnCdS nano-contact heterojunctions5Dual S-scheme C3N4/CuS/MnO2 heterojunction for promoted adsorption–photocatalytic tetracycline degradation8Electrospun core–shell structured Ni2GeO4/ZnIn2S4 nanofibers with efficient charge separation efficiency for boosting photocatalytic hydrogen generation4Engineering a dual Z-scheme copper oxide/boron carbon nitride/MXene heterojunction with tailored band alignment for high-efficiency photocatalytic degradation of refractory organic pollutants773D TiO2- and Ag10Si4O13 nanoparticals embedded into 2D thin layer g-C3N4 to construct 3D/2D/3D double Z‐scheme heterojunction for enhanced photocatalytic activity and stability4Orbital hybridization-driven singlet oxygen generation in piezo-photocatalytic self-fenton system: Synergistic band engineering and spin-state modulation for sustainable water remediation18K+ and Cl– Codoped g-C3N5 as a Catalyst for the Photocatalytic Hydrogen Evolution6Efficient photocatalytic hydrogen evolution: synergistic triple heterojunctions based on ZnIn2S4, Co3O4 and SiC@g-C3N57Solar-driven photocatalytic and photoelectrocatalytic hydrogen evolution reaction: Advances, challenges, and future directions9A high-performance S-scheme based Ti3C2Tx Mxene-enhanced S-g-C3N4/NiAl layered double hydroxide ternary heterojunction photocatalyst for sustainable hydrogen production8Boosting the photocatalytic performance for oxidative coupling of amines to imines by fabricating the Zn0.1Cd0.9S/In2O3 heterojunction2Triggering n→π∗ electronic transitions by thiazole modified graphitic carbon nitride for enhanced photocatalytic hydrogen peroxide production and Rhodamine B degradation19Efficient photocatalytic removal of ciprofloxacin antibiotic by dual Z-scheme Ag3PO4/g-C3N4/Bi2WO6 under solar irradiation8Broad-spectrum-driven g-C3N4/SnFe2O4 S-scheme heterojunction with enhanced H2O2 activation for efficient antibiotic degradation10Innovative synergistic bimetallic ion co-doped g-C3N5 for efficient photocatalytic hydrogen production0MIL Series in MOFs for the Removal of Emerging Contaminants: Application and Mechanisms5Thiazole-fused graphitic carbon nitride as dualfunctional platform for multicolor LEDs and enhanced photodegradation2A systematic review on nanostructured heterojunctions and their biomedical applications0Direct Z-scheme ZnS@g-C₃N₄ heterojunction photocatalysts synthesized via a single-step method for sunlight-assisted degradation of organic pollutants5Current advancements in bimetallic sulfides based heterojunctions towards photocatalytic environmental remediation10Construction of novel vacancies-enriched S-scheme γ-Ga2O3/g-C3N4 heterojunctions with improved photocatalytic green hydrogen production and Cr(VI) reduction performance7Directional Electron transport in In2S3 enabled by Bi3+ gradient doping and sulfur vacancies for efficient photocatalytic H2O2 production0Electrostatic adsorption-assisted self-assembly of SO 4 -ZIF-67/BiOBr Z-type heterojunctions via ammonium sulfate etching and their efficient degradation of tetracycline1Type II heterojunction of magnetic ZnIn2S4/MgFe2O4 enhanced photo-Fenton performance for efficient degradation of ofloxacin: Degradation pathway and toxicity analysis6Covalent triazine frameworks synergized with ZnIn2S4 to construct S-scheme heterojunction for achieving effective photocatalytic hydrogen evolution7Pollutant-specific reactive species fingerprints: elucidating differential photocatalytic antibiotic degradation mechanisms in ZnIn2S4-based systems3Architectural engineering of yolk-shell TiO2@g-C3N4 S-scheme heterojunctions via a peroxidation strategy for enhanced photocatalytic hydrogen evolution7Design of a Fe/FeP/ZnIn 2 S 4 Heterojunction for Enhanced Photocatalytic H 2 Evolution0Synergistic role of oxygen vacancies and heterojunction interface in g-C3N4/H2-annealed SrWO4 for enhanced photocatalytic H2 production1Recent advances in the design and application of graphitic carbon nitride-based dual Z-scheme heterojunctions3Photothermal-assisted photocatalytic strategy for hydrogen evolution over carbon dot-modified heterojunction5Synergistic Enhancement of Visible-Light-Driven Photocatalytic H2O2 Production over g-C3N4/ZnCdS by Zn Vacancies and Heterointerface Engineering2Graphitic-C3N4/TiO2(B) S-scheme heterojunctions for efficient photocatalytic H2 production and organic pollution degradation5Multifunctional g-C3N4 nanotubes@Sv-ZnIn2S4 nanosheets S-scheme heterojunction photocatalyst for wastewater purification and production of H2 and H2O26Preparation of a novel type II/Z-scheme tandem heterojunction photocatalyst AgCl/UiO-66/g-C3N4 and its performance and mechanism in the efficient photocatalytic degradation of RhB1Direct Z-scheme Bi-HOF/g-C3N4 heterojunction: construction and interfacial charge regulation0Self-assembled nanostructures for cancer chemotherapy, wastewater remediation, food safety, and CO 2 photoreduction0Rational insights into the fundamentals of a low density porous framework-N-doped ZnIn2S4 (ZIS) for photocatalytic water splitting using density functional theory calculations0Mof-derived Co3O4/g-C3N4 Z-scheme heterojunction for enhancing photocatalytic coupling with PMS activation toward pollutant0Photothermal-regulated photosensitization in hollow ZnCdS photocatalysts for enhanced photocatalytic hydrogen evolution0

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