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RESEARCH PAPER · Small · 2022

Single‐Crystalline Cathodes for Advanced Li‐Ion Batteries: Progress and Challenges

Yongkang Han, Yike Lei, Jie Ni, Yingchuan Zhang, Zhen Geng, Pingwen Ming, Cunman Zhang, Xiaorui Tian, Ji‐Lei Shi, Yu‐Guo Guo, Qiangfeng Xiao

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Single‐Crystalline Cathodes for Advanced Li‐Ion Batteries: Progress and ChallengesOriginalRecent progress in ZnCo 2 O 4 and its composites for energy storage and conversion: a review91Promoting grain growth in Ni-rich single-crystal cathodes for high-performance lithium-ion batteries through Ce doping43Synergistic enhancement on flexible solid-state supercapacitor based on redox-active Fe 3+ ions/natural spidroin modified vertically aligned carbon nanotube arrays3Transition Metal Oxides and Li 2 CO 3 as Precursors for the Synthesis of Ni-Rich Single-Crystalline NCM for Sustainable Lithium-Ion Battery Production33Morphology-Dependent Battery Performance of Ni-Rich Layered Cathodes: Single-Crystal versus Refined Polycrystal110High-rate Ni-rich single-crystal cathodes with highly exposed {0 1 0} active planes through in-situ Zr doping67Design and mechanism exploration of single-crystalline NCM811 materials with superior comprehensive performance for Li-ion batteries57Single‐Crystalline Ni‐Rich LiNi x Mn y Co 1− x − y O 2 Cathode Materials: A Perspective85PrF3 Nanocoatings for Stabilizing Spinel LiNi0.5Mn1.5O4 Cathodes8Mapping and Modeling Physicochemical Fields in Solid-State Batteries14Metal-glycerolates and their derivatives as electrode materials: A review on recent developments, challenges, and future perspectives65Upcycling spent cathodes into single-crystalline Ni-rich cathode materials through selective lithium extraction24Probing the thermal degradation mechanism of polycrystalline and single-crystal Li(Ni0.8Co0.1Mn0.1)O2 cathodes from the perspective of oxygen vacancy diffusion91Atomically selective oxidation of (Ti,V) MXene to construct TiO2@TiVCT heterojunction for high-performance Li-ion batteries41Heuristics for Molten-Salt Synthesis of Single-Crystalline Ultrahigh-Nickel Layered Oxide Cathodes50Stabilization strategies for high-capacity NCM materials targeting for safety and durability improvements49Ice‐Templating: Integrative Ice Frozen Assembly to Tailor Pore Morphology of Energy Storage and Conversion Devices39Boosting Thermal and Mechanical Properties: Achieving High‐Safety Separator Chemically Bonded with Nano TiN Particles for High Performance Lithium‐Ion Batteries56Unraveling the Mechanism and Practical Implications of the Sol-Gel Synthesis of Spinel LiMn2O4 as a Cathode Material for Li-Ion Batteries: Critical Effects of Cation Distribution at the Matrix Level25Deciphering the critical degradation factors of solid composite electrodes with halide electrolytes: Interfacial reaction versus ionic transport55One-Step Synthesis of a Single-Crystal LiNi0.83Co0.11Mn0.06O2 Cathode with Excellent Electrochemical Properties by Ti4+ Doping and LiTi2O4 In Situ Chemical Coating Using a Novel Variable Temperature Sintering Process27Ethanothermal Synthesis of Octahedral-Shaped Doped Mn 2 O 3 Single Crystals as a Precursor for LiMn 2 O 4 Spinel Cathodes in Lithium-Ion Batteries13Phosphate and Borate-Based Composite Interface of Single-Crystal LiNi0.8Co0.1Mn0.1O2 Enables Excellent Electrochemical Stability at High Operation Voltage5Highly textured and crystalline materials for rechargeable Li‐ion batteries29Quantifying Degradation Parameters of Single‐Crystalline Ni‐Rich Cathodes in Lithium‐Ion Batteries36Quantifying Degradation Parameters of Single‐Crystalline Ni‐Rich Cathodes in Lithium‐Ion Batteries4In-situ construction of metallic oxide (VNbO5) on VNbCTx MXene for enhanced Li-ion batteries performance44A Liquid and Waste-free Method for Preparing Single Crystal Positive Electrode Materials for Li-ion Batteries17Unveiling the potential of surface–beneath region doping by induced-diffusion in nickel-rich single crystal cathode for high-performance lithium-ion batteries43Mn-based cathode materials for rechargeable batteries54Challenges of thermal stability of high-energy layered oxide cathode materials for lithium-ion batteries: A review124One-step synthesis of Li2MoO4-coated and Mo-doped LiNi0.8Co0.1Mn0.1O2 single-crystals using Li2MoO4 as a sacrificial molten salt14Recent progress on sustainable recycling of spent lithium-ion battery: Efficient and closed-loop regeneration strategies for high-capacity layered NCM cathode materials84Morphology controlled performance of ternary layered oxide cathodes58Electrodes for Li-ion batteries: From high-voltage LiCoO2 to Co-reduced/Co-free layered oxides with potential anodes5The Y3+ and W6+ co-doping into Ni-rich Co‑free single-crystal cathode LiNi0.9Mn0.1O2 for achieving high electrochemical properties in lithium-ion batteries22Comparative study of polycrystalline and single-crystal NCM811 cathode materials: the role of crystal defects in electrochemical performance52Ni-rich lithium nickel manganese cobalt oxide cathode materials: A review on the synthesis methods and their electrochemical performances117Challenges and opportunities using Ni-rich layered oxide cathodes in Li-ion rechargeable batteries: the case of nickel cobalt manganese oxides39Intrinsic mechanism of Co/Mn elemental manipulation in enhancing the cycling stability of single-crystal ultrahigh-nickel layered cathodes12Mitigating hydrogen gas evolution in high nickel cathodes using single-crystalline NCM particles3Mitigating magnetic frustration to improve single-crystalline nonstoichiometric Li 1.06 Ni 0.90 Mn 0.04 O 2 for lithium-ion batteries7Quantification of single crystallinity in single crystal cathodes for lithium-ion batteries3Research on the Modification of Nickel-Rich Ternary Cathode Materials for Lithium-Ion Batteries through Ba2+ Doping0Techno-Economic Analysis of For Flame-Assisted Spray Pyrolysis For Production of High-Nickel Ternary Cathode Material Precursors0Enhancing Electrochemical Performance of Ni-rich Cathode by Utilizing Organic Anhydride Cathode Additive0Insight of Synthesis of Single Crystal Ni‐Rich LiNi 1−x−y Co x Mn y O 2 Cathodes104Controlled crystallinity of LiTaO3 surface layer for single-crystalline Ni-rich cathodes for lithium-ion batteries and all-solid-state batteries31Unique insights into the design of low-strain single-crystalline Ni-rich cathodes with superior cycling stability46Energy ceramic design for robust battery cathodes and solid electrolytes15Optimized In Situ Doping Strategy Stabling Single-Crystal Ultrahigh-Nickel Layered Cathode Materials78Degradation Processes in Current Commercialized Li-Ion Batteries and Strategies to Mitigate Them24Localized High‐Concentration Sulfone Electrolytes with High‐Voltage Stability and Flame Retardancy for Ni‐Rich Lithium Metal Batteries24Surface Engineering of Cathode Materials: Enhancing the High Performance of Lithium‐Ion Batteries48Systematic study on anisotropic lattice volume changes in Ni-rich layered oxides: Role of doping and gradient coating11Prospects and Strategies for Single‐Crystal NCM Materials to Solve All‐Solid‐State Battery Cathode Interface Problems48Single-crystal TiNb2O7 materials via sustainable synthesis for fast-charging lithium-ion battery anodes21Rational design of practical layered transition metal oxide cathode materials for sodium-ion batteries12Modulating Surface Architecture and Electronic Conductivity of Li‐rich Manganese‐Based Cathode54Direct Upcycling of Degraded LiCoO2 Material Toward High‐Performance Single‐Crystal NCM Cathode36Recent developments in coating investigation of LiNixMnyCo1-x-yO2 cathode material with promising (Li, Ni) rich layered for future generation lithium-ion batteries19Surface Atomic Rearrangement with High Cation Ordering for Ultra‐Stable Single‐Crystal Ni‐Rich Co‐Less Cathode Materials21Resources, energy consumption and economic analysis for flame synthesis of ternary cathode materials11Morphologically and Compositionally Controlled Cs2SbBr6 by Bi and Ag Substitution0Surface Phase Engineering stabilizes cycling of zero-cobalt single-crystalline layered cathodes11Restraining Planar Gliding in Single‐Crystalline LiNi 0.9 Co 0.05 Mn 0.05 O 2 Cathodes by Combining Bulk and Surface Modification Strategies33Restraining Planar Gliding in Single‐Crystalline LiNi0.9Co0.05Mn0.05O2 Cathodes by Combining Bulk and Surface Modification Strategies0Biopolymer‐Based Gel Electrolytes for Advanced Zinc Ion Batteries: Progress and Perspectives78Air Storage Impact on Surface Evolution of Stoichiometric and Li-Rich NMC81110A comprehensive understanding on the anionic redox chemistry of high-voltage cathode materials for high-energy-density lithium-ion batteries113Enabling High-Voltage and Long Lifespan Sodium Batteries via Single-Crystal Layer-Structured Oxide Cathode Material51Mitigating Diffusion‐Induced Intragranular Cracking in Single‐Crystal LiNi 0.5 Mn 1.5 O 4 via Extended Solid‐Solution Behavior5Mitigating Diffusion‐Induced Intragranular Cracking in Single‐Crystal LiNi 0.5 Mn 1.5 O 4 via Extended Solid‐Solution Behavior19Molten salts assisted synthesis of single crystalline NCM811 with surface modification for high energy density lithium‐ion batteries9Strontium Doping Promotes Low-Temperature Growth of Single-Crystalline Ni-Rich Cathodes with Enhanced Electrochemical Performance6Recent progress on solvent-free electrode fabrication for lithium-based batteries20Strengthened Zinc Anode by Trace Natural Amino Acid β-Alanine in Aqueous Electrolyte Inspired by Synial Membrane: An Experimental Survey6Cation/Anion Co‐Doping Enhances Oxygen Redox Reversibility and Structural Stability in Single‐Crystal Li‐Rich Mn‐Based Cathodes for Wide‐Temperature Performance18Techno-economic analysis of flame synthesized composite oxide precursor for high-nickel ternary cathode material8Charting the path to sustainable energy: Green polymer electrolytes for zinc-air batteries3Design Principles and Engineering Strategies for Stabilizing Ni-Rich Layered Oxides in Lithium-Ion Batteries15Recent Advances in Nanoparticle-Based Corrosion Inhibition of Metals: A Review10Thermal and morphological optimisation of Nd 2 O 3 -doped LiNi 8 Mn 1 Co 1 via hydrothermal synthesis and finite element analysis for high-performance hybrid supercapacitors0In-situ constructing Na-conductive and protective surface layer towards air-stable and durable O3-type single-crystal oxide7Tailoring the cathode-electrolyte interface in high-nickel single crystal cathodes for improved ionic transport in sulfide-based all-solid-state-batteries9Multiscale Failure Mechanisms of Ternary Oxide Cathode Materials for Lithium‐Ion Batteries49Oxygen vacancy-induced spinel phase and Li3PO4 coating enabling performance promotion of Li1.2Mn0.54Ni0.13Co0.13O2 cathodes2Fast‐Charging Single‐Crystalline O3‐NaNi 1/3 Fe 1/3 Mn 1/3 O 2 via Molten Salt Synthesis for Sodium‐Ion Batteries3Flash-sintering-assisted low-temperature synthesis of single-crystalline, high-nickel cobalt-free cathodes for lithium-ion batteries0Precursor engineering enables kinetically favorable synthesis of single-crystal Ni-rich layered oxides for high-energy lithium-ion batteries5Rational Design of NMM811: A Cobalt‐Free Cathode Rivalling NMC811 in Performance and Stability4Modeling Single-Crystal Battery Materials: From Fundamental Understanding to Performance Evaluation4Anion‐Adsorption Mediated Facet Engineering and Surface Phase Regulation for Boosting Kinetics of Li‐Rich Layered Oxides13D phase-field modeling of H2→H3 phase transition induced intragranular cracking in single-crystal Ni-rich layered cathodes2Lattice Reordering from High-Valence Mo Segregation for High-Nickel Cobalt-Free Cathodes6Review on the dimensionality (0D3D) of NCM cathode morphologies: Impact on electrochemical performance in lithium-ion batteries2Understanding the Performance Gap between Polycrystalline and Single-Crystal Nickel-Rich Layered Oxide Cathodes13Single-crystal layer-structured metal oxide cathode material for high-voltage sodium ion batteries1Bifunctional Role of Surface Cobalt Doping as a Lithium‐Residue Scavenger and Surface Stabilizer in Single‐Crystalline Ultrahigh‐Ni Cathodes2Lightweight design and underbody safety of new energy vehicle battery systems: A comprehensive review with an emphasis on aluminum foam-based enclosures7Synthesis and Characterizations of CeO₂ Nanoparticles for Gas Sensing Application0Dual-ion modification strategy for high-voltage mid-Ni single-crystal cathode1Enhancing Cycling Stability and Power Density of Ni-Rich NMC811 through CaTiO 3 Surface Coating: A Combined Experimental and Atomistic-Scale Study0Lattice, Grain, and Texture: Opportunities for Performance Enhancement of Layered Oxide Cathodes Informed by LiCoO 25Single-crystal layered oxides as cathode materials for next-generation lithium-ion batteries0Modulating carbon binder domain viscoelasticity suppresses time-dependent spring-back in single-crystal cathodes1Synergistic enhancement of structural and electrical properties in Co3O4-reinforced PVA/HPMC/CMC bio-nanocomposites for advanced dielectric applications1Acoustic Resonance-Built Island Al2O3/Li3PO4 Coating Realizes Bulk Dual Synergy for Stabilizing Single-Crystal High-Ni Cathodes0High-Nickel Single-Crystal LiNi0.9Co0.05Mn0.05O2 Cathode Materials Synthesized via One-Step All-Dry Process for Lithium-Ion Batteries0Curvature-Driven Modulation of Waveguide Lasing in Buckled CdS Nanowires for Mechanically Reconfigurable On-Chip Light Sources0Toward Single‐Crystal Upcycling of Degraded Lithium‐Ion Battery Cathodes0

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  42. Mitigating magnetic frustration to improve single-crystalline nonstoichiometric Li 1.06 Ni 0.90 Mn 0.04 O 2 for lithium-ion batteries

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  43. Quantification of single crystallinity in single crystal cathodes for lithium-ion batteries

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  44. Research on the Modification of Nickel-Rich Ternary Cathode Materials for Lithium-Ion Batteries through Ba2+ Doping

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    瑞韩 唐

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  45. Techno-Economic Analysis of For Flame-Assisted Spray Pyrolysis For Production of High-Nickel Ternary Cathode Material Precursors

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  46. Enhancing Electrochemical Performance of Ni-rich Cathode by Utilizing Organic Anhydride Cathode Additive

    Unknown journal · 2024-01-23

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