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RESEARCH PAPER · Chemical Engineering Journal · 2022

Simultaneous construction of impermeable dual-shell stabilizing fluoride phosphors for white light-emitting diodes

Peilan Luo, Menglin Ye, Wenli Zhou, Pingping Wan, Zhongyun Ma, Zhongxian Qiu, Jilin Zhang, Ru‐Shi Liu, Shixun Lian

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Simultaneous construction of impermeable dual-shell stabilizing fluoride phosphors for white light-emitting diodesOriginalManganese activated narrowband red-emitting Cs2KInF6:Mn4+ phosphor with high colour purity for backlight display16Surface lattice enhancement of red-emitting fluorides enabled by embedding small cations8Hydroquinone-modified Mn4+-activated fluoride red phosphors with improved water-resistance19Recent Research Progress of Mn4+-Doped A2MF6 (A = Li, Na, K, Cs, or Rb; M = Si, Ti, Ge, or Sn) Red Phosphors Based on a Core–Shell Structure28Highly efficient and water-resistant K3ZrF7:Mn4+ red-emitting phosphors21Optimizing the luminescent performance and water resistance of K2SiF6:Mn4+ phosphor by doping Li+ and coating BaSO414Oxyfluoride K3MoO2F5·2H2O:Mn4+ red phosphor with enhanced luminescence and moisture resistance for WLED indoor lighting and wide gamut display applications16Ion exchange-promoted surface reduction strategy: For improving the water-resistance of K2SiF6:Mn4+ red phosphors28Surface passivation of red-emitting fluoride phosphors by aminocarboxyl complexants to achieve high water-resistance for light-emitting diodes7Preparation of red phosphor K2SiF6:Mn4+ with high water-resistant and negative thermal quenching effect induced by citric acid-passivation22Enhanced luminescence encryption via Mn4+ activation with organic acid surface modification10Reconstructing the Surface of K 2 SiF 6 :Mn 4+ Phosphors toward Enhanced Moisture Resistance for White LED Applications12A Core@Dual-Shell Mn4+-activated fluoride phosphors toward highly moisture-stable light-emitting diodes with enhanced luminescence efficiency10One-step reconstruction of K2SiF6:Mn4+ with diacetyl compounds through combination of doping, surface deactivation and coating for wLED applications3Progress in the modulation of fluorescence intensity, lifetime, polychromaticity, and stability for information encryption and printing compatibility3Achieving moisture-stable red emission in core-shell-structured Mn4+-Doped fluoride phosphors for white LEDs3Progress of surface-modified inorganic phosphors for performance improvement: from methods to applications7Low-temperature crystallization of the K 2 TiF 6 :Mn 4+ phosphor with near-unity quantum efficiency in dilute HF solution1Exploiting structural benefit of cyclotetraphosphate for delayed quenching concentration of Eu3+ luminescence and efficiency enhancement via co-doping alkali metal1Thermostable luminescence and efficient energy transfer from Tb3+ to Sm3+ in a cyclo-tetraphosphate phosphor1Reductive inorganic dual-shell constructs fluoride red phosphors with negative humid quenching and intrinsic self-healing ability0Surface modification of K₂SiF₆:Mn⁴⁺ phosphors with N-(2-Acetamido)iminodiacetic acid for improved moisture resistance in white light-emitting diode applications0Revisiting the Spectrum–Crystal Field Relationship of 3d 3 Ion (Mn 4+ /Cr 3+ )‐Activated Phosphors via a Recalibrated Database0Surface Reconstruction and Controllable Synthesis of Mn4+-Activated Narrow-Band Fluoride Red Phosphors0

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  1. Manganese activated narrowband red-emitting Cs2KInF6:Mn4+ phosphor with high colour purity for backlight display

    Ceramics International · 2022-08-31

    Yong Liu, Shuai Cheng, Shengchun Yang, Zongtao Li, Zhenjuan Duan, Zhanjiang Hu, Zhengui Li, Yue‐Hua Li, Lili Yu, Anzhong Peng, Xiaodong Wen

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  2. Surface lattice enhancement of red-emitting fluorides enabled by embedding small cations

    Inorganic Chemistry Frontiers · 2023-01-01

    Pingping Wan, Chen Yang, Aolin Wang, Liping Yu, Shixun Lian, Wenli Zhou

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  3. Hydroquinone-modified Mn4+-activated fluoride red phosphors with improved water-resistance

    Colloids and Surfaces A Physicochemical and Engineering Aspects · 2023-01-09

    Feilong Liu, Yingyuan Chen, Bojana Milićević, Chunyan Jiang, Senchuan Huang, Lei Zhou, Jianbang Zhou, Mingmei M. Wu

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  4. Recent Research Progress of Mn4+-Doped A2MF6 (A = Li, Na, K, Cs, or Rb; M = Si, Ti, Ge, or Sn) Red Phosphors Based on a Core–Shell Structure

    Nanomaterials · 2023-02-02

    Yueping Xie, Tian Tian, Chengling Mao, Zhenyun Wang, Jingjia Shi, Yang Li, Cencen Wang

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  5. Highly efficient and water-resistant K3ZrF7:Mn4+ red-emitting phosphors

    Journal of Luminescence · 2023-04-20

    Tengzhi Zhao, Wenqin Luo, Kaixin Peng, Tian Rong, Jiang Hu, Kaifang Lu, Xinshun Wei

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  6. Optimizing the luminescent performance and water resistance of K2SiF6:Mn4+ phosphor by doping Li+ and coating BaSO4

    Journal of Luminescence · 2023-07-01

    Hu Wang, Yanan Li, Xiaoyi Liu, Linfang Ma, Xue Wang, Guixia Liu, Shengda Liu, Jinxian Wang, Dan Li, Wensheng Yu, Xiangting Dong

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  7. Oxyfluoride K3MoO2F5·2H2O:Mn4+ red phosphor with enhanced luminescence and moisture resistance for WLED indoor lighting and wide gamut display applications

    Journal of Alloys and Compounds · 2023-07-10

    Xiaoyi Liu, Haiming Cheng, Hu Wang, Yanan Li, Guixia Liu, Shengda Liu, Dan Li, Jinxian Wang, Wensheng Yu, Xiangting Dong

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  8. Ion exchange-promoted surface reduction strategy: For improving the water-resistance of K2SiF6:Mn4+ red phosphors

    Ceramics International · 2023-08-18

    Henghuan Ruan, Tianman Wang, Lin Wang, Yuelan Li, Jun Lei, Daishu Deng, Jiawei Qiang, Sen Liao, Yingheng Huang

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  9. Surface passivation of red-emitting fluoride phosphors by aminocarboxyl complexants to achieve high water-resistance for light-emitting diodes

    Journal of Luminescence · 2024-02-12

    Fan Su, Zhiyue Liu, Jieyi Yuan, Li Hou, Tongyi Liang, Yifei Wang, Qinfang Zhang, Yong Bing Dai, Shuhong Cao, Jingwen Chen

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  10. Preparation of red phosphor K2SiF6:Mn4+ with high water-resistant and negative thermal quenching effect induced by citric acid-passivation

    Journal of Luminescence · 2024-02-29

    Yan Yu, Chunxiao Jiang, Guangtao Chang, Sen Liao, Ruoxin Li

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  11. Enhanced luminescence encryption via Mn4+ activation with organic acid surface modification

    Ceramics International · 2024-09-12

    Yan Yu, Yiqing Zhang, Yongshuai Li, Yongshuai Li, Wenjing Xie, Yuhang Wang, Xianwu Gao, Tong Yu, Tiantian Wang, Guangtao Chang, Ruoxin Li

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  12. Reconstructing the Surface of K 2 SiF 6 :Mn 4+ Phosphors toward Enhanced Moisture Resistance for White LED Applications

    ACS Applied Materials & Interfaces · 2024-10-08

    Y.F. Wei, Qianxing Huang, Shijie Yu, Qiyue Shao, Jianqing Jiang

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  13. A Core@Dual-Shell Mn4+-activated fluoride phosphors toward highly moisture-stable light-emitting diodes with enhanced luminescence efficiency

    Ceramics International · 2025-03-10

    Xinhua Li, Yimin Gu, Sifei Liu, Haoyu Yang, Jiaqi Zhou, Xiaoxiao Huang, Donghui Zhang, Qiang Zhao

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  14. One-step reconstruction of K2SiF6:Mn4+ with diacetyl compounds through combination of doping, surface deactivation and coating for wLED applications

    Optical Materials · 2025-08-08

    Zhiyue Liu, Tongyi Liang, Li Hou, Shi Wenyan, Shuhong Cao, Yong Bing Dai, Jingwen Chen

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  15. Progress in the modulation of fluorescence intensity, lifetime, polychromaticity, and stability for information encryption and printing compatibility

    Journal of Alloys and Compounds · 2025-08-31

    Yan Yu, Jiayi Fu, Guangtao Chang, Ruoxin Li

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  16. Achieving moisture-stable red emission in core-shell-structured Mn4+-Doped fluoride phosphors for white LEDs

    Materials Today Chemistry · 2025-11-21

    Yurong Guo, Mengyan Yang, Fengsong Tan, Peng Ren, Jing Wan, Yanqing Ye, Huaijun Tang, Qiang Zhou, Zhengliang Wang

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  17. Progress of surface-modified inorganic phosphors for performance improvement: from methods to applications

    Chemical Society Reviews · 2025-12-24

    Fuyan Su, Wei Wang, Piaoyang Wu, Zhenchuan Hu, Hang Yang, Jinxuan Sun, Hanrui Liao, Yi Wei, Hua Zou, Guogang Li

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  18. Low-temperature crystallization of the K 2 TiF 6 :Mn 4+ phosphor with near-unity quantum efficiency in dilute HF solution

    Journal of Materials Chemistry C · 2026-01-01

    Tianyue Shi, Yusen Liu, Dan Yue, Liying Zhang, Haipeng Ji

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  19. Exploiting structural benefit of cyclotetraphosphate for delayed quenching concentration of Eu3+ luminescence and efficiency enhancement via co-doping alkali metal

    Applied Materials Today · 2026-03-19

    WeiGang WANG, Xichen Guo, Bowen Wang, Xianchen Huang, Yazhuo Lv, Wenjie Sun, Hongming Jiang, Wei Qian, Zhonghe Xu, Junpeng Li, Jing Zhu

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  20. Thermostable luminescence and efficient energy transfer from Tb3+ to Sm3+ in a cyclo-tetraphosphate phosphor

    Applied Materials Today · 2026-04-17

    Chengfan Di, Asif Ali Haider, Mincheng Jiang, Chenyang Jia, Xianchen Huang, Yuting Luo, Xiaoshuang Tang, Haowen Chen, Zhonghe Xu, Xiongwei Dai, Junpeng Li, Jing Zhu

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  21. Reductive inorganic dual-shell constructs fluoride red phosphors with negative humid quenching and intrinsic self-healing ability

    Ceramics International · 2026-06-14

    Zengli Ouyang, Jiaqing Peng, Jiangyan Xu, Fu Du, Yi-Xiang Wang, Yipeng Liu, Yanfei Xiao, Decai Huang, Dasheng Lu, Xinyu Ye

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  22. Surface modification of K₂SiF₆:Mn⁴⁺ phosphors with N-(2-Acetamido)iminodiacetic acid for improved moisture resistance in white light-emitting diode applications

    Journal of Alloys and Compounds · 2026-06-24

    Ying Wang, Song Zhu, Dongwei Li

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  23. Revisiting the Spectrum–Crystal Field Relationship of 3d 3 Ion (Mn 4+ /Cr 3+ )‐Activated Phosphors via a Recalibrated Database

    Advanced Functional Materials · 2026-09-01

    Jiayu Wu, Zhenzhen ZHANG, Jie Chen, Xiaoze Yuan, Zhongxian Qiu, Yuwei Zhou, Fan Ding, Shixun Lian, Xiaodong Wen

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  24. Surface Reconstruction and Controllable Synthesis of Mn4+-Activated Narrow-Band Fluoride Red Phosphors

    ACS Applied Optical Materials · 2026-09-07

    Yuhuan Tan, Wenli Zhou

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