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RESEARCH PAPER · Angewandte Chemie · 2022

Intermolecular Energy Gap‐Induced Formation of High‐Valent Cobalt Species in CoOOH Surface Layer on Cobalt Sulfides for Efficient Water Oxidation

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Intermolecular Energy Gap‐Induced Formation of High‐Valent Cobalt Species in CoOOH Surface Layer on Cobalt Sulfides for Efficient Water OxidationOriginalCeO2 Functionalized Cobalt Layered Double Hydroxide for Efficient Catalytic Oxygen‐Evolving Reaction73Copper foam-derived electrodes as efficient electrocatalysts for conventional and hybrid water electrolysis63Heterophase stimulated active species evolution in iron/cobalt sulfide nanocomposites for oxygen evolution19Enhanced photocatalytic ammonia generation from water and nitrogen by decorating BiOCl nanosheets with CoOOH oxygen evolution reaction cocatalyst15Flower-like Co3O4@NiFe-LDH nanosheets enable high-performance bifunctionality towards both electrocatalytic HER and OER in alkaline solution72Modulation of the interfacial charge density on Fe2P–CoP by coupling CeO2 for accelerating alkaline electrocatalytic hydrogen evolution reaction and overall water splitting115Direct detection of self-reconstruction-accelerated oxygen evolution activity in MoCoNi hydroxides6Impact in rational synthesis Co-ZIF templates for derived the structural Co@NC catalysis for high efficient hydrogen and oxygen evolution reactions22Effect of Proton Transfer on Electrocatalytic Water Oxidation by Manganese Phosphates56Effect of Proton Transfer on Electrocatalytic Water Oxidation by Manganese Phosphates12Design of the Heterostructure Consisting of Cop and Nife Layered Double Hydroxide for Efficient Seawater Electrolysis0Structural, Morphological, Compositional and Optical Properties of Cos2 Thin Films Synthesized by Adsorption-Diffusion Method0Tailoring the d-band center of porous CoS 2 nanospheres via low-electronegative Fe for weakened OH* adsorption and boosted oxygen evolution27Three-dimensional carbon network-supported black phosphorus-cobalt heterojunctions: An efficient electrocatalyst for high-rate oxygen evolution4Direct Dioxygen Radical Coupling Driven by Octahedral Ruthenium–Oxygen–Cobalt Collaborative Coordination for Acidic Oxygen Evolution Reaction405Space‐Confined Growth of Co9S8 Nanoparticles in Covalent Organic Framework‐Derived Porous Carbon for Efficient Bifunctional Oxygen Electrocatalysis9Quantum chemical investigation of the electronic, optoelectronic, X-ray spectroscopy, and hydrogen storage capacity of AHfO3/BAgO3 (A = Cs, Ag; B = Hf, Cs) perovskite materials13Cu-doped CoOOH activates peroxymonosulfate to generate high-valent cobalt-oxo species to degrade organic pollutants in saline environments146Molecular Mechanisms of Oxygen Evolution Reactions for Artificial Photosynthesis13Sustainable engineering of wool keratin towards cobalt atoms fixation for enhanced electrocatalytic water splitting2Constructing Hierarchical Hollow Microspheres with Cos/Co9s8 Heterostructured Nanosheets for High-Performance Sodium Storage0Constructing Hierarchical Hollow Microspheres with Cos/Co9s8 Heterostructured Nanosheets for High-Performance Sodium Storage0Electrochemical water splitting enhancement by introducing mesoporous NiCoFe-trimetallic phosphide nanosheets as catalysts for the oxygen evolution reaction17Water-surface reconstruction of sulfurized spinel-structured oxide oxygen catalysts for alkaline water electrolysis14Fe doping regulates the surface reconstruction and activates lattice oxygen of NiCr LDH for water oxidation65Zeolitic Imidazolate Framework-Derived Co 3 S 4 @NiFe-LDH Core–Shell Heterostructure as Efficient Bifunctional Electrocatalyst for Water Splitting29Electrochemically Induced Ru/CoOOH Synergistic Catalyst as Bifunctional Electrode Materials for Alkaline Overall Water Splitting25Composition-tunable Co3-xFexSe4 as efficient electrocatalysts for the oxygen evolution reaction3The CoSe2 hollow cube/CoSe2 nanosheet interface catalyst for efficient electrolysis of urea–assisted hydrogen production at industrial–grade currents76Ultrathin BiOCl-OV/CoAl-LDH S-scheme heterojunction for efficient photocatalytic peroxymonosulfate activation to boost Co (IV)=O generation132In situ fabrication of low-crystallinity (Ni,Fe)xSy nanosheet arrays via room-temperature corrosion engineering toward efficient oxygen evolution20p-Block anion compressed d/p band center of bifunctional oxygen electrocatalysts for durable aqueous Zn–air batteries35Dynamic Cation Intercalation Facilitating Chemical Oxidation of Water and Surface Stabilization During the Oxygen Evolution Reaction6Component synergistic effect of Co9S8/FeBOx composite system for efficient oxygen evolution reaction2Structural, morphological, compositional and optical properties of CoS2 thin films synthesized by adsorption-diffusion method4Topological Synthesis of 2D High‐Entropy Multimetallic (Oxy)hydroxide for Enhanced Lattice Oxygen Oxidation Mechanism45Sputtering induced the architecture of “needle mushroom” shaped Cu2O–NiCo2O4 heterostructure with novel morphology and abundant interface for high-efficiency electrochemical water oxidation5Boosting surface reconstruction in engineered nickel sites through selenium vacancies to enhance urea oxidation reaction10Heterostructure Engineering of Bimetallic Ni-Fe Hydroxide Decorated in Nickel Sulfides Array as Bifunctional Electrocatalyst for Efficient Water Splitting0In situ carbon-encapsulated CoS2/Zn0.76Co0.24S composite derived from intercalated CoZn-layered double hydroxide precursor for overall water splitting8Dynamic in-situ reconstruction of active site circulators for photo-Fenton-like reactions57Chemical Fermentation PoreCreation on Multilevel Bio-Carbon Structure with In Situ Ni–Fe Alloy Loading for Superior Oxygen Evolution Reaction Electrocatalysis8Tantalum doping triggered electronic reconfiguration of cobalt phosphide for efficient and stable overall seawater splitting7Synergistic crystal facet and defect engineering in Co3O4 drive selective CoIVO formation for efficient peracetic acid activation10Field‐Controlled Hydroxide Dynamics Drive High‐Valence Surface Reconstruction of Ferromagnetic Alloy Nanocones Toward Efficient Oxygen Evolution9Delicate Control of the Shell Structure of N‐Doped Carbon‐Coated Fe 2 P/Ni 2 P Hollow Spheres for Efficient Urea‐Assisted Hydrogen Evolution6B-site substituting strategy to boost the oxygen evolution reaction activity of hexagonal perovskite oxide 10H-BaCo0.9Ru0.1O3-δ1Study of the ReS₂-CoO/CoS₂ Heterostructure for Efficient Bifunctional Electrocatalysis1Synergistic Cr-doping and crystalline/amorphous heterointerface engineering to promote surface reconstruction of FeCo LDH for efficient oxygen evolution4Synergistic modulation of CoOOH by dual-defects to enhance the catalytic performance of the oxygen evolution reaction1One-step electrodeposition of Fe-doped CoS₂ nanosheets for efficient hydrogen evolution0Distal Spin Modulation in Two‐dimensional van der Waals VS 2 /FePSe 3 @Ni Heterostructure for Electrocatalytic Oxygen Reduction Reaction1Structure‐Property‐Application Correlations of Early Transition Metal Chalcogenides: A Dichalcogenide‐Centered Perspective5Boosting Alkaline Oxygen Evolution Kinetics by Tailoring the Noncovalent Interaction on CoOOH1Relay Low‐Valence Co Dynamic Cycle Stabilized CoFe Oxyhydroxides for 700 h at 1 A cm −2 in Alkaline Water Oxidation1CuS Nanoflower-Supported Co3O4 p–p Heterojunction Interface Structure for Efficient Oxygen Evolution Reaction0Selective Electrosynthesis of High‐Concentration Mn IV ═O in Oxidant‐Free Systems for Sustainable Water Remediation0Spin-influenced oxygen evolution driven by a honeycomb quantum magnet0

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  1. CeO2 Functionalized Cobalt Layered Double Hydroxide for Efficient Catalytic Oxygen‐Evolving Reaction

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  2. Copper foam-derived electrodes as efficient electrocatalysts for conventional and hybrid water electrolysis

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  3. Heterophase stimulated active species evolution in iron/cobalt sulfide nanocomposites for oxygen evolution

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  4. Enhanced photocatalytic ammonia generation from water and nitrogen by decorating BiOCl nanosheets with CoOOH oxygen evolution reaction cocatalyst

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  5. Flower-like Co3O4@NiFe-LDH nanosheets enable high-performance bifunctionality towards both electrocatalytic HER and OER in alkaline solution

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  6. Modulation of the interfacial charge density on Fe2P–CoP by coupling CeO2 for accelerating alkaline electrocatalytic hydrogen evolution reaction and overall water splitting

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  7. Direct detection of self-reconstruction-accelerated oxygen evolution activity in MoCoNi hydroxides

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  8. Impact in rational synthesis Co-ZIF templates for derived the structural Co@NC catalysis for high efficient hydrogen and oxygen evolution reactions

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  9. Effect of Proton Transfer on Electrocatalytic Water Oxidation by Manganese Phosphates

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  10. Effect of Proton Transfer on Electrocatalytic Water Oxidation by Manganese Phosphates

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  11. Design of the Heterostructure Consisting of Cop and Nife Layered Double Hydroxide for Efficient Seawater Electrolysis

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  12. Structural, Morphological, Compositional and Optical Properties of Cos2 Thin Films Synthesized by Adsorption-Diffusion Method

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  13. Tailoring the d-band center of porous CoS 2 nanospheres via low-electronegative Fe for weakened OH* adsorption and boosted oxygen evolution

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  14. Three-dimensional carbon network-supported black phosphorus-cobalt heterojunctions: An efficient electrocatalyst for high-rate oxygen evolution

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  15. Direct Dioxygen Radical Coupling Driven by Octahedral Ruthenium–Oxygen–Cobalt Collaborative Coordination for Acidic Oxygen Evolution Reaction

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  16. Space‐Confined Growth of Co9S8 Nanoparticles in Covalent Organic Framework‐Derived Porous Carbon for Efficient Bifunctional Oxygen Electrocatalysis

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  17. Quantum chemical investigation of the electronic, optoelectronic, X-ray spectroscopy, and hydrogen storage capacity of AHfO3/BAgO3 (A = Cs, Ag; B = Hf, Cs) perovskite materials

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  18. Cu-doped CoOOH activates peroxymonosulfate to generate high-valent cobalt-oxo species to degrade organic pollutants in saline environments

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  19. Molecular Mechanisms of Oxygen Evolution Reactions for Artificial Photosynthesis

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  20. Sustainable engineering of wool keratin towards cobalt atoms fixation for enhanced electrocatalytic water splitting

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  21. Constructing Hierarchical Hollow Microspheres with Cos/Co9s8 Heterostructured Nanosheets for High-Performance Sodium Storage

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  23. Electrochemical water splitting enhancement by introducing mesoporous NiCoFe-trimetallic phosphide nanosheets as catalysts for the oxygen evolution reaction

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  25. Fe doping regulates the surface reconstruction and activates lattice oxygen of NiCr LDH for water oxidation

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  31. In situ fabrication of low-crystallinity (Ni,Fe)xSy nanosheet arrays via room-temperature corrosion engineering toward efficient oxygen evolution

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  33. Dynamic Cation Intercalation Facilitating Chemical Oxidation of Water and Surface Stabilization During the Oxygen Evolution Reaction

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  34. Component synergistic effect of Co9S8/FeBOx composite system for efficient oxygen evolution reaction

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  50. Synergistic modulation of CoOOH by dual-defects to enhance the catalytic performance of the oxygen evolution reaction

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