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RESEARCH PAPER · The Journal of Organic Chemistry · 2021

Fluorine: A Very Special Element and Its Very Special Impacts on Chemistry

Stefanie Dehnen, Laurel L. Schafer, Thomas Lectka, Antonio Togni

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Fluorine: A Very Special Element and Its Very Special Impacts on ChemistryOriginal[Retracted] Fluoride Exposure Suppresses Proliferation and Enhances Endoplasmic Reticulum Stress and Apoptosis Pathways in Hepatocytes by Downregulating Sirtuin‐15Carbonyl and Isocyanide Complexes of Copper and Silver Supported by Fluorinated Poly(pyridyl)borates20Direct C(sp3)–H Polyfluoroarylation: Access to Polyfluoroaryl Amino Acids via Rh-Catalyzed Selective C–F Bond Cleavage3Saliva microbiome alterations in dental fluorosis population20Fluorine-a small magic bullet atom in the drug development: perspective to FDA approved and COVID-19 recommended drugs112Fluorinated electrode materials for high-energy batteries70Hypervalent Halogen Compounds in Electrochemical Reactions: Advantages and Prospects13N-(2,3-Difluorophenyl)-2-fluorobenzamide1Bridging organic, molecular, macromolecular, supramolecular and biological sciences to create functions via fluorine chemistry and fluorinated reagents15Prediction of 19F NMR chemical shifts for organic compounds with ORCA7A review of frustrated Lewis pair enabled monoselective C–F bond activation53“Fluorine Effects” in Conformational Orchestration of α/β Hybrid Peptide with a 9‐membered Pseudo β‐Turn Motif2Enzyme Engineering Renders Chlorinase the Activity of Fluorinase10Beyond Natural Channel Proteins: Recent Advances in Fluorinated Nanochannels11From alternate routes to fluorspar (CaF2) or anhydrous HF (aHF) to conversion of fluorspar into a nucleophilic fluorinating agent3(Radio)Fluoro-iodination of Alkenes Enabled by a Hydrogen Bonding Donor Solvent5Nucleophilic substitution of hydrogen (SNH) in 1,2,3-triazole 1-oxides in the synthesis of pentafluorophenylated azaheterocycles0Chloroimidazolium Deoxyfluorination Reagent with H2F3– Anion as a Sole Fluoride Source6Understanding the Selective Removal of Perfluoroalkyl and Polyfluoroalkyl Substances via Fluorine–Fluorine Interactions: A Critical Review73Late-Stage Halogenation of Complex Substrates with Readily Available Halogenating Reagents72Design of Ionic Liquids for HF/HFC-245fa Superefficient Separation: COSMO-RS Selection and Process Assessment2Highly enhanced fluoride removal from aqueous systems via solvent extraction utilizing trialkyl phosphine oxide as an efficient extractant10Polyfluorinated reagents for peptide stapling2Covalent Organic Frameworks Enhance Photocatalytic Hydrogen Peroxide Production through Synergistic Effects1056,7,8,9-Tetrafluoro-11H-indeno[1,2-b]quinoxalin-11-one2Value-added transformation of third-generation hydrofluorocarbon refrigerant0Dual Photoredox/Copper-Catalyzed Radical cis-Selective Allylic Trifluoromethylation2HF‐Free Manufacturing of Fluorochemicals from Fluorspar0HF‐Free Manufacturing of Fluorochemicals from Fluorspar0Fluorinated Aromatic Amide Helices: Synthesis and Modeling of Helical Handedness6Packing structures and piezochromic properties engineering through F functionalization in 4-position substituted coumarin based organic luminogens1Palladium‐Catalyzed Non‐Directed C─H Functionalization of Arenes with Trifluoromethylated Olefins2Synthesis and Preclinical Evaluation of Novel 99mTc-Labeled Glucose Derivatives Containing Different Proline Analogs as Linker Moieties for Tumor Imaging0Enhancing NMR Signals in Liquids by Fluorine‐19 Overhauser Dynamic Nuclear Polarization (DNP) and Hyperpolarization Transfer to Carbon‐132Enhancing NMR Signals in Liquids by Fluorine‐19 Overhauser Dynamic Nuclear Polarization (DNP) and Hyperpolarization Transfer to Carbon‐134Difluoromethylation of N-heterocyclic biomolecules23,4-Dicyanofuroxan and its heavier congeners: chalcogen-dependent switching between π- and σ-hole interactions in chalcogen bonding-based recognition and sensing of Lewis bases0Continuous flow photochemical C–H functionalization of 2-oxindole for C-3 selective fluorination0Metal- and photosensitizer-free hydrodifluoromethylation of unactivated alkenes via acetamide-activated difluoromethyl aryl sulfones7Regiospecific dearomative [2π + 2σ] photo-cycloaddition of polyfluoronaphthalenes with bicyclo[1.1.0]butanes via energy transfer catalysis2Silver‐Catalyzed Three‐Component Radical Aminofluorination of Arylalkenes with Selectfluor and Amino N ‐Heterocycles0Machine Learning-assisted QSPR modeling for accurate prediction of normal boiling points in organic fluorides0Understanding the Defluorination Mechanism of Per‐ and Polyfluoroalkyl Substances in Wastewater: From Microscopic Process to Practical Application2Intermediate-phase-directed crystallization kinetics and defect passivation synergy for high-efficiency formamidinium-based perovskite solar cells0Fluorine-Expedited Sulfur Vacancy of Mn0.6Cd0.4S Photocatalyst Enables High-Efficiency Hydrogen Production0

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45 direct citing papers saved.

  1. [Retracted] Fluoride Exposure Suppresses Proliferation and Enhances Endoplasmic Reticulum Stress and Apoptosis Pathways in Hepatocytes by Downregulating Sirtuin‐1

    BioMed Research International · 2022-01-01

    Yan-Long Yu, Ling Li, Wenfeng Yu, Zhizhong Guan

    Read original paper ↗ ·

  2. Carbonyl and Isocyanide Complexes of Copper and Silver Supported by Fluorinated Poly(pyridyl)borates

    Organometallics · 2022-05-05

    Mukundam Vanga, Anurag Noonikara‐Poyil, Jiang Wu, H. V. Rasika Dias

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  3. Direct C(sp3)–H Polyfluoroarylation: Access to Polyfluoroaryl Amino Acids via Rh-Catalyzed Selective C–F Bond Cleavage

    The Journal of Organic Chemistry · 2022-10-13

    Xuan-Wen Tao, Li−Na Yi, Meng-Yi Huang, Yun Fu, Qiang Yang

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  4. Saliva microbiome alterations in dental fluorosis population

    Journal of Oral Microbiology · 2023-02-20

    Shanshan Liu, Qiangsheng Song, Chenchen Zhang, Mengwan Li, Zhenzhen Li, Yudong Liu, Xu Li, Xiaofei Xie, Lili Zhao, Rongxiu Zhang, Qinglong Wang, Guojin Zeng, Yifan Zhang, Kai Zhang

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  5. Fluorine-a small magic bullet atom in the drug development: perspective to FDA approved and COVID-19 recommended drugs

    Chemical Papers · 2023-04-13

    Girish Chandra, Durg Vijay Singh, Gopal Kumar Mahato, Samridhi Patel

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  6. Fluorinated electrode materials for high-energy batteries

    Matter · 2023-06-01

    Jiashen Meng, Zhitong Xiao, Lujun Zhu, Xiao Zhang, Xufeng Hong, Yongfeng Jia, Fang Liu, Quanquan Pang

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  7. Hypervalent Halogen Compounds in Electrochemical Reactions: Advantages and Prospects

    Advanced Synthesis & Catalysis · 2023-06-13

    Bethan Winterson, Dhananjay Bhattacherjee, Thomas Wirth

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  8. N-(2,3-Difluorophenyl)-2-fluorobenzamide

    Molbank · 2023-09-01

    Niall Hehir, John F. Gallagher

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  9. Bridging organic, molecular, macromolecular, supramolecular and biological sciences to create functions via fluorine chemistry and fluorinated reagents

    Giant · 2023-09-15

    Virgil Percec, Dipankar Sahoo, Devendra S. Maurya

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  10. Prediction of 19F NMR chemical shifts for organic compounds with ORCA

    Journal of Magnetic Resonance · 2023-12-13

    Yueyang Li, Ping Zeng, Qing Lou, Xiao Su, Wei Li, Xiaojian Wang

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  11. A review of frustrated Lewis pair enabled monoselective C–F bond activation

    Chemical Science · 2024-01-01

    Kenneth Lye, Rowan D. Young

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  12. “Fluorine Effects” in Conformational Orchestration of α/β Hybrid Peptide with a 9‐membered Pseudo β‐Turn Motif

    Chemistry - A European Journal · 2024-01-02

    Karma Patel, Sintu Karmakar, Srinu Tothadi, J. Prakasha Reddy, Panchami Prabhakaran

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  13. Enzyme Engineering Renders Chlorinase the Activity of Fluorinase

    Journal of Agricultural and Food Chemistry · 2024-01-05

    Yixun Jiang, Mingdong Yao, Haoran Niu, Wenrui Wang, Jiale He, Bin Qiao, Bing‐Zhi Li, Min Dong, Wenhai Xiao, Ying‐Jin Yuan

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  14. Beyond Natural Channel Proteins: Recent Advances in Fluorinated Nanochannels

    Langmuir · 2024-02-02

    Kohei Sato

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  15. From alternate routes to fluorspar (CaF2) or anhydrous HF (aHF) to conversion of fluorspar into a nucleophilic fluorinating agent

    Journal of Fluorine Chemistry · 2024-03-16

    Viacheslav A. Petrov, Joseph S. Thrasher

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  16. (Radio)Fluoro-iodination of Alkenes Enabled by a Hydrogen Bonding Donor Solvent

    Organic Letters · 2024-04-17

    Junbin Han, Xiaolei Lu, Li Chen, Kehao Gong, Bo Xu, Xiaojun Zeng

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  17. Nucleophilic substitution of hydrogen (SNH) in 1,2,3-triazole 1-oxides in the synthesis of pentafluorophenylated azaheterocycles

    Russian Chemical Bulletin · 2024-06-01

    Timofey D. Moseev, Egor A. Nikiforov, Anton N. Tsmokalyuk, Mikhail V. Varaksin, Валерий Николаевич Чарушин, Олег Николаевич Чупахин

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  18. Chloroimidazolium Deoxyfluorination Reagent with H2F3– Anion as a Sole Fluoride Source

    The Journal of Organic Chemistry · 2024-07-15

    Griša Grigorij Prinčič, Blaž Omahen, Jan Jelen, Evelin Gruden, Gašper Tavčar, Jernej Iskra

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  19. Understanding the Selective Removal of Perfluoroalkyl and Polyfluoroalkyl Substances via Fluorine–Fluorine Interactions: A Critical Review

    Environmental Science & Technology · 2024-09-12

    Kaixing Fu, Jinjing Huang, Fang Luo, Zhuoya Fang, Deyou Yu, Xiaolin Zhang, Dawei Wang, Mingyang Xing, Jinming Luo

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  20. Late-Stage Halogenation of Complex Substrates with Readily Available Halogenating Reagents

    Accounts of Chemical Research · 2024-09-20

    Weijin Wang, Song Song, Ning Jiao

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  21. Design of Ionic Liquids for HF/HFC-245fa Superefficient Separation: COSMO-RS Selection and Process Assessment

    Korean Journal of Chemical Engineering · 2024-09-21

    Yuan-Hao Liao, Jijun Zeng, Zhiqiang Yang, Sheng Han, Bo Zhao, Yu an, Xiaobo Tang, Tao Yu, Wei Zhang, Jian Lü

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  22. Highly enhanced fluoride removal from aqueous systems via solvent extraction utilizing trialkyl phosphine oxide as an efficient extractant

    Journal of environmental chemical engineering · 2024-10-15

    Bharat Prasad Sharma, Razium Ali Soomro, Zhuojun Jiang, Jinping Xiong, Naveed Karim, Abdurohman Mengesha Yessuf, Liangrong Yang, Zheng Li

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  23. Polyfluorinated reagents for peptide stapling

    Organic Chemistry Frontiers · 2025-01-01

    Wanzhen Lin, Xin Ding, Junwei Han, Lishuang Yu, Fa‐Jie Chen

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  24. Covalent Organic Frameworks Enhance Photocatalytic Hydrogen Peroxide Production through Synergistic Effects

    ACS Catalysis · 2025-03-24

    Lin Wang, Changzhi Han, Shiyong Gao, Jia‐Xing Jiang, Yong an Zhang

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  25. 6,7,8,9-Tetrafluoro-11H-indeno[1,2-b]quinoxalin-11-one

    Molbank · 2025-04-28

    Anastasia R. Kovrizhina, Irina Yu. Bagryanskaya, Andrey V. Zibarev, Аndrei I. Khlebnikov

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  26. Value-added transformation of third-generation hydrofluorocarbon refrigerant

    Trends in Chemistry · 2025-05-14

    Kaixuan Chen, Zexi Zhang, Mao Chen

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  27. Dual Photoredox/Copper-Catalyzed Radical cis-Selective Allylic Trifluoromethylation

    The Journal of Organic Chemistry · 2025-05-19

    Xiaoyu Shen, Chengjun Chen, Ruizhe Yan, Xiao Yun Chen, Ying Mei Han, Qiu Sun, Huaguang Yu, Hong Hou, Changhao Yan, Shaoqun Zhu

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  28. HF‐Free Manufacturing of Fluorochemicals from Fluorspar

    Angewandte Chemie International Edition · 2025-05-21

    Ricardo I. Rodríguez, Luca Dell’Amico

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  29. HF‐Free Manufacturing of Fluorochemicals from Fluorspar

    Angewandte Chemie · 2025-05-21

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  30. Fluorinated Aromatic Amide Helices: Synthesis and Modeling of Helical Handedness

    Macromolecules · 2025-06-11

    Saquib Farooq, Miroslava Nedyalkova, Subhajit Pal, Aurélien Crochet, Marco Lattuada, Andreas F. M. Kilbinger

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  31. Packing structures and piezochromic properties engineering through F functionalization in 4-position substituted coumarin based organic luminogens

    Dyes and Pigments · 2025-07-21

    Miao Yang, Jingwen Guo, Shijie Fu, Yuhan Zhang, Longmei Yang, Qian Li, Yan Bao, Chengyuan Wang

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  32. Palladium‐Catalyzed Non‐Directed C─H Functionalization of Arenes with Trifluoromethylated Olefins

    Chemistry - A European Journal · 2025-07-23

    Levin Stockmann, Claire Empel

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  33. Synthesis and Preclinical Evaluation of Novel 99mTc-Labeled Glucose Derivatives Containing Different Proline Analogs as Linker Moieties for Tumor Imaging

    Molecular Pharmaceutics · 2025-09-04

    Guangxing Yin, Junhong Feng, Qianna Wang, Yuhao Jiang, Peiwen Han, Dajie Ding, Junbo Zhang

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  34. Enhancing NMR Signals in Liquids by Fluorine‐19 Overhauser Dynamic Nuclear Polarization (DNP) and Hyperpolarization Transfer to Carbon‐13

    Angewandte Chemie · 2025-10-23

    Maik Reinhard, Alex van der Ham, Luming Yang, Leonard Bröker, Tomas Orlando, Igor Tkach, Marcel Levien, Marina Bennati

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  35. Enhancing NMR Signals in Liquids by Fluorine‐19 Overhauser Dynamic Nuclear Polarization (DNP) and Hyperpolarization Transfer to Carbon‐13

    Angewandte Chemie International Edition · 2025-10-23

    Maik Reinhard, Alex van der Ham, Luming Yang, Leonard Bröker, Tomas Orlando, Igor Tkach, Marcel Levien, Marina Bennati

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  36. Difluoromethylation of N-heterocyclic biomolecules

    Journal of Fluorine Chemistry · 2025-10-30

    Sandeep Kumawat, Chitrarekha Dewangan, K. Jyothi, Km Sadhana, Kishore Natte

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  37. 3,4-Dicyanofuroxan and its heavier congeners: chalcogen-dependent switching between π- and σ-hole interactions in chalcogen bonding-based recognition and sensing of Lewis bases

    Physical Chemistry Chemical Physics · 2026-01-01

    Yue Zhang, Xinyi Zeng, Andrey V. Zibarev, Hui Wang

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  38. Continuous flow photochemical C–H functionalization of 2-oxindole for C-3 selective fluorination

    Organic & Biomolecular Chemistry · 2026-01-01

    Raj Kumar, Gajanan G. Nadre, Sanghapal D. Sawant

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  39. Metal- and photosensitizer-free hydrodifluoromethylation of unactivated alkenes via acetamide-activated difluoromethyl aryl sulfones

    Green Chemistry · 2026-01-01

    Lujun Lou, Tianshuai Zhu, Jing-Jing Zhang, Zhen Chen

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  40. Regiospecific dearomative [2π + 2σ] photo-cycloaddition of polyfluoronaphthalenes with bicyclo[1.1.0]butanes via energy transfer catalysis

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  41. Silver‐Catalyzed Three‐Component Radical Aminofluorination of Arylalkenes with Selectfluor and Amino N ‐Heterocycles

    European Journal of Organic Chemistry · 2026-04-22

    Qiangqiang Liu, X L Wang, Xiao-Ming Zhao, Wenyan Dan, Sheng‐Cai Zheng

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  42. Machine Learning-assisted QSPR modeling for accurate prediction of normal boiling points in organic fluorides

    Chinese Journal of Chemical Engineering · 2026-05-01

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  43. Understanding the Defluorination Mechanism of Per‐ and Polyfluoroalkyl Substances in Wastewater: From Microscopic Process to Practical Application

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  44. Intermediate-phase-directed crystallization kinetics and defect passivation synergy for high-efficiency formamidinium-based perovskite solar cells

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  45. Fluorine-Expedited Sulfur Vacancy of Mn0.6Cd0.4S Photocatalyst Enables High-Efficiency Hydrogen Production

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