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RESEARCH PAPER · Chemical Engineering Journal · 2021

Structure tailoring and defect engineering of LED phosphors with enhanced thermal stability and superior quantum efficiency

Tingxuan Yang, Ting Zhang, Saifang Huang, Timothy Daniel Christopher, Qinfen Gu, Yanwei Sui, Peng Jun Cao

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Structure tailoring and defect engineering of LED phosphors with enhanced thermal stability and superior quantum efficiencyOriginalA thermostable terbium( iii ) complex with high fluorescence quantum yields8Novel near-ultraviolet-excited and thermally-stable blue-emitting phosphor for healthy WLED lighting30Engineering the local structure of ZnGa2O4: Cr3+ via Mg substitution to realize superior luminescence18A novel bright cyan emitting phosphor of Eu 2+ activated Ba 6 BO 3 Cl 9 with robust thermal stability for full-spectrum WLED applications65Optical enhancement of highly efficient organic–inorganic oxyfluoride red phosphors via the cation co-doping strategy8Regulating anti-thermal quenching to zero thermal quenching for highly efficient blue-emitting Eu 2+ -doped K-beta-alumina phosphors21Site preference and defect engineering of a highly efficient blue-emitting phosphor Sr 2 SiO 4 :Ce 3+ /K + toward thermally enhanced luminescence30Simultaneous Thermal Enhancement of Upconversion and Downshifting Luminescence by Negative Thermal Expansion in Nonhygroscopic ZrSc(WO 4 ) 2 PO 4 :Yb/Er Phosphors68A novel broad-band red K2MgSiO4:Eu2+ phosphor and defect-induced tunable emission from red to yellow20Defect induced tunable light emitting diodes of compositionally modulated zinc gallium germanium oxides28Improved thermal stability and quantum efficiency of novel cyan phosphors toward full-visible-spectrum lighting15In Situ Glass Crystallization Enables Narrowband Blue Luminescence for Full‐Spectrum Lighting and Transparent Display19A novel extra-broadband visible-emitting garnet phosphor for efficient single-component pc-WLEDs6Achieving white emission by site-selective occupation of Eu 2+ in K 2 BaSr(PO 4 ) 2− x (BO 3 ) x :Eu 2+12An efficient blue–violet phosphor: an advanced material designed for high-quality full-spectrum lighting11Regulating luminescence thermal quenching based on the synergistic effect of energy transfer and energy gap modulation3Tuneable photoluminescence of β-K2SO4 phosphors with enhanced thermal stability and quantum efficiency by chemical substitution7Boosting the thermal stability of A2InTaO6:Cr3+ (A = Ca, Sr, Ba) NIR emitters via component regulation8Controllable Synthesis of Ba2SiO4:Eu2+ Phosphors with Uniform Size and Shape for Micro-LED Color Conversion5Recent progress of metasurfaces in light-emitting diodes11Broadband spectral cyan emission phosphor for full-spectrum LED caused by interstitial site occupation2Dual-functional application of Ca2Ta2O7:Bi3+/Eu3+ phosphors in multicolor tunable optical thermometry and WLED11Color‐Tunable Emission via Site‐Selective Occupation of Eu2+ Activators in Silicate Phosphors17α-Sr2SiO4:Ce3+, Dy3+, Na+ phosphors with abnormal thermal quenching properties for solid-state lighting applications4A narrow band blue phosphor NaBa 4 Al 2 B 8 O 18 Cl 3 :Eu 2+ for white light emitting diodes5Phosphor-converted light-emitting diodes in the marine environment: current status and future trends40Research progress on the design and regulation of Eu 2+ /Ce 3+ -activated anti-/zero thermal quenching phosphors9Trap engineering for improved thermal stability and optical properties of Ce:LuAG phosphor ceramics3Site occupation engineering induced red-shifted luminescence in (Ca, Sr)Sc2O4:Eu2+ phosphor20Luminescence characterization and performance modulation of CaScBO 4 : Eu 2+ near-infrared phosphors for night vision lighting applications4Novel ultra-broadband cyan phosphor with excellent thermal stability for full-spectrum WLED7High-Luminance Red Ba2CaB2Si4O14: Eu3+ with “Abnormal” Thermal Stability and Adjustable Photoluminescence from Defect Regulation and Energy Transfer via Dy3+ Codoping for “Warm” Illumination and Pressure Sensing Applications5Defect-engineered photoluminescence in Ba6Y2Ga4O15: Synergistic cation and atmosphere regulation for ultraviolet-driven WLEDs18Synthesis and characterization of deep-red-emitting α'-Sr2SiO4:Eu3+/Li+ phosphor with intense and thermally stable 5D0→7F4 transition16Synergistic optimization of luminescence in feldspar-structured blue-cyan phosphors via heterovalent K+ substitution coupled with bandgap engineering0Influence of barium defects in the host matrix on the structural and optical properties of CaAl2O4:Eu2+, Dy3+, Nd3+ nanoparticles1Dual site occupation toward the broadband near-infrared ZnNb2O6: Cr3+ phosphor3Breaking Concentration Quenching for Excellent Highly Efficient and Stable Narrowband Luminescence by Structural Ordering and Defect Regulation2A novel narrow-band red-emitting phosphor for lighting and backlight display1Exploration of dual-functional Mn2+-Activated orange-emitting garnet phosphor: Understanding optical transitions and photoluminescence behavior for applications in optical thermometry and WLEDs1Defect‐Engineered Zero‐Dimensional Perovskite Cs 3 LuCl 6 : Tb 3+ Scintillator with Exceptional Thermal Stability for Flexible High‐Temperature X‐Ray Imaging2Defect engineering unlocks long persistent luminescence and anti-thermal-quenching in SrGa2O4: Pr3+ phosphor via Zn2+ and Ba2+ doping0Spectroscopic investigation of Sr1−xCaxLiAl3N4:Eu2+ phosphor involving structural characterization, luminescence mechanism and potential LED applications0Preparation of high quantum efficiency broadband blue phosphors Ca0.87-xSrxAl2Si2O8:0.13Eu2+ for high color rendering white LEDs via a cation substitution strategy0

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  2. Novel near-ultraviolet-excited and thermally-stable blue-emitting phosphor for healthy WLED lighting

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  3. Engineering the local structure of ZnGa2O4: Cr3+ via Mg substitution to realize superior luminescence

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  4. A novel bright cyan emitting phosphor of Eu 2+ activated Ba 6 BO 3 Cl 9 with robust thermal stability for full-spectrum WLED applications

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  5. Optical enhancement of highly efficient organic–inorganic oxyfluoride red phosphors via the cation co-doping strategy

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  6. Regulating anti-thermal quenching to zero thermal quenching for highly efficient blue-emitting Eu 2+ -doped K-beta-alumina phosphors

    Journal of Materials Chemistry C · 2023-01-01

    Yuhang Kuang, Yunjia Li, Borui Chen, Shujuan Zhao, Mengfang Chen, Shixun Lian, Jilin Zhang

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  7. Site preference and defect engineering of a highly efficient blue-emitting phosphor Sr 2 SiO 4 :Ce 3+ /K + toward thermally enhanced luminescence

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    Kai Zhao, Zhihong Ma, Li Yin, Bin Hui, Han Si, Xinlin Tong, Huidong Tang, Peng Jun Cao, Saifang Huang

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  8. Simultaneous Thermal Enhancement of Upconversion and Downshifting Luminescence by Negative Thermal Expansion in Nonhygroscopic ZrSc(WO 4 ) 2 PO 4 :Yb/Er Phosphors

    Inorganic Chemistry · 2023-06-03

    Jinsheng Liao, Zhuo Han, Fulin Lin, Biao Fu, Guoliang Gong, Haokun Yan, Haiping Huang, He‐Rui Wen, Bao Qiu

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  9. A novel broad-band red K2MgSiO4:Eu2+ phosphor and defect-induced tunable emission from red to yellow

    Journal of Luminescence · 2023-08-14

    Minliang Deng, Shuai Huang, Yixin Sun, Yining Wang, Yu Yan, Mengmeng Shang

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  10. Defect induced tunable light emitting diodes of compositionally modulated zinc gallium germanium oxides

    Chemical Engineering Journal · 2023-08-23

    Santosh K. Gupta, Brindaban Modak, Malini Abraham, Subrata K. Das, Ruma Gupta, Kalpathy Ganapathy Girija, M. Mohapatra, Kathi Sudarshan

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  11. Improved thermal stability and quantum efficiency of novel cyan phosphors toward full-visible-spectrum lighting

    Ceramics International · 2023-10-20

    Yonghui Xu, Shuwen Yin, Xiudi Wu, Chuansheng Zhong, Xi‐Bao Zhang, Liang Yi Zhou, Hongpeng You

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  12. In Situ Glass Crystallization Enables Narrowband Blue Luminescence for Full‐Spectrum Lighting and Transparent Display

    Advanced Optical Materials · 2023-12-31

    Xinyue Li, Weigang Feng, Fengluan You, Tao Pang, Jiwen Zhu, Jidong Lin, Yongzheng Fang, Daqin Chen

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  13. A novel extra-broadband visible-emitting garnet phosphor for efficient single-component pc-WLEDs

    Inorganic Chemistry Frontiers · 2024-01-01

    Qianyi Chen, Zhenjie Lun, Dongdan Chen, Yongsheng Sun, Puxian Xiong, Siyun Li, Shanhui Xu, Zhongmin Yang

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  14. Achieving white emission by site-selective occupation of Eu 2+ in K 2 BaSr(PO 4 ) 2− x (BO 3 ) x :Eu 2+

    Journal of Materials Chemistry C · 2024-01-01

    Goudong Xie, Jiayong Si, Guihua Li, Gemei Cai, Zhi-Peng Wang, Xiaojun Wang

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  15. An efficient blue–violet phosphor: an advanced material designed for high-quality full-spectrum lighting

    Dalton Transactions · 2024-01-01

    Xiudi Wu, Yonghui Xu, Shuwen Yin, Chuansheng Zhong, xibao zhang, Liang Yi Zhou, Hongpeng You

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  16. Regulating luminescence thermal quenching based on the synergistic effect of energy transfer and energy gap modulation

    Dalton Transactions · 2024-01-01

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  17. Tuneable photoluminescence of β-K2SO4 phosphors with enhanced thermal stability and quantum efficiency by chemical substitution

    Ceramics International · 2024-01-24

    Tingxuan Yang, Ting Zhang, Timothy Daniel Christopher, Saifang Huang, Peng Jun Cao

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  18. Boosting the thermal stability of A2InTaO6:Cr3+ (A = Ca, Sr, Ba) NIR emitters via component regulation

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  19. Controllable Synthesis of Ba2SiO4:Eu2+ Phosphors with Uniform Size and Shape for Micro-LED Color Conversion

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  20. Recent progress of metasurfaces in light-emitting diodes

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  21. Broadband spectral cyan emission phosphor for full-spectrum LED caused by interstitial site occupation

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  22. Dual-functional application of Ca2Ta2O7:Bi3+/Eu3+ phosphors in multicolor tunable optical thermometry and WLED

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  23. Color‐Tunable Emission via Site‐Selective Occupation of Eu2+ Activators in Silicate Phosphors

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  24. α-Sr2SiO4:Ce3+, Dy3+, Na+ phosphors with abnormal thermal quenching properties for solid-state lighting applications

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  25. A narrow band blue phosphor NaBa 4 Al 2 B 8 O 18 Cl 3 :Eu 2+ for white light emitting diodes

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  26. Phosphor-converted light-emitting diodes in the marine environment: current status and future trends

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  28. Trap engineering for improved thermal stability and optical properties of Ce:LuAG phosphor ceramics

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  29. Site occupation engineering induced red-shifted luminescence in (Ca, Sr)Sc2O4:Eu2+ phosphor

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  30. Luminescence characterization and performance modulation of CaScBO 4 : Eu 2+ near-infrared phosphors for night vision lighting applications

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  31. Novel ultra-broadband cyan phosphor with excellent thermal stability for full-spectrum WLED

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  32. High-Luminance Red Ba2CaB2Si4O14: Eu3+ with “Abnormal” Thermal Stability and Adjustable Photoluminescence from Defect Regulation and Energy Transfer via Dy3+ Codoping for “Warm” Illumination and Pressure Sensing Applications

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  33. Defect-engineered photoluminescence in Ba6Y2Ga4O15: Synergistic cation and atmosphere regulation for ultraviolet-driven WLEDs

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  34. Synthesis and characterization of deep-red-emitting α'-Sr2SiO4:Eu3+/Li+ phosphor with intense and thermally stable 5D0→7F4 transition

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  35. Synergistic optimization of luminescence in feldspar-structured blue-cyan phosphors via heterovalent K+ substitution coupled with bandgap engineering

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  36. Influence of barium defects in the host matrix on the structural and optical properties of CaAl2O4:Eu2+, Dy3+, Nd3+ nanoparticles

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  42. Defect engineering unlocks long persistent luminescence and anti-thermal-quenching in SrGa2O4: Pr3+ phosphor via Zn2+ and Ba2+ doping

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  44. Preparation of high quantum efficiency broadband blue phosphors Ca0.87-xSrxAl2Si2O8:0.13Eu2+ for high color rendering white LEDs via a cation substitution strategy

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