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RESEARCH PAPER · Journal of the American Chemical Society · 2021

Extended Condensed Ultraphosphate Frameworks with Monovalent Ions Combine Lithium Mobility with High Computed Electrochemical Stability

Guopeng Han, Andrij Vasylenko, Alex Ryan Neale, Benjamin B. Duff, Ruiyong Chen, Matthew Stephen Dyer, Yun Dang, Matthew J. Rosseinsky, Marco Zanella, Craig M. Robertson, Laurence J. Kershaw Cook, Anna‐Lena Hansen, Michael Knapp, Laurence J. Hardwick, Frédéric Blanc, John B. Claridge, Matthew J. Rosseinsky

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Extended Condensed Ultraphosphate Frameworks with Monovalent Ions Combine Lithium Mobility with High Computed Electrochemical StabilityOriginalSurface reactions between LiHMDS, TMA and TMP leading to deposition of amorphous lithium phosphate8Enhancement of Birefringence in Borophosphate Pushing Phase-Matching into the Short-Wavelength Region150AIB3IIC3IIIQ8VI: A New Family for the Design of Infrared Nonlinear Optical Materials by Coupling Octahedra and Tetrahedra Units152Toward Understanding of the Li-Ion Migration Pathways in the Lithium Aluminum Sulfides Li3AlS3 and Li4.3AlS3.3Cl0.7 via 6,7Li Solid-State Nuclear Magnetic Resonance Spectroscopy27A database of experimentally measured lithium solid electrolyte conductivities evaluated with machine learning99The oxygen environments of divalent cations in phosphate glasses and crystals – the changes with composition and ionic radii2Inferring energy–composition relationships with Bayesian optimization enhances exploration of inorganic materials6Synthesis and optical properties of highly efficient Na7Mg13La(PO4)12:Eu3+ powders with excellent thermal stability3Revealing the Local Structure and Dynamics of the Solid Li Ion Conductor Li3P5O140AI2Mg3Ga12S22 (AI = K, Rb): T2-type supertetrahedra coupled with [MgS6] octahedra for designing wide-band gap infrared nonlinear optical materials with well-balanced properties16Influence of SiO2 on the ionic conductivity parameters and short-range order structure of Ag2O-Al2O3-P2O5 glasses1Designing High-Performance Short-Wave UV Tellurium-Based Mixed Halides Birefringent Crystals via Halogen Substitution Engineering4Water Molecule-Driven Structural Evolution from Na2ZnCl4 to Na2ZnCl4·3H2O: A Route to Promising Deep-UV Nonlinear Optical Crystals0Electrical, Magnetic, and Structural Characteristics of C, N, and O Doped AgZnF3 Perovskite: The KKR-CPA Framework1In situ construction of multifunctional metaphosphate interphase enabling stable zinc anode with fast Zn 2+ transport kinetics0[Rb 4 Cl][Cd 11 In 9 Se 26 ]: a salt inclusion chalcogenide with a diamond-like framework for infrared nonlinear optics0Zn 0.7 Hg 0.3 Ga 2 Se 4 : a defect diamond-like selenide with a balanced band gap and nonlinear optical response0Rb 2 ZnGe 3 Se 8 : A Large-Birefringence Layered Chalcogenide Enabled by Anisotropic Electrons in Tetrahedral Units0Reassessment of the proposed orthorhombic variety V of CeP5O14: Structural and luminescence insights from LaP5O14:Eu3+0Dielectric relaxation and charge transport mechanisms in LiCoO2-incorporated P2O5 glasses0

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  1. Surface reactions between LiHMDS, TMA and TMP leading to deposition of amorphous lithium phosphate

    Journal of Materials Chemistry A · 2022-01-01

    Andreas Werbrouck, Felix Mattelaer, Arpan Dhara, Mikko Nisula, Matthias M. Minjauw, Frans Munnik, Jolien Dendooven, Christophe Detavernier

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  2. Enhancement of Birefringence in Borophosphate Pushing Phase-Matching into the Short-Wavelength Region

    Journal of the American Chemical Society · 2022-05-13

    Wenbin Zhang, Junben Huang, Shujuan Han, Zhihua Yang, Shilie Pan

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  3. AIB3IIC3IIIQ8VI: A New Family for the Design of Infrared Nonlinear Optical Materials by Coupling Octahedra and Tetrahedra Units

    Journal of the American Chemical Society · 2022-11-18

    Ling Luo, Linan Wang, Jianbang Chen, Jiazheng Zhou, Zhihua Yang, Shilie Pan, Junjie Li

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  4. Toward Understanding of the Li-Ion Migration Pathways in the Lithium Aluminum Sulfides Li3AlS3 and Li4.3AlS3.3Cl0.7 via 6,7Li Solid-State Nuclear Magnetic Resonance Spectroscopy

    Chemistry of Materials · 2022-12-16

    Benjamin B. Duff, Stuart James Elliott, Jacinthe Gamon, Matthew J. Rosseinsky, Matthew J. Rosseinsky, Frédéric Blanc

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  5. A database of experimentally measured lithium solid electrolyte conductivities evaluated with machine learning

    npj Computational Materials · 2023-01-16

    Cameron J. Hargreaves, Michael W. Gaultois, Matthew J. Rosseinsky, Emma J. Watts, Vitaliy A. Kurlin, Michael J. Moran, Yun Dang, Rhun E. Morris, Alexandra Morscher, Kate Thompson, Matthew A. Wright, Beluvalli E. Prasad, Frédéric Blanc, Chris M. Collins, Catriona A. Crawford, Benjamin B. Duff, Jae A. Evans, Jacinthe Gamon, Guopeng Han, Bernhard T. Leube, Hongjun Niu, Arnaud J. Perez, Aris Robinson, Oliver Rogan, Paul M. Sharp, Elvis Shoko, Manel Sonni, William J. Thomas, Andrij Vasylenko, Lu Wang, Matthew J. Rosseinsky, Matthew Stephen Dyer

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  6. The oxygen environments of divalent cations in phosphate glasses and crystals – the changes with composition and ionic radii

    Journal of Non-Crystalline Solids · 2023-08-26

    Uwe Hoppe

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  7. Inferring energy–composition relationships with Bayesian optimization enhances exploration of inorganic materials

    The Journal of Chemical Physics · 2024-02-07

    Andrij Vasylenko, Benjamin M. Asher, Christopher M. Collins, Michael W. Gaultois, George R. Darling, Matthew Stephen Dyer, Matthew J. Rosseinsky

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  8. Synthesis and optical properties of highly efficient Na7Mg13La(PO4)12:Eu3+ powders with excellent thermal stability

    Ceramics International · 2024-07-16

    Laura Klimkevičienė, Edvin Parafjanovic, Vaidas Klimkevičius, Artūras Katelnikovas

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  9. Revealing the Local Structure and Dynamics of the Solid Li Ion Conductor Li3P5O14

    Chemistry of Materials · 2024-07-29

    Benjamin B. Duff, Lucia Corti, Bethan Turner, Guopeng Han, Matthew J. Rosseinsky, Matthew J. Rosseinsky, Frédéric Blanc

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  10. AI2Mg3Ga12S22 (AI = K, Rb): T2-type supertetrahedra coupled with [MgS6] octahedra for designing wide-band gap infrared nonlinear optical materials with well-balanced properties

    Science China Materials · 2025-01-22

    Mengmeng Chen, Xu Liu, Abudukadi Tudi, Cui Chen, Qixian Ren, Zhihua Yang, Yabo Wu, Shilie Pan

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  11. Influence of SiO2 on the ionic conductivity parameters and short-range order structure of Ag2O-Al2O3-P2O5 glasses

    Ionics · 2025-04-23

    Talib Farziev, В. А. Марков, Nikita Dybin, Ilya E. Kaliya, Valentina D. Andreeva

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  12. Designing High-Performance Short-Wave UV Tellurium-Based Mixed Halides Birefringent Crystals via Halogen Substitution Engineering

    Crystal Growth & Design · 2025-06-24

    Xiang Mao, Yu Yan, Yingzi Zhang, Xuehua Dong, Ling Huang, Liling Cao, Daojiang Gao, Guohong Zou

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  13. Water Molecule-Driven Structural Evolution from Na2ZnCl4 to Na2ZnCl4·3H2O: A Route to Promising Deep-UV Nonlinear Optical Crystals

    Crystal Growth & Design · 2025-07-08

    Mengmeng Chen, Wangfei Che, Cui Chen, Qixian Ren, Juanjuan Lu, Yabo Wu

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  14. Electrical, Magnetic, and Structural Characteristics of C, N, and O Doped AgZnF3 Perovskite: The KKR-CPA Framework

    Journal of Superconductivity and Novel Magnetism · 2025-07-17

    Ayoub Koufi, Younes Ziat, Hamza Belkhanchi

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  15. In situ construction of multifunctional metaphosphate interphase enabling stable zinc anode with fast Zn 2+ transport kinetics

    EES batteries. · 2025-11-05

    Junfeng Wang, Kaijian Yan, He Qi, Dongming Xu, Shaojie Guo, Lihua Pei, Zeya Peng, Dekang Huang, Yanzhu Luo, Feifei Cao

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  16. [Rb 4 Cl][Cd 11 In 9 Se 26 ]: a salt inclusion chalcogenide with a diamond-like framework for infrared nonlinear optics

    Dalton Transactions · 2026-01-01

    Pengzhi Xie, Qixian Ren, Junwei Feng, Hong Lei Du, Shuyi Mi

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  17. Zn 0.7 Hg 0.3 Ga 2 Se 4 : a defect diamond-like selenide with a balanced band gap and nonlinear optical response

    Dalton Transactions · 2026-01-01

    Qixian Ren, Junwei Feng, Longquan Shao, Meihuizi Zhou, Chen Cui, Yabo Wu

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  18. Rb 2 ZnGe 3 Se 8 : A Large-Birefringence Layered Chalcogenide Enabled by Anisotropic Electrons in Tetrahedral Units

    Inorganic Chemistry · 2026-06-15

    Xinchen Chen, Yabo Wu, Wangfei Che, Shuyi Mi, Juanjuan Lu, Chen Cui

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  19. Reassessment of the proposed orthorhombic variety V of CeP5O14: Structural and luminescence insights from LaP5O14:Eu3+

    Journal of Molecular Structure · 2026-10-03

    Aïcha Mbarek, Zambon Daniel

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  20. Dielectric relaxation and charge transport mechanisms in LiCoO2-incorporated P2O5 glasses

    Materials Science and Engineering B · 2026-10-05

    José A. Jiménez, Ayyagari Venkata Sekhar, Marek Kostrzewa, Adam Ingram, N. Purnachand, Vandana Ravi Kumar, Rebhadevi Monikandan, N. Veeraiah

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