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RESEARCH PAPER · Inorganic Chemistry · 2021

Structure, Magnetism, and Thermal Stability of La2NiO2.5F3: A Ruddlesden–Popper Oxyfluoride Crystallizing in Space Group P42/nnm

Jonas Jacobs, Miguel A. L. Marques, Hai‐Chen Wang, Emil Dieterich, Stefan G. Ebbinghaus

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Structure, Magnetism, and Thermal Stability of La2NiO2.5F3: A Ruddlesden–Popper Oxyfluoride Crystallizing in Space Group P42/nnmOriginalCuprate Oxyfluorides La2Cu0.8Ni0.2O3F2 and La2CuO3F2 with “Channel-like” Anion Ordering20Topochemical Fluorination of LaBaInO 4 to LaBaInO 3 F 2 , Their Optical Characterization, and Photocatalytic Activities for Hydrogen Evolution10Ruddlesden–Popper Oxyfluorides La2Ni1–xCuxO3F2 (0 ≤ x ≤ 1): Impact of the Ni/Cu Ratio on the Structure9Ruddlesden–Popper Oxyfluorides La2Ni1–xCuxO3F2 (0 ≤ x ≤ 1): Impact of the Ni/Cu Ratio on the Thermal Stability and Magnetic Properties4Synthesis and characterisation of the new oxyanion doped “0201–1201” type layered oxide, Sr4.5Fe2(S/Cr)0.5O9±δ1Is Fluorine Incorporation in the La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3− δ Improving Its Electrochemical Behavior for Solid Oxide Cells Applications?22Sol–gel synthesis of iron titanates for the photocatalytic degradation of cyanide4Topochemical Modulations from 1D Iron Fluoride Precursor to 3D Frameworks0Structure and Magnetic Properties of the n = 3 Ruddlesden–Popper Oxyfluoride La 0.5 Sr 3.5 Fe 3 O 7.5 F 2.611Structural and electronic tunability of Ruddlesden–Popper oxyfluorides through nickel–copper substitution in La 2 Ni 1− x Cu x O 2.5 F 3 (0 ≤ x ≤ 1)3Structure, magnetism and thermal stability of the n = 3 Ruddlesden–Popper oxyfluoride La 4 Ni 3 O 8.4 F 3.54Unveiling the Fluorination Pathway of Ruddlesden–Popper Oxyfluorides: A Comprehensive In Situ X-ray and Neutron Diffraction Study12Atomic-scale observation of geometric reconstruction in a fluorine-intercalated infinite layer nickelate superlattice2Atomic insights into topochemical fluorination and strong octahedral tilt in La2CoO42In Situ X‐ray Diffraction Studies on the Reduction of U 3 O 8 by Various Reducing Agents2Rapid fluorination using polyvinylidene-difluoride (PVDF) for the synthesis of oxyfluoride Bi2VO5F1−x0High-Capacity Intercalation-Based Anodes for Solid-State Fluoride-Ion Batteries Enabled by the Substitution of Conductive Carbon by Metallic Copper2Structural origins of photocatalytic properties in Ruddlesden–Popper Sr n +1 Ti n O 3 n +1 ( n = 1, 2) and their topochemically fluorinated phases Sr n +1 Ti n O (3 n +1)− x F 2 x ( x ≈ n )3Anion Exchange in LaBaInO 3 F 2 : Structural and Optical Effects of Low-Temperature Topochemical Modification3Synthesis of the Double Infinite-Layer Ni(I) Phase La 3 Ni 2 O 5 F via Sequential Topochemical Reactions2NaI-Mediated Defluorination: A Mild Route to Reduced Ruddlesden–Popper Oxyfluorides Demonstrated on La 2 CoO 3 F 3 as Model System2Topochemical Fluorination Yields Long-Range Superlattice in Epitaxial La 2 NiO 4 Thin Films0Redox-Neutral Interstitial Hydride Incorporation in Ruddlesden–Popper Oxides0From T ′-Type to Channel-like Anion Ordering: Structure, Thermal Stability, and Magnetic Properties of the Ruddlesden–Popper Oxyfluorides Pr2CuO3F2 and Nd2CuO3F20

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  1. Cuprate Oxyfluorides La2Cu0.8Ni0.2O3F2 and La2CuO3F2 with “Channel-like” Anion Ordering

    Inorganic Chemistry · 2022-10-18

    Jonas Jacobs, James Hester, Stefan G. Ebbinghaus

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  2. Topochemical Fluorination of LaBaInO 4 to LaBaInO 3 F 2 , Their Optical Characterization, and Photocatalytic Activities for Hydrogen Evolution

    Inorganic Chemistry · 2023-09-27

    Shama Perween, Kerstin Wissel, Zsolt Dallos, Morten Weiß, Yuji Ikeda, Sami Vasala, Sabine Strobel, Peter Schützendübe, Pascal M. Jeschenko, Ute Kolb, Roland Marschall, Blazej Grabowski, Pieter Glatzel

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  3. Ruddlesden–Popper Oxyfluorides La2Ni1–xCuxO3F2 (0 ≤ x ≤ 1): Impact of the Ni/Cu Ratio on the Structure

    Inorganic Chemistry · 2024-03-20

    Jonas Jacobs, Hai‐Chen Wang, Miguel A. L. Marques, Ke Xu, Jörn Schmedt auf der Günne, Stefan G. Ebbinghaus

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  4. Ruddlesden–Popper Oxyfluorides La2Ni1–xCuxO3F2 (0 ≤ x ≤ 1): Impact of the Ni/Cu Ratio on the Thermal Stability and Magnetic Properties

    Inorganic Chemistry · 2024-06-03

    Jonas Jacobs, Hai‐Chen Wang, Miguel A. L. Marques, Stefan G. Ebbinghaus

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  5. Synthesis and characterisation of the new oxyanion doped “0201–1201” type layered oxide, Sr4.5Fe2(S/Cr)0.5O9±δ

    Journal of Solid State Chemistry · 2024-06-12

    Abbey Jarvis, Abbey Jarvis, Frank John Berry, José Francisco Marco, Giannantonio Cibin, Peter Raymond Slater, Peter Raymond Slater

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  6. Is Fluorine Incorporation in the La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3− δ Improving Its Electrochemical Behavior for Solid Oxide Cells Applications?

    Advanced Energy Materials · 2024-06-20

    Zonghao Shen, Jean‐Marc Bassat, Sébastien Fourcade, Alain Demourgues, Étienne Durand, Lionel Teulé‐Gay, Mathieu Duttine, Jacinthe Gamon

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  7. Sol–gel synthesis of iron titanates for the photocatalytic degradation of cyanide

    Journal of Materials Science · 2024-07-21

    Stefanny Córdoba Miranda, Ingrid C. Ortiz-Rojas, Diana Marcela Cañas-Martínez, Juvencio Vázquez‐Samperio, J.A. Pedraza-Avella

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  8. Topochemical Modulations from 1D Iron Fluoride Precursor to 3D Frameworks

    Inorganic Chemistry · 2024-07-22

    Arindam Ghosh, Dereje Bekele Tekliye, Emily Foley, Varimalla Raghavendra Reddy, Raphaële J. Clément, Gopalakrishnan Sai Gautam, Premkumar Senguttuvan

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  9. Structure and Magnetic Properties of the n = 3 Ruddlesden–Popper Oxyfluoride La 0.5 Sr 3.5 Fe 3 O 7.5 F 2.6

    Inorganic Chemistry · 2024-10-18

    Andy Bivour, Jonas Jacobs, Florian Daumann, Gerald Hörner, Birgit Weber, C. Ritter, Stefan G. Ebbinghaus

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  10. Structural and electronic tunability of Ruddlesden–Popper oxyfluorides through nickel–copper substitution in La 2 Ni 1− x Cu x O 2.5 F 3 (0 ≤ x ≤ 1)

    Journal of Materials Chemistry A · 2025-01-01

    Jonas Jacobs, C. Ritter, Ke Xu, Jörn Schmedt auf der Günne, Hai‐Chen Wang, Miguel A. L. Marques, Anja Hofmann, Roland Marschall, Stefan G. Ebbinghaus

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  11. Structure, magnetism and thermal stability of the n = 3 Ruddlesden–Popper oxyfluoride La 4 Ni 3 O 8.4 F 3.5

    Dalton Transactions · 2025-01-01

    Jakob Geßner, Stefan G. Ebbinghaus, Jonas Jacobs

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  12. Unveiling the Fluorination Pathway of Ruddlesden–Popper Oxyfluorides: A Comprehensive In Situ X-ray and Neutron Diffraction Study

    Journal of the American Chemical Society · 2025-02-17

    Jonas Jacobs, Andy Bivour, В. Сиколенко, Holger Kohlmann, Thomas C. Hansen, James Hester, Ke Xu, Jörn Schmedt auf der Günne, Stefan G. Ebbinghaus

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  13. Atomic-scale observation of geometric reconstruction in a fluorine-intercalated infinite layer nickelate superlattice

    Nature Communications · 2025-04-06

    Chao Yang, R. A. Ortiz, Hongguang Wang, Wilfried Sigle, Kelvin Anggara, E. Benckiser, B. Keimer, Peter A. van Aken

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  14. Atomic insights into topochemical fluorination and strong octahedral tilt in La2CoO4

    Chinese Physics B · 2025-05-19

    Yuzhou 玉洲 He 何, Ting 挺 Lin 林, Shiyu 诗雨 Wang 王, Ang 昂 Gao 高, Ziang 子昂 Meng 孟, Tianping 天平 Ying 应, Zhiqi 知琪 Liu 刘, Lin Gu, Qinghua 庆华 Zhang 张, Binghui Ge

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  15. In Situ X‐ray Diffraction Studies on the Reduction of U 3 O 8 by Various Reducing Agents

    Chemistry - A European Journal · 2025-05-27

    Marvin Michak, Frank‐Constantin Ideker, Holger Kohlmann

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  16. Rapid fluorination using polyvinylidene-difluoride (PVDF) for the synthesis of oxyfluoride Bi2VO5F1−x

    Journal of the Ceramic Society of Japan · 2025-05-31

    Kengo Oka, Hideo Mizutani, Ibuki Sumitani, Joichiro Murasaki, Naoki Noma, Mitsunobu Iwasaki

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  17. High-Capacity Intercalation-Based Anodes for Solid-State Fluoride-Ion Batteries Enabled by the Substitution of Conductive Carbon by Metallic Copper

    ACS Applied Energy Materials · 2025-11-07

    Tommi Hendrik Aalto, Tobias Widder, Eberhard J. Goering, Peter Nagel, Kerstin Wissel, Oliver Clemens

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  18. Structural origins of photocatalytic properties in Ruddlesden–Popper Sr n +1 Ti n O 3 n +1 ( n = 1, 2) and their topochemically fluorinated phases Sr n +1 Ti n O (3 n +1)− x F 2 x ( x ≈ n )

    Journal of Materials Chemistry A · 2026-01-01

    Shama Perween, Kevin Matthias Ries, Anja Hofmann, Tommi Hendrik Aalto, Harol Moreno Fernández, Marc Widenmeyer, Robert Löser, Jana Timm, Guido Schmitz, Petia P. Atanasova, Jan P. Hofmann, Oliver Clemens, Roland Marschall, Chengchao Zhong

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  19. Anion Exchange in LaBaInO 3 F 2 : Structural and Optical Effects of Low-Temperature Topochemical Modification

    Inorganic Chemistry · 2026-01-24

    Shama Perween, Benjamin Knies, Margarida Barroso, Kerstin Wissel, Robert Löser, Chittaranjan Das, Michael Saliba, Oleksandr B. Bondarchuk, Hasan Yilmaz, Guido Schmitz, Marc Widenmeyer, Ingo Hartenbach, Chengchao Zhong, Oliver Clemens

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  20. Synthesis of the Double Infinite-Layer Ni(I) Phase La 3 Ni 2 O 5 F via Sequential Topochemical Reactions

    Journal of the American Chemical Society · 2026-02-04

    Romain Wernert, Robert D. Smyth, Michael A. Hayward

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  21. NaI-Mediated Defluorination: A Mild Route to Reduced Ruddlesden–Popper Oxyfluorides Demonstrated on La 2 CoO 3 F 3 as Model System

    Journal of the American Chemical Society · 2026-05-25

    Jonas Jacobs, Tommi Hendrik Aalto, Yorik Puffaldt, C. Ritter, Oliver Clemens

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  22. Topochemical Fluorination Yields Long-Range Superlattice in Epitaxial La 2 NiO 4 Thin Films

    ACS Nano · 2026-06-08

    Ari B. Turkiewicz, Abigail Y. Jiang, Suk Hyun Sung, Dan Ferenc Segedin, Grace A. Pan, Nicole K. Taylor, Megan Goh, Maria Bambrick-Santoyo, Alexander Gavrilov, Avinashi Bhandari, Suchismita Sarker, Jacob P. C. Ruff, Charles M. Brooks, Quintin N. Meier, Fabio Bernardini, Antía S. Botana, Ismail El Baggari, Jarad A. Mason, A. Cano, Julia A. Mundy

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  23. Redox-Neutral Interstitial Hydride Incorporation in Ruddlesden–Popper Oxides

    Inorganic Chemistry · 2026-06-23

    Daichi Kato, Shuhei Ueda, Tong Zhu, Hiroki Ubukata, Hikaru Takeuchi, Takashi Honda, Yusuke Nambu, Tatsuya Tsumori, Kotaro Nakai, Cédric Tassel, Itaru Oikawa, Hitoshi Takamura, Teruki Motohashi, Miwa Saito, Yusuke Asai, Ryotaro Aso, Koji Fujita, Hiroshi Kageyama

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  24. From T ′-Type to Channel-like Anion Ordering: Structure, Thermal Stability, and Magnetic Properties of the Ruddlesden–Popper Oxyfluorides Pr2CuO3F2 and Nd2CuO3F2

    Chemistry of Materials · 2026-07-28

    Jonas Jacobs, Gina-Lee Pitulle, Stefan G. Ebbinghaus

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