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RESEARCH PAPER · Nature Reviews Materials · 2021

Emerging applications of zeolites in catalysis, separation and host–guest assembly

Yi Li, Jihong Yu

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Emerging applications of zeolites in catalysis, separation and host–guest assemblyOriginalSelective Hydrogenation of CO 2 to Ethanol over Sodium-Modified Rhodium Nanoparticles Embedded in Zeolite Silicalite-195Zeolite-Encaged Isolated Platinum Ions Enable Heterolytic Dihydrogen Activation and Selective Hydrogenations196Controlling Nucleation Pathways in Zeolite Crystallization: Seeding Conceptual Methodologies for Advanced Materials Design156Research Progress on the Applications of Electrospun Nanofibers in Catalysis49Achieving highly selective CO 2 adsorption on SAPO-35 zeolites by template-modulating the framework silicon content30Advances in zeolite-supported metal catalysts for propane dehydrogenation73Exploring the materials space in the smallest particle size range: from heterogeneous catalysis to electrocatalysis and photocatalysis36Mechanically interlocked molecules in metal–organic frameworks63Progress in Seed-assisted Synthesis of (Silico)Aluminophosphate Molecular Sieves19Mixed-Matrix Ion Gel Membranes for Gas Separation21Low-energy adsorptive separation by zeolites175Catalytic Cracking of Crude Oil: Mini Review of Catalyst Formulations for Enhanced Selectivity to Light Olefins95Tandem Reactions over Zeolite-Based Catalysts in Syngas Conversion51Synthesis of mesoporous high-silica zeolite Y and their catalytic cracking performance59Single Atom Catalysts for Selective Methane Oxidation to Oxygenates140Hydrogen sulfide capture and removal technologies: A comprehensive review of recent developments and emerging trends258Repurposing Templates for Zeolite Synthesis from Simulations and Data Mining18Silica samurai: Aristocrat of energy and environmental catalysis39Imidazolium salts facilitate mechanochemical synthesis of well-dispersed MFI zeolite crystals with c-axis orientation20Unveiling Secondary-Ion-Promoted Catalytic Properties of Cu-SSZ-13 Zeolites for Selective Catalytic Reduction of NOx187Zeolite Catalysts for Green Production of Caprolactam37Environmental and Pharmacokinetic Aspects of Zeolite/Pharmaceuticals Systems—Two Facets of Adsorption Ability41Recent advances in solid-state NMR of zeolite catalysts90Design and syntheses of hybrid zeolitic imidazolate frameworks47H-beta zeolite-based dispersive solid-phase strategy for the multi-residue determination of pesticides20Metal Sites in Zeolites: Synthesis, Characterization, and Catalysis618A general method for rapid synthesis of refractory carbides by low-pressure carbothermal shock reduction46Engine emissions with air pollutants and greenhouse gases and their control technologies219Synthesis and Biomedical Applications of Highly Porous Metal–Organic Frameworks23Adsorption-Enhanced Bifunctional Catalysts for In Situ CO2 Capture and Utilization in Propylene Production: A Proof-Of-Concept Study32Encapsulating Metal Nanoparticles into a Layered Zeolite Precursor with Surface Silanol Nests Enhances Sintering Resistance**31Recent Catalytic Advances on the Sustainable Production of Primary Furanic Amines from the One‐Pot Reductive Amination of 5‐Hydroxymethylfurfural44Charge-separation driven mechanism via acylium ion intermediate migration during catalytic carbonylation in mordenite zeolite40Our journey in zeolite science23A Comprehensive Review on Zeolite Chemistry for Catalytic Conversion of Biomass/Waste into Green Fuels39Highly Reversible Solid‐State Lithium‐Oxygen Batteries by Size‐Matching Between Fe‐Fe Cluster and Li2‐xO236Topological characterization and entropy measures of tetragonal zeolite merlinoites49Zeolite-Based Electrolytes: A Promising Choice for Solid-State Batteries19Recent Advances in the Use of Covalent Organic Frameworks as Heterogenous Photocatalysts in Organic Synthesis267Alkynyl-anchored silver nanoclusters in lanthanide metal-organic framework for luminescent thermometer and CO2 cycloaddition23Hydrogen bonding to oxygen in siloxane bonds drives liquid phase adsorption of primary alcohols in high-silica zeolites21Inorganic synthesis-structure maps in zeolites with machine learning and crystallographic distances18Magnetic boron nitride adorned with Pd nanoparticles: an efficient catalyst for the reduction of nitroarenes in aqueous media29Recent progress in anion exchange membranes (AEMs) in water electrolysis: synthesis, physio-chemical analysis, properties, and applications90Review on supported metal catalysts with partial/porous overlayers for stabilization20Understanding and controlling the nucleation and growth of metal–organic frameworks186Zeolites as a Class of Semiconductors for High-Performance Electrically Transduced Sensing57La ions-enhanced NH3-SCR performance over Cu-SSZ-13 catalysts62A Six-Membered Ring Molecular Sieve Achieved by a Reconstruction Route21Atomic-Level Imaging of Zeolite Local Structures Using Electron Ptychography39Dimensional Regulation of Titanosilicate by Kinetically Controlled Intergrowth Crystals27Zeolite ZSM ‐5 synthesized from natural silica sources and its applications: a critical review32Regioselective Surface Assembly of Mesoporous Carbon on Zeolites Creating Anisotropic Wettability for Biphasic Interface Catalysis54Catching a New Zeolite as a Transition Material during Deconstruction18Synthesis of nanosized IM-5 zeolite and its CH4/N2 adsorption and separation23Three-dimensional inhomogeneity of zeolite structure and composition revealed by electron ptychography127Fabrication of biomass-based functional carbon materials for energy conversion and storage123Tailoring hydrophobic-aerophilic microenvironment for robust electrochemical ozone production17Advanced Materials Design for Adsorption of Toxic Substances in Cigarette Smoke59Surface Restructuring of Zeolite‐Encapsulated Halide Perovskite to Activate Lattice Oxygen Oxidation for Water Electrolysis48Cu-based high-entropy two-dimensional oxide as stable and active photothermal catalyst169Bimetallic clusters confined inside silicalite-1 for stable propane dehydrogenation60Palladium Nanoparticles Supported on Porous Silica Materials as Heterogeneous Catalysts of C−C Coupling and Cross‐Coupling Reactions42Surface Diffusion Barriers and Catalytic Activity Driven by Terminal Groups at Zeolite Catalysts28Atomic Imaging of Zeolites and Confined Single Molecules by iDPC-STEM31Outlooks for zeolite catalysts in a low-carbon scenario32Ferric Single‐Site Catalyst Confined in a Zeolite Framework for Propane Dehydrogenation36Microwave-Assisted Synthesis of Zeolite A from Metakaolinite for CO2 Adsorption23Intergrowth Zeolites, Synthesis, Characterization, and Catalysis100A Bismuth‐Based Zeolitic Organic Framework with Coordination‐Linked Metal Cages for Efficient Electrocatalytic CO2 Reduction to HCOOH71Silanol-Engineered Nonclassical Growth of Zeolite Nanosheets from Oriented Attachment of Amorphous Protozeolite Nanoparticles78Enabling High-Performance All-Solid-State Batteries via Guest Wrench in Zeolite Strategy54Mixed Plastics Wastes Upcycling with High-Stability Single-Atom Ru Catalyst188Recent progress and issues facing zeolite and metal-organic framework membranes: From membrane synthesis to applications37Carbon neutrality enabled by structure-tailored zeolite-based nanomaterials49Highly dispersed Pd-based pseudo-single atoms in zeolites for hydrogen generation and pollutant disposal42Recent Advances in Metal−Zeolite Catalysts for Direct Propane Dehydrogenation31Heterometallic supramolecular polymers: From synthesis to properties and applications44Double Four Ring Units‐Containing Zeolites: Synthesis, Structural Modification and Catalytic Applications18A Critical Assessment on Calculating Vibrational Spectra in Nanostructured Materials19Antimicrobial zeolites and metal–organic frameworks20Cyanuric chloride as a linker towards the synthesis of covalent triazine polymers: a review19Efficiency, mechanism and application prospect of ammonium adsorption and desorption over a sodium-acetate-modified synthetic zeolite24Encapsulation engineering of porous crystalline frameworks for delayed luminescence and circularly polarized luminescence128Improving the hydrothermal stability of Al-rich Cu-SSZ-13 zeolite via Pr-ion modification35Interconversion and functional composites of metal–organic frameworks and hydrogen-bonded organic frameworks25Latest technological advances and insights into capture and removal of hydrogen sulfide: a critical review56Recent advances on metal–organic frameworks for deep purification of olefins54Understanding deNO x mechanisms in transition metal exchanged zeolites28Accurate Measurements of NH 3 Differential Adsorption Heat Unveil Structural Sensitivity of Brønsted Acid and Brønsted/Lewis Acid Synergy in Zeolites19Kinetics, Isotherms, and Thermodynamics Studies on Adsorption of Methyl Green Dye Onto Different Zeolites20Research Progress on Hygroscopic Agents for Atmospheric Water Harvesting Systems25Confinement of CsPbBr 3 Perovskite Nanocrystals into Extra‐large‐pore Zeolite for Efficient and Stable Photocatalytic Hydrogen Evolution55Spatiotemporal Heterogeneity of Temperature and Catalytic Activation within Individual Catalyst Particles23Upgrading waste plastics to value-added aromatics30Zeolite Properties, Methods of Synthesis, and Selected Applications215Zeolites for the environment57Modelling atomic and nanoscale structure in the silicon–oxygen system through active machine learning75Boosting propane dehydrogenation performance over the highly dispersed Co(Ⅱ) sites on ultra-high silica ZSM-5 zeolite28Unraveling Spatially Dependent Hydrophilicity and Reactivity of Confined Carbocation Intermediates during Methanol Conversion over ZSM-5 Zeolite24Control of Zeolite Local Polarity toward Efficient Xenon/Krypton Separation57Epitaxial Growth of Two-Dimensional MWW Zeolite24Organic Solvent Nanofiltration in Pharmaceutical Applications117Hierarchical FAU Zeolites Boosting the Hydrocracking of Polyolefin Waste into Liquid Fuels38Implanting Colloidal Nanoparticles into Single‐Crystalline Zeolites for Catalytic Dehydration17Supramolecular Entanglement in a Hydrogen‐Bonded Organic Framework Enables Flexible‐Robust Porosity for Highly Efficient Purification of Natural Gas85Toward Scalable and Sustainable Synthesis of Metal–Organic Frameworks61High-performance near-infrared OLEDs maximized at 925 nm and 1022 nm through interfacial energy transfer34A comprehensive review of nanomaterials for efficient heavy metal ions removal in water treatment67Microporous Materials in Polymer Electrolytes: The Merit of Order57MOF-based membranes: Preparation, modification, and oil/water separation application28Heteroatoms‐Stabilized Single Palladium Atoms on Amorphous Zeolites: Breaking the Tradeoff between Catalytic Activity and Selectivity for Alkyne Semihydrogenation53Colloidal Templating in Catalyst Design for Thermocatalysis21Self-Driving Laboratories for Chemistry and Materials Science674Color center-rich γ-Al2O3 promotes propane dehydrogenation22Zeolite-based materials for greenhouse gas capture and conversion41Synergy of pore size and silanols in an –SVR-type zeolite for efficient dynamic benzene/cyclohexane separation19Reactivity Inside Molecular Flasks: Acceleration Modes and Types of Selectivity Obtainable23Restricting Linker Rotation in Nanocages of ZIF‐8 Membranes using Crown Ether “Molecular Locks” for Enhanced Propylene/Propane Separation31Steering diffusion selectivity of chemical isomers within aligned nanochannels of metal-organic framework thin film17Utilization of Electric Fields to Modulate Molecular Activities on the Nanoscale: From Physical Properties to Chemical Reactions63Synergistic functionality of metal–organic framework-cellulose composites structures for advanced high-performance energy materials33Design principles of single-atom catalysts anchored over porous materials for green catalysis and conversion71Coke-induced deactivation in zeolite catalysts: mechanisms, anti-coking modifications, and regeneration approaches32Covalent organic frameworks for radioactive iodine capture: structure and functionality60Dynamic evolution of metal structures on/in zeolites for catalysis26Exploring guest species in zeolites using transmission electron microscopy: a review and outlook17Tailoring Cu-based small-pore zeolites towards NH 3 -SCR for NO x abatement49Hierarchy design of zeolite mesocrystals203D-Printed photocatalysts for revolutionizing catalytic conversion of solar to chemical energy62Lattice Oxygen Redox Dynamics in Zeolite‐Encapsulated CsPbBr 3 Perovskite OER Electrocatalysts21Covalent organic frameworks with nitrogen-rich triazine units and suitable pore size for highly efficient adsorption and sensitive detection of bisphenols in water28Interfacial Catalysis at Atomic Level161The strategies to improve the interfacial compatibility in mixed-matrix membranes: A review26Heterogeneous Frustrated Lewis Pair Catalysts: Rational Structure Design and Mechanistic Elucidation Based on Intrinsic Properties of Supports40MOFs@COFs composites: Advances, challenges, and multifunctional applications in emerging technologies28Toward a Circular Economy of Heteroatom Containing Plastics: A Focus on Heterogeneous Catalysis in Recycling21Highly efficient and stable single-atom Cu encapsulated in silicalite-1 zeolite for selective catalytic oxidation of nitrogen-containing VOCs21Ethylene Pretreatment Enhances Ethylene Adsorption and Separation over Cu@SAPO‐RHO Zeolite30Zeolite–Water Chemistry: Characterization Methods to Unveil Zeolite Structure19Solvent-free green synthesis of zeolite A from coal fly ash for the removal of Pb2+18Structurally Engineering Multi‐Shell Hollow Zeolite Single Crystals via Defect‐Directed Oriented‐Kinetics Transformation and Their Heterostructures for Hydrodeoxygenation Reaction18Efficient Kinetic Separation of Carbon Dioxide from Acetylene Using Mordenites Featuring Modified 1D Channels with Excellent Selectivity and Diffusion18Double-Walled Mesoporous Hydrogen-Bonded Organic Frameworks with High Methane Storage Capacity32Carbon‐Based Catalysts for Electrosynthesis of Hydrogen Peroxide18Revealing the Crucial Roles of Pore Interconnectivity between Zeolitic and Nonzeolitic Components in Enhancing Diffusion and Catalytic Efficiency of Industrial Zeolite-Based Catalysts37Dynamic Evolution of Structural Ordering and Aluminum Redistribution During ZSM‐5 Zeolite Crystallization23Building ultramicroporous zirconium metal‒organic frameworks with ligands of high coordination density through a reticular approach53Zeolites as Photoactive Scaffolds for Efficient Photooxidation26Covalent organic frameworks for gas storage and separation24

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  4. Zeolite-Encaged Isolated Platinum Ions Enable Heterolytic Dihydrogen Activation and Selective Hydrogenations

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  5. Controlling Nucleation Pathways in Zeolite Crystallization: Seeding Conceptual Methodologies for Advanced Materials Design

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  37. Imidazolium salts facilitate mechanochemical synthesis of well-dispersed MFI zeolite crystals with c-axis orientation

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  47. Structural Stability and Phase Transitions in Zeolite A: An In Situ High Pressure–High Temperature Investigation

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  48. H-beta zeolite-based dispersive solid-phase strategy for the multi-residue determination of pesticides

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  49. Metal Sites in Zeolites: Synthesis, Characterization, and Catalysis

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  50. A general method for rapid synthesis of refractory carbides by low-pressure carbothermal shock reduction

    Proceedings of the National Academy of Sciences · 2022-09-06

    Ye‐Chuang Han, Mengli Liu, Li Sun, Shuxing Li, Gen Li, Wei-Shen Song, Yanjie Wang, Zi‐Ang Nan, Song‐Yuan Ding, Hong‐Gang Liao, Yonggang Yao, Galen Dean Stucky, Feng Ru Fan, Zhong‐Qun Tian

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