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RESEARCH PAPER · Chemical Engineering Journal · 2021

Superior thermally-stable narrow-band green emitter from Mn2+-doped zero thermal expansion (ZTE) material

Wei Wang, Hang Yang, Meiqian Fu, Xinyang Zhang, Mengyu Guan, Yi Wei, Chun Che Lin, Guogang Li

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Superior thermally-stable narrow-band green emitter from Mn2+-doped zero thermal expansion (ZTE) materialOriginalA zero-thermal-quenching perovskite-like phosphor with an ultra-narrow-band blue-emission for wide color gamut backlight display applications67Constructing a Model for Tuning the Thermal Quenching Properties of Bismuth-Doped Phosphors by Energy-Gap Modulation34Anti-thermal-quenching red-emitting phosphors based on lanthanide doped negative-thermal-expansion (NTE) hosts46Deep insight into the luminescence performance of Li2MgSiO4:Mn2+ green phosphor synthesized by a sol-gel process14Variation from Zero to Negative Thermal Quenching of Phosphor with Assistance of Defect States45Achieving highly thermostable red emission in singly Mn 2+ -doped BaXP 2 O 7 (X = Mg/Zn) via self-reduction36Broad luminescence tuning in Mn 2+ -doped Rb 2 Zn 3 (P 2 O 7 ) 2 via doping level control based on multiple synergies10Thermal stability and self-reduction of a new red phosphor NaMg(PO 3 ) 3 :Mn 2+17Tuning of the thermal quenching performance of Bi 3+ -doped scheelite Ca(Mo/W)O 4 solid solution phosphors13How to Obtain Anti‐Thermal‐Quenching Inorganic Luminescent Materials for Light‐Emitting Diode Applications252High-performance narrow-band green-emitting phosphor enabled by substituting Na with Rb6Luminescence and interstitial-defect-related self-reduction in Mn2+ activated Ba3BP3O12 phosphor13Photoluminescence spectroscopy of Mn2+ in zero-thermal expansion Zn4B6O13 green-emitting phosphor12Synthesis, crystal structure, and anti‐thermal quenching performance of Lu 2 Sr (1− x ) Al 4 SiO 12 : x Eu 2+ phosphors9Enhanced thermostability of Eu3+ ions photoluminescence by multi-level electron traps with various temperature responses4Thermal Quenching Mechanism of Metal–Metal Charge Transfer State Transition Luminescence Based on Double-Band-Gap Modulation24A novel blue emitting phosphor LaScO3:Bi3+ for white LEDs: high quantum efficiency, high color purity and excellent thermal stability34Defect and energy transfer induced abnormal thermally stable and highly efficient narrow-band green emission19Review—Temperature Dependence of Transition-Metal and Rare-Earth Ion Luminescence (Mn 4+ , Cr 3+ , Mn 2+ , Eu 2+ , Eu 3+ , Tb 3+ , etc.) II: Experimental Data Analyses20Zn3GaB6O12As and Zn4P6N12S: Isotropic Zero Thermal Expansion Materials Based on the “Cage-Restricting” Model13Luminescence Properties and Energy Transfer in SrLa2Sc2O7 Co-Doped with Bi3+/M (M = Eu3+, Mn4+, or Yb3+)4Nanostructured Silver Films with a Low Coefficient of Thermal Expansion as a Promising Material for Nanoelectronics3Mn2+ doped BaAl11O16N phosphors with narrow band green emission and superior thermal stability for backlighting display applications11Highly Luminescent Earth‐Benign Organometallic Manganese Halide Crystals with Ultrahigh Thermal Stability of Emission from 4 to 623 K26A novel bright cyan emitting phosphor of Eu 2+ activated Ba 6 BO 3 Cl 9 with robust thermal stability for full-spectrum WLED applications65Achieving excellent thermostable red emission in singly Mn 2+ -doped near-zero thermal expansion (NZTE) material Li 2 Zn 3 (P 2 O 7 ) 26An Efficient Narrow-band Blue-emitting Phosphor Ba3Y2B6O15:Bi3+ and Its Application7Design of anti-thermal quenching Pr 3+ -doped niobate phosphors based on a charge transfer and intervalence charge transfer band excitation-driven strategy18High performance of broad excitation and narrow emission green phosphor NaAl 11 O 17 :Eu 2+ , Mn 2+ for backlight displays20Suppressed Self‐Reduction of Manganese in Mg 2 SnO 4 via Li + Incorporation with Polychromatic Luminescence for Versatile Applications66Precisely Manipulating the Self‐Reduction of Manganese in MgGa2O4 through Lithium Incorporation for Optical Thermometry and Anti‐Counterfeiting64Mn4+ vs Mn2+—A comparative study as efficient activator ions in phosphor materials: A review60Photoluminescence of Mn2+ in the Borosulfate Zn[B2(SO4)4] : Mn2+—A Tool to Detect Weak Coordination Behavior of Ligands18Photolumineszenz von Mn2+ in dem Borosulfat Zn[B2(SO4)4] : Mn2+ – Eine Möglichkeit zum Nachweis schwach koordinierender Liganden0High-Quantum-Efficiency Blue Phosphors with Superior Thermal Stability Derived from Eu3+-Doped Faujasite Y Zeolite11Isolated Coordination Polyhedron Confinement in ABP2O7:Mn2+ (A = Ba/Sr; B = Mg/Zn)5K2CaPO4F:Eu2+,RE3+ for pc-WLEDs: Cationic substitution inducing tunable emission and anti-thermal quenching8Structure, luminescence properties and anti-thermal quenching of a novel Eu3+-activated red phosphor based on the negative thermal expansion material In0.5Sc1.5(MoO4)332Review—Photoluminescence Spectroscopy of Mn2+-Activated Phosphors: Part I. Fundamentals15A highly Mn 2+ -doped narrowband green phosphor toward wide color-gamut display applications26Cr 3+ ↔Fe 3+ Energy Transfer Offset Enabling Anti‐Thermal Quenching Near‐Infrared Emission for Coded Wireless‐Communication Applications43Design strategies of rare-earth luminescent complexes with zero thermal quenching protected by the wire-in-tube structure and the construction of a W-WLED with highly stable illumination and colour reproduction3Dual-Mode Optical Thermometers Via the Thermochromic Mn2+/Mn4+ Co-Doped Mg0.388al2.408o4 Phosphors for Real-Time Chip Temperature Monitoring0Highly efficient blue-green dual-narrow-emission in RbAl 11 O 17 :Eu 2+ ,Mn 2+ toward wide-color-gamut human-centric backlights7Luminescence analysis of heavily Mn 2+ -doped LaMgAl 11 O 19 phosphors: crystallographic site occupation and the formation of Mn 2+ –Mn 2+ dimers18Designing high thermally stable deep red phosphors based on low thermal expansion coefficients for optical applications16Tunable Anti‐Thermal Quenching Luminescence of Eu 3+ ‐Doped Metal‐Organic Framework and Temperature‐Dependent Photonic Coding48Negative Thermal Expansion Materials as Anti-Thermal-Quenching Phosphor Matrixes: Status, Opportunities, and Challenges51Mn–Mn Magnetic Coupling Interaction-Induced Red Emission in a Tetra-Coordinated Lattice23Mn 2+ –Mn 2+ Dimers Induced Robust Light Absorption in Heavy Mn 2+ Doped ZnAl 2 O 4 Near‐Infrared Phosphor with an Excellent Photoluminescence Quantum Yield and Thermal Stability28Thermal Stability Enhancement by a Cationic Substitution Strategy in Red-Emitting Eu2W3–xMoxO12 Solid-Solution Phosphors1Broadband spectral cyan emission phosphor for full-spectrum LED caused by interstitial site occupation2Fiber temperature sensor based on dual-wavelength emitting Mg0.388Al2.408O4: Mn2+/Mn4+ phosphors for real-time temperature monitoring5Efficient protection of perovskite nanoparticles in salicylic acid hollow crystal via super simple standing method5Self‐reduction triggered color tuning of Eu 3+ ‐doped aluminosilicate glass for solid‐state white illumination4High-performance, narrow-band green-emitting phosphors for white LEDs: recent advances and perspectives36Potential Laser Crystal of Zn4B6O13:Mn2+ with Low Thermal Expansion and High Thermal Conductivity: Single-Crystal Growth and Characterization3Dual-emission ultra-wideband phosphor applied to yellow light LED and temperature visualization5Review—Mn2+-Based Codopant Phosphor System: Fundamentals and Some Representatives7Prediction and explanation of the self-reduction of Eu3+ → Eu2+ and Mn4+ → Mn2+ using Site Occupancy Theory (SOT)6Modulating anti-thermal and concentration quenching for enhanced dysprosium emission6Mn–Mn Dimers Induced Multimode Emitters in Mn2+-Activated AZn4(PO4)3 (A = K, Rb, and Cs) with Unique [Zn4PO12] Chains and [ZnOn] Groups3CaLu 2 Sc 2 Al 2 SiO 12 :Ce 3+ Green Phosphors for High-Quality White LEDs31Local charge regulation induced manganese valence adjustment in Mn2+/Mn4+ doped β-Al2O3 structure phosphor for visual temperature sensing8Mn 2+ ‐Activated Alkali Lithooxidosilicate Phosphors as Sustainable Alternative White‐Light Emitters10Mn 2+ ‐aktivierte Alkalilithooxidosilikat‐Leuchtstoffe als nachhaltige alternative Weißlichtemitter1Novel red-emitting phosphor Na3LaW3O12: Sm3+, Eu3+: synthesis, luminescent properties, anti-thermal quenching and LED packaging3Novel ultra-broadband cyan phosphor with excellent thermal stability for full-spectrum WLED7Self-reduction-induced Mn heterovalent coexistence for Vis–NIR dual-emission16A review of recent advances in Ce3+-activated garnet phosphors for blue-chip-pumped pc-WLEDs81Enhanced thermal stability and energy transfer in Mn2+ co-doped MgAl2O4:Cr3+ for potential applications3Narrow‐Band Green Phosphors for Advanced Display Technologies: Material Design, Performance Optimization, and Future Prospects6Dual-mechanism regulation of energy transfer and structural engineering for anti-concentration quenching in Eu3+-alloyed Sr3BiY3B4O15 phosphors3Compositional Design of Mn 2+ ‐Activated Phosphors: Toward Narrow‐Band Green Emission for Wide Color Gamut Displays11Dual green and red emission of novel Mn doped Mg 0.3 Zn 0.7 Al 2 O 4 phosphors synthesized by a solid-state method for high-sensitivity temperature sensor applications0Luminescence properties, energy transfer, and potential applications of Sr2MgAl22O36:Mn2+,Cr3+ phosphor1Conversion narrow-band green emission from Mn2+ in BaAl12O19 via a self-reduction synthesis from Mn4+ precursors0Unlocking Controllable Multi‐Band Emission from a Mn‐Doped Spinel: Ranging from Narrow‐Band Green to Efficient NIR0

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  49. Mn–Mn Magnetic Coupling Interaction-Induced Red Emission in a Tetra-Coordinated Lattice

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