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RESEARCH PAPER · Advanced Energy Materials · 2021

Organic Negative Electrode Materials for Metal‐Ion and Molecular‐Ion Batteries: Progress and Challenges from a Molecular Engineering Perspective

Alae Eddine Lakraychi, Franck Dolhem, Alexandru Vlad, Matthieu Robert Becuwe

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Organic Negative Electrode Materials for Metal‐Ion and Molecular‐Ion Batteries: Progress and Challenges from a Molecular Engineering PerspectiveOriginalRoadmap of Solid-State Lithium-Organic Batteries toward 500 Wh kg –192N‐doped carbon nanotube sponges and their excellent lithium storage performances8Chemical Upcycling of PET Waste towards Terephthalate Redox Nanoparticles for Energy Storage16Flexible Transparent Electrochemical Energy Conversion and Storage: From Electrode Structures to Integrated Applications37Regulating Steric Hindrance in Redox‐Active Porous Organic Frameworks Achieves Enhanced Sodium Storage Performance22High performance Li-, Na-, and K-ion storage in electrically conducting coordination polymers67Highly efficient phenanthroline-based organic anode materials with a three-electron redox mechanism17Materials, electrodes and electrolytes advances for next-generation lithium-based anode-free batteries13Molecular structure design of planar zwitterionic polymer electrode materials for all-organic symmetric batteries26Revealing the Solid-State Electrochemistry of Conjugated Oximates: Towards a New Functionality for Organic Batteries1Conjugated Copolymer Design in Phenothiazine-Based Battery Materials Enables High Mass Loading Electrodes30Experimentally Validated Three‐Dimensional Modeling of Organic‐Based Sodium‐Ion Battery Electrode Manufacturing35New insights into the electrochemical activity of maleic acid in lithium ion battery4Influence of Polymorphism on the Electrochemical Behavior of Dilithium (2,3-Dilithium-oxy)-terephthalate vs. Li11Azo Compounds as Active Materials of Energy Storage Systems63Azo Compounds as Active Materials of Energy Storage Systems2Organic batteries for a greener rechargeable world456Molecular Engineering of Quinone-Based Nickel Complexes and Polymers for All-Organic Li-Ion Batteries3Advanced Covalent Organic Frameworks for Multi‐Valent Metal Ion Batteries16Emerging Lithiated Organic Cathode Materials for Lithium‐Ion Full Batteries70Emerging Lithiated Organic Cathode Materials for Lithium‐Ion Full Batteries13New Avenues for Organic Redox Materials as Sustainable Lithium-ion Battery Cathodes3Validating the reversible redox of alkali-ion disulfonyl-methanide as organic positive electrode materials8Revealing the Reversible Solid-State Electrochemistry of Lithium-Containing Conjugated Oximates: Towards a New Functionality for Organic Batteries0Fusing Thiadiazole and Terephthalate: A Concept to Promote the Electrochemical Performance of Conjugated Dicarboxylates8A stable aqueous ammonium ion hybrid supercapacitor based on pre-intercalated MnOx electrodes and ammonium sulphate electrolyte42Revealing the reversible solid-state electrochemistry of lithium-containing conjugated oximates for organic batteries30Disodium naphthalene dicarboxylate based negative electrode engineering for organic-inorganic hybrid sodium batteries5Lithiated indole derivative in reduced graphene oxide framework as efficient electrode for lithium-ion battery3Small Molecule Azaacene as an Anode Material for Lithium-Ion Batteries2Small-molecule organic electrode materials for rechargeable batteries66Assessing n‐type organic materials for lithium batteries: A techno‐economic review36Des nouveaux matériaux pour des batteries sans métaux0High-Output-Voltage and -Energy-Density All-Organic Dual-Ion Battery Using Molecular Thianthrene22Strongly Hydrogen-Bonded Networks Formed by Sulfate and Bisulfate Salts of Benzenetetramines4Suppressing Shuttle Effect with a Size-Selective Covalent Organic Framework Based Bilayer Membrane22Refreshing the Legacy of Rudolf Nietzki: Benzene-1,2,4,5-tetramine and Related Compounds1Impact of the Microstructure on Electrochemical Performances of Dilithium Benzoquinone Dioximate as a Positive Material for a Li-Ion Battery7A donor–acceptor (D–A) conjugated polymer for fast storage of anions79A donor–acceptor (D–A) conjugated polymer for fast storage of anions14A bipolar polymer cathode for sodium-ion batteries3A redox acceptor–acceptor nitro functionalized naphthalene diimide/rGO anode for sustainable lithium-ion batteries5Polyimide-Based Aqueous Potassium Energy Storage Systems Using Concentrated WiSE Electrolyte25A Safe Organic/Inorganic Composite Anode for Sodium‐Ion Batteries19Challenge and Design Strategies of Polymer Organic Electrodes for Lithium‐Ion Batteries15Steric hindrance modulation of hexaazatribenzanthraquinone isomers for high-capacity and wide-temperature-range aqueous proton battery28Metal- and binder-free dual-ion battery based on green synthetic nano-embroidered spherical organic anode and pure ionic liquid electrolyte26Cost and performance analysis as a valuable tool for battery material research75Organic Anode0Designing Organic Material Electrodes for Lithium-Ion Batteries: Progress, Challenges, and Perspectives103Combining Polyester-Based Solid Polymer Electrolytes with Lithiated Organic Cathodes for 3.5 V-Class Li-Organic Rechargeable Batteries12Triphenylamine‐Supported Benzoquinone Polymer as High Performance Cathode for Lithium‐Ion Batteries5Design Principles of Quinone Redox Systems for Advanced Sulfide Solid‐State Organic Lithium Metal Batteries22High-Rate Performance Organic Cathodes Based on Carbon Nanotube-Modified Anthraquinone-Based Polyimides for All-Organic Lithium/Sodium-Ion Batteries12Synergetic effects of S, N co-doping and surface concave-pores rich in lotus-leaf-like carbon nanosheets enabled threefold lithium storage mechanisms14Molecular Engineering and Microstructure Modulation of High‐Performance Organic Batteries0Nickel Complex Based Electrodes for Li‐ion Batteries0Carbonyl-based organic electrode materials spanning from nonaqueous rechargeable lithium to calcium batteries13Fused-ring engineering endows conjugated polymer cathode with accelerated charge storage kinetics and improved reversibility in aqueous zinc-ion batteries0In Situ Electrochemical Reconstruction of Terephthalate Metal–Organic Framework Nanosheets for High‐Efficiency Lithium‐Ion Storage8Boosting reaction kinetics in vanadium oxide cathode via carboxylated conjugate multi-ring molecular intercalation3Anti-detachment interface enabled ultra-flexible quinone-rich polydopamine/carbonized silk textile for reversible sodium storage8Evaluating the present and future of organic batteries42A Scalable Synthesis of a New Quasi‐Reversible Redox Compound with a High Positive Redox Potential0Unveiling the Peierls effect during electrochemical delithiation/lithiation process in magnesium (2,5-dilithium-oxy)-terephthalate using combined experimental and computational studies4Phenothiazine Dimer as Efficient and Recyclable p‐Type Organic Positive Electrode Material for Anion‐Ion and Dual‐Ion Batteries1Investigation of 2,6-Sodium Naphthalene Dicarboxylate Structure–Reactivity Relationship by Operando X-ray Diffraction and Post-Mortem Transmission Electron microscopy2Coordination-regulated Zn/N-functionalized hierarchical hollow carbon for selective Pb2+ removal by capacitive deionization4Ethynyl/Thienyl-Functionalized Porphyrin Complexes as High-Performance Cathodes for Electrochemical Energy Storage0

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  1. Roadmap of Solid-State Lithium-Organic Batteries toward 500 Wh kg –1

    ACS Energy Letters · 2021-08-25

    Lihong Zhao, Alae Eddine Lakraychi, Zhaoyang Chen, Yanliang Liang, Yan Li Yao

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  2. N‐doped carbon nanotube sponges and their excellent lithium storage performances

    Nano Select · 2021-09-02

    Qi Zhu, Andrés R. Botello‐Méndez, Luhua Cheng, Juan L. Fajardo‐Díaz, Emilio Muñoz‐Sandoval, Florentino Lopéz‐Urías, Jiande Wang, Jean‐François Gohy, Jean‐Christophe Charlier, Alexandru Vlad

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  3. Chemical Upcycling of PET Waste towards Terephthalate Redox Nanoparticles for Energy Storage

    Sustainable Chemistry · 2021-11-03

    Nicolas Goujon, Jérémy Demarteau, Xabier Lopez de Pariza, Nerea Casado, Haritz Sardón, David Mecerreyes

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  4. Flexible Transparent Electrochemical Energy Conversion and Storage: From Electrode Structures to Integrated Applications

    Energy & environment materials · 2021-11-07

    Yanli Zhao, Huaizhi Liu, Yu Yan, Tianwei Chen, Huihuang Yu, Lucky Ogheneakpobo Ejeta, Guanhua Zhang, Huigao Duan

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  5. Regulating Steric Hindrance in Redox‐Active Porous Organic Frameworks Achieves Enhanced Sodium Storage Performance

    Small · 2021-12-04

    Yilin Shan, Yanyan He, Na Yang, Xiang Zhu, Honglai Liu, Hao Jiang, Chunzhong Li

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  6. High performance Li-, Na-, and K-ion storage in electrically conducting coordination polymers

    Energy & Environmental Science · 2022-01-01

    Jiande Wang, Xiaolong Guo, Petru Apostol, Xuelian Liu, Koen Robeyns, Loïk Gence, Cristian Morari, Jean‐François Gohy, Alexandru Vlad

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  7. Highly efficient phenanthroline-based organic anode materials with a three-electron redox mechanism

    Journal of Materials Chemistry A · 2022-01-01

    Kangkang Jia, Haitao Liu, Guimei Huang, Jingwei Zhang, Xiaorui Liu, Lu Li, Linna Zhu, Fei Wu

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  8. Materials, electrodes and electrolytes advances for next-generation lithium-based anode-free batteries

    Oxford Open Materials Science · 2022-01-01

    Shubhadeep Pal, Xiaozhe Zhang, Binson Babu, Xiaodong Lin, Jiande Wang, Alexandru Vlad

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  9. Molecular structure design of planar zwitterionic polymer electrode materials for all-organic symmetric batteries

    Chemical Science · 2022-01-01

    Jun Wang, Haichao Liu, Chunya Du, Yu Liu, Bing Liu, Haoran Guan, Shaowei Guan, Zhenhua Sun, Hongyan Yao

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  10. Revealing the Solid-State Electrochemistry of Conjugated Oximates: Towards a New Functionality for Organic Batteries

    Research Square · 2022-02-18

    Jiande Wang, Petru Apostol, Darsi Rambabu, Xuelian Liu, Xiaolong Guo, Koen Robeyns, Alae Eddine Lakraychi, Cristian Morari, Jean‐François Gohy, Deepak Gupta, Alexandru Vlad

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  11. Conjugated Copolymer Design in Phenothiazine-Based Battery Materials Enables High Mass Loading Electrodes

    ACS Sustainable Chemistry & Engineering · 2022-02-25

    Pascal Acker, Jan S. Wössner, Gauthier Desmaizieres, Birgit Esser

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  12. Experimentally Validated Three‐Dimensional Modeling of Organic‐Based Sodium‐Ion Battery Electrode Manufacturing

    Batteries & Supercaps · 2022-03-29

    Teo Lombardo, Fanny Lambert, Roberto Russo, Franco M. Zanotto, Christine Frayret, Gwenaëlle Toussaint, Philippe Stevens, Matthieu Robert Becuwe, Alejandro A. Franco

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  13. New insights into the electrochemical activity of maleic acid in lithium ion battery

    Chemical Engineering Journal · 2022-04-19

    Fangyuan Xiao, Yuruo Qi, Hao Wang, Yijun Liu, Shu‐Juan Bao, Maowen Xu

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  14. Influence of Polymorphism on the Electrochemical Behavior of Dilithium (2,3-Dilithium-oxy)-terephthalate vs. Li

    Inorganics · 2022-05-10

    Lou Bernard, Alia Jouhara, Éric Quarez, Yanis Levieux‐Souid, Sophie Le Caër, Pierre Tran‐Van, Stéven Renault, Philippe Poizot

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  15. Azo Compounds as Active Materials of Energy Storage Systems

    Angewandte Chemie International Edition · 2022-06-19

    Takeshi Shimizu, Naoki Tanifuji, Hirofumi Yoshikawa

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  16. Azo Compounds as Active Materials of Energy Storage Systems

    Angewandte Chemie · 2022-06-20

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  17. Organic batteries for a greener rechargeable world

    Nature Reviews Materials · 2022-09-20

    Jihyeon Kim, Youngsu Kim, Jaekyun Yoo, Giyun Kwon, Youngmin Ko, Kisuk Kang

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  18. Molecular Engineering of Quinone-Based Nickel Complexes and Polymers for All-Organic Li-Ion Batteries

    Molecules · 2022-10-11

    Yanislav Danchovski, Hristo Rasheev, Radostina K. Stoyanova, Alia Tadjer

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  19. Advanced Covalent Organic Frameworks for Multi‐Valent Metal Ion Batteries

    Chemistry - A European Journal · 2022-10-17

    Xiaoxi Luo, Xiaotong Wang, Edison Huixiang Ang, Kai-Yang Zhang, Xin‐Xin Zhao, Hong‐Yan Lü, Xing‐Long Wu

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  20. Emerging Lithiated Organic Cathode Materials for Lithium‐Ion Full Batteries

    Angewandte Chemie International Edition · 2022-11-29

    Yong Lü, Qiu Zhang, Fujun Li, Jun Chen

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  21. Emerging Lithiated Organic Cathode Materials for Lithium‐Ion Full Batteries

    Angewandte Chemie · 2022-11-29

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  22. New Avenues for Organic Redox Materials as Sustainable Lithium-ion Battery Cathodes

    Organic Materials · 2023-01-01

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  23. Validating the reversible redox of alkali-ion disulfonyl-methanide as organic positive electrode materials

    Materials Today Chemistry · 2023-02-03

    Yan Zhang, Petru Apostol, Xiaolong Guo, Xiao-Yang LIU, Darsi Rambabu, Jiande Wang, Xiong Jing Chen, Alexandru Vlad

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  24. Revealing the Reversible Solid-State Electrochemistry of Lithium-Containing Conjugated Oximates: Towards a New Functionality for Organic Batteries

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  25. Fusing Thiadiazole and Terephthalate: A Concept to Promote the Electrochemical Performance of Conjugated Dicarboxylates

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  26. A stable aqueous ammonium ion hybrid supercapacitor based on pre-intercalated MnOx electrodes and ammonium sulphate electrolyte

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  27. Revealing the reversible solid-state electrochemistry of lithium-containing conjugated oximates for organic batteries

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  28. Disodium naphthalene dicarboxylate based negative electrode engineering for organic-inorganic hybrid sodium batteries

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  29. Lithiated indole derivative in reduced graphene oxide framework as efficient electrode for lithium-ion battery

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  30. Small Molecule Azaacene as an Anode Material for Lithium-Ion Batteries

    Energy & Fuels · 2023-08-24

    James W. Sturman, Eloi Grignon, Bryony T. McAllister, Chae-Ho Yim, Elena A. Baranova, Dwight S. Seferos, Yaser Abu‐Lebdeh

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  31. Small-molecule organic electrode materials for rechargeable batteries

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  32. Assessing n‐type organic materials for lithium batteries: A techno‐economic review

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  33. Des nouveaux matériaux pour des batteries sans métaux

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  34. High-Output-Voltage and -Energy-Density All-Organic Dual-Ion Battery Using Molecular Thianthrene

    ACS Energy Letters · 2023-10-11

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  35. Strongly Hydrogen-Bonded Networks Formed by Sulfate and Bisulfate Salts of Benzenetetramines

    Crystal Growth & Design · 2023-10-25

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  36. Suppressing Shuttle Effect with a Size-Selective Covalent Organic Framework Based Bilayer Membrane

    ACS Energy Letters · 2023-11-06

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  37. Refreshing the Legacy of Rudolf Nietzki: Benzene-1,2,4,5-tetramine and Related Compounds

    The Journal of Organic Chemistry · 2023-11-13

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  38. Impact of the Microstructure on Electrochemical Performances of Dilithium Benzoquinone Dioximate as a Positive Material for a Li-Ion Battery

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  39. A donor–acceptor (D–A) conjugated polymer for fast storage of anions

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  40. A donor–acceptor (D–A) conjugated polymer for fast storage of anions

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  41. A bipolar polymer cathode for sodium-ion batteries

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  42. A redox acceptor–acceptor nitro functionalized naphthalene diimide/rGO anode for sustainable lithium-ion batteries

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  43. Polyimide-Based Aqueous Potassium Energy Storage Systems Using Concentrated WiSE Electrolyte

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  44. A Safe Organic/Inorganic Composite Anode for Sodium‐Ion Batteries

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  45. Challenge and Design Strategies of Polymer Organic Electrodes for Lithium‐Ion Batteries

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  46. Steric hindrance modulation of hexaazatribenzanthraquinone isomers for high-capacity and wide-temperature-range aqueous proton battery

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  47. Metal- and binder-free dual-ion battery based on green synthetic nano-embroidered spherical organic anode and pure ionic liquid electrolyte

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  48. Cost and performance analysis as a valuable tool for battery material research

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  49. Organic Anode

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  50. Designing Organic Material Electrodes for Lithium-Ion Batteries: Progress, Challenges, and Perspectives

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    Qiyu Wang, Thomas O'Carroll, Fengchun Shi, Yafei Huang, Guorong Chen, Xiaoxuan Yang, Alena A. Nevar, Natallia Dudko, Н. В. Тарасенко, Jingying Xie, Liyi Shi, Gang Wu, Dengsong Zhang

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