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RESEARCH PAPER · Inorganic Chemistry · 2021

Role of the Polar Electric Field in Bismuth Oxyhalides for Photocatalytic Water Splitting

Xudong Dong, Yi-Man Zhang, Zong‐Yan Zhao

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Role of the Polar Electric Field in Bismuth Oxyhalides for Photocatalytic Water SplittingOriginalFacile synthesis of mesoporous polymeric carbon nitride nanosheets anchored by Pt with ultralow loading for high-efficiency photocatalytic H 2 evolution2Facile fabrication of flower-like NH2-UIO-66/BiOCl Z-scheme heterojunctions with largely improved photocatalytic performance for removal of tetracycline under solar irradiation54Dual modification of BiOIO3 via doping iodine and fabricating heterojunction with basic bismuth salt: Facile synthesis, superior performance for degradation of multiple refractory organics10Boosting and regulating solar energy conversion performance of delafossite AgFeO 2 by spin polarization20Ammonia-dependent synthesis of (BiO)2OHCl@Bi24O31Cl10 heterostructures with enhanced visible-light induced photocatalytic activities on levofloxacin removal14Indirect Substitution Constructing Halogen-Vacancy BiOCl1–xIn Solid Solution with a Suitable Surface Structure for Enhanced Photoredox Performance18One-pot synthesis of delafossite CuCoO2 microcrystal as visible-light-driven photocatalyst35Tunable Photocatalytic Water Splitting Performance of Armchair MoSSe Nanotubes Realized by Polarization Engineering16Photocatalytic and Photocurrent Responses to Visible Light of the Lone-Pair-Based Oxysulfide Sr6Cd2Sb6S10O728Sustainable Production of Layered Bismuth Oxyhalides for Photocatalytic H 2 Production26High-Throughput Strategies for the Design, Discovery, and Analysis of Bismuth-Based Photocatalysts18New Modification of Polar Nonlinear Optical Iodate Fluoride PbF(IO3), the Family MX(IO3), M = Bi, Ba, Pb, X = O, F, (OH) Related to Aurivillius Phases and Similar Iodates3Bismuth-Based Photocatalytic Material for Clean Energy Production and CO2 Reduction2Bismuth-based semiconductors applied in photocatalytic reduction processes: fundamentals, advances and future perspectives65Photocatalytic Water Splitting and Co2 Reduction with Internal Electric Field Modulation1Review: applications of the functional photocatalysts BiOX (X = Cl, Br, I) for clean energy, the environment, and future photobiorefineries90Recent Advances in Efficient Photocatalysis via Modulation of Electric and Magnetic Fields and Reactive Phase Control122Delafossite CuFeO2 nanosheets with highly exposed {0 0 1} crystal facets for enhancing charge separation efficiency12Visible light and iodate/iodide mediated degradation of bisphenol A by self-assembly 3D hierarchical BiOIO3/Bi5O7I Z-scheme heterojunction: Intermediates identification, radical mechanism and DFT calculation73A BiOIO3/BiOBr n-n heterojunction was constructed to enhance the photocatalytic degradation of TC91BiOCl1−xBrx solid solution – Novel synthesis, highly-efficient visible-light-driven photocatalyst, and DFT study19Fabrication of BrO3- bridged Cr2Bi3O11 for enhanced photocatalytic degradation of phenol under visible light2Bismuth-based nanomaterials-assisted photocatalytic water splitting for sustainable hydrogen production70Strong metal-carrier interactions via modulation of Pt oxidation states on defective BiOBr with greatly improved photocatalytic activity7Constructing BiOBr 1– x I x – y with Abundant Surface Br Vacancies for Excellent Visible-Light Photodegradation Capability of High-Concentration Refractory Contaminants10Boron-Doped Exfoliated g-C3N4 Nanosheet-Based Phosphors for White Light-Emission and Photocatalytic Degradation40Dependence of photocatalytic activity on the direction of the intrinsic dipole in GaOI-based Janus structures3Photocatalysts for chemical-free PFOA degradation – What we know and where we go from here?46Towards the design of oxychalcogenide materials as candidates for solar water- splitting photocatalysis0Low Carrier Effective Masses in Photoactive Sr2Sb2O2Q3 (Q = S, Se): The Role of the Lone Pair17In situ preparation of a novel Z-scheme BiOBr/BiVO 4 composite film with enhanced photocatalytic CO 2 reduction performance17The influence of intrinsic electric field regulation on photocatalytic activity in Janus group-III chalcogenide heterostructure3A novel GO hoisted SnO 2 –BiOBr bifunctional catalyst for the remediation of organic dyes under illumination by visible light and electrocatalytic water splitting12Discovery of excellent ultraviolet nonlinear optical materials in chlorates and bromates with highly stereochemically active lone pairs12Layered 2D material heterostructures – a colloidal perspective23Recent Advancements in Bismuth Oxyhalide Photocatalysis for Energy and Environmental Applications2Review on synthetic approaches and PEC activity performance of bismuth binary and mixed-anion compounds for potential applications in marine engineering7Iron Oxychalcogenides and Their Photocurrent Responses16Photocatalytic H2O splitting and CO2 reduction with internal electric field modulation23Insight into the key role of proton-functionalization in metal-free C3N5 activated visible light system for efficient hydrogen evolution reaction16Modulation of the Internal Electric Field in Te-Doped Bi2MoO6 Nanosheets: Implication for the Photocatalytic Degradation of Rhodamine B and Photooxidation of Benzylamine16Effect of polarization electric field in photodegradation over ε-Cd(IO3)2 photocatalyst against antibiotics and dyes1Surface states of photoelectrodes by surface-specific steady-state and time-resolved sum frequency spectroscopies2Excellent performance of BiOI/AgEuW2O8 S-Scheme heterojunction for photocatalytic degradation of contaminants under visible light: Experimental and computational studies21Efficiently enhanced degradation for the organic pollutants over GO/BiOI/NiWO4 with Z-scheme heterojunction and DFT studies18CFs-supported La-BiOIO3/Bi2O3 heterostructures via in situ growth strategies for efficiently removing diclofenac: Fermi level modulation, intermediates identification and radical mechanism16Asymmetric electric field structure boosts photocharge spatial separation and transfer to enhance antibiotics removal: In-situ construction and directed induction4Visible-light-responsive homologous heterostructure of oxynitrides constructed to boost charge separation and water splitting7Phosphorus dopants triggered enhanced bulk polarization and new active sites in hexagonal ZnIn2S4 toward efficient photocatalytic selective oxidation of benzyl alcohol coupled with H2 evolution3Bismuth oxyiodide-oxychloride mixed phase nanocomposites: synthesis, adsorption capacity, and photocatalytic activity under visible light2Nanoscale quantification and structure–dynamics correlation of photoredox reactions on 2D nanoplates via single-molecule localization microscopy1Progress on synthesis, characterization and photocatalytic applications of bismuth oxyhalide based nanomaterials in cleaner environment and energy - A review46Morphology-Dependent Charge-Separated Character in the Photoexcited States of the Photocatalytic Bismuth Oxyiodide Nanocrystals and Nanosheets: Implications for Photodynamic Therapy6Research progress of polarized perovskite type ferroelectric materials for photocatalytic hydrogen production14Unveiling Polaronic Effects on Carrier Transport in BiOBr, BiOI, and BiOBr–BiOI Heterostructures10First-principles investigation of Al2CO/h-XN (X = B, Al, Ga) heterostructures: Stability, electronic structure, and HER activity5Synthesis temperature-driven enhancements in BiOI photocatalysis: A hydrothermal approach3Piezo-photocatalytic applications of BiOBr-based materials for organic pollutants degradation11Ni doping induced lattice distortion engineering in Bi2WO6 for band gap modulation and enhanced photocatalysis10Dynamic Tunable Multifunctional Platform BiOCl: Yb 3+ /Ho 3+ With Multimodal Photo‐Response for Intelligent Anti‐Counterfeiting8Tailoring Crystal Symmetry to Boost the Photocatalytic Degradation of Mixed Dyes and Antibiotics over Centrosymmetric BiOBr and Non-Centrosymmetric BiOBrO 3 Nanosheets1Tunable photocatalytic hydrogen evolution of templated BiOBr/BiOBr-OVs/Pt: Experimental and computational insights4MIL‐125(Ti)‐Based Heterojunctions: Progress in Photocatalytic Applications2The effects of halogen layers and orientations on the X-ray detection performance of BiOX (X = Cl, Br, I) single crystals: a systematic investigation0Systematic comparison of halogen effects on BiOX for supercapacitors0Internal-field-oriented BrO3-/IO3- solid-solution engineering of BiOIO3 for efficient photocatalytic water purification0Precursor-Concentration-Controlled Interface Engineering in Bi2O3/Bi2O2CO3/BiOCOOH Nanostructures for Improved CO2 Photoreduction0

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  2. Facile fabrication of flower-like NH2-UIO-66/BiOCl Z-scheme heterojunctions with largely improved photocatalytic performance for removal of tetracycline under solar irradiation

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  3. Dual modification of BiOIO3 via doping iodine and fabricating heterojunction with basic bismuth salt: Facile synthesis, superior performance for degradation of multiple refractory organics

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  4. Boosting and regulating solar energy conversion performance of delafossite AgFeO 2 by spin polarization

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  5. Ammonia-dependent synthesis of (BiO)2OHCl@Bi24O31Cl10 heterostructures with enhanced visible-light induced photocatalytic activities on levofloxacin removal

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  6. Indirect Substitution Constructing Halogen-Vacancy BiOCl1–xIn Solid Solution with a Suitable Surface Structure for Enhanced Photoredox Performance

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  7. One-pot synthesis of delafossite CuCoO2 microcrystal as visible-light-driven photocatalyst

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  8. Tunable Photocatalytic Water Splitting Performance of Armchair MoSSe Nanotubes Realized by Polarization Engineering

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  9. Photocatalytic and Photocurrent Responses to Visible Light of the Lone-Pair-Based Oxysulfide Sr6Cd2Sb6S10O7

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  19. Visible light and iodate/iodide mediated degradation of bisphenol A by self-assembly 3D hierarchical BiOIO3/Bi5O7I Z-scheme heterojunction: Intermediates identification, radical mechanism and DFT calculation

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  20. A BiOIO3/BiOBr n-n heterojunction was constructed to enhance the photocatalytic degradation of TC

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  21. BiOCl1−xBrx solid solution – Novel synthesis, highly-efficient visible-light-driven photocatalyst, and DFT study

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  22. Fabrication of BrO3- bridged Cr2Bi3O11 for enhanced photocatalytic degradation of phenol under visible light

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