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RESEARCH PAPER · Frontiers of Physics · 2021

Negative thermal expansion: Mechanisms and materials

Erjun Liang, Qiang Sun, Huanli Yuan, Jiaqi Wang, Gaojie Zeng, Qilong Gao

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Negative thermal expansion: Mechanisms and materialsOriginalA linear scaling law for predicting phase transition temperature via averaged effective electronegativity derived from A 2 M 3 O 12 -based compounds29Theoretical Study of Abnormal Thermal Expansion of CuSCN and Effect on Electronic Structure6Why does volume sometimes decrease with the increase of temperature0Negative Thermal Expansion of Carbon Nanotube Bundles22The role of average atomic volume in predicting negative thermal expansion: The case of REFe(CN)630Near-zero thermal expansion in β-CuZnV2O7 in a large temperature range8Anomalous Thermal Expansion in Ta2WO8 Oxide Semiconductor over a Wide Temperature Range13Zero thermal expansion in metal–organic framework with imidazole dicarboxylate ligands6Bi 0.33 Zr 2 (PO 4 ) 3 , a negative thermal expansion material with a Nasicon-type structure6Thermomechanical properties of carbon nanotube forest1Unexpected low thermal expansion coefficients of pentadiamond5Zirconium Tungstate Reinforced Energetic Composites with Inhibited Thermal Expansion and Reduced Thermal Stress25Zentropy Theory for Positive and Negative Thermal Expansion60Negative thermal expansion of two-dimensional magnets10Optimized negative thermal expansion property in low-cost Mg2P2O7-based bulk material26Understanding the role of guest ions in the control of thermal expansion of FeFe(CN)67Isotropic negative thermal expansion and its mechanism in tetracyanidoborate salt CuB(CN)44Thermal enhancing photoluminescence intensities of Eu3+ doped Lu2(MoO4)311Expanding negative thermal expansion range of ZrMnMo3O12 to cover room temperature by introducing V5+1Thermally boosted upconversion and downshifting luminescence in Sc2(MoO4)3:Yb/Er with two-dimensional negative thermal expansion303II-VI based organic-inorganic hybrid structures: Brief review and perspective9Understanding Large Negative Thermal Expansion of NdFe(CN)6 through the Electronic Structure and Lattice Dynamics10Large negative thermal expansion in GdFe(CN)6 driven by unusual low-frequency modes18Two-Dimensional Negative Thermal Expansion in a Facile and Low-Cost Oxalate-Based Metal–Organic Framework5Phase transition, thermal expansion and hygroscopicity of Fe2-2(HfMg) W3O127Flower-like Sc2Mo3O12 nanosheet clusters: Synthesis, thermal expansion and photocatalytic properties6Anomalous behavior of a two-dimensional Hertzian disk system8Synthesis of high-entropy La2B2O7 ceramics with non-equivalent principal elements in B-sites and their CMAS resistance performance16Hydrogen Bond-Driven Order–Disorder Phase Transition in the Near-Room-Temperature Nonlinear Optical Switch [Ag(NH3)2]2SO424Effect of twin grain boundary on material thermal expansion6Insight into the Relationship between Negative Thermal Expansion and Structure Flexibility: The Case of Zn(CN)2-Type Compounds7Preparation, uniaxial negative thermal expansion and Raman study in semiconductor oxide Nb2WO8 ceramic5Extrinsic Point Defects in Low-Positive Thermal Expansion Al2W3O12 and Their Effects on Thermal and Optical Properties16Diverse Thermal Expansion Behaviors in Ferromagnetic Cr1−δTe with NiAs-Type, Defective Structures18Synergistically program thermal expansional and mechanical performances in 3D metamaterials: Design-Architecture-Performance71Tailoring Negative Thermal Expansion via Tunable Induced Strain in La–Fe–Si-Based Multifunctional Material18Phonon anharmonicity and thermal conductivity of two-dimensional van der Waals materials: A review20Tuning Negative Thermal Expansion in AlPO4-17 by Insertion of Guest Molecules15Mean-field theory of the spin-1/2 transverse field Ising model with a negative thermal expansion1Phononic transport in 1T′-MoTe2: Anisotropic structure with an isotropic lattice thermal conductivity8The periodicity of negative thermal expansion in rare earth trifluorides2Thermo-mechanical performance of two-dimensional porous metamaterial plates20Impact of Negative Thermal Expansion on Thermal Quenching of Luminescence of Sc2Mo3O12:Eu3+73Poly(vinyl pyrrolidone)-assisted hydrothermal synthesis of erythrocyte-like Sc2W3O12 with negative thermal expansion5Nanostructured Silver Films with a Low Coefficient of Thermal Expansion as a Promising Material for Nanoelectronics3The enhanced negative thermal expansion in less-oxygen-vacancies copper pyrophosphate30Spatial Modulation and Thermal-Induced Spin Phase Transition on the Negative Thermal Expansion of ScF3 with Metal Dopants4Origin of Near-Zero Thermal Expansion in A2O(PO4)2 Oxides over an Ultrawide Temperature Range2Colossal negative thermal expansion in a cucurbit[8]uril-enabled uranyl-organic polythreading framework via thermally induced relaxation11Fluorescent Probe Effect of Super-Sensitive Transition Dy3+ Ions in Negative Thermal Expansion Materials Sc2w3o121Phonon mechanism for the negative thermal expansion of zirconium tungstate, ZrW 2 O 815Tuning of thermal expansion properties of a mixed-ligand MOF by ligand variation7Weakening Negative Thermal Expansion in Cu 2 P 2 O 7 Through Oxygen Vacancies0High Entropy Rare-Earth Molybdate Ceramics with Broad Operating-Temperature Window and Anti-Hygroscopicity Ability: A Promising Strategy for Negative Thermal Expansion Materials13Structural Origin of Anisotropic Thermal Expansion of Molecular Crystals and Implication for the Density Rule Probed with Four ROY Polymorphs2Negative Thermal Expansion of Sulphur-Doped Graphene Oxide4Spin-orbital mechanisms for negative thermal expansion in Ca 2 RuO 45Noncoplanar antiferromagnetism induced zero thermal expansion behavior in the antiperovskite Mn3Sn0.5Zn0.5Cx11The rigid unit mode model: review of ideas and applications23Origin of negative thermal expansion in strongly correlated f− electron systems2Full optimization of quasiharmonic free energy with an anharmonic lattice model: Application to thermal expansion and pyroelectricity of wurtzite GaN and ZnO34Comments on the paper “The phenomenon of ‘‘partial isobaric compression” of urea as a solute in tertiary butanol: Comparison with a similar effect in the (methanol + urea) system” by E.V. Ivanov, E.Yu. Lebedeva [J. Mol. Liq. 370 (2023) 121039-10]5Control of Thermal Expansion in TaVO5 by Double Chemical Substitution4Uniaxial Negative Thermal Expansion in a Tetragonal V3S-Type Superconductor IrZr35Giant Negative Thermal Expansion Materials: Progress of Research and Future Prospects2Zero thermal expansion, high specific thermal conductivity, and good machinability of Cu2P2O7/2024Al composite17Zero thermal expansion in Cs2W3O107Temperature-induced luminescence enhancement and quenching behavior of Eu3+ in Lu2(WO4)3 phosphors16Influence of A/B Element Substitution on Negative Thermal Expansion in AB(CN) 6 (A = Al, Ga, In; B = Co, Fe, Mn, Cr, V, Ti): A Density Functional Theory Study5Research progress in thermal expansion characteristics of TATB based polymer bonded explosives9Negative thermal expansion in Co2-xMnxP2O715Construction of zirconium tungstate modified polymer bonded energetic composites with highly inhibited thermal expansion via bioinspired interfacial reinforcement10Modeling Wear and Friction Regimes on Ceramic Materials with Positive and Negative Thermal Expansion13Role of alkali ions in the near-zero thermal expansion of NaSICON-type AZr2(PO4)3 (A=Na,K,Rb,Cs) and Zr2(PO4)3 compounds32A Comparative Thermodynamic Study of AlF3, ScF3, Al0.5Sc0.5F3, and In0.5Sc0.5F3 for Optical Coatings: A Computational Study2Multi-phase metamaterials containing framework structures to program thermal expansion and mechanical performances25Reply to comments by G.I. Egorov [J. Mol. Liq. 383 (2023) 122128] concerning the terminology to the phenomenon of “partial isobaric compression” being occurred in a number of binary liquid systems [J. Mol. Liq. 370 (2023) 121039]5Single thiolate replacement of metal nanoclusters10Structure, luminescence properties and anti-thermal quenching of a novel Eu3+-activated red phosphor based on the negative thermal expansion material In0.5Sc1.5(MoO4)333Preparation of fluorinated poly(aryl ether) with high dimensional stability and high temperature resistance by photo‐thermal dual crosslinking reaction4The formation energy, phase transition, and negative thermal expansion of Fe 2− x Sc x W 3 O 126Lanthanide Contraction in LnF3 (Ln = Ce-Lu) and Its Chemical and Structural Consequences: Part 2: Specialized Empirical System of R3+ (R = Y, La, and 14 Ln) and F1− Ionic Radii for RF3 Series8Mechanism of Negative Thermal Expansion in Monoclinic Cu2P2O7 from First Principles14Improved Sofc Performance by Enhancing Cathode/Electrolyte Bonding and Grain Refinement of Composite Cathode0Vat photopolymerization 3D printing applications in metamaterials2The Negative Thermal Expansion Property of NdMnO3 Based on Pores Effect and Phase Transition6Simple chemical synthesis and isotropic negative thermal expansion in MHfF6 (M = Ca, Mn, Fe, and Co)32Li+-induced triple optimization strategy for enhancing upconversion luminescence, anti-thermal quenching and optical thermometry performance in Yb2W3O12: Er3+ phosphors18Near-zero thermal expansion of GeNb18O47 ceramic5Controlling mass and energy diffusion with metamaterials153Giant Negative Thermal Expansion Materials: Progress of Research and Future Prospects30Continuous strain tuning of oxygen evolution catalysts with anisotropic thermal expansion93Fluorescent probe effect of super-sensitive transition Dy3+ ions in the negative thermal expansion materials Sc2W3O124Raman scattering evolution in temperature-induced ferroelectric phase transition of few-layer NbOCl222Heat/light/size-tuned dual fluorescence, colossal anisotropic thermal expansion and applications in temperature-range-tunable thermometry/anticounterfeiting3Ultralow-Permittivity and Temperature-Stable Ba1–xCaxMg2Al6Si9O30 Dielectric Ceramics for C-Band Patch Antenna Applications4Particle size effect on surface/interfacial tension and Tolman length of nanomaterials: A simple experimental method combining with theoretical4High-pressure and temperature dependent Raman studies on negative thermal expansion material Zn2P2O77The Synergy Reinforcement Effect of Sm0.85Zn0.15MnO3 and ZrMgMo3O12 on Sm0.85Zn0.15MnO3-ZrMgMo3O12/Al-20Si Composites1Intelligent microsphere-gel structures: Pioneering multi-range temperature sensing technology9Isotropic negative thermal expansion in the multiple-phase La-Fe-Co-Si alloys with enhanced strength and ductility17Zero thermal expansion in NiPt(CN)62High performance thermal expansion offset LSCF-SZM cathodes of IT-SOFCs22Designing (Hf,Ta)Fe 2 ‐based zero thermal expansion composites consisting of multiple Laves phases9Synthesis, structure, and thermal expansion in CaZrF6 with two polymorphs10Mobility of dislocations in carbon nanotube bundles3Facile Coordination Transitions in AgCrX2 (X = S, Se): Unprecedented Electrostrain, Negative Piezoelectricity and Thermal Expansion10Multidoped CeO2 single-phase as electrolyte for IT-SOFC12Octahedral tilt distortion in negative thermal expansion in the fluorides CaZr F 6 and Sc F 326Improved SOFC performance by enhancing cathode/electrolyte bonding and grain refinement of cathode with thermal expansion offset18The approaches to conducting in-situ heterostructure electrodes for SOCs: A mini review14Structure and tribological behavior of a polyetherimide/polytetrafluoroethylene matrix filled with negative thermal expansion zirconium tungstate particles6Negative Thermal Expansion Realized by an Incomplete Bimaterial Ring5Negative and near-zero thermal expansion driven by cooperative Jahn–Teller effect in Fe2P2O710Tailoring thermal expansion of β-Cu2V2O7 with improved mechanical properties by incorporation of Li+Fe3+2Giant Inverse Barocaloric Effect of Ferroelectric Salts Driven by Negative Thermal Expansion1Negative Thermal Expansion Behavior Enabling Good Electrochemical‐Energy‐Storage Performance at Low Temperatures3Negative Thermal Expansion Behavior Enabling Good Electrochemical‐Energy‐Storage Performance at Low Temperatures11Novel Y2(SO4)3:Eu3+ Phosphors with Anti-Thermal Quenching of Luminescence Due to Giant Negative Thermal Expansion13Fundamentals on dependence of volume on pressure and temperature5Fabrication of MnCoGe-Based Composites with Giant Negative Thermal Expansion via Magnetic-Field-Assisted Dynamic Self-Assembly0Predicting thermal expansion in framework compounds using a charge interaction index11Recent developments and perspective of zero thermal expansion magnetic materials0Temperature-Dependent X-Ray Absorption Study of the Anisotropic Negative Thermal Expansion of Co and Fe-Based Trzr3 Compounds0Temperature-Dependent X-Ray Absorption Study of the Anisotropic Negative Thermal Expansion of Co and Fe-Based Trzr3 Compounds0Tuning luminescence thermal quenching performance of K x Mg x Sc 1.95− x Mo 3 O 12 :5%Eu 3+ phosphor via synergistic negative thermal expansion and charge compensation effects12Improving the thermoelectric properties of septuple atomic-layer SnBi2Se4 by regulating the carrier concentration through Nb doping9Thermally Enhanced Upconversion Luminescence by Negative Expansion in Er3+/Yb3+ Co-doped ZrScW2PO12 Phosphors3Improved Performance of Solid Oxide Fuel Cells with the BaCo0.4Fe0.4Zr0.1Y0.1O3−δ Cathode by a Modified Acid Etch of Sm0.2Ce0.8O2−δ Electrolyte5Review on research progress of crystalline materials with abnormal thermal properties0Multi-material isogeometric topology optimization for thermoelastic metamaterials11Multiferroicity and thermal expansion of the layered metal–organic framework [NH 4 Cl] 2 [Ni(HCOO) 2 (NH 3 ) 2 ]3Temperature-stable dielectric constant and low thermal expansion in linear low-density polyethylene/copper vanadate composites2Impact of lattice distortions and overdamped vibrations on the structural properties and thermal transport of strongly anharmonic AgSnSbTe 3 crystals17An extended Euler-Bernoulli beam principle in multi-component metamaterial towards tunable Poisson’s ratio5Structural Distortions and Uniaxial Negative Thermal Expansion in the Polar Dion–Jacobson Oxide RbNdTa 2 O 70A review of cellular metamaterials with thermal expansion coefficient that is negative, zero, or large positive3Enhanced structure flexibility in oxygen-deficient open framework Al2W3O12: Evidence from heat capacity and high-pressure Raman spectroscopy1Distinct Jahn-Teller–induced negative thermal expansion behaviors in C r 2 P 2 O 77Temperature-dependent X-ray absorption study of the anisotropic negative thermal expansion of Co and Fe-based TrZr 3 compounds0Exploring Zero Thermal Expansion in Magnetocaloric Materials5Unraveling low thermal expansion of CrBO3 via atomic scale analysis: Flexible CrO6 octahedron vs rigid BO3 triangle group2Quantitative Role of Phonons and Elasticity in Tuning Uniaxial Negative Thermal Expansion of M Zr 2 ( M = Fe , Co , and Ni )12Low Thermal Expansion in Niobate Borate NbBO4 Enabled by Compensated Grüneisen Parameters of NbO8 Polyhedra1Enhancing the Anti‐Thermal Quenching Photoluminescence of Yb 3+ in Double Perovskites via Thermally‐Accelerated Energy Transfer14Thermal Expansion Matching as a Key Criterion for Developing High‐Performance Mn‐based Mullite Cathodes in SOFCs10Near-Zero Thermal Expansion and High Strength in Multi-Phase La0.6Ce0.4(Fe0.91Co0.09)11.9Si1.1/Ag Compounds Produced Through Spark Plasma Sintering0Anharmonic Phonon Dynamics and the Origin of Ultralow Lattice Thermal Conductivity in CuBiI 4 : Implications for Thermoelectric Applications2Negative thermal expansion of two-dimensional materials: A review9Low-frequency phonon driven enhancement of negative thermal expansion in Zn2−xMnxGeO47

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  46. The enhanced negative thermal expansion in less-oxygen-vacancies copper pyrophosphate

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