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RESEARCH PAPER · Chemical Society Reviews · 2021

Defect engineering in thermoelectric materials: what have we learned?

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Defect engineering in thermoelectric materials: what have we learned?OriginalEnhanced thermoelectric performance of InTe through Pb doping26Hierarchically Interlaced 2D Copper Iodide/MXene Composite for High Thermoelectric Performance25Ab Initio Modeling of Magnetic Materials in the High-Temperature Paramagnetic Phase0Zn-Induced Defect Complexity for the High Thermoelectric Performance of n-Type PbTe Compounds36Growth defects of organic crystals: A review60Insight into the effects of dislocations in nanoscale titanium niobium oxide (Ti2Nb14O39) anode for boosting lithium-ion storage30High Power Factor and Thermoelectric Figure of Merit in Sb2Si2Te6 through Synergetic Effect of Ca Doping28Effect of Nanostructuring on the Thermoelectric Properties of β-FeSi225Thermoelectric converter: Strategies from materials to device application280A Systematic Approach for Semiconductor Half-Heusler47Synergistically Enhanced Thermoelectric Performance of Cu2SnSe3-Based Composites via Ag Doping Balance17Physical Intuition to Improve Electronic Properties of Thermoelectrics5Ionic thermoelectrics: principles, materials and applications106Achieving High‐Performance Ge0.92Bi0.08Te Thermoelectrics via LaB6‐Alloying‐Induced Band Engineering and Multi‐Scale Structure Manipulation11Improved zT in Nb 5 Ge 3 –GeTe thermoelectric nanocomposite25Valence band convergence and nanostructured phonon scattering trigger high thermoelectric performance in SnTe11Strain Engineering in Electrocatalysts: Fundamentals, Progress, and Perspectives276Preparation and characterization of nonstoichiometric Te-deficient and Te-rich thermoelectric Bi2-Gd Te3± compounds5A mechanistic view of defect engineered VFeSb half-Heusler alloys10All-scale hierarchical nanostructures and superior valence band convergence lead to ultra-high thermoelectric performance in cubic GeTe86Breaking the sodium solubility limit for extraordinary thermoelectric performance in p-type PbTe78EFFECT OF FEATURES IN GRAIN STRUCTURE ON THE THERMOELECTRIC PROPERTIES OF COMPOUNDS BASED ON BISMUTH TELLURIDE0First-principles study on bilayer SnP 3 as a promising thermoelectric material3Integrating recyclable polymers into thermoelectric devices for green electronics61Recent advances in designing thermoelectric materials169Synergistic effect of Zn doping on thermoelectric properties to realize a high figure-of-merit and conversion efficiency in Bi 2− x Zn x Te 3 based thermoelectric generators30The Roles of Grain Boundaries in Thermoelectric Transports58Thermoelectric properties of high-performance n-type lead telluride measured in s itu in a nuclear reactor core2Thermoelectricity: Phenomenon and applications0Understanding the influence of Bi/Sb substitution on carrier concentration in Mg 3 Sb 2 -based materials: decreasing bandgap enhances the degree of impurity ionization5Thermoelectric Coolers: Progress, Challenges, and Opportunities219High thermoelectric and mechanical performance in the n-type polycrystalline SnSe incorporated with multi-walled carbon nanotubes58Thermoelectric Performance of the 2D Bi 2 Si 2 Te 6 Semiconductor70Achieving Enhanced Thermoelectric Performance in Multiphase Materials42Additive Manufacturing of Thermoelectrics: Emerging Trends and Outlook83Enhanced Thermoelectric Properties of Cu2SnSe3-Based Materials with Ag2Se Addition22Cold-Sintered Bi2Te3-Based Materials for Engineering Nanograined Thermoelectrics48Flexible elemental thermoelectrics with ultra-high power density51Potential of Recycled Silicon and Silicon-Based Thermoelectrics for Power Generation16Application of Materials Genome Methods in Thermoelectrics15Upcycling Silicon Photovoltaic Waste into Thermoelectrics71Recent Progress of Two-Dimensional Transition Metal Dichalcogenides for Thermoelectric Applications53Effect of intrinsic defects on the electronic structure and thermoelectricity of two-dimensional boron arsenide16Compromise of thermoelectric and mechanical properties in LiSbTe2 and LiBiTe2 alloyed SnTe42A Solvothermal Synthetic Environmental Design for High‐Performance SnSe‐Based Thermoelectric Materials158Compression Induced Deformation Twinning Evolution in Liquid-Like Cu2Se8Influence of Grain Structure Features on the Thermoelectric Properties of Compounds Based on Bismuth Telluride1Graphite Nanosheets as Multifunctional Nanoinclusions to Boost the Thermoelectric Performance of the Shear‐Exfoliated Bi2O2Se58Polycrystalline NiSe-Alloyed SnSe with Improved Medium-Temperature Thermoelectric Performance9Interfacial‐Modulated Growth of Nanostructured Bi2Te3 Films for Enhancing Thermoelectric Performance2Synergistic Effect of Band and Nanostructure Engineering on the Boosted Thermoelectric Performance of n‐Type Mg 3+ δ (Sb, Bi) 2 Zintls115Thermoelectric properties of monolayer and bilayer buckled X Te ( X = Ge, Sn, and Pb)6Insights into Low Thermal Conductivity in Inorganic Materials for Thermoelectrics202Quantum confinement effect on defect level of hydrogen doped rutile VO2 nanowires7Cross-scale porous structure design leads to optimized thermoelectric performance and high output power for CaMnO3 ceramics and their uni-leg modules23Enhanced near‐room‐temperature thermoelectric performance in GeTe41Thermoelectric properties of a high entropy half-Heusler alloy processed by a fast powder metallurgy route31Developing a two-parabolic band model for thermoelectric transport modelling using Mg 2 Sn as an example14Ni doping and rational annealing boost thermoelectric performance of nanostructured double perovskite Pr1.8Sr0.2CoFeO617Dose-Efficient Defect Contrast with 4D-STEM1Advances in the design and assembly of flexible thermoelectric device387Microstructure design via novel thermodynamic route to enhance the thermoelectric performance of GeTe16Enhancing the thermoelectric performance of solution-synthesized SnSe-based materials via incorporating Ti3C2T MXene10High thermoelectric performance in GeTe with compositional insensitivity38Thermoelectric properties of γ-graphyne and its derivatives: First-principles calculations1Unraveling the Role of Defects in Electrocatalysts for Water Splitting: Recent Advances and Perspectives51Solution-Processed Inorganic Thermoelectric Materials: Opportunities and Challenges39Effects of Bi Alloying on the Thermoelectric Properties of p‐Type Mg3Sb2‐xBix Solid Solutions5Self-Powered Thermoelectric Hydrogen Sensors Based on Low-Cost Bismuth Sulfide Thin Films: Quick Response at Room Temperature27Role of Pb Doping on the Thermoelectric Properties of Mg3Sb1.8‐yBi0.2Pby Alloys1Atomic Level Defect Structure Engineering for Unusually High Average Thermoelectric Figure of Merit in n‐Type PbSe Rivalling PbTe82Thermoelectric performance enhancement in p-type Si via dilute Ge alloying and B doping4Enhanced thermoelectric performance of N-type Bi2Te2.7Se0.3-based materials by superparamagnetic Fe3O4 nanoparticles13Electronic structures of defects in bottom-up N-doped graphene nanoribbons: Experiment and theory5Identifying the effect of Ni solubility on the thermoelectric properties of HfNiSn-based half-Heuslers20Emerging homogeneous superlattices in CaTiO 3 bulk thermoelectric materials15Broad Temperature Plateau for High Thermoelectric Properties of n-Type Bi 2 Te 2.7 Se 0.3 by 3D Printing-Driven Defect Engineering38Advancement of modification engineering in lean methane combustion catalysts based on defect chemistry71Defect engineering in carbon materials for electrochemical energy storage and catalytic conversion205Enhanced thermoelectric performance in Bi 0.5 Sb 1.5 Te 3 /SiC composites prepared by low-temperature liquid phase sintering28Exploring electrical property improvement for thermoelectric sulfides2Extrinsic doping of Hg 2 GeTe 4 in the face of defect compensation and phase competition2Molecular precursor approach to develop catalytically relevant nanosized metals, palladium chalcogenides and ternary/quaternary metal chalcogenides4Probing an enhanced anisotropy Seebeck coefficient and low thermal conductivity in polycrystalline Al doped SnSe nanostructure10Realizing an excellent conversion efficiency of 14.5% in the Mg 3 Sb 2 /GeTe-based thermoelectric module for waste heat recovery75Recent progress in phosphide materials for thermoelectric conversion25Recent progress of 2-dimensional layered thermoelectric materials7The manipulation of natural mineral chalcopyrite CuFeS 2 via mechanochemistry: properties and thermoelectric potential6Thermoelectric properties of the aliovalent half-Heusler alloy Zn 0.5 Ti 0.5 NiSb with intrinsic low thermal conductivity6Thermoelectric Properties of the Snx$_{2}$ (X = Se, Te) and Janus Snsete 1t-Monolayers: A Dft-D3 Study1Tuning the lattice thermal conductivity of Sb 2 Te 3 by Cr doping: a deep potential molecular dynamics study14Hierarchical Architectural Structures Induce High Performance in n‐Type GeTe‐Based Thermoelectrics73Fine Tuning of Defects Enables High Carrier Mobility and Enhanced Thermoelectric Performance of n-Type PbTe106Discordant Distortion in Cubic GeMnTe 2 and High Thermoelectric Properties of GeMnTe 2 - x %SbTe54Advances in Ionic Thermoelectrics: From Materials to Devices237ElecTra code: Full-band electronic transport properties of materials44Silver Atom Off-Centering in Diamondoid Solid Solutions Causes Crystallographic Distortion and Suppresses Lattice Thermal Conductivity68Tightened 1D/3D carbon heterostructure infiltrating phase change materials for solar–thermoelectric energy harvesting: Faster and better66AgSbSe2 inclusions enabling high thermoelectric and mechanical performance in n-type Ag2Se-based composites51Computationally efficient Monte Carlo electron transport algorithm for nanostructured thermoelectric material configurations9Texture Engineering to Boost the Thermoelectric Properties6A Critical Review of Machine Learning Techniques on Thermoelectric Materials65Defect Reconfiguration in Hole-Doped PbSe via Minute Te Doping for Significantly Enhanced Thermoelectric Performance9Dispositivos de almacenamiento y generación de energía eléctrica basados en materiales cerámicos avanzados0Realize high thermoelectric properties in n-type Bi2Te2.7Se0.3 materials via ZrO2 ceramic nanoparticles mediated heterogeneous interface24Lead Vacancy Promotes Sodium Solubility to Achieve Ultra‐High zT in Only Ternary Pb1‐xNaxTe24Electronic Transport Properties of Bi2Te2.7Se0.3 Fabricated by Hot Extrusion0Roadmap on energy harvesting materials118Enhanced thermoelectric properties of n-type CoSb3-based composites by incorporating In particles14Defect Contrast with 4D-STEM: Understanding Crystalline Order with Virtual Detectors and Beam Modification3Enhancing Thermoelectric and Mechanical Properties of p-Type (Bi, Sb)2Te3 through Rickardite Mineral (Cu2.9Te2) Incorporation16Mechanistic Insights into the Formation of Thermoelectric TiNiSn from In Situ Neutron Powder Diffraction13Investigation of the annealing treatment on the performance of TiO2 photoanode25Synergetic Enhancement of Strength–Ductility and Thermoelectric Properties of Ag2Te by Domain Boundaries35Thermoelectric properties and Kondo transition in the pseudo‐gap metals TiNiSi and TiNiGe0Ultrafast and Cost-Effective Fabrication of High-Performance Carbon-Based Flexible Thermoelectric Hybrid Films and Their Devices21Employing multi-functional SnSe inclusions to boost the thermoelectric performance of the shear-exfoliated Bi2Te2.7Se0.324Challenges and opportunities in low-dimensional thermoelectric nanomaterials109Flexible, Self‐powered Thermoelectric Module for Body‐heat Recovery3Re‐Doped p ‐Type Thermoelectric SnSe Polycrystals with Enhanced Power Factor and High ZT > 244Modeling and property study of thermoelectric converter based on subwavelength photothermal absorption structure2Competition between intrinsic and extrinsic phonon scatterings in cubic BP and BAs with point defects14Thermoelectric Properties Investigation of Ni/Co Doped ZrCoBi Half-Heusler Alloy1Defect Engineering in Biomedical Sciences74Semiclassical electron and phonon transport from first principles: application to layered thermoelectrics5Direct Observation of the Conventional Epitaxial and Novel Heteroaxial ZB-WZ Stacking Faults2Enhanced thermoelectric properties of Cu3SbSe4-based materials by synergistic modulation of carrier concentration and phonon scattering19Enhanced thermoelectric performance of SnSe by controlled vacancy population13Breaking Rayleigh’s Law with Spatially Correlated Disorder to Control Phonon Transport18Enhanced thermoelectric transport properties of Bi2Te3 polycrystalline alloys via carrier type change arising from slight Pb doping19In situ photocatalytically enhanced thermogalvanic cells for electricity and hydrogen production210Non-Equilibrium Thermodynamics of Heat Transport in Superlattices, Graded Systems, and Thermal Metamaterials with Defects9Enhanced thermoelectric properties of n-type Bi2Te2.7Se0.3 materials by TiO2 ceramic nanoparticle dispersion-induced energy filtering effect21Reinforcing bond covalency for high thermoelectric performance in Cu3SbSe4-based thermoelectric material19Hybrid Data‐Driven Discovery of High‐Performance Silver Selenide‐Based Thermoelectric Composites32Advances in Ag2S-based thermoelectrics for wearable electronics: progress and perspective40Composites of metal-organic frameworks (MOFs) and LDHs for energy storage and environmental applications: Fundamentals, progress, and perspectives35Chemical Bonding Tuned Lattice Anharmonicity Leads to a High Thermoelectric Performance in Cubic AgSnSbTe322Chemical Bonding Tuned Lattice Anharmonicity Leads to a High Thermoelectric Performance in Cubic AgSnSbTe311Challenges of thermal stability of high-energy layered oxide cathode materials for lithium-ion batteries: A review124Self-triggered thermoelectric nanoheterojunction for cancer catalytic and immunotherapy94Densification Induced Decoupling of Electrical and Thermal Properties in Free‐Standing MWCNT Films for Ultrahigh p‐ and n‐Type Power Factors and Enhanced ZT18High‐Performance Thermoelectric Devices Made Faster: Interface Design from First Principles Calculations15Progress and perspectives in thermoelectric generators for waste-heat recovery and space applications21Microstructural evolution and failure mechanism dominated by Bi, Sb cooperative diffusion at p-type thermoelectric pillar Bi-Sb-Te/Sn interface8Achieving n-type Conduction in AMg2Sb2 (A = Yb, Eu, Ca, Sr, Ba) Zintl Phases15Alloying and Doping Control in the Layered Metal Phosphide Thermoelectric CaCuP9Advances in Ag2S-based thermoelectrics for wearable electronics: Progress and perspective41Artificial Intelligence for Learning Material Synthesis Processes of Thermoelectric Materials21Phase Equilibria Study in Ga-Sn-Te System Using Thermodynamic Modeling and Experimental Validation2

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  49. Polycrystalline NiSe-Alloyed SnSe with Improved Medium-Temperature Thermoelectric Performance

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  50. Interfacial‐Modulated Growth of Nanostructured Bi2Te3 Films for Enhancing Thermoelectric Performance

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