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RESEARCH PAPER · Journal of Materials Chemistry A · 2021

Bonding heterogeneity in mixed-anion compounds realizes ultralow lattice thermal conductivity

Naoki Sato, Norihide Kuroda, Shun Nakamura, Yukari Katsura, Ikuzo Kanazawa, Kaoru Kimura, Takao Mori

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Bonding heterogeneity in mixed-anion compounds realizes ultralow lattice thermal conductivityOriginalThe Effect of Reactive Electric Field-Assisted Sintering of MoS2/Bi2Te3 Heterostructure on the Phase Integrity of Bi2Te3 Matrix and the Thermoelectric Properties13Promoted thermoelectric performance of (Ag, Na) co-doped polycrystalline BiSe by optimizing the thermal and electrical transports simultaneously15Predicting the lattice thermal conductivity of alloyed compounds from the perspective of configurational entropy20Expanding multiple anion superlattice chemistry: Synthesis, structure and properties of Bi4O4SeBr2 and Bi6O6Se2Cl212Talnakhite: A potential n-type thermoelectric sulphide with low thermal conductivity3Ultralow Lattice Thermal Conductivity and Improved Thermoelectric Performance in Cl-Doped Bi 2 Te 3– x Se x Alloys70Keynote Review of Latest Advances in Thermoelectric Generation Materials, Devices, and Technologies 2022169Physical insights into the ultralow lattice thermal conductivity and high thermoelectric performance of bulk LiMTe 2 (M = Al, Ga)18Ultralow thermal conductivity in the mixed-anion solid solution Sn 2 SbS 2− x Se x I 319Lone Pair Rotation and Bond Heterogeneity Leading to Ultralow Thermal Conductivity in Aikinite51Extremely Low Lattice Thermal Conductivity Leading to Superior Thermoelectric Performance in Cu4TiSe417Effect of Atomic Mass Contrast on Lattice Thermal Conductivity: A Case Study for Alkali Halides and Alkaline-Earth Chalcogenides16Strategies for Development of High Performance Thermoelectric Materials0Origin of low lattice thermal conductivity in promising ternary Pb Bi2S3+ (m = 1–10) thermoelectric materials19Synthesis, Structure, and Properties of CuBiSeCl 2 : A Chalcohalide Material with Low Thermal Conductivity20Chemical Pressure-Driven Band Convergence and Discordant Atoms Intensify Phonon Scattering Leading to High Thermoelectric Performance in SnTe57Lone Pair Induced 1D Character and Weak Cation–Anion Interactions: Two Ingredients for Low Thermal Conductivity in Mixed-Anion Metal Chalcohalide CuBiSCl236Influence of Subvalent Twin-Rattler for High n -Type Thermoelectric Performance in Bi 13 S 18 Br 2 Chalcohalide26Machine learning-assisted screening of intrinsic rattling compounds with large atomic displacement0Report on the Tenth U.S.-Japan Joint Seminar on Nanoscale Transport Phenomena0Excellent thermoelectric performance of Bi 2 MO 4 Cl (M = Y, La, and Bi) derived from ultra-low lattice thermal conductivity10Structurally disordered In 2 Te 3 semiconductor: novel insights7Wide-ranging predictions of new stable compounds powered by recommendation engines12Bonding Heterogeneity and Nanoprecipitation on Substituting the Anionic Framework in Mg3Sb2 for p‐Type Zintl Thermoelectrics5Realizing Intrinsically Ultralow and Glass‐Like Thermal Transport via Chemical Bonding Engineering18Exploiting chemical bonding principles to design high-performance thermoelectric materials58Atomic hopping induced dynamic disorder phonon scattering and suppressed thermal transport in Cu4TiSe42Layered Ordered Multianion Semiconductor Bi18O21.6Se1.8Cl7.2 with Low c-Axial Thermal Conductivity0Effect of four-phonon scattering on strain-dependent thermal and thermoelectric transport of ferroelectric α-In2Se3 monolayer7Unravelling the Influence of the Local Structure on the Ultralow Thermal Conductivity of the Bismuthinite–Aikinite Series, Cu1–x□xPb1–xBi1+xS31Mixed-anion thermoelectrics: Advanced tuning of electron and phonon transport10Forced bond ionization–driven design of ultralow lattice thermal conductivity materials for flexible thermoelectrics4Layered mixed-anion chalcohalides Pb 4 Sb 4 Q 9 Cl 2 (Q = S, Se): puckered 2D frameworks, indirect band gaps, and low thermal conductivity0Simultaneous enhancement of power factor and suppression of thermal conductivity in bulk TlFe 1.6 Se 2 via embedded atomically thin FeSe layers0Thermoelectric properties of layered Bi 2 YO 4 Br: a cageless rattler host structure0Strain-Induced Suppression of Coherent Phonon Transport and Thermoelectric Enhancement in CuBiSeCl 2 with Strong Quartic Anharmonicity2Computational Investigation of the Thermoelectric Performance of Environmentally Friendly and Earth-Abundant SrZn 2 S 2 O0Unveiling the impact of bonding asymmetry on the lattice thermal conductivity of MnXS2Cl (X=Sb, Bi) for promising thermoelectric applications1Low lattice thermal conductivity in thermoelectric PbBi 2 Te 4 induced by double lone pair electrons4Cu 7.62 Bi 6 Se 12 Cl 6 I: Discovery of a Low Band Gap, Low Thermal Conductivity Mixed-Anion Material0Nanoscale Local Symmetry Optimization Induced Low Lattice Thermal Conductivity in I‐V‐VI 2 Compounds1Interplay between Cu Delocalization and Bonding Anisotropy on the Thermoelectric Performance of Double-Cation Chalcohalides CuBiSeX 2 (X = Cl, Br)1Ambipolar thermoelectric performance enabled by low lattice thermal conductivity and high-mobility carriers in Ag 3 SX ( X = Cl , Br, I) antiperovskites2A Critical Assessment of Bonding Descriptors for Predicting Materials Properties1Role of heavy cations and bonding heterogeneity on the extremely low thermal conductivities of Ba3Bi6.67Se13 and Pb/Sn-substituted structures0Coupled carrier–phonon–ion transport in binary copper-based superionic conductors: thermoelectric performance, stability, and devices0

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  1. The Effect of Reactive Electric Field-Assisted Sintering of MoS2/Bi2Te3 Heterostructure on the Phase Integrity of Bi2Te3 Matrix and the Thermoelectric Properties

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    Yanan Wang, Cédric Bourgès, Ralph Rajamathi, C. Nethravathi, Michael Rajamathi, Takao Mori

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  2. Promoted thermoelectric performance of (Ag, Na) co-doped polycrystalline BiSe by optimizing the thermal and electrical transports simultaneously

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    Zimin He, Kailiang Lan, Siyuan Chen, Youzhong Dong, Xiaofang Lai, Fusheng Liu, Jikang Jian

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  3. Predicting the lattice thermal conductivity of alloyed compounds from the perspective of configurational entropy

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  4. Expanding multiple anion superlattice chemistry: Synthesis, structure and properties of Bi4O4SeBr2 and Bi6O6Se2Cl2

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    Quinn Gibson, Jon A. Newnham, Matthew Stephen Dyer, Craig M. Robertson, Marco Zanella, Todd Wesley Surta, Matthew J. Rosseinsky, Jonathan Alaria, John B. Claridge, Matthew J. Rosseinsky

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  5. Talnakhite: A potential n-type thermoelectric sulphide with low thermal conductivity

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  6. Ultralow Lattice Thermal Conductivity and Improved Thermoelectric Performance in Cl-Doped Bi 2 Te 3– x Se x Alloys

    ACS Applied Materials & Interfaces · 2022-07-13

    Taras Parashchuk, Rafał Knura, Oleksandr Cherniushok, Krzysztof T. Wojciechowski

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  7. Keynote Review of Latest Advances in Thermoelectric Generation Materials, Devices, and Technologies 2022

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  8. Physical insights into the ultralow lattice thermal conductivity and high thermoelectric performance of bulk LiMTe 2 (M = Al, Ga)

    Journal of Materials Chemistry C · 2023-01-01

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  9. Ultralow thermal conductivity in the mixed-anion solid solution Sn 2 SbS 2− x Se x I 3

    Journal of Materials Chemistry A · 2023-01-01

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  10. Lone Pair Rotation and Bond Heterogeneity Leading to Ultralow Thermal Conductivity in Aikinite

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  11. Extremely Low Lattice Thermal Conductivity Leading to Superior Thermoelectric Performance in Cu4TiSe4

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  12. Effect of Atomic Mass Contrast on Lattice Thermal Conductivity: A Case Study for Alkali Halides and Alkaline-Earth Chalcogenides

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    S. C. Rakesh Roshan, N. Yedukondalu, Tribhuwan Pandey, Lavanya Kunduru, Rajmohan Muthaiah, Rajaboina Rakesh Kumar, Lars Ehm, John B. Parise

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  13. Strategies for Development of High Performance Thermoelectric Materials

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  14. Origin of low lattice thermal conductivity in promising ternary Pb Bi2S3+ (m = 1–10) thermoelectric materials

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  15. Synthesis, Structure, and Properties of CuBiSeCl 2 : A Chalcohalide Material with Low Thermal Conductivity

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  16. Chemical Pressure-Driven Band Convergence and Discordant Atoms Intensify Phonon Scattering Leading to High Thermoelectric Performance in SnTe

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  17. Lone Pair Induced 1D Character and Weak Cation–Anion Interactions: Two Ingredients for Low Thermal Conductivity in Mixed-Anion Metal Chalcohalide CuBiSCl2

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  18. Influence of Subvalent Twin-Rattler for High n -Type Thermoelectric Performance in Bi 13 S 18 Br 2 Chalcohalide

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  20. Report on the Tenth U.S.-Japan Joint Seminar on Nanoscale Transport Phenomena

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  21. Excellent thermoelectric performance of Bi 2 MO 4 Cl (M = Y, La, and Bi) derived from ultra-low lattice thermal conductivity

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  29. Effect of four-phonon scattering on strain-dependent thermal and thermoelectric transport of ferroelectric α-In2Se3 monolayer

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