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RESEARCH PAPER · ACS Energy Letters · 2021

High-Efficiency (>14%) and Air-Stable Carbon-Based, All-Inorganic CsPbI2Br Perovskite Solar Cells through a Top-Seeded Growth Strategy

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High-Efficiency (>14%) and Air-Stable Carbon-Based, All-Inorganic CsPbI2Br Perovskite Solar Cells through a Top-Seeded Growth StrategyOriginalAmidation induced self-reduction of p-GO with Lewis-base termination for all-inorganic CsPbIBr 2 perovskite solar cells12Biomass-derived carbon electrodes for supercapacitors and hybrid solar cells: towards sustainable photo-supercapacitors51In situ polymer-covered annealing strategy for high-efficiency carbon-electrode CsPbIBr 2 solar cells4PbS/CdS heterojunction thin layer affords high-performance carbon-based all-inorganic solar cells93Interface engineering of high performance all-inorganic perovskite solar cells via low-temperature processed TiO2 nanopillar arrays30Carbon-based all-inorganic perovskite solar cells: Progress, challenges and strategies toward 20% efficiency61Suppressing the Defects in CsPbI2Br Perovskite Photovoltaic Films via a Homogeneous Cap-Mediated Annealing Strategy10Modification of compact TiO2 layer by TiCl4-TiCl3 mixture treatment and construction of high-efficiency carbon-based CsPbI2Br perovskite solar cells34Size mismatch induces cation segregation in CsPbI3: Forming energy level gradient and 3D/2D heterojunction promotes the efficiency of carbon-based perovskite solar cells to over 15%62Growth Temperature Influence on Atomic-Layer-Deposited In2O3 Thin Films and Their Application in Inorganic Perovskite Solar Cells30Low temperature fabrication for high-performance semitransparent CsPbI2Br perovskite solar cells30n-type absorber by Cd2+ doping achieves high-performance carbon-based CsPbIBr2 perovskite solar cells48Effect of the decrease of Pb concentration on the properties of pentarnary mixed-halide perovskites CsPb8-xSnxIBr2 and CsPb8-xSnxI2Br (1≤x≤7) for solar-cell applications: A DFT study9Synergistic passivation by alkali metal and halogenoid ions for high efficiency HTM-free carbon-based CsPbI2Br solar cells47Organic additives in all-inorganic perovskite solar cells and modules: from moisture endurance to enhanced efficiency and operational stability34A Universal Dopant-Free Polymeric Hole-Transporting Material for Efficient and Stable All-Inorganic and Organic–Inorganic Perovskite Solar Cells33High-performance carbon-based CsPbI2Br perovskite solar cells via small molecule modification22Generic water-based spray-assisted growth for scalable high-efficiency carbon-electrode all-inorganic perovskite solar cells21In Situ Constructing Intermediate Energy‐Level Perovskite Transition Layer for 15.03% Efficiency HTL‐Free Carbon‐Based Perovskite Solar Cells with a High Fill Factor of 0.8119Mitigating voltage loss in efficient CsPbI2Br all-inorganic perovskite solar cells via metal ion-doped ZnO electron transport layer19Efficient and Stable Carbon‐Based CsPbIBr2 Perovskite Solar Cells by 4‐Aminomethyltetrahydropyran Acetate Modification17Fine coverage and uniform phase distribution in 2D (PEA)2Cs3Pb4I13 solar cells with a record efficiency beyond 15%37Crystallization kinetics modulation and defect suppression of all-inorganic CsPbX 3 perovskite films120Understanding steric-charge-dependence of conjugated passivators on π-Pb2+ bond strength for efficient all-inorganic perovskite solar cells53Facet orientation tailoring via 2D-seed- induced growth enables highly efficient and stable perovskite solar cells336In situ , seed-free formation of a Ruddlesden–Popper perovskite Cs 2 PbI 2 Cl 2 nanowires/PbI 2 heterojunction for a high-responsivity, self-powered photodetector7NH4Ac boosts the efficiency of carbon-based all-inorganic perovskite solar cells fabricated in the full ambient air to 15.43%17The disappearing additive: introducing volatile ethyl acetate into a perovskite precursor for fabricating high efficiency stable devices in open air8The high open-circuit voltage of perovskite solar cells: a review430The synergistic effect of defect passivation and energy level adjustment for low-temperature carbon-based CsPbI 2 Br perovskite solar cells22Extracting ammonium halides by solvent from the hybrid perovskites with various dimensions to promote the crystallization of CsPbI3 perovskite54A counter electrode modified with renewable carbonized biomass for an all-inorganic CsPbBr3 perovskite solar cell28Double-Side healing at CsPbI2Br/ZnO interface by bipyrimidine hydroiodide enables inverted solar cells with enhanced efficiency and stability24A facile interface engineering method to improve the performance of FTO/ZnO/CsPbI3−xBrx (x < 1)/C solar cells4Intermediate Phase‐Assisted Sequential Deposition Toward 15.24%‐Efficiency Carbon‐Electrode Cspbi2br Perovskite Solar Cells24Universal Dynamic Liquid Interface for Healing Perovskite Solar Cells130Mitigating interfacial and bulk defects via chlorine modulation for HTL-free all-inorganic CsPbI2Br carbon-based perovskite solar cells with efficiency over 14%50All‐inorganic CsPbX 3 Perovskite Solar Cells0A Novel Multiple‐Ring Aromatic Spacer Based 2D Ruddlesden–Popper CsPbI3 Solar Cell with Record Efficiency Beyond 16%41High-efficient hole-transport-material-free carbon-based all-inorganic perovskite solar cells using Cs-doped TiO2 nanorods array as the electron transport layer7Fluorinated Interfaces for Efficient and Stable Low‐Temperature Carbon‐Based CsPbI2Br Perovskite Solar Cells87The investigation of the electronic, optical, and thermoelectric properties of the Ge‐based halide perovskite AGeI 2 Br (a = K, Rb, Cs) compound for a photovoltaic application: First principles calculations79Recent Progress of Carbon‐Based Inorganic Perovskite Solar Cells: From Efficiency to Stability119Investigating the capacitive properties of all-inorganic lead halides perovskite solar cells using energy band diagrams5Organic Molecules in All‐Inorganic CsPbIxBr3−x Perovskite Solar Cells: Interface Modifiers or Precursor Additives7Synergistic Effects of Bipolar Additives on Grain Boundary-Mediated Charge Transport for Efficient Carbon-Based Inorganic Perovskite Solar Cells7Moisture-triggered fast crystallization enables efficient and stable perovskite solar cells219Recent Advances in CsPb X 3 Perovskite Solar Cells: Focus on Crystallization Characteristics and Controlling Strategies94High-performance carbon-based all-inorganic CsPbI2Br perovskite solar cells via ethylammonium iodide and phenethylammonium iodide synergistic passivation31A One‐Step Ionic Liquid Interface‐to‐Bulk Modification for Stable Carbon‐Based CsPbI3 Perovskite Solar Cells with Efficiency Over 15%23Advances in Processing Kinetics for All‐Inorganic Halide Perovskite: Towards Efficient and Thermodynamic Stable Solar Cells11Stabilization of Perovskite Solar Cells: Recent Developments and Future Perspectives248CsPbBr3 seeds improve crystallization and energy level alignment for highly efficient CsPbI3 perovskite solar cells47Organic Additive Engineering to Grow High‐Quality Inorganic CsPbX3 Perovskite Films for Efficient and Stable Solar Cells24Evaluation of the Passivation Effects of PEDOT:PSS on Inverted Perovskite Solar Cells116All-inorganic CsPb1-xSnxI2Br perovskites mediated by dicyandiamide additive for efficient 4-terminal tandem solar cell36Study the C-V behavior of cesium-lead halides perovskite solar cells under various simulation parameters4The opportunities and challenges of ionic liquids in perovskite solar cells44Full Life-Cycle Lead Management and Recycling Transparent Conductors for Low-Cost Perovskite Solar Cell29Clothing CsPbI 3 perovskite in a robust phase-pure armor to boost the thermal stability12A 2D/3D heterojunction engineered for carbon-based hole-transport-layer-free perovskite solar cells7Air-processed MAPbI 3 perovskite solar cells achieve 20.87% efficiency and excellent bending resistance enabled via a polymer dual-passivation strategy18Crosslinked thioctic acid as a multifunctional buried interface modifier for high-performance inorganic perovskite solar cells10Efficient All-Inorganic Cspbibr2 Perovskite Solar Cells with an Open Voltage Over 1.33 V by Dual-Additive Strategy0Inorganic CsPbI 2 Br halide perovskites: from fundamentals to solar cell optimizations82Interfacial engineering between SnO 2 /MAPbI 3 by maleate pheniramine halides toward carbon counter electrode-based perovskite solar cells with 16.21% efficiency17Effective improvement of the carbon-based CsPbI2Br perovskite solar cells through additive and interface strategies18All-Inorganic CsPb2I4Br/CsPbI2Br 2D/3D Bulk Heterojunction Boosting Carbon-Based CsPbI2Br Perovskite Solar Cells with an Efficiency of Over 15%64Seeding Agents in Metal Halide Perovskite Solar Cells: From Material to Mechanism19Constructing a Surface Multi-cationic Heterojunction for CsPbI 1.5 Br 1.5 Perovskite Solar Cells with Efficiency beyond 14%12Preparation of High-Efficiency (>14%) HTL-Free Carbon-Based All-Inorganic Perovskite Solar Cells by Passivation with PABr Derivatives20Carbon-based perovskite solar cells with electron and hole-transporting/-blocking layers20Cl-terminated Ti3C2 MXene-modulated carbon/CsPbIBr2 interface boosting efficiency and stability of all-inorganic perovskite solar cells19Constructing gradient structure to increase efficiency for carbon-based hole transport layer free all-inorganic perovskite solar cells using SCAPS-1D38NiOx for interface and work function engineering in carbon-based all-inorganic perovskite solar cells36Surface Passivation of CsPbI 3 Films for Efficient and Stable Hole-Transporting Layer-Free Carbon-Based Perovskite Solar Cells13Insight into structure defects in high-performance perovskite solar cells30Synchronous Modulation of Energy Level Gradient and Defects for High‐Efficiency HTL‐Free Carbon‐Based All‐Inorganic Perovskite Solar Cells18The stability of inorganic perovskite solar cells: from materials to devices36Interfacial modification to improve all-inorganic perovskite solar cells by a multifunctional 4-aminodiphenylamine layer20Novel Materials in Perovskite Solar Cells: Efficiency, Stability, and Future Perspectives45Ionic Bilateral Passivator Carboxyethylisothiuronium Chloride for CsPbI3-xBrx Perovskite Solar Cells with PCE 20.9% and Superior Stability30Efficient all-inorganic CsPbIBr2 perovskite solar cells with an open voltage over 1.33 V by dual-additive strategy6Organic Bromide Salts Interface Modification for High‐Efficiency Perovskite Solar Cells with Printed Carbon Electrode13Thick film high-performance carbon-based CsPbIBr2 perovskite solar cells vis nano-perovskite modified hot casting method7Mixed‐Halide Inorganic Perovskite Solar Cells: Opportunities and Challenges110From planar structures to curved optoelectronic devices: The advances of halide perovskite arrays16The design and performance optimization of all-inorganic CsPbIBr2/CsSnI3 heterojunction perovskite solar cells45Low-temperature synergistic effect of MA and Cl towards high-quality α-FAPbI 3 films for humid-air-processed perovskite solar cells12Moisture Induced Secondary Crystal Growth Boosting the Efficiency of Hole Transport Layer‐Free Carbon‐Based Perovskite Solar Cells beyond 19.5%69Comparative Study of Distinct Halide Composites for Highly Efficient Cesium-Based Perovskite Solar Cells23Interfacial Treatment by 1,4-Phenyldiammonium Diiodide to Significantly Improve the Performance of Carbon-Based CsPbI 2 Br Solar Cells16Critical role of post-treatment induced surface reconstruction for high performance inorganic tin-lead perovskite solar cells33[Gd3+–Ho3+-Dy3+]:CsPbI2.2Br0.8: Lanthanide impelled stabilization of perovskite material for sustainable energy harvesting, generation, and charge storage1Advances in Crystallization Regulation and Defect Suppression Strategies for All-inorganic CsPbX3 Perovskite Solar Sells69Flexible p-i-n perovskite solar cell with optimized performance by KBF 4 additive7Templated-seeding renders tailored crystallization in perovskite photovoltaics: path towards future efficient modules15The dominant roles of the seed template in driving controllable growth of perovskite crystal20Continuous flash sublimation of inorganic halide perovskites: overcoming rate and continuity limitations of vapor deposition22Toward durable all-inorganic perovskite solar cells: from lead-based to lead-free29All‐Inorganic Perovskite Solar Cells: Modification Strategies and Challenges21Integration of SWCNT and WO3 for efficient charge extraction in all-inorganic perovskite solar cells18Bottom-up multi-interface modification boosts the performance of carbon-based HTL-free all-inorganic CsPbI2Br perovskite solar cells44Simplified Fabrication for High-Performance CsPbIBr2 Perovskite Solar Cells via Nanoparticle Centrifugal Deposition3Strategies for achieving high efficiency and stability in carbon-based all-inorganic perovskite solar cells112-Iodoaniline-Modified High-Efficiency Carbon-Based CsPbIBr2 perovskite solar cells9Crystallization management and defect passivation via additive engineering for efficient and stable carbon-based CsPbI2Br perovskite solar cells13Seed-assisted growth for high-performance perovskite solar cells: A review13Interface engineering for highly efficient carbon-based all-inorganic perovskite solar cells using functionalized amino acid salts3Why Perovskite Thermal Stress is Unaffected by Thin Contact Layers17Polar Species Modified Dielectric Constant of CsPbI2Br Perovskite Nanocrystals: Implications for Carbon-Based Perovskite Solar Cells6Control of CsPbI2Br Perovskite Colloidal Dispersion with 4-Methoxybenzenethiol for Slow Nucleation in CsPbI2Br Perovskite and Enhanced Solar Cell Performance12Exploration HTL-Free all inorganic mixed halide perovskite solar cells: effects of 4-ADPA passivation8Pseudohalide‐Based Ionic Liquids: Advancing Crystallization Kinetics and Optoelectronic Properties in All‐Inorganic Perovskite Solar Cells29Crystallinity Control and Strain Release in Wide-Bandgap Perovskite Film via Seed-Induced Growth for Efficient Photovoltaics9Low‐Temperature Stable CsPbI2Br Perovskite for Solar Photovoltaics and Blue Photodetection7Columnar Macrocyclic Molecule Tailored Grain Cage to Stabilize Inorganic Perovskite Solar Cells with Suppressed Halide Segregation38Unveiling the potential of additives in optimizing halide perovskite solar cells performance and reliability7In Situ Forming of a 2D Inorganic Perovskite Capping Layer by Surface Reconstruction for Efficient and Stable CsPbI2Br Perovskite Solar Cells7High-efficiency carbon-electrode CsPbI 2 Br solar cells prepared by double ion regulation of cadmium acetate additive4Thermal conduction-induced crystallization and achieving high efficiency in HTM-free carbon-based CsPbI 2 Br solar cells by regulating the dipole moment of aliphatic amine acetate additives4Two-Dimensional Ruddlesden–Popper Perovskite Cs2PbI2Cl2 Nanostructures for Self-Powered Visible–Blind Ultraviolet Photodetectors5Theoretical evaluation of the realizable power conversion efficiency and the possible scheme for hole-transport-layer-free carbon-cathode CsPbI 2 Br solar cells8Cesium Moderation and Structural Transformation on α-CsPbI2Br Perovskite Durability via Cation Retarding Migration: A Combined Simulation and Experimental Study3Difunctional organic cation doping induced crystallization dynamic Modulation and residual strain compensation for efficient perovskite solar cells9Advancements and Strategies in CsPbI2Br Perovskite Solar Cells for Enhanced Efficiency and Stability9Surface Halide Manipulation for Stable Inorganic Perovskite Solar Cells and Modules12Surface Halide Manipulation for Stable Inorganic Perovskite Solar Cells and Modules3Practical Interface Engineering between Perovskite and Carbon Electrode in Regular Carbon-Based Perovskite Solar Cells15Enhancing the Photovoltaic Performance of Carbon-Based Hole-Transport-Layer-Free CsPbI2Br Solar Cells via Trifluoromethyl Thianthrenium Triflate Additive3Surface planarization enabled low-dimensional perovskite-leveling compound for carbon-based CsPbI2Br perovskite solar cells4Synergistic defect passivation and energy-level optimization toward high-efficiency HTL-free carbon-based CsPbI2.75Br0.25 perovskite solar cells4Electron Transport Layer Optimization for All-Inorganic, Vacuum-Deposited Perovskite-Based Photodiodes with Improved Reverse Bias Stability and High Speed5Synergistic enhancement of carbon-based perovskite solar cells via Ce-MOF-derived interfacial layer and hot pressing1“Sterilizing” the surface of inorganic CsPbI2.75Br0.25 perovskite by a bactericide molecule for high-performance carbon-based perovskite solar cells4CsPbBr 3 Nanocrystals as Bottom Interface Nucleation Seeds for Printing Oriented FAPbI 3 Thin Films: An In Situ Study15Controlled Synthesis and Doping of MAPbBr3 Single Crystals for Enhanced Scintillation Performance at Cryogenic Temperatures6Sodium Oxamate‐Assisted Dual Interface Modulation for High‐Efficient Hole Transport Layer‐Free Carbon‐Based Perovskite Solar Cells5Engineering inorganic perovskite solar cells: overcoming efficiency and stability barriers for next-generation photovoltaics12Alkali metal fluoride synergistically passivates the buried interface to achieve high-efficiency and stable all-inorganic CsPbBr3 perovskite solar cells0Design and simulation of a high-V OC CsPbI 2 Br solar cell with enhanced thermal stability2Multifunctional ionic liquid boosts the efficiency of hole transport layer‐free carbon‐based perovskite solar cells beyond 20%7Synergistic Crystallization and Surface Passivation: A Bifunctional Aminium Chloride Additive for High-Performance CsPbI 2 Br Perovskite Solar Cells2Multifunctional three-dimensional polymer-mediated defect passivation enabling efficient and stable inverted inorganic CsPbI2Br perovskite solar cells1Beyond Conventional Designs: Dual Gradient Strategies Unlock 22.5% PCE in Carbon‐PSCs0Facile Molecular Modification for Efficient and Stable Carbon-Based CsPbI 3 Perovskite Solar Cells0Multisite Molecular Coordination for Defect and Structural Regulation in Carbon‐Cathode Hole‐Transport‐Layer‐Free CsPbI 2 Br Solar Cells0

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