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RESEARCH PAPER · Chemistry of Materials · 2021

Exploring the Stability of Mixed-Halide Vacancy-Ordered Quadruple Perovskites

Matthew B. Gray, Jackson D. Majher, Noah P. Holzapfel, Patrick M. Woodward

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Exploring the Stability of Mixed-Halide Vacancy-Ordered Quadruple PerovskitesOriginalColloidal synthesis and charge carrier dynamics of Cs4Cd1−Cu Sb2Cl12 (0 ≤ x ≤ 1) layered double perovskite nanocrystals32Lanthanide doping enabled multimodal luminescence in layered lead-free double perovskite Cs 4 MnBi 2 Cl 1237Theoretical Prediction of Mixed-Valence Layered Halide Perovskites Cs4M(IV)M(II)2X12 (M = Ge, Sn; X = Cl, Br)14Tailoring red-NIR luminescence in rare earth doped lead-free layered double perovskites by bivalent manganese energy bridge0Hybrid Organic–Inorganic Halide Derivatives of the 2H Hexagonal Perovskite Structure7Recent Progress of Bismuth Effect on All‐Inorganic Lead‐Free Metal Halide Derivatives: Crystals Structure, Luminescence Properties, and Applications70Progress in all-inorganic heterometallic halide layered double perovskites26Highly Stable and Panchromatic Light Absorbing Cs2OsX6 (X = Cl−, Br−, I−) Vacancy Ordered Perovskites as Photoanodes for Solar Water Oxidation19Challenges and future prospects2Red–NIR Luminescence in Rare-Earth and Manganese Ions Codoped Cs 4 CdBi 2 Cl 12 Vacancy-Ordered Quadruple Perovskites51Enhanced Photoluminescence and Reduced Dimensionality via Vacancy Ordering in a 10H Halide Perovskite8Lead-Free Solid State Mechanochemical Synthesis of Cs 2 NaBi 1– x Fe x Cl 6 Double Perovskite: Reduces Band Gap and Enhances Optical Properties34First-principles calculations to investigate role of 4d electrons spin (Mo/Tc) in half metallic ferromagnetism, and thermoelectric characteristics of Rb2(Tc, Mo)X6 (X =Cl, Br)21Mn2+‐Based Luminescent Metal Halides: Syntheses, Properties, and Applications155Halide Double Perovskites8Physical properties of vacancy-ordered double perovskites K 2 TcZ 6 (Z = Cl, Br) for spintronics applications: DFT calculations42Lanthanide Doping into All-Inorganic Heterometallic Halide Layered Double Perovskite Nanocrystals for Multimodal Visible and Near-Infrared Emission66Moisture‐Resistant Orange Emitters with Near‐Unity Quantum Yield from Mn2+ Alloyed Vacancy‐Ordered Quadruple Perovskites10High-stability double perovskite scintillator for flexible X-ray imaging27Recent Advances in Fast-Decaying Metal Halide Perovskites Scintillators30Polyurethane-coated double perovskite (Cs4Mn1-xCdxBi2Cl12) significantly improves stability and flexible anticounterfeiting1Lead-free lanthanide-based Cs 3 LnCl 6 metal halides6Fluorine-Induced Anomalous Optical Stability and Pressure-Enhanced Emission Property of 0D Lead Perovskite Derivatives10Metal Halide Perovskite and Perovskite-inspired Materials: Solid-state NMR of Quadrupolar Nuclei2Ag Doping Triggered Electronic Structural Engineering in Halide Quadruple Perovskite Toward Near‐Unity Luminescence Quantum Yield8Structural Polytypism in B-Site-Deficient Azetidinium-Based Pnictogen Halide Hexagonal Perovskites3Boosting luminescence in Cs3Sb2Cl9-derived Cs4MnSb2Cl12 through Cd2+ dopant incorporation1Pb-Apatite Framework as a Generator of Novel Flat-Band CuO-Based Physics0Rb 4 CuSb 2 X 12 ( X = Cl, Br) as Novel Vacancy‐Ordered Quadruple Perovskites0Kinetically Trapped High‐Density Interstitial Mn 2+ Enables Concentration‐Quenching‐Free Persistent Luminescence in CsCdCl 3 Perovskites1Kinetically Trapped High‐Density Interstitial Mn 2+ Enables Concentration‐Quenching‐Free Persistent Luminescence in CsCdCl 3 Perovskites0Bi3+ doping-regulated optical properties of 2D perovskite Cs4MnSb2-xBixCl12 and its application in fingerprint visualization0Challenges and Opportunities for Layered Double Perovskite Solar Cells0

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  1. Colloidal synthesis and charge carrier dynamics of Cs4Cd1−Cu Sb2Cl12 (0 ≤ x ≤ 1) layered double perovskite nanocrystals

    Matter · 2021-08-19

    Tong Cai, Wenwu Shi, David J. Gosztola, Kanishka Kobbekaduwa, Hanjun Yang, Na Jin, Yasutaka Nagaoka, Lacie Dube, Jeremy Robin Schneider, Sooyeon Hwang, Jianbo Gao, Xuedan Ma, Ou Chen

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  2. Lanthanide doping enabled multimodal luminescence in layered lead-free double perovskite Cs 4 MnBi 2 Cl 12

    Journal of Materials Chemistry C · 2022-01-01

    Jingyu Li, Jiawen Xiao, Taifeng Lin, Zhengguang Yan, Xiaodong Han

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  3. Theoretical Prediction of Mixed-Valence Layered Halide Perovskites Cs4M(IV)M(II)2X12 (M = Ge, Sn; X = Cl, Br)

    The Journal of Physical Chemistry Letters · 2022-01-25

    Chunbao Feng, Qing Xiang Zhao, Changhe Wu, Xin Luo, Shichang Li, Dengfeng Li, Gang Tang, Gang Zhang

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  4. Tailoring red-NIR luminescence in rare earth doped lead-free layered double perovskites by bivalent manganese energy bridge

    Research Square · 2022-07-08

    Jun Lin, Peipei Dang, Guodong Zhang, Wei Yang, Hongzhou Lian, Guogang Li

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  5. Hybrid Organic–Inorganic Halide Derivatives of the 2H Hexagonal Perovskite Structure

    Chemistry of Materials · 2022-08-25

    Noah P. Holzapfel, Alexander Milder, Patrick M. Woodward

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  6. Recent Progress of Bismuth Effect on All‐Inorganic Lead‐Free Metal Halide Derivatives: Crystals Structure, Luminescence Properties, and Applications

    Advanced Functional Materials · 2022-11-06

    Yi Min Wei, Wei Wang, Zhennan Wang, Hang Yang, Xinyu You, Yunna Zhao, Peipei Dang, Hongzhou Lian, Jianhua Hao, Guogang Li, Jun Lin

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  7. Progress in all-inorganic heterometallic halide layered double perovskites

    Trends in Chemistry · 2022-11-18

    Tong Cai, Lacie Dube, Péter Sághy, Hanjun Yang, Ou Chen

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  8. Highly Stable and Panchromatic Light Absorbing Cs2OsX6 (X = Cl−, Br−, I−) Vacancy Ordered Perovskites as Photoanodes for Solar Water Oxidation

    Advanced Materials Interfaces · 2022-11-27

    Nandhini Shanmugam, Jigar Shaileshkumar Halpati, Aravind Kumar Chandiran

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  9. Challenges and future prospects

    Elsevier eBooks · 2023-01-01

    Paulina Carmona‐Monroy, Brenda Cabral Vargas, Diego Solís-Ibarra

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  10. Red–NIR Luminescence in Rare-Earth and Manganese Ions Codoped Cs 4 CdBi 2 Cl 12 Vacancy-Ordered Quadruple Perovskites

    Chemistry of Materials · 2023-02-07

    Peipei Dang, Guodong Zhang, Wei Yang, Hongzhou Lian, Guogang Li, Jun Lin

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  11. Enhanced Photoluminescence and Reduced Dimensionality via Vacancy Ordering in a 10H Halide Perovskite

    Inorganic Chemistry · 2023-02-13

    Hang Liu, Hassan Hafeez, David B. Cordes, Alexandra M. Z. Slawin, Gavin S. Peters, Stephen Lee, Ifor D. W. Samuel, Finlay D. Morrison

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  12. Lead-Free Solid State Mechanochemical Synthesis of Cs 2 NaBi 1– x Fe x Cl 6 Double Perovskite: Reduces Band Gap and Enhances Optical Properties

    Inorganic Chemistry · 2023-03-15

    Rohini Udavant, Sachin R. Thawarkar, Sachin R. Rondiya, Ankita Shelke, Rahul Aher, Thalasseril Govindankuttykaimal Ajithkumar, Russell W. Cross, Nelson Yaw Dzade, Sandesh Jadkar

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  13. First-principles calculations to investigate role of 4d electrons spin (Mo/Tc) in half metallic ferromagnetism, and thermoelectric characteristics of Rb2(Tc, Mo)X6 (X =Cl, Br)

    Ceramics International · 2023-05-05

    Qasim Mahmood

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  14. Mn2+‐Based Luminescent Metal Halides: Syntheses, Properties, and Applications

    Advanced Optical Materials · 2023-05-23

    Dehai Liang, Hongbin Xiao, Wensi Cai, Shirong Lu, Shuangyi Zhao, Zhigang Zang, Lei Xie

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  15. Halide Double Perovskites

    Unknown journal · 2023-12-22

    Carina Pareja‐Rivera, Dulce Zugasti‐Fernández, P. Olalde-Velasco, Diego Solís-Ibarra

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  16. Physical properties of vacancy-ordered double perovskites K 2 TcZ 6 (Z = Cl, Br) for spintronics applications: DFT calculations

    RSC Advances · 2024-01-01

    Huda A. Alburaih, Sadia Nazir, Naveed Ahmad Noor, A. Laref, M. Musa Saad H.‐E.

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  17. Lanthanide Doping into All-Inorganic Heterometallic Halide Layered Double Perovskite Nanocrystals for Multimodal Visible and Near-Infrared Emission

    Journal of the American Chemical Society · 2024-01-26

    Tong Cai, Wenwu Shi, Rongzhen Wu, Chun Chu, Na Jin, Junyu Wang, Weiwei Zheng, Xinzhong Wang, Ou Chen

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  18. Moisture‐Resistant Orange Emitters with Near‐Unity Quantum Yield from Mn2+ Alloyed Vacancy‐Ordered Quadruple Perovskites

    Laser & Photonics Review · 2024-04-09

    Peipei Dang, Qianqian Gu, Guodong Zhang, Hongzhou Lian, Guogang Li, Jun Lin

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  19. High-stability double perovskite scintillator for flexible X-ray imaging

    Journal of Colloid and Interface Science · 2024-05-29

    Jingyu Li, Qingsong Hu, Jiawen Xiao, Zhengguang Yan

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  20. Recent Advances in Fast-Decaying Metal Halide Perovskites Scintillators

    The Journal of Physical Chemistry Letters · 2024-07-01

    Yangmin Tang, Guiqiang Pu, Yanfeng Tang, Tongming Sun, Minmin Wang, Jiacheng Wang

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  21. Polyurethane-coated double perovskite (Cs4Mn1-xCdxBi2Cl12) significantly improves stability and flexible anticounterfeiting

    Journal of Alloys and Compounds · 2024-11-03

    Qian Zhang, Wanyin Ge, Peng He, Maohao Yang, Xin Xie, Zili Luo, Shifan Shang

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  22. Lead-free lanthanide-based Cs 3 LnCl 6 metal halides

    Journal of Materials Chemistry C · 2024-12-09

    Yuanzhe Ding, Dongjie Liu, Peipei Dang, Guogang Li, Jun Lin

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  23. Fluorine-Induced Anomalous Optical Stability and Pressure-Enhanced Emission Property of 0D Lead Perovskite Derivatives

    Chemistry of Materials · 2025-03-17

    Congcong Chen, Y. M. Zhang, Huan Liu, Xuanyu Zhang, Zhiyong Luo, Jiawei Lin, Yuhong Mao, Rui Chen, Songhao Guo, Xujie Lü, Lingling Mao

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  24. Metal Halide Perovskite and Perovskite-inspired Materials: Solid-state NMR of Quadrupolar Nuclei

    Royal Society of Chemistry eBooks · 2025-03-31

    Diganta Sarkar, Amy Bacon, Guy M. Bernard, Vladimir K. Michaelis

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  25. Ag Doping Triggered Electronic Structural Engineering in Halide Quadruple Perovskite Toward Near‐Unity Luminescence Quantum Yield

    Laser & Photonics Review · 2025-05-19

    Dengbang Zhao, Zhipeng Chen, Meng Wang, Mochen Jia, Jibin Zhang, Linyuan Lian, Yanbin Han, Xu Chen, Zhuangzhuang Ma, Ying Liu, Zhifeng Shi

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  26. Structural Polytypism in B-Site-Deficient Azetidinium-Based Pnictogen Halide Hexagonal Perovskites

    Inorganic Chemistry · 2025-06-26

    Hang Liu, Rebecca Rae, James Dalzell, Gavin S. Peters, Herbert Früchtl, Aidan P. McKay, David B. Cordes, Amit Kumar, Caroline A. Kirk, Finlay D. Morrison

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  27. Boosting luminescence in Cs3Sb2Cl9-derived Cs4MnSb2Cl12 through Cd2+ dopant incorporation

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    Cang Zhang, Ling He, Junhao Li, Kunpeng Shi, Peng Chang, Yujie Zheng, Yong Yang, Dacheng Zhou, Qiu Jianbei

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  28. Pb-Apatite Framework as a Generator of Novel Flat-Band CuO-Based Physics

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    R. Kurleto, Stephan Lany, Dimitar L. Pashov, Swagata Acharya, Mark van Schilfgaarde, D. S. Dessau

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  29. Rb 4 CuSb 2 X 12 ( X = Cl, Br) as Novel Vacancy‐Ordered Quadruple Perovskites

    Zeitschrift für anorganische und allgemeine Chemie · 2026-03-05

    Mirko Bravic, Markus Otteny, Kevin Eble, Julian Gebhardt, Christian Elsässer, Michael Daub

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  30. Kinetically Trapped High‐Density Interstitial Mn 2+ Enables Concentration‐Quenching‐Free Persistent Luminescence in CsCdCl 3 Perovskites

    Angewandte Chemie International Edition · 2026-08-27

    Qiudong Duan, Shuo Zhang, Zhenhua Song, Yuxuan Fang, Guo Yang, Zhirou Chen, Huanyu Chen, Ying Tan, Wenhuai Feng, Wu‐Qiang Wu

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  31. Kinetically Trapped High‐Density Interstitial Mn 2+ Enables Concentration‐Quenching‐Free Persistent Luminescence in CsCdCl 3 Perovskites

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  32. Bi3+ doping-regulated optical properties of 2D perovskite Cs4MnSb2-xBixCl12 and its application in fingerprint visualization

    Ceramics International · 2026-09-01

    严晓敏, Gang Yang, Zizheng Yin, Yidan Lai, Ruijing Zhang, Hongbo Qi, Degui Kong

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  33. Challenges and Opportunities for Layered Double Perovskite Solar Cells

    Solar RRL · 2026-09-08

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