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RESEARCH PAPER · Advanced Materials · 2021

Engineering the Optical Emission and Robustness of Metal‐Halide Layered Perovskites through Ligand Accommodation

Balaji Dhanabalan, Giulia Biffi, Anna Moliterni, Vincent Oliéric, Cinzia Giannini, Gabriele Saleh, Louis Ponet, Mirko Prato, Muhammad Imran, Liberato Manna, Roman Krahne, Sergey Artyukhin, Milena P. Arciniegas

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Engineering the Optical Emission and Robustness of Metal‐Halide Layered Perovskites through Ligand AccommodationOriginalReversible Emission Tunability from 2D‐Layered Perovskites with Conjugated Organic Cations13Triple-decker layered perovskite materials10Single‐Component White‐Light Emitters with Excellent Color Rendering Indexes and High Photoluminescence Quantum Efficiencies45Two-Dimensional Layered Perovskites for Photonic Devices2Free and self-trapped exciton emission in perovskite CsPbBr 3 microcrystals49Temperature-induced structural transition in an organic–inorganic hybrid layered perovskite (MA) 2 PbI 2− x Br x (SCN) 26Correlating Symmetries of Low‐Frequency Vibrations and Self‐Trapped Excitons in Layered Perovskites for Light Emission with Different Colors23Low‐Frequency Phonon Modes in Layered Silver‐Bismuth Double Perovskites: Symmetry, Polarity, and Relation to Phase Transitions10Designing Ruddlesden–Popper Layered Perovskites through Their Organic Cations40Are Mixed-Halide Ruddlesden–Popper Perovskites Really Mixed?31Spacer Cation Alloying Enables Markedly Improved Chiroptical Properties of Two‐Dimensional Chiral Hybrid Perovskite Nanosheets37A high-performance metal halide perovskite-based laser-driven display29Impact of the organic cation on the band-edge emission of two-dimensional lead–bromide perovskites13The interface microenvironment mediates the emission of a semiconductor nanocluster via surface-dopant-involving direct charge transfer6Growth and Self-Assembly of CsPbBr3 Nanocrystals in the TOPO/PbBr2 Synthesis as Seen with X-ray Scattering52Effect of Electron–Phonon Coupling on the Color Purity of Two-Dimensional Ruddlesden–Popper Hybrid Lead Iodide Perovskites9Insight into efficient photoluminescence regulation mechanism by lattice distortion and Mn2+ doping in organic-inorganic hybrid perovskites1Stable Sn-Based Hybrid Perovskite-Related Structures with Tunable Color Coordinates via Organic Cations in Low-Temperature Synthesis20All-Inorganic Lead-Free Doped-Metal Halides for Bright Solid-State Emission from Primary Colors to White Light20Micro‐ and Nano‐Structured Bacteria Growth Media for Planar Bio‐Photonics4Accommodative Organoammonium Cations in A‐Sites of Sb─In Halide Perovskite Derivatives for Tailoring BroadBand Photoluminescence with X‐Ray Scintillation and White‐Light Emission75Distinct Excitonic Emissions in 2D (C7H7N2)2PbX4 (X = Cl, Br) under Compression11Mapping emission heterogeneity in layered halide perovskites using cathodoluminescence5Ferroelasticity in Two-Dimensional Hybrid Ruddlesden–Popper Perovskites Mediated by Cross-Plane Intermolecular Coupling and Metastable Funnel-like Phases7Reversible Local Protonation‐Deprotonation: Tuning Stimuli‐Responsive Circularly Polarized Luminescence in Chiral Hybrid Zinc Halides for Anti‐Counterfeiting and Encryption9Reversible Local Protonation‐Deprotonation: Tuning Stimuli‐Responsive Circularly Polarized Luminescence in Chiral Hybrid Zinc Halides for Anti‐Counterfeiting and Encryption47Interplay of Phonon Directionality and Emission Polarization in Two-Dimensional Layered Metal Halide Perovskites17Phonon Directionality Impacts Electron–Phonon Coupling and Polarization of the Band-Edge Emission in Two-Dimensional Metal Halide Perovskites9Biological metasurfaces based on tailored Luria Bertani Agar growth medium formulations for photonic applications2Direct Crystallographic Observation of Obvious Structural Deformation in a Lead Halide Framework Induced by Host–Guest Interactions5Selective Growth of FAPbBr3 Nanocrystals with Precisely Tailored Optical Properties for Advanced Optoelectronic Applications1Revealing the True Nature of Double‐Peak Emission in 2D Perovskite Single Crystals Using Polariton Waveguides6Controlling Energy Flow in Perovskite Heterostructures Through Dimensionality and Phase Engineering7Direct Growth of Rectangular 2D Layered Metal‐Halide Perovskite Microcrystal Photonic Cavities on Functional Substrates6Structural Tuning of Layered Perovskites for Enhanced Broadband Emission at Room Temperature4Extended Dual-Functional Engineering for High-Performance 2D Dion–Jacobson CsPbI 3 Perovskite Solar Cells with Enhanced Stability1Pressure-induced enhancement of deep-blue photoluminescence in two-dimensional hybrid organic-inorganic perovskites0Harnessing Metal-Halide Layered Perovskite Structures for Next-Generation Lighting Sources1Programming Structural Symmetry and Emission in Low‐Dimensional Hybrid Perovskites via Time and Temperature0Deterministic Nucleation of Nanocrystal Superlattices on 2D Perovskites for Light‐Funneling Heterostructures0

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  1. Reversible Emission Tunability from 2D‐Layered Perovskites with Conjugated Organic Cations

    Advanced Photonics Research · 2021-02-19

    Balaji Dhanabalan, Renuka Devi Pothuraju, Sergio Marras, Lea Pasquale, Liberato Manna, Roman Krahne, Milena P. Arciniegas

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  2. Triple-decker layered perovskite materials

    Nature · 2021-09-15

    Roman Krahne, Milena P. Arciniegas

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  3. Single‐Component White‐Light Emitters with Excellent Color Rendering Indexes and High Photoluminescence Quantum Efficiencies

    Advanced Optical Materials · 2021-11-01

    Linyuan Lian, Song Wang, Huaiyi Ding, Guijie Liang, Yong‐Biao Zhao, Haisheng Song, Xinzheng Lan, Jianbo Gao, Rong Chen, Daoli Zhang, Jianbing Zhang

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  4. Two-Dimensional Layered Perovskites for Photonic Devices

    Unknown journal · 2021-12-07

    Roman Krahne

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  5. Free and self-trapped exciton emission in perovskite CsPbBr 3 microcrystals

    RSC Advances · 2022-01-01

    Fang Pan, Jingrui Li, Xiaoman Ma, Yang Nie, Beichen Liu, Honggang Ye

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  6. Temperature-induced structural transition in an organic–inorganic hybrid layered perovskite (MA) 2 PbI 2− x Br x (SCN) 2

    CrystEngComm · 2022-01-01

    Takuya Ohmi, Tomoaki Miura, Kei Shigematsu, Alexandra A. Koegel, Brian S. Newell, James Richmond Neilson, Tadaaki Ikoma, Masaki Azuma, Takafumi Yamamoto

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  7. Correlating Symmetries of Low‐Frequency Vibrations and Self‐Trapped Excitons in Layered Perovskites for Light Emission with Different Colors

    Small · 2022-02-26

    Miao‐Ling Lin, Balaji Dhanabalan, Giulia Biffi, Yu‐Chen Leng, Seda Kutkan, Milena P. Arciniegas, Ping‐Heng Tan, Roman Krahne

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  8. Low‐Frequency Phonon Modes in Layered Silver‐Bismuth Double Perovskites: Symmetry, Polarity, and Relation to Phase Transitions

    Advanced Optical Materials · 2022-06-09

    Beatriz Martín‐García, Davide Spirito, Miao‐Ling Lin, Yu‐Chen Leng, Sergey Artyukhin, Ping‐Heng Tan, Roman Krahne

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  9. Designing Ruddlesden–Popper Layered Perovskites through Their Organic Cations

    ACS Energy Letters · 2022-08-11

    Milena P. Arciniegas, Liberato Manna

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  10. Are Mixed-Halide Ruddlesden–Popper Perovskites Really Mixed?

    ACS Energy Letters · 2022-10-31

    Stefano Toso, Irina Gushchina, Allen G. Oliver, Liberato Manna, Masaru K. Kuno

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  11. Spacer Cation Alloying Enables Markedly Improved Chiroptical Properties of Two‐Dimensional Chiral Hybrid Perovskite Nanosheets

    Advanced Optical Materials · 2022-12-14

    Rong Lu, Zhangchuan Wen, Mei Zhao, Jun Li, Lijie Zhang, Yun Xia Yang, Huile Jin, Yihuang Chen, Shuang Pan, Shuang Pan

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  12. A high-performance metal halide perovskite-based laser-driven display

    Materials Horizons · 2023-01-01

    Shaoan Zhang, Zhenzhang Li, Zaijin Fang, Bao Qiu, Janak Lal. Pathak, Kaniyarakkal N. Sharafudeen, Subramanian Saravanakumar, Zhanjun Li, Gang Han, Yang Li

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  13. Impact of the organic cation on the band-edge emission of two-dimensional lead–bromide perovskites

    Nanoscale · 2023-01-01

    Seda Kutkan, Balaji Dhanabalan, Miao‐Ling Lin, Ping‐Heng Tan, Alexander Schleusener, Milena P. Arciniegas, Roman Krahne

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  14. The interface microenvironment mediates the emission of a semiconductor nanocluster via surface-dopant-involving direct charge transfer

    Chemical Science · 2023-01-01

    Zhiqiang Wang, Hao Ma, Jiaxu Zhang, Yingjia Lan, Jiaxing Liu, Shang‐Fu Yuan, Xiao‐Ping Zhou, Xiaohong Li, Chaochao Qin, Dong‐Sheng Li, Tao Wu

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  15. Growth and Self-Assembly of CsPbBr3 Nanocrystals in the TOPO/PbBr2 Synthesis as Seen with X-ray Scattering

    Nano Letters · 2023-01-06

    Federico Montanarella, Quinten A. Akkerman, Dennis Bonatz, Maaike M. van der Sluijs, Johanna C. van der Bok, P. Tim Prins, Marcel Aebli, Alf Mews, Daniel A. M. Vanmaekelbergh, Maksym V. Kovalenko

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  16. Effect of Electron–Phonon Coupling on the Color Purity of Two-Dimensional Ruddlesden–Popper Hybrid Lead Iodide Perovskites

    The Journal of Physical Chemistry C · 2023-03-23

    Jing Li, Guochao Lu, Haowei Xie, Xinyi Jiang, Zhishan Fang, Y. J. Zeng, Haiping He, Zhizhen Ye

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  17. Insight into efficient photoluminescence regulation mechanism by lattice distortion and Mn2+ doping in organic-inorganic hybrid perovskites

    Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · 2023-05-06

    Hui Wang, Chao Wang, Mengjiao Sun, Zhen Zhang, Guangjiu Zhao

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  18. Stable Sn-Based Hybrid Perovskite-Related Structures with Tunable Color Coordinates via Organic Cations in Low-Temperature Synthesis

    ACS Energy Letters · 2023-05-16

    Aarya Prabhakaran, Balaji Dhanabalan, Iryna Andrusenko, Andrea Pianetti, Simone Lauciello, Mirko Prato, Sergio Marras, Pavlo Solokha, Mauro Gemmi, Sergio Brovelli, Liberato Manna, Milena P. Arciniegas

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  19. All-Inorganic Lead-Free Doped-Metal Halides for Bright Solid-State Emission from Primary Colors to White Light

    ACS Applied Materials & Interfaces · 2023-07-17

    Ramavath Babu, Iago López‐Fernández, Seelam Prasanthkumar, Lakshminarayana Polavarapu

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  20. Micro‐ and Nano‐Structured Bacteria Growth Media for Planar Bio‐Photonics

    Advanced Optical Materials · 2023-10-26

    Vincenzo Caligiuri, Francesca Leone, Olga Favale, Maria De Santo, Mauro Daniel Luigi Bruno, Olga Mileti, Alfredo Pane, Aniket Patra, Lucia Petti, Susana Guzmán‐Puyol, José A. Heredia‐Guerrero, Roman Krahne, Noemi Baldino, Roberto Bartolino, Michele Galluccio, Ferdinanda Annesi, Antonio De Luca

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  21. Accommodative Organoammonium Cations in A‐Sites of Sb─In Halide Perovskite Derivatives for Tailoring BroadBand Photoluminescence with X‐Ray Scintillation and White‐Light Emission

    Advanced Functional Materials · 2023-11-08

    Hanlin Huang, Yalin Yang, Shuoyan Qiao, Xiaodong Wu, Zheyan Chen, Yu Chao, Kaidong Yang, Weiping Guo, Zhong‐Zhen Luo, Xiaorong Song, Qiushui Chen, Chengkai Yang, Yan Yu, Zhigang Zou

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  22. Distinct Excitonic Emissions in 2D (C7H7N2)2PbX4 (X = Cl, Br) under Compression

    Advanced Science · 2023-11-20

    Hai Zhang, Peijie Zhang, Chenlong Xie, Han Jiang, Bin Xu, Zewei Quan

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  23. Mapping emission heterogeneity in layered halide perovskites using cathodoluminescence

    Nanotechnology · 2023-12-06

    Andrea Griesi, Mehrdad Faraji, Gunnar Kusch, Sirous Khabbazabkenar, Martina Borreani, Simone Lauciello, Alexander Schleusener, Rachel A. Oliver, Roman Krahne, Giorgio Divitini

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  24. Ferroelasticity in Two-Dimensional Hybrid Ruddlesden–Popper Perovskites Mediated by Cross-Plane Intermolecular Coupling and Metastable Funnel-like Phases

    ACS Nano · 2024-05-20

    Devesh R. Kripalani, Qiye Guan, Hejin Yan, Yongqing Cai, Kun Zhou

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  25. Reversible Local Protonation‐Deprotonation: Tuning Stimuli‐Responsive Circularly Polarized Luminescence in Chiral Hybrid Zinc Halides for Anti‐Counterfeiting and Encryption

    Angewandte Chemie · 2024-08-13

    Danyang Liu, Lin‐Yuan Xiong, Xi‐Yan Dong, Zhen Han, Hua‐Li Liu, Shuang‐Quan Zang

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  26. Reversible Local Protonation‐Deprotonation: Tuning Stimuli‐Responsive Circularly Polarized Luminescence in Chiral Hybrid Zinc Halides for Anti‐Counterfeiting and Encryption

    Angewandte Chemie International Edition · 2024-08-13

    Danyang Liu, Lin‐Yuan Xiong, Xi‐Yan Dong, Zhen Han, Zhen Han, Hua‐Li Liu, Hua‐Li Liu, Shuang‐Quan Zang

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  27. Interplay of Phonon Directionality and Emission Polarization in Two-Dimensional Layered Metal Halide Perovskites

    Accounts of Chemical Research · 2024-08-21

    Roman Krahne, Miao‐Ling Lin, Ping‐Heng Tan

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  28. Phonon Directionality Impacts Electron–Phonon Coupling and Polarization of the Band-Edge Emission in Two-Dimensional Metal Halide Perovskites

    Nano Letters · 2024-08-22

    Roman Krahne, Alexander Schleusener, Mehrdad Faraji, Linhan Li, Miao‐Ling Lin, Ping‐Heng Tan

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  29. Biological metasurfaces based on tailored Luria Bertani Agar growth medium formulations for photonic applications

    Materials Horizons · 2024-10-29

    Francesca Leone, Olga Favale, Mauro Daniel Luigi Bruno, Roberto Bartolino, Ferdinanda Annesi, Vincenzo Caligiuri, Antonio De Luca

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  30. Direct Crystallographic Observation of Obvious Structural Deformation in a Lead Halide Framework Induced by Host–Guest Interactions

    Advanced Functional Materials · 2024-12-23

    Xinfeng Chen, Quanzheng Deng, Shi Wang, Yichong Chen, Yukong Li, Wenyan Dan, Yang Liu, Yi‐nan Wu, Lu Han, Honghan Fei

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  31. Selective Growth of FAPbBr3 Nanocrystals with Precisely Tailored Optical Properties for Advanced Optoelectronic Applications

    ACS Applied Nano Materials · 2025-03-10

    C. Meric Guvenc, Nahit Polat, Tugce A. Arica, Sinan Balci

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  32. Revealing the True Nature of Double‐Peak Emission in 2D Perovskite Single Crystals Using Polariton Waveguides

    Advanced Optical Materials · 2025-06-13

    Annalisa Coriolano, Anna Moliterni, Francesco Todisco, Laura Polimeno, Rosanna Mastria, Vincent Oliéric, Carlotta Giacobbe, Milena De Giorgi, Dario Ballarini, Aurora Rizzo, Giuseppe Gigli, Cinzia Giannini, Ilenia Viola, D. Sanvitto, Luisa De Marco

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  33. Controlling Energy Flow in Perovskite Heterostructures Through Dimensionality and Phase Engineering

    Advanced Science · 2025-06-20

    Danila A. Tatarinov, Alexander Schleusener, Roman Krahne

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  34. Direct Growth of Rectangular 2D Layered Metal‐Halide Perovskite Microcrystal Photonic Cavities on Functional Substrates

    Advanced Optical Materials · 2025-07-24

    Martina Borreani, Sudhir Kumar Saini, Alexander Schleusener, Roman Krahne

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  35. Structural Tuning of Layered Perovskites for Enhanced Broadband Emission at Room Temperature

    Small Structures · 2025-09-12

    Aarya Prabhakaran, Quentin Evrard, Danilo Marchetti, Sirous Khabbaz Abkenar, Luiz Gustavo Bonato, Balaji Dhanabalan, Iryna Andrusenko, Simone Lauciello, Pavlo Solokha, Serena DE NEGRI, Luca Goldoni, Moussa D. Faye Diouf, Liberato Manna, Giorgio Divitini, Mauro Gemmi, Milena P. Arciniegas

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  36. Extended Dual-Functional Engineering for High-Performance 2D Dion–Jacobson CsPbI 3 Perovskite Solar Cells with Enhanced Stability

    Chemistry of Materials · 2026-01-06

    Fuwei Shang, Youkui Xu, Feifei Chai, Xiushan Wang, Xingxuan Zuo, Mengge Zhao, Lin Zheng, Zhenhua Li, Zhun Yao

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  37. Pressure-induced enhancement of deep-blue photoluminescence in two-dimensional hybrid organic-inorganic perovskites

    Physical Review Applied · 2026-03-09

    Wei Wang, Xuening Sun, Tieshan Yang, Mengmeng Jiao, Chuanlu Yang, Kai Wang, Defang Duan, Qinfeng Xu

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  38. Harnessing Metal-Halide Layered Perovskite Structures for Next-Generation Lighting Sources

    Accounts of Materials Research · 2026-04-01

    Balaji Dhanabalan, Milena P. Arciniegas

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  39. Programming Structural Symmetry and Emission in Low‐Dimensional Hybrid Perovskites via Time and Temperature

    Advanced Science · 2026-07-23

    Luiz Gustavo Bonato, Sirous Khabbaz Abkenar, Balaji Dhanabalan, Quentin Evrard, Luca Goldoni, Sergio Marras, Giorgio Divitini, Milena P. Arciniegas

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  40. Deterministic Nucleation of Nanocrystal Superlattices on 2D Perovskites for Light‐Funneling Heterostructures

    Advanced Materials · 2026-08-06

    Umberto Filippi, Alexander Schleusener, Simone Lauciello, Roman Krahne, Dmitry Baranov, Liberato Manna, Masaru K. Kuno

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