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RESEARCH PAPER · Coordination Chemistry Reviews · 2021

Band gap engineering of metal-organic frameworks for solar fuel productions

Xiangyang Guo, Lifang Liu, Yu Xiao, Yu Qi, Chunying Duan, Fuxiang Zhang

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Band gap engineering of metal-organic frameworks for solar fuel productionsOriginalUNITCENTRE PLANS CONTAINER TERMINAL ON THE MAASVLAKTE.0Current Trends and Approaches to Boost the Performance of Metal Organic Frameworks for Carbon Dioxide Methanation through Photo/Thermal Hydrogenation: A Review54Band-Gap Engineering: A New Tool for Tailoring the Activity of Semiconducting Oxide Catalysts for CO Oxidation39Nanomaterials for Fuel Production0A Novel Cerium(IV)‐Based Metal‐Organic Framework for CO2 Chemical Fixation and Photocatalytic Overall Water Splitting37Eight semiconducting MOFs constructed with conjugated ligands and d-metals (Cd, Zn, Co and Ni) serve as functional materials for oxygen evolution reactions, photocatalytic degradation of dyes and photoluminescence6Irmof-3/Go/Cufe2o4 Nanostructure: A Reusable and Efficient Nanocatalyst for the Preparation of Substituted Pyridines and Hydroquinolones0M Ultifunctional Mn(Ii) M Etal- O Rganic F Ramework for Photocatalytic Aerobic Oxidation and C-H Direct Trifluoromethylation0Photocatalytic Water Splitting for Hydrogen Production※14Recent advances on cobalt metal organic frameworks (MOFs) for photocatalytic CO2 reduction to renewable energy and fuels: A review on current progress and future directions139Water-Stable Nickel Metal–Organic Framework Nanobelts for Cocatalyst-Free Photocatalytic Water Splitting to Produce Hydrogen229Trans–Cis Kinetic Study of Azobenzene-4,4′-dicarboxylic Acid and Aluminium and Zirconium Based Azobenzene-4,4′-dicarboxylate MOFs10Enhancing the performance of Dye-Sensitized Solar cells by Co2+ Doping in MOF derived TiO24Advances and challenges of MOF derived carbon-based electrocatalysts and photocatalyst for water splitting: A review83Graph neural network predictions of metal organic framework CO 2 adsorption properties92Visible-Light-Driven Production of Solar Fuels Catalyzed by Nanosized Porphyrin-Based Metal–Organic Frameworks and Covalent–Organic Frameworks: A Review59Donor–Acceptor Hybrid Heterostructures: An Emerging Class of Photoactive Materials with Inorganic and Organic Semiconductive Components55Enhanced 4-chlorophenol Degradation under Visible and Solar Radiation through TiO2/g-C3N4 Z-Scheme Heterojunction4Uncovering the Nature of Band Gap Engineering of Adsorption Energy by Elucidating an Adsorbate Bonding Mechanism on Two-Dimensional TiO2(110)8MOF‐Based Chemiresistive Gas Sensors: Toward New Functionalities409Multifunctional Mn(II) Metal-Organic framework for photocatalytic aerobic oxidation and C H direct trifluoromethylation32Rational design of TiO2/MnMoO4/MoO3 nanocomposites: Visible-light-promoted photocatalysts for decomposition of tetracycline with tandem n-n heterojunctions19Selective and moisture-sensitive degradation of bromocresol green for isostructural MOFs assembled with D-camphorate and bipyridine0Artificial and Semi‐artificial Photosynthesis ( AP and SAP ) Systems Based on Metal‐Organic Frameworks15Synthesis and Characterization of Heat-Tempered Cu2Zn0.6Ca0.4SnS4 Alloy Thin Film0Exploring Deep Learning for Metalloporphyrins: Databases, Molecular Representations, and Model Architectures7Advanced energy materials: Current trends and challenges in electro- and photo-catalysts for H2O splitting26A State-of-the-Art of Metal-Organic Frameworks for Chromium Photoreduction vs. Photocatalytic Water Remediation24Turning CO2 into Fuels and Chemicals: An Introduction0Band-gap engineering of ceramic coatings3Computational modeling guided design of metal–organic frameworks for photocatalysis – a mini review10Cu-Fe Bimetallic Mof Enhanced Selectivity of Photocatalytic Co2 Reduction for Product Co0Cu–Fe bimetallic MOF enhances the selectivity of photocatalytic CO 2 reduction toward CO production39Metal‐Organic Frameworks for Photocatalytic Water Splitting and CO 2 Reduction69Metal‐Organic Frameworks for Photocatalytic Water Splitting and CO2 Reduction414Facile Energy Gap Tuning in Nanographene-MOFs0Role of Linear Defects on the Electronic, Transport, and Thermoelectric Properties of Armchair Edge Silicene Nanoribbons15Elucidating d- π conjugated two-dimensional 2,3,6,7,10,11-hexahydroxytriphenylene based conductive metal-organic framework for hybrid supercapacitors11In situ construction of cyano-modified g-C3N4 nanolayer-coated SrTiO3 nanotubes by gas-solid reaction for efficient photocatalytic solar fuel production35An efficient protocol for the synthesis of pyridines and hydroquinolones using IRMOF-3/GO/CuFe2O4 composite as a magnetically separable heterogeneous catalyst3A Calix[4]resorcinarene-Copper(II) Based Supramolecular Nanocapsule with Encapsulated Polyoxometalates for Enhanced Photocatalytic Activity15netDFT: JAVA Density Functional Theory for solid0Effect of drying temperature and drying time on the crystallinity degree of Zn(II)-tartrate complex4Band Gap Engineering of MOF-801 via Loading of γ-Fe2O3 Quantum Dots Inside It as a Visible Light-Responsive Photocatalyst for Degradation of Acid Orange 721Effect of Vertical Magnetic Field on the Electronic and Transport Properties of Armchair Silicene Nanoribbons0A new mixed-linker Fe-MOF as a multifunctional bio-photocatalyst for tandem photo-oxidation condensation reaction15Facile Optical Gap Tuning in Nanographene Metal–Organic Frameworks4Heterostructured Ag@MOF-801/MIL-88A(Fe) Nanocomposite as a Biocompatible Photocatalyst for Degradation of Reactive Black 5 under Visible Light31Fluorinated Metal–Organic Frameworks with Dual-Functionalized Linkers to Enhance Photocatalytic H2 Evolution and High Water Adsorption98Facile construction of tourmaline@MOFs composites via micron-scale electrical polarization to enhance photodegradation of gaseous formaldehyde27Cu(I)-4,4′-bipyridine coordination polymer for photocatalytic H2 generation9Dissecting the Water Uptake Behavior of Metal–Organic Frameworks Using Their Isolated Linkers and Metal Nodes10Host-guest interactions between gaseous iodine and MOF materials : exploring dynamics and reactivity0Aqueous syntheses of anthracene-based mixed-ligand coordination polymers and their structural and optical properties4Enhanced photocatalytic CO 2 reduction using a trimetallic organic framework as the catalyst under visible light8Metalation of metal–organic frameworks: fundamentals and applications250Selective anchoring of Pt NPs on covalent triazine-based frameworks via in situ derived bridging ligands for boosting photocatalytic hydrogen evolution5Terahertz spectroscopy of MOFs reveals dynamic structure and contact free ultrafast photoconductivity16Multifunctional In-MOF and Its S-Scheme Heterojunction toward Pollutant Decontamination via Fluorescence Detection, Physical Adsorption, and Photocatalytic REDOX53MOFs materials as photocatalysts for CO2 reduction: Progress, challenges and perspectives69Stimuli-responsive coordination polymers toward next-generation smart materials and devices97Metal‐organic Frameworks in Semiconductor Devices89Metal‐organic Frameworks in Semiconductor Devices7Solar-Driven Ammonia Production through Engineering of the Electronic Structure of a Zr-Based MOF12Semimetallic Bismuthene with Edge‐Rich Dangling Bonds: Broad‐Spectrum‐Driven and Edge‐Confined Electron Enhancement Boosting CO2 Hydrogenation Reduction77Band gap analysis in MOF materials: Distinguishing direct and indirect transitions using UV–vis spectroscopy189Bioinspired Photoactive Cu–Halide Coordination Polymers for Reduction Activation and Oxygen Conversion5Laser Processing of Emerging Nanomaterials for Optoelectronics and Photocatalysis27Water‐Stable High‐Entropy Metal‐Organic Framework Nanosheets for Photocatalytic Hydrogen Production127Black Ultrathin Single‐Crystalline Flakes of CuVP 2 S 6 and CuCrP 2 S 6 for Near‐Infrared‐Driven Photocatalytic Hydrogen Evolution31Direct Use of Copper Slag as Photocatalytic Material for Solar Hydrogen Production2Structural crystal engineering for energy: Unleashing the potential of metal-organic frameworks for photocatalytic reduction of carbon dioxide11Sustainability and photocatalytic performance of MOFs: Synthesis strategies and structural insights43Structural, optical and photoelectric properties of magnesium phthalocyanine − 1,4-benzenedicarboxylate blend with various thicknesses for photodiode applications3Band Structure Engineering in 2D Metal–Organic Frameworks25A review of novel materials for nano-photocatalytic and optoelectronic applications: Recent perspectives, water splitting and environmental remediation42Metal-Organic Frameworks (MOFs) as an Anti-Reflective Coating for Crystalline Silicon Solar Cells4Band gap effect of TiO2 on supported Ru single-atom catalysts for CO2 methanation by DFT calculations4Studying the properties of green synthesized silver oxide nanoparticles in the application of organic dye degradation under visible light51Contribution of Copper Slag to Water Treatment and Hydrogen Production by Photocatalytic Mechanisms in Aqueous Solutions: A Mini Review6DFT-Based Mechanistic Exploration and Application in Photocatalytic Heterojunctions47Emerging metal-organic framework-based photocatalysts for solar-driven fuel production62Self-sensitization-induced protonation sites for weak-light-driven hydrogen evolution in coordination polymers4The photocatalytic hydrogen production performance of porous titanium dioxide, a derivative of Mil-125 (Ti), improved by using lignin-based carbon quantum2Computational Modeling of Reticular Materials: The Past, the Present, and the Future243D hierarchical rare-earth metal composite nanofiber membranes for highly durable and efficient photodegradations of organic pollutants17Design and fabrication of nanoarchitectures of rGO-decorated ZnCo2O4 hybrid photocatalyst for high-efficiency solar fuel generation52Metal–organic frameworks built from a carborane linker isolating ideal one-dimensional large-spin chains of Co ( S = 3/2) or Ni ( S = 1)4MOFs-based S-scheme heterojunction photocatalysts: Challenges and prospects to break the selectivity limitation forintensified C1 products in CO2 photoreduction128Band Gap Engineering, Dark Conductivity, and Photoconductive Properties of Semiconductive Self-Assembled Rhenium Nanotube by Structural Topology Modification63D-Printed photocatalysts for revolutionizing catalytic conversion of solar to chemical energy62A review on hydrogen production using decorated metal-organic frameworks by electrocatalytic and photocatalytic water splitting29Fabrication of MOF-derived Ce–Cu nanofibers for ameliorating photo-catalytic properties2Balancing the photoactive center and reactive center tandem in Cu/La bimetallic site metal−organic frameworks for boosted photocatalytic CO2-to-CO reduction6Defect engineering and auxochrome group co-assisted hierarchical mesoporous MIL-Fe/NH2-D(x) of a full-spectrum solar-light-response for enhanced rehabilitation of water5Substrate Stabilized Charge Transfer Scheme In Coverage Controlled 2D Metal Organic Frameworks7Recent avenues in the photocatalytic splitting of water for eco-friendly hydrogen production32Coupling Water Oxidation and Oxygen Reduction for Photocatalytic H 2 O 2 Production over ZnIn 2 S 4 /UiO66-NH 2 Heterojunctions via Dual Channel Pathways31Boosting Electrocatalytic Activity of Bimetallic CoNi‐MOF for OER and HER Through a Synergistic Bimetallic Approach41DFT-Driven Approaches to Optimizing Small Bandgap Doping Structures: A Brief Review5Topological Design of Pyrene‐Based Metal‐Organic Framework Nanosheets as a Luminescent Thermometer for Live Bioimaging11Dimensional Control and Optical Properties of Tunable Silver Coordination Polymers via Nanocluster Assembly6Solar-driven nanocatalysts for CO2 upcycling: the structure-performance correlation13Two functionalized metal-organic frameworks with multiple hydrogen-bond donors as SALDI-TOF-MS matrix for sensitive and rapid determination of pesticides1Recent advances in photocatalytic HER based on zirconium-containing MOFs over the past three years1Comprehensive Investigation of High-Performance Green-Synthesized NaTi2(PO4)3 Nanocomposites for Advanced Electrochemical Energy Storage Applications0Crystal growth by chemical vapor transport method and photoelectric properties of SnS, Sn2S3, SnS24Pulsed laser-assisted solid-state annealing method synthesised Au@S,O-GCN photocatalyst for efficient photocatalytic degradation of rose bengal dye1Advancing CO 2 Upgrading to Multicarbon Products: Synergies Between Photo/Electrochemical and Biological Conversion12Metal–Organic Framework (MOF)-Based Catalysts for Sustainable Energy Technologies: A Review53Revealing the Character of Coordination Bonding in 2D Metal–Organic Frameworks11Metal–Organic Frameworks for Photocatalytic CO 2 Reduction: Progress and Prospects30Metal–organic frameworks for photocatalytic water splitting0Polarization-Driven Catalytic Mechanisms in Ferroelectric Materials for Wastewater Treatment: A Review0Trimetallic metal–organic frameworks for CO 2 reduction reactions0Unraveling the Role of Manganese in Enhancing Ni/TiO 2 Catalysts for Photothermal CO 2 Methanation1Performance of CuTiO3 Photocatalytic Oxidation for Treating Organic Peroxide Production Wastewater Under Visible Light1Construction of Ag‐ NH 2 ‐ UiO ‐66 composites with boosted photocatalytic activity for the removal of contaminants0Band‐Gap Engineering of Isoreticular Hydrogen‐Bonded Organic Frameworks for Boosting Photocatalytic Hydrogen Evolution12Band‐Gap Engineering of Isoreticular Hydrogen‐Bonded Organic Frameworks for Boosting Photocatalytic Hydrogen Evolution2Enhancing CO2-to-CO conversion over B-Cd Co-doped TiO2 through band structure tuning and photothermal synergy2White‐Light Emission in Zeolitic Imidazolate Framework Glasses4Nonlinear optical modulation and ultrafast dynamics of Fe-BTC in a 2 μm thulium-holmium fiber laser0Photocatalytic CO2 reduction using metal-organic frameworks: Recent advances, challenges and machine learning based future perspectives0Single Ni Atoms Drive Carboxyl Deprotonation in Metal–Organic Chains2Metal-organic frameworks for catalytic degradation of emerging dye contaminants in wastewater: A critical review of material design, reaction mechanisms, and engineering application11Advances in Photocatalytic Materials for Organic Pollutant Degradation: From Perovskite Oxides to Perovskite@MOF Composites0Synthesis of samarium-MOFs and their application for photocatalytic hydrogen production with Box-Behnken response surface methodology for performance optimization0APTES-assisted interface engineering of ZnIn2S4/g-C3N4 heterojunctions for optimized charge transfer and PFBA photocatalytic degradation0Synergistic Modulation of the Bandgap and Electrochemical Properties of HKUST-1 via Curcumin Infiltration0Tailorable metal-organic frameworks for combating ice accretion: from molecular design to interfacial engineering0Cu-BDC·DMF/Zn-BDC MOF composite photoanodes for photo-assisted hydrogen generation in saline electrolyte0Metal-organic framework scintillators: mechanisms, design strategies and perspectives0Postoxidation of Zr-MOFs for Gas–Solid Photocatalytic Reduction of Dilute CO20Engineering MOF-based photocatalysts for hexavalent chromium reduction: mechanistic insights and performance optimization0Advanced MOFs-based materials as platforms for carbon dioxide capture and simultaneous photocatalytic conversion0Beyond composition: Local metal mixing controls the electronic structure of metal–organic frameworks0Built-in electric field regulated direct S-scheme BiVO4/Er–B–TiO2 heterojunction for enhanced visible-light photocatalytic hydrogen evolution: From interfacial charge transfer to process feasibility0

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