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RESEARCH PAPER · Batteries & Supercaps · 2021

Through the Maze of Multivalent‐Ion Batteries: A Critical Review on the Status of the Research on Cathode Materials for Mg 2+ and Ca 2+ Ions Insertion

Fabio Maroni, Saustin Dongmo, Cornelius Gauckler, Mario Marinaro, Margret Wohlfahrt‐Mehrens

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Through the Maze of Multivalent‐Ion Batteries: A Critical Review on the Status of the Research on Cathode Materials for Mg 2+ and Ca 2+ Ions InsertionOriginalDescriptor and scaling relations for ion mobility in crystalline solids0The mystery and promise of multivalent metal-ion batteries44Layered Iron Vanadate as a High-Capacity Cathode Material for Nonaqueous Calcium-Ion Batteries40Exploring the electrochemical properties of Na2S -V2O5-P2O5 glass-ceramic nanocomposites as a cathode for magnesium-ion batteries22On the Electrochemical Insertion of Mg 2+ in Na 7 V 4 (P 2 O 7 ) 4 (PO 4 ) and Na 3 V 2 (PO 4 ) 3 Host Materials11Exploring the Insertion Properties of Mg2+ in H2v3o8 as a Function of the Water Content in the Organic Electrolyte12Descriptor and Scaling Relations for Ion Mobility in Crystalline Solids37Revisiting the Chevrel Phase: Impact of Dispersion Corrections on the Properties of Mo6S8 for Cathode Applications**16A Novel and Highly Efficient Indolyl‐Based Electrolyte for Mg Batteries7Cathodes for Mg batteries: A condensed review13Microstructure, electrical, optical and electrochemical characteristics of silver phosphate glasses cathode for magnesium battery applications28Pre‐intercalation Strategies to Layered Vanadium‐based Electrode Materials for Aqueous Zinc Batteries37Roadmap for a sustainable circular economy in lithium-ion and future battery technologies136AMOEBA Polarizable Force Field for Molecular Dynamics Simulations of Glyme Solvents14Structural, Morphological and Interfacial Investigation of H2V3O8 upon Mg2+ Intercalation3Sodium Insertion into Fe[Fe(CN)6] Framework Prepared by Microwave‐Assisted Co‐Precipitation17Experimental and Computational Aspects of Electrochemical Reflection Anisotropy Spectroscopy: A Review13Assessing n‐type organic materials for lithium batteries: A techno‐economic review36Impact of water on structure stabilization in layered manganese-oxide for high-voltage zinc storage in non-aqueous electrolyte: Experimental and theoretical aspects4Computational Screening of Oxide Perovskites as Insertion‐Type Cathode Material6A review of metal sulfide cathode materials for non-aqueous multivalent ion (Mg2+, Ca2+, Al3+) batteries19State-of-the-art design of cathodes of multivalent batteries by electrospinning: A mini review on opportunities and challenges8Cost and performance analysis as a valuable tool for battery material research75Modification of Layered Cathodes of Sodium-Ion Batteries with Conducting Polymers11Revealing Dynamic Evolution of the Anode‐Electrolyte Interphase in All‐Solid‐State Batteries with Excellent Cyclability14Nucleation Mechanisms of Electrodeposited Magnesium on Metal Substrates7Porous Azatruxene Covalent Organic Frameworks for Anion Insertion in Battery Cells34Desalination performance in versatile capacitive/battery deionization configurations using a cation intercalating electrode13Direct Spectroscopic Observation of Ultraslow Ion Desolvation at an Interface4Progress and Challenges of Vanadium Oxide Cathodes for Rechargeable Magnesium Batteries17Assessing Correlations between Phonon Features and Cation Migration Barriers in Multivalent Solid Electrolytes8Modification of Lithium‐Rich Manganese Oxide Materials: Coating, Doping and Single Crystallization13NaMoO2PO4 glass ceramic nanocomposite as a novel cathode material for magnesium-ion batteries4Interlayer expansion of kinetically grown molybdenum oxide for Mg batteries with enhanced energy density10Ca Mobility in NASICON Battery Materials Studied from First-Principles0Multivalent Ion Mobility in Layered NbS2 and NbSe2 Structures with Trigonal Prismatic Transition Metal Coordination3Electrodeposition Chemistry Toward High‐Safety and High‐Energy‐Density Rechargeable Multivalent Ion Batteries16An efficient route to prepare ultrathin calcium vanadate (CaV8O20) nanobelts for solid-state supercapacitor application5Self-Supporting Quasi-1D TaS3 Nanofiber Films with Dual Cationic/Anionic Redox for High-Performance Mg–Li Hybrid Ion Batteries1Copper fluoride electrode for aluminum rechargeable battery with optimized electrolyte, conductive material, binder, and mixing method of electrode material0Theoretical Investigation of Ca2+ Intercalation in WS2 as a Negative Electrode Material for Calcium-Ion Batteries: Supported by Experimental Evaluation0Employing S(-I)/S(-II) Redox Chemistry in Quasi-1D Niobium Trisulfide-Graphene Cathodes for High-Capacity Magnesium–Lithium Hybrid Ion Batteries3High Performance of a Hybrid K Ion/Al Ion Graphene-Boosted Hexacyanoferrate-Based Aqueous Battery0Stable calcium metal batteries enabled by ionic covalent organic framework artificial protection layers2Relationship between corrosion behavior and Ca diffusion of anorthite-mullite saggar during calcination of Li-ion cathode materials0Tuning interlayer water content for optimized stability and mechanistic insights in bilayered V2O5∙nH2O cathode material for Zinc (Magnesium)-ion batteries: A DFT and AIMD study1Atomistic and electronic insights into Ca2+ and Li+ intercalation in TiS2: a first-principles approach supported by electrochemical validation1Vanadium-doped CuO–lithium phosphate glass as high-capacity amorphous cathodes for magnesium-ion batteries0Defect‐Mediated Mg 2+ Transport and Structural Stability in the Sulfide Cathodes for Rechargeable Magnesium Batteries0

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  2. The mystery and promise of multivalent metal-ion batteries

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  3. Layered Iron Vanadate as a High-Capacity Cathode Material for Nonaqueous Calcium-Ion Batteries

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  4. Exploring the electrochemical properties of Na2S -V2O5-P2O5 glass-ceramic nanocomposites as a cathode for magnesium-ion batteries

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  5. On the Electrochemical Insertion of Mg 2+ in Na 7 V 4 (P 2 O 7 ) 4 (PO 4 ) and Na 3 V 2 (PO 4 ) 3 Host Materials

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  6. Exploring the Insertion Properties of Mg2+ in H2v3o8 as a Function of the Water Content in the Organic Electrolyte

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  7. Descriptor and Scaling Relations for Ion Mobility in Crystalline Solids

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  8. Revisiting the Chevrel Phase: Impact of Dispersion Corrections on the Properties of Mo6S8 for Cathode Applications**

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  9. A Novel and Highly Efficient Indolyl‐Based Electrolyte for Mg Batteries

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  10. Cathodes for Mg batteries: A condensed review

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  11. Microstructure, electrical, optical and electrochemical characteristics of silver phosphate glasses cathode for magnesium battery applications

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  12. Pre‐intercalation Strategies to Layered Vanadium‐based Electrode Materials for Aqueous Zinc Batteries

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  13. Roadmap for a sustainable circular economy in lithium-ion and future battery technologies

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  14. AMOEBA Polarizable Force Field for Molecular Dynamics Simulations of Glyme Solvents

    Journal of Chemical Theory and Computation · 2023-01-24

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  15. Structural, Morphological and Interfacial Investigation of H2V3O8 upon Mg2+ Intercalation

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    Yuri Surace, Martina Romio, Marco Amores, Raad Hamid, Damian Marlon Cupid, Markus Sauer, Annette Foelske, Marcus Jahn

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  16. Sodium Insertion into Fe[Fe(CN)6] Framework Prepared by Microwave‐Assisted Co‐Precipitation

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  17. Experimental and Computational Aspects of Electrochemical Reflection Anisotropy Spectroscopy: A Review

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  18. Assessing n‐type organic materials for lithium batteries: A techno‐economic review

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  19. Impact of water on structure stabilization in layered manganese-oxide for high-voltage zinc storage in non-aqueous electrolyte: Experimental and theoretical aspects

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  20. Computational Screening of Oxide Perovskites as Insertion‐Type Cathode Material

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  21. A review of metal sulfide cathode materials for non-aqueous multivalent ion (Mg2+, Ca2+, Al3+) batteries

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  22. State-of-the-art design of cathodes of multivalent batteries by electrospinning: A mini review on opportunities and challenges

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  23. Cost and performance analysis as a valuable tool for battery material research

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  26. Nucleation Mechanisms of Electrodeposited Magnesium on Metal Substrates

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  27. Porous Azatruxene Covalent Organic Frameworks for Anion Insertion in Battery Cells

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  32. Modification of Lithium‐Rich Manganese Oxide Materials: Coating, Doping and Single Crystallization

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  33. NaMoO2PO4 glass ceramic nanocomposite as a novel cathode material for magnesium-ion batteries

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  34. Interlayer expansion of kinetically grown molybdenum oxide for Mg batteries with enhanced energy density

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