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Papers citing Arresting Elevated-Temperature Creep and Achieving Full Cross-Link Density Recovery in Reprocessable Polymer Networks and Network Composites via Nitroxide-Mediated Dynamic Chemistry

  1. Multiscale experimental characterisation of mode-I interfacial fracture behaviour of vitrimer composites

    Materials & Design · 2023-08-09

    Heshan Bai, Ruixiang Bai, Tianyu Zhao, Zhenkun Lei, Qian Li, Cheng Yan, Xiang Hong, Chen Liu

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  2. Improving the Recyclability of an Epoxy Resin through the Addition of New Biobased Vitrimer

    Polymers · 2023-09-12

    Antonio Veloso, Leire Ruiz‐Rubio, Imanol Yugueros, Isabel Moreno, José Manuel Laza, José Luis Vilas‐Vilela

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  3. Recent Progress on the 3D Printing of Dynamically Cross‐Linked Polymers

    Advanced Functional Materials · 2023-09-28

    Yunchao Jia, Haodi Xie, Jingjing Qian, Yueshuai Zhang, Hongjuan Zheng, Fengchun Wei, Yilong Li, Zhiwei Zhao

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  4. Polybenzoxazine-based covalent adaptable networks: A mini-review

    Polymer · 2023-10-25

    Antoine Adjaoud, Laura Puchot, Pierre Verge

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  5. A weak but inert hindered urethane bond for high-performance dynamic polyurethane polymers

    Chinese Chemical Letters · 2023-11-17

    Fangzhou Wang, Wentong Gao, Cheng‐Hui Li

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  6. Length effect of crosslinkers on the mechanical properties and dimensional stability of vitrimer elastomers with inhomogeneous networks

    Polymer · 2023-12-02

    Mei-Juan Xie, Chang-Cheng Wang, Rong Zhang, Jian Cao, Maozhu Tang, Yun‐Xiang Xu

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  7. Covalent adaptable networks and thermosets of multi-block ethylene/1-octene copolymers made by free-radical processing: Effects of melt flow index and crystallinity on thermomechanical properties and reprocessability

    European Polymer Journal · 2023-12-05

    Logan M. Fenimore, Boran Chen, Yixuan Chen, Stephanie M. Barbon, Hayley A. Brown, Evelyn Auyeung, Colin Li Pi Shan, John M. Torkelson

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  8. Reprocessable Biobased Statistical and Block Copolymer Methacrylic-Based Vitrimers with a Shape Memory Effect

    ACS Applied Polymer Materials · 2023-12-16

    Farhad Asempour, Eline Laurent, Yvan Ecochard, Milan Marić

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  9. Biobased Vitrimeric Epoxy Networks

    Macromolecular Materials and Engineering · 2023-12-24

    Marco Sangermano, Matteo Bergoglio, Sandra Schögl

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  10. Critical effect of exchangeable units distribution on properties of vitrimers: Quantitatively controlling dynamics thus suppressing creep

    Polymer · 2023-12-28

    Jian Cao, Mei-Juan Xie, Ying Yang, Yu Zou, Shiqi Li, Rong Zhang, Maozhu Tang, Xiancheng Ren, Yun‐Xiang Xu

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  11. Increasing the Cross-Link Density in a Dual Dissociative and Associative Polythiourethane Covalent Adaptable Network Improves Both Creep Resistance and Extrudability

    Polymer · 2024-01-01

    Sergio Serna, Nathan S. Purwanto, Logan M. Fenimore, John M. Torkelson

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  12. Multi-network Systems Including Dynamic and Static Covalent Bonds “Coexistence between Thermoplasticity and Creep Resistance” 3 Ionic Bond・Dynamic Covalent Bond

    NIPPON GOMU KYOKAISHI · 2024-01-01

    Keisuke Chino

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  13. Rheological and Mechanical Comparison of Di and Tri-Block Copolymer Vitrimers Using Dynamic Imine Exchange

    SSRN Electronic Journal · 2024-01-01

    Farhad Asempour, Eline Laurent, Theo Bride, Milan Marić

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  14. State-of-the-art epoxy vitrimer nanocomposites with graphene, carbon nanotube and silica—fundamentals and applications (radiation shielding, sensing and corrosion resistance)

    Journal of Plastic Film & Sheeting · 2024-01-04

    Ayesha Kausar, Ishaq Ahmad

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  15. Multi-network systems in elastomers using dynamic bonds and static covalent bonds “Coexistence between thermoplasticity and heat resistance”

    Polymer · 2024-03-04

    Keisuke Chino

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  16. Covalent Adaptable Networks Made by Reactive Processing of Highly Entangled Polymer: Synthesis-Structure-Thermomechanical Property-Reprocessing Relationship in Covalent Adaptable Networks

    Macromolecules · 2024-03-06

    Logan M. Fenimore, Mathew J. Suazo, John M. Torkelson

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  17. Investigating Dynamic Changes in 3D‐Printed Covalent Adaptable Polymer Networks

    Macromolecular Materials and Engineering · 2024-03-10

    Yixuan Jia, Christoph Alexander Spiegel, Juliane Diehm, Daniel Zimmermann, Birgit Huber, Hatice Mutlu, Matthias Franzreb, Manfred Wilhelm, Patrick Théato, Eva Blasco, Manuel M. Tsotsalas

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  18. Catalyst‐Free α‐Acetyl Cinnamate/Acetoacetate Exchange to Enable High Creep‐Resistant Vitrimers

    Angewandte Chemie International Edition · 2024-03-16

    Hongzhi Feng, Sheng Wang, Jason Y. C. Lim, Bofan Li, Wendy Rusli, Feng Liu, Nikos Hadjichristidis, Zibiao Li, Jin Zhu

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  19. Catalyst‐Free α‐Acetyl Cinnamate/Acetoacetate Exchange to Enable High Creep‐Resistant Vitrimers

    Angewandte Chemie · 2024-03-16

    Hongzhi Feng, Sheng Wang, Jason Y. C. Lim, Bofan Li, Wendy Rusli, Feng Liu, Nikos Hadjichristidis, Zibiao Li, Jin Zhu

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  20. Investigation on UV-curing Reprocessable Thermosets Bearing Hindered Urea Bonds and Their Composites with Modified Zinc Oxide Nanoparticles

    Chinese Journal of Polymer Science · 2024-04-15

    Jun-Hao Zhou, Liming Tang

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  21. Poly(epoxy-imine) vitrimers. Effect of the structure on the stress relaxation and creep resistance

    Polymer Testing · 2024-05-22

    Tommaso Telatin, Silvia De la Flor, Àngels Serra, Xavier Montané

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  22. Reprocessable Polymer Networks Containing Sulfur‐Based, Percolated Dynamic Covalent Cross‐Links and Percolated or Non‐Percolated, Static Cross‐Links

    Macromolecular Rapid Communications · 2024-07-11

    Logan M. Fenimore, Mohammed A. Bin Rusayyis, Claire C. Onsager, M. Grayson, John M. Torkelson

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  23. Reprocessable Covalent Adaptable Networks via Free-Radical Polymerization with an Aromatic Disulfide Cross-Linker

    ACS Applied Polymer Materials · 2024-07-22

    Mathew J. Suazo, John M. Torkelson

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  24. Reprocessable, Self-Healing, and Creep-Resistant Covalent Adaptable Network Made from Chain-Growth Monomers with Dynamic Covalent Thionourethane and Disulfide Cross-Links

    ACS Macro Letters · 2024-08-16

    Tong Wang, Yixuan Chen, Boran Chen, Mathew J. Suazo, Nathan S. Purwanto, John M. Torkelson

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  25. Rheological and mechanical comparison of di-and tri-block copolymer imine vitrimers

    European Polymer Journal · 2024-08-31

    Farhad Asempour, Eline Laurent, Theo Bride, Milan Marić

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  26. Recent Advances in Vitrimers: A Detailed Study on the Synthesis, Properties and Applications of Bio-Vitrimers

    Journal of Polymers and the Environment · 2024-10-10

    Venkata Rao Madduluri, Anjaneyulu Bendi, Chinmay, Gaanty Pragas Maniam, Rasidi Roslan, Mohd Hasbi Ab. Rahim

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  27. Large‐scale Conformational Changes of Diindole Functional Groups Driven by Cation‐π Interactions and the Toughening Mechanism of Thermosets

    Macromolecular Rapid Communications · 2024-11-23

    Yuhan Qiao, Dongxin Li, Qianqian Liang, Ming Kang, Yewei Xu, Li Yang, Guanjun Chang

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  28. 3D Printing of Strong and Room-Temperature Reprocessable Silicone Vitrimers

    ACS Applied Materials & Interfaces · 2024-12-04

    Stefano Menasce, Rafael Libanori, Fergal B. Coulter, André R. Studart

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  29. Enabling the Reprocessability and Debonding of Epoxy Thermosets Using Dynamic Poly(β‐Amino Amide) Curing Agents

    Advanced Functional Materials · 2024-12-30

    Loc Tan Nguyen, Stephan Maes, Filip Du Prez

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  30. Exploring transamidation and chemical recycling of β-amino amide-derived covalent adaptable networks

    Polymer Chemistry · 2025-01-01

    Loc Tan Nguyen, Adithya Tharayil, Nezha Badi, Johan M. Winne, Filip Du Prez

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  31. Molecular Dynamics Simulation and Theoretical Analysis of Structural Relaxation, Bond Exchange Dynamics, and Glass Transition in Vitrimers

    Macromolecules · 2025-01-30

    Tsai-Wei Lin, Baicheng Mei, Sarit Dutta, Kenneth S. Schweizer, Charles E. Sing

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  32. Polypropylene Covalent Adaptable Networks with Full Cross-Link Density Recovery after Reprocessing: Development by Free-Radical Reactive Processing with Resonance-Stabilized, Aromatic Disulfide Cross-Linkers

    ACS Macro Letters · 2025-03-05

    Yen‐Wen Huang, Mathew J. Suazo, Stephanie M. Barbon, Hayley A. Brown, Evelyn Auyeung, Colin Li Pi Shan, John M. Torkelson

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  33. Reprocessable Polypropylene Covalent Adaptable Networks via Free-Radical Reactive Processing with Vinyl Aromatic Additives

    Macromolecules · 2025-04-23

    Yen‐Wen Huang, Mathew J. Suazo, John M. Torkelson

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  34. Catalyst-Free Polyhydroxyurethane Covalent Adaptable Networks Exhibiting Full Cross-Link Density Recovery after Reprocessing: Facilitation by Synthesis with Well-Designed Secondary Amines

    Macromolecules · 2025-05-09

    Yen‐Wen Huang, John M. Torkelson

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  35. Covalent Adaptable Networks with Associative Siloxane Exchange Enabled by Amide‐Based Internal Catalysis: Designing for Reprocessability and Extrudability by Increasing the Cross‐Link Density

    Advanced Functional Materials · 2025-05-09

    Nathan S. Purwanto, Tong Wang, Xiaoyang Liu, Linda J. Broadbelt, Tapas Debsharma, John M. Torkelson

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  36. Dynamic crosslinked elastomers and rubbers

    Progress in Materials Science · 2025-07-15

    Jing Bai, Baochun Guo, Ming Tian, Fei Chen, Liqun Zhang

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  37. Reprocessable and Highly Creep-Resistant Covalent Adaptable Networks Incorporating Azine Dynamic Cross-Links via Free-Radical Polymerization

    ACS Macro Letters · 2025-08-18

    Mathew J. Suazo, John M. Torkelson

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  38. Understanding Non-isothermal Crystallization Behaviors of Polyethylene-Derived Vitrimers

    Macromolecules · 2025-08-20

    Sara Valdez, Zhe Qiang

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  39. Recyclable Ethylene-Vinyl Acetate Covalent Adaptable Networks and Their Structure–Property Relationships

    Macromolecules · 2025-08-28

    Logan M. Fenimore, Mathew J. Suazo, Boran Chen, Stephanie M. Barbon, Hayley A. Brown, Evelyn Auyeung, Colin Li Pi Shan, John M. Torkelson

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  40. Propylene–Ethylene Copolymer Covalent Adaptable Networks Synthesized by Resonance‐Stabilized, Radical‐Based Reactive Processing with Excellent Elevated‐Temperature Creep Resistance

    ChemSusChem · 2025-08-30

    Yen‐Wen Huang, Mathew J. Suazo, Stephanie M. Barbon, Hayley A. Brown, Evelyn Auyeung, Colin Li Pi Shan, John M. Torkelson

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  41. From β-Dicarbonyl Chemistry to Dynamic Polymers

    Chemical Reviews · 2025-09-23

    Youwei Ma, Christoph Weder, Filip Du Prez, José Augusto Berrocal

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  42. Reprocessing and degradation capability of biobased epoxy vitrimer composites

    Elsevier eBooks · 2025-09-27

    Sukhila Krishnan, Sudheer Kumar, Karuppanan Prabakaran, Ananthakumar Ramadoss

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  43. A review on the formulation and performance of epoxidized vegetable oil-based vitrimer: stoichiometric calculations, curing agent functionalities and catalyst efficiency

    Royal Society Open Science · 2025-10-01

    Chuan Li Lee, Balkis Fatomer A. Bakar, Kit Ling Chin, Luqman Chuah Abdullah

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  44. Catalyst Influence on the Crystallization Behaviors and Mechanical Properties of Polyethylene Vitrimers

    Macromolecules · 2025-10-27

    Sara Valdez, Zhe Qiang

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  45. Creep-resistant, extrudable, and recyclable polyolefin covalent adaptable networks incorporating azine cross-links via reactive processing

    Polymer Chemistry · 2026-01-01

    Mathew J. Suazo, Stephanie M. Barbon, Hayley A. Brown, Evelyn Auyeung, Colin Li Pi Shan, Pi Shan, John M. Torkelson

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  46. Cross-Linker Selection Controls Glass Transition Elevation or Reduction in Dynamic Covalently Bonded Polymer Networks

    Macromolecules · 2026-01-13

    Baicheng Mei, Sirui Ge, Christopher M. Evans, Kenneth S. Schweizer

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  47. Covalent Adaptable Networks: Reprocessable Cross-Linked Polymers

    Chemical Reviews · 2026-01-16

    Molly Sun, Lillian M. Felsenthal, Subeen Kim, Elizabeth Y. Choi, Laura J. Reed, Benjamin R. Elling, William R. Dichtel

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  48. Vitrimer-enabled circularity through upcycling mixed polyolefin waste from milk packets into valuable 3D printing feedstock

    Communications Sustainability · 2026-03-19

    Indranil Dey, Ketaki Samanta, Tanay Debnath, Suryasarathi Bose

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  49. A tutorial review on designing pluripotent olefinic hybrids via covalent adaptable networks: integrating dynamic chemistry with machine‑learning

    Advanced Composites and Hybrid Materials · 2026-06-01

    Reshma Kailas Kumar, Chaoying Wan, Paresh Kumar Samantaray

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  50. Restricting chain mobility in semicrystalline polyethylene and polypropylene via dynamic covalent cross-links: Major effects on elevated-temperature creep, heat distortion temperature, and wear resistance

    Polymer · 2026-06-06

    Yen‐Wen Huang, Tobias V. Martin, Q. Jane Wang, S. Raziyeh Mohammadi, Ellen C. Lee, Xiaojiang Wang, John M. Torkelson

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