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RESEARCH PAPER · Nature Communications · 2021

2,2-difluorovinyl benzoates for diverse synthesis of gem-difluoroenol ethers by Ni-catalyzed cross-coupling reactions

Bingnan Du, Chun‐Ming Chan, Pui‐Yiu Lee, Leong‐Hung Cheung, Xin Hua Xu, Zhenyang Lin, Wing‐Yiu Yu

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2,2-difluorovinyl benzoates for diverse synthesis of gem-difluoroenol ethers by Ni-catalyzed cross-coupling reactionsOriginalVisible light-induced one-pot synthesis of CF 3 /CF 2 -substituted cyclobutene derivatives17Construction of gem-Difluoroenol Esters through Catalytic O-Selective Addition of Difluoroenoxysilanes to Ketenes15Fluoride-Triggered Synthesis of 1-Aryl-2,2-difluoroalkenes via Desilylative Defluorination of (1-Aryl)-2,2,2-trifluoroethyl-silanes10Synthesis of Difluoroalkenes from Thiocarbonyl Compounds via Difluorothiiranes: Electrophilic Counterpart to Wittig-Type Difluoromethylidenation4Access to gem-Difluoroalkenes via Organic Photoredox-Catalyzed gem-Difluoroallylation of Alkyl Iodides35Mechanistic views and computational studies on transition-metal-catalyzed reductive coupling reactions48Synthesis of gem-Difluoroalkenes through Nickel-Promoted Electrochemical Reductive Cross-Coupling15Cross‐Electrophile Coupling between Aryl/Vinyl Triflates and Vinyl Tosylates for the Synthesis of gem‐Difluoroalkenes via Ni/Pd Cooperative Catalysis8Direct gem‐Difluoroalkenylation of X−H Bonds with Trifluoromethyl Ketone N‐Triftosylhydrazones for Synthesis of Tetrasubstituted Heteroatomic gem‐Difluoroalkenes21Nickel-Catalyzed Cross-Electrophile Coupling Reactions between Allylic Acetates and gem-Difluorovinyl Tosylate9Stereospecific/stereoselective nickel catalyzed reductive cross-coupling: An efficient tool for the synthesis of biological active targeted molecules6Understanding the Organometallic Step: SO2 Insertion into Bi(III)−C(Ph) Bond8Visible-light photoredox-catalyzed coupling of alkylsulfones with α-(trifluoromethyl)styrenes3Identified Isosteric Replacements of Ligands’ Glycosyl Domain by Data Mining5Tunable Synthesis of Monofluoroalkenes and Gem‐Difluoroalkenes via Solvent‐Controlled Rhodium‐Catalyzed Arylation of 1‐Bromo‐2,2‐difluoroethylene14Tunable Synthesis of Monofluoroalkenes and Gem‐Difluoroalkenes via Solvent‐Controlled Rhodium‐Catalyzed Arylation of 1‐Bromo‐2,2‐difluoroethylene0Sulfonium-based precise alkyl transposition reactions22Morpholine-mediated defluorinative cycloaddition of gem -difluoroalkenes and organic azides1Photoredox Radical Truce–Smiles Rearrangement of N- Sulfinyl Acrylamides with Bromodifluoroacetamides25Difluoroenol phosphinates as difluoroenolate surrogates: synthesis and applications in defluorination and deoxygenative coupling7gem-Difluoroalkenylation of aldehydes and ketones with bis(difluoromethyl)triphenylphosphorane under operationally simple conditions3Diastereoselective synthesis of 5,5-Difluoroisoxazolidine via [3 + 2] cycloaddition between Nitrones and Difluoroacrylates3Mechanochemical Nickel-Catalyzed Dechlorination-Deuteration of Aryl Chlorides via Piezoelectric-Promoted Ar–Zn–X Intermediates11Ni-Catalyzed Distal-Selective gem-Difluorovinylation of Unactivated Alkenes with 2,2-Difluorovinyl Benzoates1Modular Synthesis of Diverse gem -Difluoroalkenes from Trifluoroacetic Anhydride via Phosphorus-Assisted Fluoride Elimination0Facile Synthesis of Gem-Difluoroalkene-Based Bis (silanes) via Copper-Catalyzed Disilylative Defluorination of 1-Chloro-1-trifluoromethylalkenes6Modelling damming effect on spatial flood conditions and its consequences on kharif crop0

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27 direct citing papers saved.

  1. Visible light-induced one-pot synthesis of CF 3 /CF 2 -substituted cyclobutene derivatives

    Chemical Communications · 2021-01-01

    Xiao Hu, Aishun Ding, Dawen Xu, Hao Chi Guo

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  2. Construction of gem-Difluoroenol Esters through Catalytic O-Selective Addition of Difluoroenoxysilanes to Ketenes

    The Journal of Organic Chemistry · 2021-05-17

    Yang Shi, Bo‐Wen Pan, Jun‐Xiong He, Ying Zhou, Jian Er Zhou, Jin‐Sheng Yu

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  3. Fluoride-Triggered Synthesis of 1-Aryl-2,2-difluoroalkenes via Desilylative Defluorination of (1-Aryl)-2,2,2-trifluoroethyl-silanes

    The Journal of Organic Chemistry · 2021-09-03

    Virginie Carreras, Thierry Ollevier

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  4. Synthesis of Difluoroalkenes from Thiocarbonyl Compounds via Difluorothiiranes: Electrophilic Counterpart to Wittig-Type Difluoromethylidenation

    Bulletin of the Chemical Society of Japan · 2021-09-16

    Kohei Fuchibe, Atsushi Yamada, Kosei Hachinohe, Kana Matsumoto, Ryo Takayama, Junji Ichikawa

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  5. Access to gem-Difluoroalkenes via Organic Photoredox-Catalyzed gem-Difluoroallylation of Alkyl Iodides

    The Journal of Organic Chemistry · 2021-12-29

    Songlin Yan, Weijie Yu, Jianye Zhang, Hongmei Fan, Zhi‐Feng Lu, Zhenming Zhang, Tao Wang

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  6. Mechanistic views and computational studies on transition-metal-catalyzed reductive coupling reactions

    Chemical Society Reviews · 2022-01-01

    Abing Duan, Fengjiao Xiao, Yu Lan, Linbin Niu

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  7. Synthesis of gem-Difluoroalkenes through Nickel-Promoted Electrochemical Reductive Cross-Coupling

    Chinese Journal of Organic Chemistry · 2022-01-01

    Zhe Chang, Jiaxin Wang, Xi Hong Lu, Yao Fu

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  8. Cross‐Electrophile Coupling between Aryl/Vinyl Triflates and Vinyl Tosylates for the Synthesis of gem‐Difluoroalkenes via Ni/Pd Cooperative Catalysis

    Advanced Synthesis & Catalysis · 2022-01-20

    Baojian Xiong, Yue Li, Jinyu Zhang, Jiangjun Liu, Xuemei Zhang, Zhong Lian

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  9. Direct gem‐Difluoroalkenylation of X−H Bonds with Trifluoromethyl Ketone N‐Triftosylhydrazones for Synthesis of Tetrasubstituted Heteroatomic gem‐Difluoroalkenes

    Chemistry - A European Journal · 2022-02-22

    Xinyu Zhang, Linxuan Li, Giuseppe Zanoni, Xin‐Yue Han, Xihe Bi

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  10. Nickel-Catalyzed Cross-Electrophile Coupling Reactions between Allylic Acetates and gem-Difluorovinyl Tosylate

    Organic Letters · 2022-05-05

    Xiaochun He, Jiangjun Liu, Gang Chen, Baojian Xiong, Xue Xiao, Lei Chen, Xuemei Zhang, Lin Dong, Xuelei Ma, Zhong Lian

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  11. Stereospecific/stereoselective nickel catalyzed reductive cross-coupling: An efficient tool for the synthesis of biological active targeted molecules

    Journal of Saudi Chemical Society · 2022-12-26

    Uzma Afzal, Muhammad Bılal, Muhammad Zubair, Nasır Rasool, Syed Adnan Alı Shah, Zainul Amiruddin Zakaria

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  12. Understanding the Organometallic Step: SO2 Insertion into Bi(III)−C(Ph) Bond

    Chemistry - An Asian Journal · 2023-01-13

    Wing Hei Marco Wong, Xueying Guo, Hok Tsun Chan, Tilong Yang, Zhenyang Lin

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  13. Visible-light photoredox-catalyzed coupling of alkylsulfones with α-(trifluoromethyl)styrenes

    Canadian Journal of Chemistry · 2023-04-05

    Yasuyo Tahara, Koushik Ghosh, Masakazu Nambo

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  14. Identified Isosteric Replacements of Ligands’ Glycosyl Domain by Data Mining

    ACS Omega · 2023-07-05

    Tinghao Zhang, Shenghao Jiang, Ting Li, Yan Liu, Yuezhou Zhang

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  15. Tunable Synthesis of Monofluoroalkenes and Gem‐Difluoroalkenes via Solvent‐Controlled Rhodium‐Catalyzed Arylation of 1‐Bromo‐2,2‐difluoroethylene

    Angewandte Chemie International Edition · 2023-08-17

    Wen‐Yan Xu, Zheyuan Xu, Ze‐Kuan Zhang, Tian‐Jun Gong, Yao Fu

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  16. Tunable Synthesis of Monofluoroalkenes and Gem‐Difluoroalkenes via Solvent‐Controlled Rhodium‐Catalyzed Arylation of 1‐Bromo‐2,2‐difluoroethylene

    Angewandte Chemie · 2023-08-17

    Wen‐Yan Xu, Zheyuan Xu, Ze‐Kuan Zhang, Tian‐Jun Gong, Yao Fu

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  17. Sulfonium-based precise alkyl transposition reactions

    Science Advances · 2023-09-15

    Jian Chen, Shilu Liu, Shuaisong Su, Rong Fan, Ruirui Zhang, Wei Meng, Jiajing Tan

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  18. Morpholine-mediated defluorinative cycloaddition of gem -difluoroalkenes and organic azides

    Beilstein Journal of Organic Chemistry · 2023-10-05

    Tzu‐Yu Huang, Mario Djugovski, Sweta Adhikari, Destinee L. Manning, Sudeshna Roy

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  19. Photoredox Radical Truce–Smiles Rearrangement of N- Sulfinyl Acrylamides with Bromodifluoroacetamides

    Organic Letters · 2024-12-18

    Lin Tian, Pu Chen, Xiaochen Ji, Guo‐Jun Deng, Huawen Huang

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  20. Difluoroenol phosphinates as difluoroenolate surrogates: synthesis and applications in defluorination and deoxygenative coupling

    Chemical Science · 2025-01-01

    Miki B. Kurosawa, Shuhei Shimoyama, Hiroki Tanaka, Junichiro Yamaguchi

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  21. gem-Difluoroalkenylation of aldehydes and ketones with bis(difluoromethyl)triphenylphosphorane under operationally simple conditions

    Tetrahedron · 2025-01-09

    Jiaxi Cai, Huanhuan Song, Xin Liu, Haixia Song, Le Liu, Xin‐Hua Duan, Mingyou Hu

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  22. Diastereoselective synthesis of 5,5-Difluoroisoxazolidine via [3 + 2] cycloaddition between Nitrones and Difluoroacrylates

    Tetrahedron Letters · 2025-05-09

    Miaomiao Zhang, Lingyu Kong, Shengqiang Li, Shang Gao, Xuanyi Li

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  23. Mechanochemical Nickel-Catalyzed Dechlorination-Deuteration of Aryl Chlorides via Piezoelectric-Promoted Ar–Zn–X Intermediates

    ACS Catalysis · 2025-08-11

    Jun Zhang, Yumeng Zhang, Tingrui Liu, Bowen Fu, Weigang Zhang, Bingnan Du

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  24. Ni-Catalyzed Distal-Selective gem-Difluorovinylation of Unactivated Alkenes with 2,2-Difluorovinyl Benzoates

    JACS Au · 2025-08-27

    Mingyu Luo, Lin‐Ya Xu, Xin Gao, Chun‐Ming Chan, Qiushi Shen, Bingnan Du, Wing‐Yiu Yu

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  25. Modular Synthesis of Diverse gem -Difluoroalkenes from Trifluoroacetic Anhydride via Phosphorus-Assisted Fluoride Elimination

    Organic Letters · 2025-11-10

    Likun Dong, Jin‐Dong Yang, Jin‐Pei Cheng

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  26. Facile Synthesis of Gem-Difluoroalkene-Based Bis (silanes) via Copper-Catalyzed Disilylative Defluorination of 1-Chloro-1-trifluoromethylalkenes

    Journal of the American Chemical Society · 2026-04-10

    Mingxing Ye, Haotian Yang, Xuzhao Du, Shanglin Chen, Yuhan Wang, Peiyuan Yu, Xingxing Ma, Qiuling Song

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  27. Modelling damming effect on spatial flood conditions and its consequences on kharif crop

    Spatial Information Research · 2026-06-09

    Sudarshan Sarkar, Prabir Hembram, Satyajit Paul, Priyanka Das, Ripan Ghosh, Tuli Karmakar, Pallabi Chowdhury, Swades Pal

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