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RESEARCH PAPER · Journal of the American Chemical Society · 2021

One Site, Two Cations, Three Environments: s2 and s0 Electronic Configurations Generate Pb-Free Relaxor Behavior in a Perovskite Oxide

Todd Wesley Surta, Thomas A. Whittle, Matthew A. Wright, Hongjun Niu, Jacinthe Gamon, Quinn Gibson, Matthew J. Rosseinsky, William J. Thomas, Marco Zanella, Philippa M. Shepley, Yang Li, Anton Goetzee-Barral, Andrew J. Bell, Jonathan Alaria, John B. Claridge, Matthew J. Rosseinsky

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One Site, Two Cations, Three Environments: s2 and s0 Electronic Configurations Generate Pb-Free Relaxor Behavior in a Perovskite OxideOriginalSpark plasma sintering routes to consolidated inorganic functional materials0Expanding multiple anion superlattice chemistry: Synthesis, structure and properties of Bi4O4SeBr2 and Bi6O6Se2Cl212Coupling effects of the A-site ions on high-performance potassium sodium niobate ceramics32Sn1/3Na2/3Sn(OH)6 Perovskite with Sn4+/Na+ Disorder for Photocatalytic Degradation of 2,4-Dichlorophenol6Research progress of synthesis of high-performance perovskites and its derivatives based on polyhedral distortion0Deciphering the role of A-site ions of AZrO3-type dopants in (K, Na)NbO3 ceramics30Electrical property optimization of BaTiO 3 ‐based lead‐free piezoceramics by chemical doping9Composition–electric field phase diagram of the Pb-free piezoelectric system Na0.5Bi0.5TiO3−BaTiO37Separation of K+ and Bi3+ displacements in a Pb-free, monoclinic piezoelectric at the morphotropic phase boundary3Effect of Pr3+ doping on relaxation behavior and strain response of PHT-based piezoelectric ceramics9Nature of the morphotropic phase boundary in the lead-free piezoelectric systems K 1 / 2 Bi 1 / 2 ( M 1 / 3 Nb 2 / 3 ) x Ti 1 − x O 3 ( M =Mg, Zn)0Shifting and tilting towards enhanced piezoelectricity in high-temperature ceramics: an average structure study of (1 − x )BiFe 2/8 Ti 3/8 Mg 3/8 O 3 – x PbTiO 3 through X-ray and neutron diffraction1Perspective on polarization regulation for advanced energy storage13High–entropy lead-free NaNbO3-modified (Bi0.2Na0.2Ba0.2Sr0.2Ca0.2)TiO3 relaxor–ferroelectric ceramics for capacitors0Origin of diffused O-T phase transition for enhanced temperature stability in KNN-based ceramics2Cationic Size Mismatch Dictates Structural Topology and Magnetic Properties of Honeycomb-Derived Na0.5 RE 0.5Ni2TeO6 ( RE = La–Lu and Y)0

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16 direct citing papers saved.

  1. Spark plasma sintering routes to consolidated inorganic functional materials

    Elsevier eBooks · 2022-02-01

    Michael W. Gaultois, Todd Wesley Surta

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  2. Expanding multiple anion superlattice chemistry: Synthesis, structure and properties of Bi4O4SeBr2 and Bi6O6Se2Cl2

    Journal of Solid State Chemistry · 2022-05-19

    Quinn Gibson, Jon A. Newnham, Matthew Stephen Dyer, Craig M. Robertson, Marco Zanella, Todd Wesley Surta, Matthew J. Rosseinsky, Jonathan Alaria, John B. Claridge, Matthew J. Rosseinsky

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  3. Coupling effects of the A-site ions on high-performance potassium sodium niobate ceramics

    Journal of Material Science and Technology · 2022-06-11

    Xiang Lv, Nan Zhang, Yinchang Ma, Xixiang Zhang, Jiagang Wu

    Read original paper ↗ ·

  4. Sn1/3Na2/3Sn(OH)6 Perovskite with Sn4+/Na+ Disorder for Photocatalytic Degradation of 2,4-Dichlorophenol

    Inorganic Chemistry · 2022-08-16

    Yuanyuan Li, Hongzheng Pu, Ying Mei Zhou, Fengling Yin, Siwei Chen, Yurou Tang, Pengfei Jiang, Ya Wu, Zhenhua Zhang, Dingfeng Yang

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  5. Research progress of synthesis of high-performance perovskites and its derivatives based on polyhedral distortion

    Acta Physica Sinica · 2023-01-01

    Cheng Fang, Hong Wang, Siqi Shi

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  6. Deciphering the role of A-site ions of AZrO3-type dopants in (K, Na)NbO3 ceramics

    Acta Materialia · 2023-05-10

    Xin Long Wang, Xiang Lv, Yinchang Ma, Xixiang Zhang, Jing Lyu, Jiagang Wu

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  7. Electrical property optimization of BaTiO 3 ‐based lead‐free piezoceramics by chemical doping

    Journal of the American Ceramic Society · 2023-06-27

    Enpei Cai, Huaizhang Gu, Qibin Liu

    Read original paper ↗ ·

  8. Composition–electric field phase diagram of the Pb-free piezoelectric system Na0.5Bi0.5TiO3−BaTiO3

    Physical review. B./Physical review. B · 2023-12-07

    Gobinda Das Adhikary, Gudeta Jafo Muleta, Rajeev Ranjan

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  9. Separation of K+ and Bi3+ displacements in a Pb-free, monoclinic piezoelectric at the morphotropic phase boundary

    Acta Materialia · 2023-12-13

    Todd Wesley Surta, Lynette Keeney, Alicia Maria Manjón-Sanz, Catriona A. Crawford, Alexandra Morscher, Matthew J. Rosseinsky, John B. Claridge, Andrew J. Bell, Jonathan Alaria, Matthew J. Rosseinsky

    Read original paper ↗ ·

  10. Effect of Pr3+ doping on relaxation behavior and strain response of PHT-based piezoelectric ceramics

    Ceramics International · 2024-05-02

    Yushan Deng, Xi Ouyang, Manwen Yao, Xi Yao

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  11. Nature of the morphotropic phase boundary in the lead-free piezoelectric systems K 1 / 2 Bi 1 / 2 ( M 1 / 3 Nb 2 / 3 ) x Ti 1 − x O 3 ( M =Mg, Zn)

    Physical review. B./Physical review. B · 2024-12-26

    Pooja Punetha, Vimlesh Chouhan, Gobinda Das Adhikary, Pavan Nukala, Rajeev Ranjan

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  12. Shifting and tilting towards enhanced piezoelectricity in high-temperature ceramics: an average structure study of (1 − x )BiFe 2/8 Ti 3/8 Mg 3/8 O 3 – x PbTiO 3 through X-ray and neutron diffraction

    Acta Crystallographica Section B Structural Science Crystal Engineering and Materials · 2025-04-22

    Brooke N. Richtik, Alicia Maria Manjón-Sanz, Michelle Dolgos

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  13. Perspective on polarization regulation for advanced energy storage

    Applied Physics Letters · 2025-09-30

    Leiyang Zhang, Fukang Chen, Yunyao Huang, Ruiyi Jing, Li Jin

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  14. High–entropy lead-free NaNbO3-modified (Bi0.2Na0.2Ba0.2Sr0.2Ca0.2)TiO3 relaxor–ferroelectric ceramics for capacitors

    Journal of Materials Science Materials in Electronics · 2025-10-01

    Varun Kamboj, Harshit Tripathi, Rishabh Sharma, Sunny Zafar, Moolchand Sharma, Sanjeev Kumar, Gurpreet Singh

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  15. Origin of diffused O-T phase transition for enhanced temperature stability in KNN-based ceramics

    Ceramics International · 2025-12-24

    Chen Liao, Zixin Liu, Hong Tao, Haoyue Xue, Lin Zhao, Feng Miao, Jian Ma, Bo Wu

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  16. Cationic Size Mismatch Dictates Structural Topology and Magnetic Properties of Honeycomb-Derived Na0.5 RE 0.5Ni2TeO6 ( RE = La–Lu and Y)

    Inorganic Chemistry · 2026-07-15

    Siqi Ma, Shunjie Tang, Zien Cheng, Keyu Chen, Qiang Zhang, Wenhai Ji, Ping Miao, Rihong Cong, Tao Yang, Pengfei Jiang

    Read original paper ↗ ·
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