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RESEARCH PAPER · ACS ES&T Engineering · 2021

Review of Advances in Engineering Nanomaterial Adsorbents for Metal Removal and Recovery from Water: Synthesis and Microstructure Impacts

Jinming Luo, Kaixing Fu, Deyou Yu, Kiril D. Hristovski, Paul K. Westerhoff, John C. Crittenden

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Review of Advances in Engineering Nanomaterial Adsorbents for Metal Removal and Recovery from Water: Synthesis and Microstructure ImpactsOriginalRecent Progress on Two-Dimensional Materials472Enhanced adsorption of perfluorooctanoic acid using functionalized imidazolium iodide ionic liquid‐based poly (glycidyl methacrylate)14Bio-functionalized few-layer graphene for in situ growth of gold nanoparticles, improvement of polymer properties, and dye removal19Preparation of Porous Hydroxyapatite Using Cetyl Trimethyl Ammonium Bromide as Surfactant for the Removal of Lead Ions from Aquatic Solutions36Chitosan/Zeolite Composite Aerogels for a Fast and Effective Removal of Both Anionic and Cationic Dyes from Water30Enhanced Photocatalytic Activity of Cu2O Cabbage/RGO Nanocomposites under Visible Light Irradiation18Hydroxyapatite Coatings on Calcite Powder for the Removal of Heavy Metals from Contaminated Water26The Development and Characterization of a Cotton–Chitosan Composite for Lead Removal from Water16An environmentally benign synthesis of Fe3O4 nanoparticles to Fe3O4 nanoclusters: Rapid separation and removal of Hg(II) from an aqueous medium54Advanced Oxidation Processes Coupled with Nanomaterials for Water Treatment119Enhanced Performance of Chitosan via a Novel Quaternary Magnetic Nanocomposite Chitosan/Grafted Halloysitenanotubes@ZnγFe3O4 for Uptake of Cr (III), Fe (III), and Mn (II) from Wastewater37Copper(II) and lead(II) adsorption onto zinc sulfide nanoparticles effects of light, pH, time, temperature, and interferences3Extraction of Cellulose Polymeric Material from Populus tremula Fibers: Characterization and Application to the Adsorption of Methylene Blue and Crystal Violet32Titanium Carbide‐Based Adsorbents for Removal of Heavy Metal Ions and Radionuclides: From Nanomaterials to 3D Architectures13Synthesis and Characterization of a Nano-Adsorbent Derivative Derived from Grape Seeds for Cadmium Ion Removal in an Aqueous Solution4Macroporous chitin microspheres prepared by surfactant micelle swelling strategy for rapid capture of lead (II) from wastewater20Environmentally Friendly Polyvinyl Alcohol−Alginate/Bentonite Semi-Interpenetrating Polymer Network Nanocomposite Hydrogel Beads as an Efficient Adsorbent for the Removal of Methylene Blue from Aqueous Solution70Machine learning approaches to predict adsorption capacity of Azolla pinnata in the removal of methylene blue119Joule-Heated Layered Double Hydroxide Sponge for Rapid Removal of Silica from Water25Coordination/cation exchangeable dual sites intercalated multilayered T 3 C 2 T x MXene for selective and ultrafast removal of thallium( i ) from water12Hematite decorated functional porous graphitic carbon nitride binary nanohybrid: Mechanistic insight into the formation and arsenic adsorption study17Photoinduced Self-Organized Precipitation in Leachate for Remediation of Heavy Metal Contaminated Soils18Nanocatalyst in remediating environmental pollutants109Superselective Hg(II) Removal from Water Using a Thiol-Laced MOF-Based Sponge Monolith: Performance and Mechanism171Detoxification and selective separation of Cr(VI) and As(III) in wastewater based on interfacial coupling in BiOBr with {110} facet under visible-light irradiation46Double-Network Hydrogel: A Potential Practical Adsorbent for Critical Metals Extraction and Recovery from Water35Metal-organic frameworks: A new generation potential material for aqueous environmental remediation51Hazardous ions decontamination: From the element to the material22Insights into the Crucial Role of Electron and Spin Structures in Heteroatom-Doped Covalent Triazine Frameworks for Removing Organic Micropollutants101Facile synthesis of multifunctional C@Fe3O4–MoO3-rGO ternary composite and its versatile roles as sonoadsorbent to ameliorate triphenylmethane textile dye and as potential electrode for supercapacitor applications9Assessment of antimicrobial, cytotoxicity, and antiviral impact of a green zinc oxide/activated carbon nanocomposite34The enhanced removal of arsenite from water by double-shell CuOx@MnOy hollow spheres (DCMHS): behavior and mechanisms4MIL-100(Fe)-Hybridized Nanofibers for Adsorption and Visible Light Photocatalytic Degradation of Water Pollutants: Experimental and DFT Approach39Enhanced Methylene Blue Adsorption by Cu-BTC Metal-Organic Frameworks with Engineered Particle Size Using Surfactant Modulators21Continuous silicic acid removal in a fixed-bed column using a modified resin: Experiment investigation and artificial neural network modeling9Facile Synthesis of Sustainable Tannin/Sodium Alginate Composite Hydrogel Beads for Efficient Removal of Methylene Blue26Lacunary polyoxometalate @ ZIF for ultradeep Pb(II) adsorption27A mechanism of ion exchange by interface-coupled dissolution-precipitation in the presence of an aqueous fluid32Tailored architectures of mesoporous carbon nanostructures: From synthesis to applications60A Review on MXene Synthesis, Stability, and Photocatalytic Applications668Sorption and continuous filtration of heavy metals and radionuclides using novel nano-Farringtonite: Mechanisms delineation using EXAFS7An Optimized Protocol for Seed Sterilization and Shoot Regeneration from Mature Embryo in Wheat (Triticum Aestivum L.) var. HD29672Cerium–Bismuth Oxides/Oxynitrates with Low Toxicity for the Removal and Degradation of Organophosphates and Bisphenols15Mechanism of Interaction of Nanomaterial and Microbes to Treat Emerging Pollutants0Anchoring NH 2 -MIL-101(Fe/Ce) within Melamine Sponge Boosts Rapid Adsorption and Recovery of Phosphate from Water47Specific Surface Area Versus Adsorptive Capacity: an Application View of 3D Graphene-Based Materials for the Removal of Emerging Water Pollutants34Accessibility of adsorption sites for superfine powdered activated carbons incorporated into electrospun polystyrene fibers3Post-modified ligand exchange of UiO-66 with high-exposure rhodanine sites for enhancing the rapid and selective capture of Ag(I) from wastewater21Mechanistic Study of Arsenate Adsorption onto Different Amorphous Grades of Titanium (Hydr)Oxides Impregnated into a Point-of-Use Activated Carbon Block15Process optimization and mechanism revealing of KMnO4 pre-oxidation coupled powdered activated carbon adsorption for 2-MIB removal22Overview of emerging catalytic materials for electrochemical green ammonia synthesis and process73Occurrence, fate, and impact of engineered metal/carbonaceous nanomaterials in the environment, detection, and quantitation methods26Hydrothermal synthesis of Zr-doped chitosan carbon-shell protected magnetic composites (Zr–Fe3O4@C) for stable removal of Cr(VI) from water: Enhanced adsorption and pH adaptability26Green synthesis of a mesoporous hyper-cross-linked polyamide/polyamine 3D network through Michael addition for the treatment of heavy metals and organic dyes contaminated wastewater10Electrically Controlled Adsorptive Membranes with Tunable Affinity for Selective Chromium (VI) Separation from Water26MOF-based Ca-alginate/PAA granulate beads for efficient heavy metal removal from water: Synthesis, performance, and mechanism20Sous Vide-Inspired Impregnation of Amorphous Titanium (Hydr)Oxide into Carbon Block Point-of-Use Filters for Arsenic Removal from Water14Sulfite activation of Fe-Mn bimetallic oxides for rapid oxidative removal of As(III) in water: Involvement of active Mn(III)30A method for the efficient removal of Pb(II) by D001 resin in a rotating packed bed10ZnO-NPs/AC composite antibacterial agents with N-halamine glycinate functionalized silica-mesoporous silica coating for water disinfection5Preparation of Macroporous Double-Network MoS2-Based Beads for Efficient and Selective Removal of Hg(II) from Water9Surface engineering of multifunctional nanostructured adsorbents for enhanced wastewater treatment: A review57Insights into the biogeochemical transformation, environmental impacts and biochar-based soil decontamination of antimony33Removal of hexavalent chromium in water by chitosan-modified Enteromorpha prolifera biochar loaded with iron-manganese oxides: Application performances and reaction mechanisms28Electrodeposited Palladium Nanoparticles Enhancing Atomic Hydrogen-Mediated Electrochemical Recovery of Antimony6Bottom-up synthesis of a sulfhydryl-modified heteroporous covalent organic framework for ultrafast removal of trace Hg(Ⅱ) from water23Synergistic Removal of U (VI), Pb(II), and HA on nZVI/MoS2 Composites Investigated by Batch, Spectroscopic, and Modeling Techniques6Integrated Solution for As(III) Contamination in Water Based on Crystalline Porous Organic Salts6RSM-CCD directed modeling and optimization of a low-cost adsorbent based on sodium dodecyl sulfate for the selective removal of malachite green and methylene blue dyes: Kinetics, isotherm, and thermodynamics analysis22Antimony removal using zero-valent iron-manganese bimetallic nanomaterial: Adsorption behavior and mechanism18Metal and metal oxide nanomaterials for heavy metal remediation: novel approaches for selective, regenerative, and scalable water treatment117Guidance on aqueous matrices for evaluating novel precipitants and adsorbents for phosphorus removal and recovery4Recent advances in cellulose nanospheres: production, formation mechanisms, properties and applications6The Electronic Properties and Adsorption Performance of LDH/Graphene, and LDH/g-C3N4 for the Removal of Pharmaceutical Contaminants: A Molecular Dynamics Simulation9Innovative Approaches to Water Purification Harnessing Bio-Chemical Adsorbents for Multistage Potable Water Filtration3Animal manure biochar for the removal of hazardous pollutants from wastewater5Novel materials and methods for dibenzothiophene removal from diesel fuel: A comprehensive review of efficiency, cost, scalability, and environmental impact2Nanochitin: Green nanomaterial for sustainable applications in agriculture and environmental remediation7Few-layer graphene-hybrid sulfonate hydrogels for high-efficient adsorption of heavy metal (Pb2+, Ni2+, Cd2+) in water treatment14Magnetite Stoichiometry (Fe(II)/Fe(III)) Controls on Trivalent Chromium Surface Speciation10Tunable Synthesis of Conjugated Microporous Polymers and Their Adsorption Performance Toward Heavy Metals4Eco-Friendly Green Synthesis: Harnessing Ni/Al-Layered Double Hydroxide-Activated Carbon Nanocomposite for Sustainable Environmental Remediation1Modulating the Central Metal Redox-State Ratios of Amorphous Titanium (Hydr)Oxide by Incorporating Cerium Enhances Mixtures of Oxyanions Removal from Water4299Chapter 12 Advancing nanomaterial safety: AIartificial intelligence in toxicity and environmental assessments0Electronic Textiles Based on Conductive Metal–Organic Frameworks as Scavengers and Sensors of Toxic Oxyanions from Water18Colloidal Stability of Aqueous Suspensions of Bentonite Clays from the Krantau Deposit. Analysis via Dynamic Light Scattering6Carbamodithioate‐Modified Nanoscale Zerovalent Iron: Redox‐Active Hybrid for Cr (VI) and p‐Nitrophenol Remediation0Photocatalytic nanostructured materials for heavy metal remediation: Mechanisms, challenges, and future prospects8Remediation of heavy metal complexes from water and wastewater: a comprehensive review of commonly used methods8A Review of the Strategies Used in the Recovery and Passivation of Lead in Lead‐Based Perovskite Solar Cells: Balancing Device Efficiency, Toxicity, and Environmental Sustainability7Reusability of spent adsorbents for a circular materials economy in the sustainable chemical industry40A novel FeTiZn ternary oxide nanocomposite for spontaneous and efficient adsorptive removal of hexavalent chromium from polluted water0Adsorption with Transition Metal-Based Layered Double Hydroxides0Bacterial Exopolymeric Substances (EPS): Promising Biomaterials for Synthesis of Biogenic Nanoparticles for Environmental Bioremediation1Fuel-free micro/nanomotors as adsorptive platforms for water treatment1Nanoremediation of arsenic from contaminated water by new generation graphene-based nanomaterials: a comprehensive review3Synthesis cost of adsorbent materials0Earthen-Pot Assisted Carbon Aerogel Synthesis for the Adsorption of Multiple Organic Contaminants2Bio and waste derived sustainable adsorbents for efficient removal of Pb, Cr, and As from wastewater: Advances and global trends2Nanotechnology-enabled natural adsorbents for water pollutants remediation: a review0Strategic enhancement in charge carrier dynamics of photoactive Fe2O3 by decorating WS2 nanosheets for enhanced photoelectrochemical water splitting1MXene-based innovations for ciprofloxacin removal: advanced adsorption mechanisms and sustainable water quality management0Circular upcycling of end-of-life batteries into functional adsorbents: Process pathways, environmental applications, and emerging sodium and zinc-ion battery opportunities0

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  49. Mechanistic Study of Arsenate Adsorption onto Different Amorphous Grades of Titanium (Hydr)Oxides Impregnated into a Point-of-Use Activated Carbon Block

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  50. Process optimization and mechanism revealing of KMnO4 pre-oxidation coupled powdered activated carbon adsorption for 2-MIB removal

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