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RESEARCH PAPER · The Journal of Physical Chemistry C · 2020

Nanopyramidal Reconstruction of Cu2O(111): A Long-Standing Surface Puzzle Solved by STM and DFT

Alexander Gloystein, Niklas Nilius, Jacek Goniakowski, Claudine Noguera

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Nanopyramidal Reconstruction of Cu2O(111): A Long-Standing Surface Puzzle Solved by STM and DFTOriginalHigh-Pressure Oxidation of Copper on Au(111)—A Route toward Bulk-like Cuprous Oxide Films15Atomic Structure of the Cu2O(111) Surface: A Transmission Electron Microscopy and DFT + U Study11Synthetic Data in Quantitative Scanning Probe Microscopy16Empty Valence‐Band Pocket in p‐Type Cu2O(111) Probed with Scanning Tunneling Spectroscopy9Copper oxide phases probed via plasmonic light emission in the STM6Termination-dependent electronic structure and atomic-scale screening behavior of the Cu 2 O(111) surface10Revisit of XPS Studies of Supersonic O2 Molecular Adsorption on Cu(111): Copper Oxides33Importance of surface oxygen vacancies for ultrafast hot carrier relaxation and transport in Cu2 O17Morphology-Controlled Synthesis of Cu2o Encapsulated Phase Change Materials: Superior Photothermal Conversion and Storage Performance in Visible Light Regime0Atomic View on the (111) Surface of a Cu2O Single Crystal: Reconstruction, Electronic Properties, and Band-Bending Effects7Spatiotemporal imaging of charge transfer in photocatalyst particles553Luminescence from Cuprous Oxide in a Scanning Tunneling Microscope: Competition between Plasmonic and Excitonic Response7Morphology-controlled synthesis of Cu2O encapsulated phase change materials: Photothermal conversion and storage performance in visible light regime55Photoluminescence Spectroscopy of Cuprous Oxide: Bulk Crystal versus Crystalline Films27Light Emission from Single Oxygen Vacancies in Cu2O Films Probed with Scanning Tunneling Microscopy16Host-guest assembly functionalization through molecular selective adsorption into chiral Kagome-like frameworks6A surface science view onto cuprous oxide: Growth, termination, electronic structure and optical response29h-BN/Metal-Oxide Interface Grown by Intercalation: A Model System for Nano-Confined Catalysis5Surface Facets Reconstruction in Copper‐Based Materials for Enhanced Electrochemical CO2 Reduction50Investigation of Pyridine as a Cocatalyst for the CO 2 Reduction Reaction on the Cu 2 O Cathode Surface17Surface reconstruction in the CuO(001) surface: From square-planar to tetrahedral coordination for CuO4 unit5The surface chemistry of cuprous oxide4Nitrogen doping of cuprous oxide films: A surface science perspective7Electrocatalytic Pathways and Efficiency of Cuprous Oxide (Cu2O) Surfaces in CO2 Electrochemical Reduction (CO2ER) to Methanol: A Computational Approach5Augmentation of Universal Potentials for Broad Applications16Titanium deposition onto Cu2O/Pt(111) films: violent redox-chemistry at a metal-oxide interface3Cryogenic Carbon Monoxide Oxidation on Cuprous Oxide0Cryogenic Carbon Monoxide Oxidation on Cuprous Oxide2Machine learning study of surface reconstructions of the Cu 2 O ( 111 ) surface0Chelation-enabled efficient CO2 electroreduction to methane in natural seawater using low-coordinated Cu catalyst1Noncovalent copper oxide framework on Cu(111) with open honeycomb structure0Titanium-Doped Cu2O Thin Films: Oxide Alloying Versus Phase Separation0Solving the Long-Standing Cu(111) “8” Surface Oxide Puzzle0

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  1. High-Pressure Oxidation of Copper on Au(111)—A Route toward Bulk-like Cuprous Oxide Films

    The Journal of Physical Chemistry C · 2020-12-18

    Alexander Gloystein, Niklas Nilius

    Read original paper ↗ ·

  2. Atomic Structure of the Cu2O(111) Surface: A Transmission Electron Microscopy and DFT + U Study

    physica status solidi (b) · 2021-07-01

    Wandong Xing, Fanyan Meng, Rong Yu

    Read original paper ↗ ·

  3. Synthetic Data in Quantitative Scanning Probe Microscopy

    Nanomaterials · 2021-07-02

    David Nečas, Petr Klapetek

    Read original paper ↗ ·

  4. Empty Valence‐Band Pocket in p‐Type Cu2O(111) Probed with Scanning Tunneling Spectroscopy

    physica status solidi (b) · 2021-08-11

    Alexander Gloystein, Niklas Nilius

    Read original paper ↗ ·

  5. Copper oxide phases probed via plasmonic light emission in the STM

    New Journal of Physics · 2021-08-26

    Alexander Gloystein, Niklas Nilius

    Read original paper ↗ ·

  6. Termination-dependent electronic structure and atomic-scale screening behavior of the Cu 2 O(111) surface

    Journal of Physics Condensed Matter · 2021-09-09

    Alexander Gloystein, Niklas Nilius, Claudine Noguera, Jacek Goniakowski

    Read original paper ↗ ·

  7. Revisit of XPS Studies of Supersonic O2 Molecular Adsorption on Cu(111): Copper Oxides

    ACS Omega · 2021-09-29

    Koki Hayashida, Yasutaka Tsuda, Takashi Yamada, Akitaka Yoshigoe, Michio Okada

    Read original paper ↗ ·

  8. Importance of surface oxygen vacancies for ultrafast hot carrier relaxation and transport in Cu2 O

    Physical Review Research · 2021-12-27

    Chiara Ricca, Lisa Grad, Matthias Hengsberger, Jürg Osterwalder, Ulrich Aschauer

    Read original paper ↗ ·

  9. Morphology-Controlled Synthesis of Cu2o Encapsulated Phase Change Materials: Superior Photothermal Conversion and Storage Performance in Visible Light Regime

    SSRN Electronic Journal · 2022-01-01

    Zhenghao Chen, Zeyi Jiang, Shiqing Deng, Xinru Zhang, Nien‐Chu Lai

    Read original paper ↗ ·

  10. Atomic View on the (111) Surface of a Cu2O Single Crystal: Reconstruction, Electronic Properties, and Band-Bending Effects

    The Journal of Physical Chemistry C · 2022-09-26

    Alexander Gloystein, Jack Anthony Creed, Niklas Nilius

    Read original paper ↗ ·

  11. Spatiotemporal imaging of charge transfer in photocatalyst particles

    Nature · 2022-10-12

    Ruotian Chen, Zefeng Ren, Yu Liang, Guanhua Zhang, Thomas R. Dittrich, Runze Liu, Yang Liu, Yüe Zhao, Shan Pang, Hongyu An, Chenwei Ni, Panwang Zhou, Keli Han, Fengtao Fan, Can Li

    Read original paper ↗ ·

  12. Luminescence from Cuprous Oxide in a Scanning Tunneling Microscope: Competition between Plasmonic and Excitonic Response

    ACS Photonics · 2022-10-13

    Alexander Gloystein, Niklas Nilius

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  13. Morphology-controlled synthesis of Cu2O encapsulated phase change materials: Photothermal conversion and storage performance in visible light regime

    Chemical Engineering Journal · 2022-10-30

    Zhenghao Chen, Jinhui Zhang, Shiqing Deng, Mingtai Hou, Xinru Zhang, Zeyi Jiang, Nien‐Chu Lai

    Read original paper ↗ ·

  14. Photoluminescence Spectroscopy of Cuprous Oxide: Bulk Crystal versus Crystalline Films

    physica status solidi (a) · 2023-02-08

    Mina Soltanmohammadi, Eleonora Spurio, Alexander Gloystein, P. Luches, Niklas Nilius

    Read original paper ↗ ·

  15. Light Emission from Single Oxygen Vacancies in Cu2O Films Probed with Scanning Tunneling Microscopy

    The Journal of Physical Chemistry Letters · 2023-04-21

    Alexander Gloystein, Mina Soltanmohammadi, Niklas Nilius

    Read original paper ↗ ·

  16. Host-guest assembly functionalization through molecular selective adsorption into chiral Kagome-like frameworks

    Applied Surface Science · 2023-06-12

    Shijie Sun, Baijin Li, Wei Xiong, Boyu Fu, Yong Zhang, Zilin Ruan, Lei Gao, Xiaoqing Zuo, Jianchen Lu, Jinming Cai

    Read original paper ↗ ·

  17. A surface science view onto cuprous oxide: Growth, termination, electronic structure and optical response

    Surface Science Reports · 2024-03-01

    Niklas Nilius, Jacek Goniakowski, Claudine Noguera

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  18. h-BN/Metal-Oxide Interface Grown by Intercalation: A Model System for Nano-Confined Catalysis

    The Journal of Physical Chemistry C · 2024-03-13

    J. Trey Diulus, Zbyněk Novotný, Nanchen Dongfang, Jan Beckord, Yasmine S. Al-Hamdani, Nicoló Comini, Matthias Muntwiler, Matthias Hengsberger, Marcella Iannuzzi, Jürg Osterwalder

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  19. Surface Facets Reconstruction in Copper‐Based Materials for Enhanced Electrochemical CO2 Reduction

    Small · 2024-05-15

    Zezhong Xie, Qiushi Wang, Hao Yang, Jin Feng, Jian Chen, Shuqin Song, Changgong Meng, Kun Wang, Yexiang Tong

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  20. Investigation of Pyridine as a Cocatalyst for the CO 2 Reduction Reaction on the Cu 2 O Cathode Surface

    ACS Catalysis · 2024-06-10

    Linhan Xu, Shenzhen Xu

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  21. Surface reconstruction in the CuO(001) surface: From square-planar to tetrahedral coordination for CuO4 unit

    Applied Surface Science · 2024-07-02

    Mingyue Wang, Xiaoyan Li, Xiangkai Zeng, Quanpan Zhao, Mengmeng Zhang, Fanyan Meng, Rong Yu, Wandong Xing

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  22. The surface chemistry of cuprous oxide

    Surface Science · 2024-10-01

    Tianhao Hu, Burcu Karagoz, Fang Xu, Ashley R. Head, Jonas Weissenrieder, Darío J. Stacchiola

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  23. Nitrogen doping of cuprous oxide films: A surface science perspective

    Applied Surface Science · 2024-10-12

    Mina Soltanmohammadi, Niklas Nilius

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  24. Electrocatalytic Pathways and Efficiency of Cuprous Oxide (Cu2O) Surfaces in CO2 Electrochemical Reduction (CO2ER) to Methanol: A Computational Approach

    Catalysts · 2025-01-29

    Zubair Ahmed Laghari, Wan Zaireen Nisa Yahya, Sulafa Abdalmageed Saadaldeen Mohammed, Mohamad Azmi Bustam

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  25. Augmentation of Universal Potentials for Broad Applications

    Physical Review Letters · 2025-02-04

    Joe Pitfield, Florian Brix, Zeyuan Tang, Andreas Møller Slavensky, Nikolaj Rønne, Mads-Peter Verner Christiansen, Bjørk Hammer

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  26. Titanium deposition onto Cu2O/Pt(111) films: violent redox-chemistry at a metal-oxide interface

    Journal of Physics D Applied Physics · 2025-03-24

    Soeke Sabelus, Bo-Yi Zhong, Niklas Nilius

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  27. Cryogenic Carbon Monoxide Oxidation on Cuprous Oxide

    Angewandte Chemie · 2025-11-10

    Burcu Karagoz, Tianhao Hu, Joakim Halldin Stenlid, Xiaoming Hu, Markus Soldemo, Frank Abild‐Pedersen, Kess Marks, Henrik Öström, Darío J. Stacchiola, Jonas Weissenrieder, Ashley R. Head

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  28. Cryogenic Carbon Monoxide Oxidation on Cuprous Oxide

    Angewandte Chemie International Edition · 2025-11-10

    Burcu Karagoz, Tianhao Hu, Joakim Halldin Stenlid, Xiaoming Hu, Markus Soldemo, Frank Abild‐Pedersen, Kess Marks, Henrik Öström, Darío J. Stacchiola, Jonas Weissenrieder, Ashley R. Head

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  29. Machine learning study of surface reconstructions of the Cu 2 O ( 111 ) surface

    Physical review. B./Physical review. B · 2025-11-17

    Payal Wadhwa, Michael Schmid, Georg Kresse

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  30. Chelation-enabled efficient CO2 electroreduction to methane in natural seawater using low-coordinated Cu catalyst

    Applied Catalysis B: Environmental · 2026-01-19

    Donggeun Eom, Yoojin Lee, Jeong Woo Han, Sangwook Park

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  31. Noncovalent copper oxide framework on Cu(111) with open honeycomb structure

    The Journal of Chemical Physics · 2026-05-08

    Sijia Yue, Yini He, Pu Yang, Luting Geng, Wenyu Sun, Qi Wang, Jiahui Wang, Duanyun Cao, Jing Guo

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  32. Titanium-Doped Cu2O Thin Films: Oxide Alloying Versus Phase Separation

    Topics in Catalysis · 2026-06-29

    Bo-Yi Zhong, Niklas Nilius

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  33. Solving the Long-Standing Cu(111) “8” Surface Oxide Puzzle

    ACS Nano · 2026-08-27

    Romain Bernard, Jacek Goniakowski, Claudine Noguera, Alessandro Coati, Y. Garreau, G. Simon, Axel Wilson, Lei Zhang, Ahmed Naitabdi, Geoffroy Prévot

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