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RESEARCH PAPER · Chem · 2020

A Robust Titanium Isophthalate Metal-Organic Framework for Visible-Light Photocatalytic CO2 Methanation

Sujing Wang, María Cabrero‐Antonino, Sergio Navalón, Chen‐Chen Cao, Antoine Tissot, Iurii Dovgaliuk, Jérôme Marrot, Charlotte Martineau, Liang Yu, Hao Wang, William Shepard, Hermenegildo Garcı́a, Christian Serre

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A Robust Titanium Isophthalate Metal-Organic Framework for Visible-Light Photocatalytic CO2 MethanationOriginalEffects of ligand functionalization on the band gaps and luminescent properties of a Zr 12 oxo-cluster based metal–organic framework16H 2 S Stability of Metal–Organic Frameworks: A Computational Assessment15Metal–Organic Frameworks for Photo/Electrocatalysis181A Showcase of Green Chemistry: Sustainable Synthetic Approach of Zirconium‐Based MOF Materials78Synthesis of newly amorphous-porous titanium-based 3D-MOFs9Current Trends and Approaches to Boost the Performance of Metal Organic Frameworks for Carbon Dioxide Methanation through Photo/Thermal Hydrogenation: A Review54Performance tuning of a DBD plasma catalytic hybrid process for CO2 methanation0Mixed component metal-organic frameworks: Heterogeneity and complexity at the service of application performances146A critical review on the development of metal-organic frameworks for boosting photocatalysis in the fields of energy and environment102In situ Ce-doped catalyst derived from NiCeAl-LDHs with enhanced low-temperature performance for CO2 methanation42Spatially separated oxygen vacancies and nickel sites for ensemble promotion of selective CO2 photoreduction to CO22Strategies for improving the photocatalytic performance of metal-organic frameworks for CO2 reduction: A review90Rational Design of Metal–Organic Framework‐Based Materials for Photocatalytic CO2 Reduction63Toward solar-driven photocatalytic CO2 methanation under continuous flow operation using benchmark MIL-125(Ti)–NH2 supported ruthenium nanoparticles46Development of soluble UiO-66 to improve photocatalytic CO2 reduction45Advances and Perspectives of Photopromoted CO2 Hydrogenation for Methane Production: Catalyst Development and Mechanism Investigations34Metal‐Organic‐Frameworks and Their Derived Materials in Photo‐Thermal Catalysis32Amino-Functionalized Titanium Based Metal-Organic Framework for Photocatalytic Hydrogen Production41Diversity and recent progressive trend in MOFs-based photo-electrocatalysts for selective CO2 reduction14Selective Photocatalytic Dehydrogenation of Formic Acid by an In Situ -Restructured Copper-Postmetalated Metal–Organic Framework under Visible Light85Heterometallic Metal-organic frameworks (MOFs) catalysts0Switchable Metal Sites in Metal–Organic Framework MFM‐300(Sc): Lewis Acid Catalysis Driven by Metal–Hemilabile Linker Bond Dynamics35Switchable Metal Sites in Metal–Organic Framework MFM‐300(Sc): Lewis Acid Catalysis Driven by Metal–Hemilabile Linker Bond Dynamics7Recent advances on photo-thermo-catalysis for carbon dioxide methanation23A Critical Review of the Use of Bismuth Halide Perovskites for CO2 Photoreduction: Stability Challenges and Strategies Implemented28Cu(II)-Based Molecular Hexagons Forming Honeycomb-like Networks Exhibit High Electrical Conductivity4A State-of-the-Art of Metal-Organic Frameworks for Chromium Photoreduction vs. Photocatalytic Water Remediation24Metal–Organic Framework‐Based Photocatalysis for Solar Fuel Production129Metal–organic frameworks as chemical nanoreactors for the preparation of catalytically active metal compounds12Classification of the MOFs Based on the Secondary Building Units (SBUs)3Insights into the sacrificial structure–activity relationship of a Ti-based metal–organic framework in an oxidative desulfurization reaction2Zr- and Ti-based metal–organic frameworks: synthesis, structures and catalytic applications84Electron microscopy and diffraction study of metal-organic frameworks0Equilibrium photo-thermodynamics enables a sustainable methanol synthesis48Controlled Supramolecular Self‐assembly in MOF Confined Spaces2Solar-driven gas phase photocatalytic CO2 methanation by multimetallic UiO-66 solids decorated with RuOx nanoparticles37Metal-organic frameworks for environmental and energy related applications0The Emergence of 2D Building Units in Metal‐Organic Frameworks for Photocatalytic Hydrogen Evolution: A Case Study with COK‐4739Metal organic framework composites for reduction of CO2102Calix[4]arene-Functionalized Titanium-Oxo Compounds for Perceiving Differences in Catalytic Reactivity Between Mono- and Multimetallic Sites59Microporous Organic Network: Superhydrophobic Coating to Protect Metal–Organic Frameworks from Hydrolytic Degradation24A chelating coordination modulation method for the synthesis of Ti-MOF single crystals28Harnessing a Ti-based MOF for selective adsorption and visible-light-driven water remediation15High adsorption of ammonia in a titanium-based metal–organic framework28Metal–organic frameworks for organic transformations by photocatalysis and photothermal catalysis347Water-stable metal–organic frameworks (MOFs): rational construction and carbon dioxide capture246Construction of a Ti-Based Bimetallic Metal–Organic Framework Using a One-Pot Method for Efficient C 2 H 2 /C 2 H 4 and C 2 H 2 /CO 2 Separation13Modulating interfacial charges in CTF-based metal-insulator-semiconductor promotes selective CO2 reduction to CH413CO2 photocatalytic reduction with robust and stable metal–organic framework: a review23Solar Gas-Phase CO 2 Hydrogenation by Multifunctional UiO-66 Photocatalysts41An Outlook on the Applications of Ru-Based Nanocatalysts for CO2 Hydrogenation to CO and CH49Iron salicylaldehydate conjugated metal–organic framework for quasi solid-state supercapacitor17Synthesis of amorphous titanium isophthalic acid catalyst with hierarchical porosity for efficient oxidative desulfurization of model feed with minimum oxidant19Ligand-Engineered Structural and Physiochemical Properties of 1D Molybdenum-MOFs: A Seldom Explored System for Photocatalytic Applications10Progress and Challenges of Monometallic Titanium Coordination Polymers11Solar‐Assisted CO2 Methanation via Photocatalytic Sabatier Reaction by Calcined Titanium‐based Organic Framework Supported RuOx Nanoparticles4Ratiometric surface-enhanced Raman spectroscopy detection of 5-hydroxyindole-3-acetic acid based on Au@MIL-125@MIPs substrates8Photocatalytic water splitting reaction: The pathway from semiconductors to MOFs11Metal-Organic Framework-Based Photocatalysts for Fuels Production0Exponential developments of quantum dots ecosystem for solar energy conversion and photocatalytic reactions: From photoanode design to renewable energy applications16Identifying and tuning coordinated water molecules for efficient electrocatalytic water oxidation17Defect engineered Ti-MOFs and their applications75Recent advances of photothermal technology in CO 2 capture and methanation5Synthesis of synergistic catalysts: integrating defects, SMSI, and plasmonic effects for enhanced photocatalytic CO 2 reduction27In-situ restructuring of Ni-based metal organic frameworks for photocatalytic CO2 hydrogenation57Time‐Resolved Control of MOF‐Nanoparticle Heterojunctions for Crystal Composites with Tailorable Photocatalytic Performance9A Novel Ti 12 ‐Based Metal‐Organic Framework for Photocatalytic Hydrogen Evolution21Sandwiching of MOF nanoparticles between graphene oxide nanosheets among ice grains26Titanium-based metal-organic frameworks: Synthesis innovations and multifunctional applications51Nucleophilic oxygen atom enabled surface charge reorganization on Ti-based MOF-MXene hybrid for ultra-trace ammonia detection8Investigation of Gd(III) 2D Metal–Organic Frameworks for Magnetic Refrigeration6Thermal Crystal-to-Crystal Transformation Unlocks Ti8O10(OOC)12-Cluster-Based Metal–Organic Frameworks13Ti-Bimetallic MOFs as Photo-Reformers and Degraders of Emerging Water Contaminants0Photo-thermal Catalytic CO 2 Methanation by RuO x @MIL-101(Cr) with 9.2% Apparent Quantum Yield under Visible Light Irradiation14Photocatalytic Reactors for CO2 Reduction: Review on Simulation Studies10Tetrazine‐Based Coordination Polymers as Versatile Photocatalysts for Wastewater Treatment1Metal–organic frameworks for photocatalytic CO2 reduction1Rational Design and Application of MOF‐Based Materials for Photocatalytic CO 2 Reduction9Inducing Reactivity by Cluster Strain in Titanium Frameworks2MOFs and MOF materials in catalysis0Enhanced Pb2+ remediation using bimetallic room temperature synthesized ZnNi-MOF-74 and ZnMg-MOF-74 adsorbents3Unlocking solar photo-thermal catalytic CO2 methanation at mild conditions using porphyrin-based metal-organic frameworks2An aqueous in situ approach to discover crystalline coordination materials for adsorptive separation2Reaction Mechanisms and Advanced Catalysts for Photothermal CO 2 Methanation: A Comprehensive Review2Mesoporous titanium-based organic frameworks for highly efficient room-temperature oxidative desulfurization using diluted H2O20Metal–Oxo Cluster Composition in Metal–Organic Frameworks Controls Solar-Driven CO2 Methanation Pathways0Metal-Organic Frameworks for Gas-Solid Reactive Carbon Dioxide Capture – Photo/Thermochemical Routes0

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  1. Effects of ligand functionalization on the band gaps and luminescent properties of a Zr 12 oxo-cluster based metal–organic framework

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  2. H 2 S Stability of Metal–Organic Frameworks: A Computational Assessment

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  3. Metal–Organic Frameworks for Photo/Electrocatalysis

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  4. A Showcase of Green Chemistry: Sustainable Synthetic Approach of Zirconium‐Based MOF Materials

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  5. Synthesis of newly amorphous-porous titanium-based 3D-MOFs

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  6. Current Trends and Approaches to Boost the Performance of Metal Organic Frameworks for Carbon Dioxide Methanation through Photo/Thermal Hydrogenation: A Review

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  7. Performance tuning of a DBD plasma catalytic hybrid process for CO2 methanation

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  8. Mixed component metal-organic frameworks: Heterogeneity and complexity at the service of application performances

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  9. A critical review on the development of metal-organic frameworks for boosting photocatalysis in the fields of energy and environment

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  10. In situ Ce-doped catalyst derived from NiCeAl-LDHs with enhanced low-temperature performance for CO2 methanation

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  11. Spatially separated oxygen vacancies and nickel sites for ensemble promotion of selective CO2 photoreduction to CO

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  12. Strategies for improving the photocatalytic performance of metal-organic frameworks for CO2 reduction: A review

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  13. Rational Design of Metal–Organic Framework‐Based Materials for Photocatalytic CO2 Reduction

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  14. Toward solar-driven photocatalytic CO2 methanation under continuous flow operation using benchmark MIL-125(Ti)–NH2 supported ruthenium nanoparticles

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  15. Development of soluble UiO-66 to improve photocatalytic CO2 reduction

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  16. Advances and Perspectives of Photopromoted CO2 Hydrogenation for Methane Production: Catalyst Development and Mechanism Investigations

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  17. Metal‐Organic‐Frameworks and Their Derived Materials in Photo‐Thermal Catalysis

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  18. Amino-Functionalized Titanium Based Metal-Organic Framework for Photocatalytic Hydrogen Production

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  19. Diversity and recent progressive trend in MOFs-based photo-electrocatalysts for selective CO2 reduction

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  20. Selective Photocatalytic Dehydrogenation of Formic Acid by an In Situ -Restructured Copper-Postmetalated Metal–Organic Framework under Visible Light

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  21. Heterometallic Metal-organic frameworks (MOFs) catalysts

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  22. Switchable Metal Sites in Metal–Organic Framework MFM‐300(Sc): Lewis Acid Catalysis Driven by Metal–Hemilabile Linker Bond Dynamics

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  23. Switchable Metal Sites in Metal–Organic Framework MFM‐300(Sc): Lewis Acid Catalysis Driven by Metal–Hemilabile Linker Bond Dynamics

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  24. Recent advances on photo-thermo-catalysis for carbon dioxide methanation

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  25. A Critical Review of the Use of Bismuth Halide Perovskites for CO2 Photoreduction: Stability Challenges and Strategies Implemented

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  26. Cu(II)-Based Molecular Hexagons Forming Honeycomb-like Networks Exhibit High Electrical Conductivity

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  27. A State-of-the-Art of Metal-Organic Frameworks for Chromium Photoreduction vs. Photocatalytic Water Remediation

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  28. Metal–Organic Framework‐Based Photocatalysis for Solar Fuel Production

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  29. Metal–organic frameworks as chemical nanoreactors for the preparation of catalytically active metal compounds

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  30. Classification of the MOFs Based on the Secondary Building Units (SBUs)

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  31. Insights into the sacrificial structure–activity relationship of a Ti-based metal–organic framework in an oxidative desulfurization reaction

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  32. Zr- and Ti-based metal–organic frameworks: synthesis, structures and catalytic applications

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  33. Electron microscopy and diffraction study of metal-organic frameworks

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  34. Equilibrium photo-thermodynamics enables a sustainable methanol synthesis

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  35. Controlled Supramolecular Self‐assembly in MOF Confined Spaces

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  36. Solar-driven gas phase photocatalytic CO2 methanation by multimetallic UiO-66 solids decorated with RuOx nanoparticles

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  37. Metal-organic frameworks for environmental and energy related applications

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  38. The Emergence of 2D Building Units in Metal‐Organic Frameworks for Photocatalytic Hydrogen Evolution: A Case Study with COK‐47

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  39. Metal organic framework composites for reduction of CO2

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  40. Calix[4]arene-Functionalized Titanium-Oxo Compounds for Perceiving Differences in Catalytic Reactivity Between Mono- and Multimetallic Sites

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  41. Microporous Organic Network: Superhydrophobic Coating to Protect Metal–Organic Frameworks from Hydrolytic Degradation

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  42. A chelating coordination modulation method for the synthesis of Ti-MOF single crystals

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  43. Harnessing a Ti-based MOF for selective adsorption and visible-light-driven water remediation

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  45. Metal–organic frameworks for organic transformations by photocatalysis and photothermal catalysis

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  46. Water-stable metal–organic frameworks (MOFs): rational construction and carbon dioxide capture

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  47. Construction of a Ti-Based Bimetallic Metal–Organic Framework Using a One-Pot Method for Efficient C 2 H 2 /C 2 H 4 and C 2 H 2 /CO 2 Separation

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  48. Modulating interfacial charges in CTF-based metal-insulator-semiconductor promotes selective CO2 reduction to CH4

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  49. CO2 photocatalytic reduction with robust and stable metal–organic framework: a review

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  50. Solar Gas-Phase CO 2 Hydrogenation by Multifunctional UiO-66 Photocatalysts

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