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RESEARCH PAPER · Journal of Materials Chemistry A · 2020

Advances in rechargeable Mg batteries

Chaolin You, Xiongwei Wu, Xinhai Yuan, Yuhui Chen, Lili Liu, Yusong Zhu, Lijun Fu, Yuping Wu, Yu‐Guo Guo, Teunis van Ree

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Advances in rechargeable Mg batteriesOriginalBuilt-in electric field enhanced ionic transport kinetics in the T-Nb 2 O 5 @MoO 2 heterostructure17Catalytic mechanism of spinel oxides for oxidative electrolyte decomposition in Mg rechargeable batteries37Rechargeable Mg–Na and Mg–K hybrid batteries based on a low-defect Co 3 [Co(CN) 6 ] 2 nanocube cathode6Operation Mechanism in Hybrid Mg–Li Batteries with TiNb2O7 Allowing Stable High-Rate Cycling21Ultralong-Lifespan Magnesium Batteries Enabled by the Synergetic Manipulation of Oxygen Vacancies and Electronic Conduction25An Overview on Anodes for Magnesium Batteries: Challenges towards a Promising Storage Solution for Renewables130Co0.85Se hollow polyhedrons entangled by carbon nanotubes as a high-performance cathode for magnesium secondary batteries38The Quest for Functional Oxide Cathodes for Magnesium Batteries: A Critical Perspective77Characteristics of Electrochemical Energy Storage Materials in Light of Advanced Characterization Techniques0Uniform Magnesium Electrodeposition via Synergistic Coupling of Current Homogenization, Geometric Confinement, and Chemisorption Effect123Progress on graphitic carbon materials for potassium- based energy storage27Dendrite‐Suppressing Polymer Materials for Safe Rechargeable Metal Battery Applications: From the Electro‐Chemo‐Mechanical Viewpoint of Macromolecular Design25High-rate performance magnesium batteries achieved by direct growth of honeycomb-like V2O5 electrodes with rich oxygen vacancies41AZ31 Magnesium Alloy Foils as Thin Anodes for Rechargeable Magnesium Batteries43A Microcapsule‐Assistant Self‐Healing Magnesium Battery Cathodes6New phases of MBenes M2B (M = Sc, Ti, and V) as high-capacity electrode materials for rechargeable magnesium ion batteries80The electrochemical properties of iodine cathode in a novel rechargeable hydrogen ion supercapattery system with molybdenum trioxide as anode12NiCo2O4 nanowire-supported NiCoMnS4 nanosheets on carbon cloth as a flexible cathode for high-performance aqueous supercapacitors51Current Design Strategies for Rechargeable Magnesium-Based Batteries208Exploring the electrochemical properties of Na2S -V2O5-P2O5 glass-ceramic nanocomposites as a cathode for magnesium-ion batteries22Atom-efficient synthesis of a benchmark electrolyte for magnesium battery applications14Less is more: tiny amounts of insoluble multi-functional nanoporous additives play a big role in lithium secondary batteries11Repurposing metal containing wastes and mass-produced materials as electrocatalysts for water electrolysis22PVP-induced synergistic engineering of interlayer, self-doping, active surface and vacancies in VS4 for enhancing magnesium ions storage and durability89Pre-intercalation chemistry of electrode materials in aqueous energy storage systems68Structural design and optimization of metal-organic framework-derived FeO @C/rGO anode materials for constructing high-performance hybrid supercapacitors51Highly reversible Mg metal anodes enabled by interfacial liquid metal engineering for high-energy Mg-S batteries101First-principles calculations of carboxylic acid adsorption on carbonate surfaces: Chain size and aqueous interface effects12In Situ Anchoring Anion‐Rich and Multi‐Cavity NiS 2 Nanoparticles on NCNTs for Advanced Magnesium‐Ion Batteries63p‐Type Redox‐Active Organic Electrode Materials for Next‐Generation Rechargeable Batteries113Ionic Liquid Electrolytes for Next-generation Electrochemical Energy Devices93Recent advances in kinetic optimizations of cathode materials for rechargeable magnesium batteries56Review of room-temperature liquid metals for advanced metal anodes in rechargeable batteries84First-principles investigations to evaluate Mo2B monolayers as promising two-dimensional anode materials for Mg-ion batteries12A long-cycle life recharge magnesium ion battery using the Na2Li2Ti6O14 nanoparticles as an anode material5High area-capacity Mg batteries enabled by sulfur/copper integrated cathode design21A High Potential Polyanion Cathode Material for Rechargeable Mg‐Ion Batteries30Modification of a Cu Mesh with Nanowires and Magnesiophilic Ag Sites to Induce Uniform Magnesium Deposition30A Charge Equalizer in Accordion— MXene‐Modified Layer Leading to Spherical Lithium Deposition11TiVCTx MXene/Chalcogenide Heterostructure‐Based High‐Performance Magnesium‐Ion Battery as Flexible Integrated Units78A high-performance room-temperature magnesium ion battery with self-healing liquid alloy anode mediated with a bifunctional intermetallic compound18Sodium diffusion in scheelite-type Na2Zr(MoO4)3 and Na4Zr(MoO4)46Eumelanin-inspired nanomaterials in electrochemical energy storage devices: A review37P2 ‐type Na x TmO 2 oxides as cathodes for non‐aqueous sodium‐ion batteries—Structural evolution and commercial prospects26Cobalt hexacyanoferrate enhanced by common ion effect for aqueous potassium-ion batteries18Decoupling Ion Transport and Matrix Dynamics to Make High Performance Solid Polymer Electrolytes72β-V2O5 as Magnesium Intercalation Cathode28Impedance spectroscopy of Na2S – V2O5 – P2O5 glass-ceramic nanocomposites10Organic Electrolyte Design for Rechargeable Batteries: From Lithium to Magnesium95Organic Electrolyte Design for Rechargeable Batteries: From Lithium to Magnesium3Tailoring a Hybrid Functional Layer for Mg Metal Anodes in Conventional Electrolytes with a Low Overpotential25Methodologies for Operando ATR-IR Spectroscopy of Magnesium Battery Electrolytes8A Density Functional Theory Study on Rechargeable Mg‐ion Batteries: C 20 Fullerene as a Promising Anode Material5Recent Progress in Bi-Based Anodes for Magnesium Ion Batteries8A Molybdenum Polysulfide In-Situ Generated from Ammonium Tetrathiomolybdate for High-Capacity and High-Power Rechargeable Magnesium Battery Cathodes41Chloride‐Free Electrolytes for High‐Voltage Magnesium Metal Batteries: Challenges, Strategies, and Perspectives21Surface Amalgam on Magnesium Electrode: Protective Coating or Not?4Progress and perspective on rechargeable magnesium-ion batteries38Fundamentals and Scientific Challenges in Structural Design of Cathode Materials for Zinc‐Ion Hybrid Supercapacitors242Unexplored Class of Eutectic Electrolytes for Rechargeable Magnesium Batteries20Defect Chemistry in Zn3V4(PO4)61Facile synthesis of cobalt-doped sodium lithium manganese oxide with superior rate capability and excellent cycling performance for sodium-ion battery12Hierarchical BiOCl flowerlike microspheres via a room-temperature solid-state chemical reaction as a new anode for rechargeable magnesium-ion batteries22Recent progress in structural modification of polymer gel electrolytes for use in solid-state zinc-ion batteries19A Single Mg Ion-conductive Polymer-coated MgCo2O4 for Mg Rechargeable Batteries3On the bramble way to Mg metal anodes in secondary Mg ion batteries22Research progress towards the corrosion and protection of electrodes in energy-storage batteries98A critical review of vanadium-based electrode materials for rechargeable magnesium batteries45The Proof‐of‐Concept of Anode‐Free Rechargeable Mg Batteries30Poly(quinone-1,4-diaminoanthraquinone) cathodes for stable Zn2+ storage in aqueous zinc-ion batteries22Bismuth Nanoparticle-Embedded Carbon Microrod for High-Rate Electrochemical Magnesium Storage20High stability In–Sn–Bi multi-element alloy anode for Mg ion batteries18Understanding the Unique Thermodynamic Behavior of MgTFSI2/DME Solutions. Part 1: Phase Diagram, Partial Volumes, and Densities2BN endofullerenes as anode materials for magnesium-ion batteries: a density functional theory study5Increasing the cell voltage of a magnesium ion battery with B 24 O 24 anode through encapsulating halides: a DFT study1Covalent Organic Framework-Based Electrolytes for Lithium Solid-State Batteries—Recent Progress14Magnesium-based energy materials: Progress, challenges, and perspectives181Mechanism of sodium diffusion in Na5-xM1-xZrx(MoO4)4 (M = Y, La, Bi; 0 ≤ x ≤ 0.1) revealed from 23Na NMR, impedance spectroscopy and ab initio calculations3Boosting adsorption and dissociation kinetics of magnesium-chloride ion pair via bismuth/indium-based artificial interface8Recent Advances in Liquid Metals for Rechargeable Batteries30Investigation of the electrochemical performance of Mg-ion batteries based on PVDF-HFP thin polymer electrolyte films19Potassium ion pre-intercalated MnO2 for aqueous multivalent ion batteries13Optimizing interfacial process of Mg metal anode by porphyrin adsorption layer in Cl-free conventional electrolyte13Toward high-energy magnesium battery anode: recent progress and future perspectives34Securing cation vacancies to enable reversible Mg insertion/extraction in rocksalt oxides11Structural, Electronic and Vibrational Properties of B24N24 Nanocapsules: Novel Anodes for Magnesium Batteries8Unraveling the potential of Al2CO bilayer as anode material in magnesium ion battery and unsuitability for lithium ion battery84Pillar‐Structured Ti 3 C 2 T x MXene with Engineered Interlayer Spacing for High‐Performance Magnesium Batteries23First-Principles Insights on Solid-State Phase Transitions in P2-NaxMnO2-Based High Energy Cathode during Na-Ion Battery Operations30Batteries – Battery Types – Lithium Batteries | Electrolytes0Inducing Rigidity in Layered Structures for Improved Anodic Performance in Magnesium-Ion Battery: A Computational Design6Cost-Effective Rechargeable Magnesium Battery Based on a Fluorinated Alkoxyaluminate Electrolyte and a Carbonyl Polymer Cathode12Phase-field simulation of magnesium-metal anode interface growth in different electrolytes during electrodeposition2Utilizing machine learning and phonon density of states for innovative approaches to design and optimize high-performance solid-state Mg-ion electrolytes10Recent progress in the research on magnesium and magnesium alloy foils: A short review22Linker-Derived Contortion Controls Performance in Organic Polymer Pseudocapacitors6Sustainable LiFePO4 and LiMnxFe1-xPO4 (x=0.1–1) cathode materials for lithium-ion batteries: A systematic review from mine to chassis111Alkali‐Ion‐Assisted Activation of ε‐VOPO4 as a Cathode Material for Mg‐Ion Batteries13Carbon-coated BiOCl/Bi heterojunction flowerlike microspheres for collaboratively boosting storage magnesium performance25Machine learning molecular dynamics insight into high interface stability and fast kinetics of low-cost magnesium chloride amine electrolyte for rechargeable magnesium batteries23Silicene/BN heterostructure as high-performance anode material for Mg-ion batteries5Dealloying induced Porous Bi anodes for rechargeable magnesium-ion batteries7Gel Polymer Electrolytes Based on Facile In Situ Ring‐Opening Polymerization Enabling High‐Performance Rechargeable Magnesium Batteries14Progress and Challenges of Vanadium Oxide Cathodes for Rechargeable Magnesium Batteries17Influence of Simple Salts on Solvent Reduction Stability at Mg‐Alloy Anodes Interface: A Potential‐Dependent DFT Study2TiO2_ZnTiO3 with carbon nanotubes catalytically improve the hydrogen storage characteristics of MgH220A Li/Mg Double‐Salt Strategy Based on Amine Solvent Achieves Bulk Phase‐Interface‐Electrode Multi‐Scale Optimization for Mg Metal Batteries21Stabilizing zinc anodes by a solvation sheath modification with toluenesulfonate additive14Magnesium 4, 5, and 6 coordinate complexes with ligands bound via sp or sp2 hybridized atoms4Insights into Hyper-Efficient Construction of Compact Artificial SEI for Highly Reversible Mg Metal Anode61Uncovering the Potential of Two-Dimensional SrRuO3 as anode material in Li, Na, Mg, Ca, K, and Zn ion Batteries: First-Principles investigations of structural, electronic and electrochemical properties58Kirkendall effect-assisted synthesis of hollow MoS 2 nanospheres with interlayer expansion for improved magnesium diffusion kinetics and durability6The “sweet spot” in length for contorted conjugated ladders in ultrafast-charging Li and Mg batteries3Magnesium Alginate as an Electrolyte for Magnesium Batteries8Magnesium bromide/aniline magnesium bromide sustained-release layer enables highly efficient Mg metal anode5Deformation behavior and fracture mechanism of magnesium foil under low-temperature on-line heating rolling5Review: Overview of Organic Cathode Materials in Lithium-Ion Batteries and Supercapacitors13Design of Electrolyte Using Deep Eutectic Solvents for High‐Performance Rechargeable Nickel‐Iodine Batteries5Uncovering the Potential of Layered InOCI as Anode Material in Lithium, Magnesium, and Aluminum Ion Batteries: First‐Principles Investigations2Oxygen vacancies and Li+ pre-embedding for magnesium storage in Anatase TiO2 toward magnesium/lithium hybrid batteries7Interfacial atomistic reactive mechanisms of magnesium batteries5Simultaneous Enhancement of Interface Stability and Ionic Transport by Li+ and BH4– in Magnesium-Based Energy Storage6Uncovering the Potential of Layered InOCI as Anode Material in Lithium, Magnesium, and Aluminum Ion Batteries: First‐Principles Investigations26Self-supporting composite anodes with three-dimensional network by wood-derived hard carbon in rechargeable metallic magnesium batteries3Calcium batteries: synergistic effects of Ca(BF4)2 and acetonitrile for calcium deposition/stripping2Anion‐Confined Interface Enabling Uniform Stripping of Magnesium Anode2Functionalized Separators for Batteries: Universality and Individuality16MgMoV2O6/TiO2 nanocomposite: Synthesis, structure, morphology and electrochemical performance0Uncovering the potential of two-dimensional T-BC monolayer as anode for Ca-ion batteries: A computer-based study and electrochemical properties0Bismuth‐Integrated Nitrogen‐Doped Carbon Nanostructures Enabling Broad Electrolyte Compatibility for Mg‐Ion Batteries1Composition optimization of ternary Bi-Sn-In alloy anodes for magnesium ion batteries0Can the development of batteries keep pace with the ever-increasing demands of consumers?1High-performance aqueous Mg-ion batteries achieved through entropic stabilization of Prussian blue analogs in water-in-salt electrolytes4Zn‐Assisted Mg Ion Transport in Spinel Oxide Cathodes: Insights From Neural Network Simulations2Unlocking Mg 2+ storage in imine-functionalized CNTs@COF hybrids: role of in situ coatings in enhancing magnesium battery performance2Machine-learned interatomic potentials for battery materials: from fundamental methodology to emerging applications in electrodes, electrolytes, and interfaces0Vanadium-based MBene monolayers revealed as high-capacity anode materials for bivalent metal-ion batteries: A DFT investigation0Mechanistic Insights into Magnesium Metal Anodes: Interfacial Challenges and Design Principles in Organic and Aqueous Electrolytes17Rechargeable magnesium batteries: System-level opportunities and challenges for battery energy storage applications12Rational design of sulfone-based electrolytes for dual-ion batteries1Synergistic effect of morphology engineering and oxygen vacancies on enhancing the electrochemical performance of MgMn2O4 cathode for magnesium-ion batteries0Synergistic enhancement of magnesium storage in biphase In2Bi/InBi alloy films2Interlayer anion engineering in LDHs: Dominant hydrogen-bonding network with tuned interlayer/electronic structure for high-performance aqueous magnesium-ion batteries0Successive electrodeposition for precision construction of multi-layered magnesium-philic films to improve the electrochemical performance of magnesium batteries0Vanadium-based MBene (VB2 and V2B2) monolayers revealed as high-capacity anode materials for bivalent metal-ion batteries: A density functional theory investigation3Magnesium ion conducting PVB-PMMA blend polymer electrolytes: Comprehensive structural, dielectric and electrochemical investigation0Carbon‐Based Materials for Rechargeable Magnesium Batteries: Multifunctional Roles, Mechanistic Insights, and Future Perspectives0An Organic‐Aqueous Miscible Electrolyte Enables High‐Voltage Magnesium Batteries With Outstanding Cycling Stability0

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  5. Ultralong-Lifespan Magnesium Batteries Enabled by the Synergetic Manipulation of Oxygen Vacancies and Electronic Conduction

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  34. First-principles investigations to evaluate Mo2B monolayers as promising two-dimensional anode materials for Mg-ion batteries

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  35. A long-cycle life recharge magnesium ion battery using the Na2Li2Ti6O14 nanoparticles as an anode material

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  45. Cobalt hexacyanoferrate enhanced by common ion effect for aqueous potassium-ion batteries

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