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RESEARCH PAPER · Annual Review of Materials Research · 2021

Ternary Nitride Materials: Fundamentals and Emerging Device Applications

Ann L. Greenaway, Celeste L. Melamed, M. Brooks Tellekamp, Rachel Woods‐Robinson, Eric S. Toberer, James Richmond Neilson, Adele C. Tamboli

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Ternary Nitride Materials: Fundamentals and Emerging Device ApplicationsOriginalThe role of disorder in the synthesis of metastable ternary nitrides2Exploring the phase space of Zn 2 SbN 3 , a novel semiconducting nitride7The Effect of Al2O3 Oxygen Sub-Lattice on Femon2 Phase Stability0Band gap bowing and spectral width of Ga (1−x) In x N alloys for modelling light emitting diodes6Reactive phosphine combinatorial co-sputtering of cation disordered ZnGeP 2 films15Zinc germanium nitrides and oxide nitrides: the influence of oxygen on electronic and structural properties2Heteroepitaxial ZnGeN2on AlN: Growth, Structure, and Optical Properties11Experimental Synthesis of Theoretically Predicted Multivalent Ternary Nitride Materials73Metathesis routes to materials6Discovery of Two Polymorphs of TiP4N8Synthesized from Binary Nitrides2Discovery of Two Polymorphs of TiP4N8Synthesized from Binary Nitrides14CeTaN 3 and CeNbN 3 : Prospective Nitride Perovskites with Optimal Photovoltaic Band Gaps36Self-doping behavior and cation disorder in MgSnN217Role of disorder in the synthesis of metastable zinc zirconium nitrides37Short-Range Order Tunes Optical Properties in Long-Range Disordered ZnSnN2–ZnO Alloy7From MAX Phase Carbides to Nitrides: Synthesis of V2GaC, V2GaN, and the Carbonitride V2GaC1–xNx37Zinc Titanium Nitride Semiconductor toward Durable Photoelectrochemical Applications38Oxynitride-surface engineering of rhodium-decorated gallium nitride for efficient thermocatalytic hydrogenation of carbon dioxide to carbon monoxide19A flexible and scalable scheme for mixing computed formation energies from different levels of theory49Synthesis, Crystal Structures, Mechanical Properties, and Formation Mechanisms of Cubic Tungsten Nitrides16Li and group-III impurity doping in ZnSnN2 : Potential and limitations3Bulk and film synthesis pathways to ternary magnesium tungsten nitrides17Study of pnictides for photovoltaic applications8Electronic, mechanical, optical and thermodynamic properties of the quaternary semiconductors Sr3GeMgN4 and Ba3GeMgN41Combinatorial Synthesis of Cation-Disordered Manganese Tin Nitride MnSnN 2 Thin Films with Magnetic and Semiconducting Properties16Anti-perovskite nitrides and oxides: Properties and preparation44Elastic, electronic, optical and thermoelectric properties of Ca5Si2N6 and Sr5Ge2N6 ternary nitrides10Polar Nitride Perovskite LaWN3‐δ with Orthorhombic Structure20Cation-Disorder-Enhanced Unintentional Doping in MgSnN24Canted antiferromagnetism in polar MnSiN2 with high Néel temperature5Uncovering cation disorder in ternary Zn 1+ x Ge 1− x (N 1− x O x ) 2 and its effect on the optoelectronic properties3Low-temperature synthesis of cation-ordered bulk Zn 3 WN 4 semiconductor via heterovalent solid-state metathesis6Optimising Gas Composition in Rf Sputtering Plasma for Enhanced Properties of Eco-Friendly Cu3n Films for Photodetection Applications0Stability and electronic properties of ‘4-8’-type ZnSnN2 thin films free of spontaneous polarization for optoelectronic applications0Exploring the Potential of Nitride and Carbonitride MAX Phases: Synthesis, Magnetic and Electrical Transport Properties of V2GeC, V2GeC0.5N0.5, and V2GeN14Mechanistically Guided Materials Chemistry: Synthesis of Ternary Nitrides, CaZrN 2 and CaHfN 222Comparing the influence of cation order and composition in simulated Zn(Sn, Ge)N2 on structure, elastic moduli, and polarization for solid state lighting1Theoretical exploration of ternary nitrides for high-efficiency ferroelectric photovoltaics5First-Principles Studies of the Electronic and Optical Properties of Zinc Titanium Nitride: The Role of Cation Disorder11The Critical Role of Anharmonic Lattice Dynamics for Macroscopic Properties of the Visible Light Absorbing Nitride Semiconductor CuTaN 210Exploring ferroelectric and photovoltaic attributes of Pna21-LaWN3: A first-principles approach9Identification of a Ternary Nitride Ti10Cu3N4 with a Unique Structure Type2P 1− x Ta 8+ x N 13 ( x =0.1–0.15): A Phosphorus Tantalum Nitride Featuring Mixed‐Valent Tantalum and P/Ta Disorder Visualized by Scanning Transmission Electron Microscopy2P1−xTa8+xN13 (x=0.1–0.15): A Phosphorus Tantalum Nitride Featuring Mixed‐Valent Tantalum and P/Ta Disorder Visualized by Scanning Transmission Electron Microscopy1Cation disorder in MgSnN 2 and its effects on the electronic properties8Expanding the Phase Space for Halide-Based Solid Electrolytes: Li–Mg–Zr–Cl Spinels23Synthesis, Crystal Structure, Stability, and Mechanical Properties of the Hexagonal Tungsten Nitride WN1−δ10Synthesis pathways to thin films of stable layered nitrides18Phase engineering of nitride thin films1Plasmonic Hyperbolic Dispersion in Epitaxial Rock Salt/Wurtzite Superlattices1Ultrahigh carrier mobility and anisotropy of the layered semiconductor ATiN2 (A = Ca, Sr and Ba)2Strategic lattice manipulation in transition metal nitrides for improved solubility4Theoretical and data-driven approaches to semiconductors and dielectrics: from prediction to experiment2Scalable Bulk Synthesis of Phase‐Pure γ‐ Sn 3 N 4 as a Model for an Argon‐Flow‐Mediated Metathesis Reaction1Bixbyite‐Type Zirconium Tantalum Oxynitride Thin Films as Composition‐Tunable High Refractive Index Semiconductors1Effect of N2 concentration on structural, morphological, and optoelectronic properties of Cu3N films fabricated by RF magnetron sputtering for photodetection applications7Amorphous nitride semiconductors with highly tunable optical and electronic properties: the benefits of disorder in Ca–Zn–N thin films0Enhancing photocatalytic efficiency of Zn2NbN3: A first-principles study on phosphorus doping and ferroelectric properties0Bonding profiling of gapless ceramic V 2 GaC/N MAX phases: a spectroscopic and dual theoretical approach4Nitride thin films grown by thermal laser epitaxy6Two-dimensional high-entropy MWN 2 nanosheets for boosted water oxidation in alkaline media3Why is BeGeN 2 different? A computational bonding analysis0Transition metal nitrides: Essential and potential use in low-temperature fuel cells13Exploring nitrides: A promising alternative class of narrow bandgap semiconductors4Basin-Size Mapping: Prediction of Metastable Polymorph Synthesizability Across TaC–TaN Alloys3Oxygen Incorporation as a Route to Nondegenerate Zinc Nitride Semiconductor Thin Films6Realization of Non‐Equilibrium Wurtzite Structure in Heterovalent Ternary MgSiN2 Film Grown by Reactive Sputtering5Understanding the properties of novel ternary LiXN2 (X = V, Nb) nitrides for energy harvesting applications: A first-principles study3Lone Pair and Unique N‐Bridging of Novel Titanium Nitridophosphate2Ion Exchange Synthesizes a Metastable Layered Polymorph of MgZrN2 and MgHfN2 Semiconductors2Zwischen flüssig und fest: Synthese ternärer Carbide und Nitride0ZnTiN2 as an Electron-Selective, Protective Layer on Si Photocathodes4Dimensional Evolution Guides Property Control in the A n Cu 4– n TiS 4 Semiconductor Series6Cation‐Site Disordered Cu 3 PdN Nanoparticles for Hydrogen Evolution Electrocatalysis4Ferroelectric polarization and piezoelectric properties in orthorhombic Z n 3 W N 4 and Zn 3 MoN 4 : An atomic sublattice decomposition2Dimensional Reduction Guides Electronic Structure Evolution in the A n Cu 4– n SnS 4 Semiconductor Series8Temperature-dependent phonon dispersion, elasticity, and anharmonic properties of nitride perovskite LaMoN3: A first-principles study1Exploring p-type conductivity and homojunction devices in amorphous zinc tin nitride: A step toward enhanced nitride semiconductor applications2Synthesis of Free‐Standing Alloyed Plasmonic Zr x Hf 1‐x N Nanoparticles2Perspectives on oxynitride glasses: Transparency, compositions, redox, composites, crystallization, and applications3Electronic and optical properties of biaxially strained Al1-xGaxN and In1-xGaxN0Unraveling low-temperature optoelectronic and thermoelectric excellence in cation-ordered Zn3WN40Tuning Properties of II‐IV‐Nitrides for Optoelectronic Applications1First-principles insights into the multifunctional properties of the nitridogermanate Sr4GeN40Pressure-enhanced superconductivity in VN with coexistence of weakly interacting spin fluctuations1Orthorhombic Nitride Perovskite CeTaN 3‐ δ With Switchable and Robust Ferroelectric Polarization3Effective mass and isostructural phase transition of MgSiN2 under pressure and temperature0Growth of wurtzite Hf x Al1 − x N up to x = 0.39 by sputtering with bandgap shift and c/a-ratio anomaly0Electron-Enhanced Atomic Layer Deposition of Tunable TiC x N y Ternary Nitride Films Using Tetrakis(dimethylamido)titanium with Ammonia Reactive Background Gas0Superconductivity in hard nitride cP 6 -WN0Potential energy curves and transition dipole moments of the 51 lowest electronic states of the N2 molecule0Radiation-Immune Broadband Photodetection via a Plasmonic TiN Nanoantenna on 4H-SiC: Overcoming the Limits of Noble Metals1Synthesis and structural evaluation of lanthanum tungsten oxynitride perovskite nanostructures by ammonothermal nitridation approach0Observation of thermally stable polar metallic state in perovskite nitride CeWN 30The energetics of high temperature oxidation and formation mechanisms in binary lanthanide nitrides (LnN)0

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  1. The role of disorder in the synthesis of metastable ternary nitrides

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  2. Exploring the phase space of Zn 2 SbN 3 , a novel semiconducting nitride

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  3. The Effect of Al2O3 Oxygen Sub-Lattice on Femon2 Phase Stability

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  4. Band gap bowing and spectral width of Ga (1−x) In x N alloys for modelling light emitting diodes

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  5. Reactive phosphine combinatorial co-sputtering of cation disordered ZnGeP 2 films

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  6. Zinc germanium nitrides and oxide nitrides: the influence of oxygen on electronic and structural properties

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  8. Experimental Synthesis of Theoretically Predicted Multivalent Ternary Nitride Materials

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  9. Metathesis routes to materials

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  10. Discovery of Two Polymorphs of TiP4N8Synthesized from Binary Nitrides

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  12. CeTaN 3 and CeNbN 3 : Prospective Nitride Perovskites with Optimal Photovoltaic Band Gaps

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  13. Self-doping behavior and cation disorder in MgSnN2

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  14. Role of disorder in the synthesis of metastable zinc zirconium nitrides

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  15. Short-Range Order Tunes Optical Properties in Long-Range Disordered ZnSnN2–ZnO Alloy

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  16. From MAX Phase Carbides to Nitrides: Synthesis of V2GaC, V2GaN, and the Carbonitride V2GaC1–xNx

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  17. Zinc Titanium Nitride Semiconductor toward Durable Photoelectrochemical Applications

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  18. Oxynitride-surface engineering of rhodium-decorated gallium nitride for efficient thermocatalytic hydrogenation of carbon dioxide to carbon monoxide

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  19. A flexible and scalable scheme for mixing computed formation energies from different levels of theory

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  20. Synthesis, Crystal Structures, Mechanical Properties, and Formation Mechanisms of Cubic Tungsten Nitrides

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  21. Li and group-III impurity doping in ZnSnN2 : Potential and limitations

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  22. Bulk and film synthesis pathways to ternary magnesium tungsten nitrides

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  24. Electronic, mechanical, optical and thermodynamic properties of the quaternary semiconductors Sr3GeMgN4 and Ba3GeMgN4

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  29. Cation-Disorder-Enhanced Unintentional Doping in MgSnN2

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  30. Canted antiferromagnetism in polar MnSiN2 with high Néel temperature

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  31. Uncovering cation disorder in ternary Zn 1+ x Ge 1− x (N 1− x O x ) 2 and its effect on the optoelectronic properties

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  32. Low-temperature synthesis of cation-ordered bulk Zn 3 WN 4 semiconductor via heterovalent solid-state metathesis

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  34. Stability and electronic properties of ‘4-8’-type ZnSnN2 thin films free of spontaneous polarization for optoelectronic applications

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  39. First-Principles Studies of the Electronic and Optical Properties of Zinc Titanium Nitride: The Role of Cation Disorder

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  40. The Critical Role of Anharmonic Lattice Dynamics for Macroscopic Properties of the Visible Light Absorbing Nitride Semiconductor CuTaN 2

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  42. Identification of a Ternary Nitride Ti10Cu3N4 with a Unique Structure Type

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  44. P1−xTa8+xN13 (x=0.1–0.15): A Phosphorus Tantalum Nitride Featuring Mixed‐Valent Tantalum and P/Ta Disorder Visualized by Scanning Transmission Electron Microscopy

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  45. Cation disorder in MgSnN 2 and its effects on the electronic properties

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  46. Expanding the Phase Space for Halide-Based Solid Electrolytes: Li–Mg–Zr–Cl Spinels

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  47. Synthesis, Crystal Structure, Stability, and Mechanical Properties of the Hexagonal Tungsten Nitride WN1−δ

    Chemistry of Materials · 2024-08-20

    Xuefeng Zhou, Yongcheng Liang, Chao Gu, Leiming Fang, Bin Chen, Yusheng Zhao, Shanmin Wang

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  48. Synthesis pathways to thin films of stable layered nitrides

    Nature Synthesis · 2024-09-06

    Andriy Zakutayev, Matthew Jankousky, Laszlo Wolf, Yijun Feng, Christopher L. Rom, Sage R. Bauers, Olaf J. Borkiewicz, David A. LaVan, Rebecca W. Smaha, Vladan Stevanović

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  49. Phase engineering of nitride thin films

    Nature Synthesis · 2024-09-30

    Xing Ming, Xiaojun Kuang

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  50. Plasmonic Hyperbolic Dispersion in Epitaxial Rock Salt/Wurtzite Superlattices

    ACS Applied Electronic Materials · 2024-10-03

    Xinwei Wang, Shaoqin Peng, Wei Chen, Shao‐Dong Cheng, Shunda Zhang, Jie J. Sun, Hongtao Cao, Ruyi Zhang, Yanwei Cao

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