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RESEARCH PAPER · Angewandte Chemie International Edition · 2020

Potential‐Dependent Morphology of Copper Catalysts During CO 2 Electroreduction Revealed by In Situ Atomic Force Microscopy

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Potential‐Dependent Morphology of Copper Catalysts During CO 2 Electroreduction Revealed by In Situ Atomic Force MicroscopyOriginalThe role of electrode wettability in electrochemical reduction of carbon dioxide239The role of site coordination on the CO2 electroreduction pathway on stepped and defective copper surfaces13Two-dimensional materials for electrochemical CO 2 reduction: materials, in situ / operando characterizations, and perspective32HKUST-1-derived highly ordered Cu nanosheets with enriched edge sites, stepped (211) surfaces and (200) facets for effective electrochemical CO2 reduction23Sub‐Second Time‐Resolved Surface‐Enhanced Raman Spectroscopy Reveals Dynamic CO Intermediates during Electrochemical CO 2 Reduction on Copper352Sub‐Second Time‐Resolved Surface‐Enhanced Raman Spectroscopy Reveals Dynamic CO Intermediates during Electrochemical CO2 Reduction on Copper21Designing Copper‐Based Catalysts for Efficient Carbon Dioxide Electroreduction350Reconstruction of Copper Nanoparticles at Electrochemical CO 2 Reduction Reaction Conditions Occurs via Two‐step Dissolution/Redeposition Mechanism65Identifying Structure–Selectivity Correlations in the Electrochemical Reduction of CO 2 : A Comparison of Well‐Ordered Atomically Clean and Chemically Etched Copper Single‐Crystal Surfaces130Identifying Structure–Selectivity Correlations in the Electrochemical Reduction of CO2: A Comparison of Well‐Ordered Atomically Clean and Chemically Etched Copper Single‐Crystal Surfaces14Pulse check: Potential opportunities in pulsed electrochemical CO2 reduction205CO 2 electroreduction by AuCu bimetallic clusters: A first principles study21Operando toolbox for heterogeneous interface in electrocatalysis39Interfacial Water Structure as a Descriptor for Its Electro-Reduction on Ni(OH)2-Modified Cu(111)46Insight into Structural Evolution, Active Sites, and Stability of Heterogeneous Electrocatalysts376Insight into Structural Evolution, Active Sites, and Stability of Heterogeneous Electrocatalysts55Cu(111) single crystal electrodes: Modifying interfacial properties to tailor electrocatalysis7Dramatic Change in the Step Edges of the Cu(100) Electrocatalyst upon Exposure to CO: Operando Observations by Electrochemical STM and Explanation Using Quantum Mechanical Calculations28Seeing is believing: In-situ visualising dynamic evolution in CO2 electrolysis14The interface is a tunable dimension in electricity‐driven organic synthesis10Morphological Stability of Copper Surfaces under Reducing Conditions81Engineering Electrochemical Surface for Efficient Carbon Dioxide Upgrade90Restructuring of copper catalysts by potential cycling and enhanced two-carbon production for electroreduction of carbon dioxide13Exploring the adsorption site coordination as a strategy to tune copper catalysts for CO 2 electro-reduction18Copper/Cuprous Oxide Nanowires with High Density Defects for Enhanced Co2 Electrocatalytic Reduction to Ethylene Over a Wide Potential Window0In situ regeneration of copper catalysts for long-term electrochemical CO 2 reduction to multiple carbon products61Recent Advances and Performance Enhancement Mechanisms of Pulsed Electrocatalysis5The role of crystal facets and disorder on photo-electrosynthesis19Dynamic Evolution of Active Sites in Electrocatalytic CO 2 Reduction Reaction: Fundamental Understanding and Recent Progress213Enhanced Electrocatalytic CO 2 Reduction to C 2+ Products by Adjusting the Local Reaction Environment with Polymer Binders193The concept of active site in heterogeneous catalysis850Shaping Copper Nanocatalysts to Steer Selectivity in the Electrochemical CO2 Reduction Reaction135The Interactive Dynamics of Nanocatalyst Structure and Microenvironment during Electrochemical CO 2 Conversion100Surface Reconstruction with a Sandwich-like C/Cu/C Catalyst for Selective and Stable CO 2 Electroreduction36WITHDRAWN4Steering the structure and selectivity of CO2 electroreduction catalysts by potential pulses433Structural Reconstruction of Catalysts in Electroreduction Reaction: Identifying, Understanding, and Manipulating69Modeling Operando Electrochemical CO 2 Reduction155Modulating AgIn@In2O3 Core–Shell Catalysts for Amplified Electrochemical Reduction of CO2 to Formate2Carbon Catalysts for Electrochemical CO2 Reduction toward Multicarbon Products118Screening Surface Structure–Electrochemical Activity Relationships of Copper Electrodes under CO2 Electroreduction Conditions73Surface cavity effect on C2H4 formation from electrochemical reduction of CO2 as studied using Cu2O cubes14Steering surface reconstruction of copper with electrolyte additives for CO2 electroreduction1732022 roadmap on low temperature electrochemical CO 2 reduction232Tandem effect of Ag@C@Cu catalysts enhances ethanol selectivity for electrochemical CO2 reduction in flow reactors73Single Particle Hopping as an Indicator for Evaluating Electrocatalysts18Structure–activity relations of Cu-based single-crystal model electrocatalysts3Electrochemical CO2reduction to C2+products using Cu-based electrocatalysts: A review224Dealloyed Intermetallic Cu5Ca Fine Powders as Nanoporous Electrocatalysts for CO2Reduction4Rational Manipulation of Intermediates on Copper for CO2 Electroreduction Toward Multicarbon Products52Probing the Dynamics of Low-Overpotential CO 2 -to-CO Activation on Copper Electrodes with Time-Resolved Raman Spectroscopy147Structure of the (Bi)carbonate Adlayer on Cu(100) Electrodes20Structure of the (Bi)carbonate Adlayer on Cu(100) Electrodes0Enhanced Electrochemical CO2 Reduction to Formate on Poly(4-vinylpyridine)-Modified Copper and Gold Electrodes48Challenges and strategies towards copper-based catalysts for enhanced electrochemical CO2 reduction to multi-carbon products94Hot Electron Phenomena at Solid–Liquid Interfaces17Active site identification and engineering during the dynamic evolution of copper-based catalysts for electrocatalytic CO2 reduction45Restructuring of well-defined Pt-based electrode surfaces under mild electrochemical conditions11Surface-enhanced vibrational spectroscopies in electrocatalysis: Fundamentals, challenges, and perspectives29Water electrolysis497Upgrading the Detection of Electrocatalyst Degradation During the Oxygen Evolution Reaction0Advanced In Situ Characterization Techniques for Direct Observation of Gas‐Involved Electrochemical Reactions72In Situ Monitoring of the Surface Evolution of a Silver Electrode from Polycrystalline to Well-Defined Structures6Recent Advances and Perspectives of Electrochemical CO2 Reduction Toward C2+ Products on Cu-Based Catalysts103FTIR-Assisted Electroreduction of CO2 and H2O to CO and H2 by Electrochemically Deposited Copper on Oxidized Graphite Felt12Electrochemical Approaches to CO 2 Conversion on Copper-Based Catalysts38Selective CO2 Reduction to Ethylene Over a Wide Potential Window by Copper Nanowires with High Density of Defects10Recent Advances in In Situ/Operando Surface/Interface Characterization Techniques for the Study of Artificial Photosynthesis19Electrochemical scanning probe microscopies for artificial photosynthesis6The Necessity for Multiscale In Situ Characterization of Tailored Electrocatalyst Nanoparticle Stability19In situ/operando characterization techniques for electrochemical CO2 reduction84The New Era of High-Throughput Nanoelectrochemistry132Near ambient N2 fixation on solid electrodes versus enzymes and homogeneous catalysts92Upgrading the detection of electrocatalyst degradation during the oxygen evolution reaction34Stabilizing Cu Catalysts for Electrochemical CO2 Reduction Using a Carbon Overlayer8Visualizing Catalytic Dynamics Processes via Synchrotron Radiation Multitechniques43Nanoscale Electron Transfer Variations at Electrocatalyst–Electrolyte Interfaces Resolved by in Situ Conductive Atomic Force Microscopy51Localized Alkaline Environment via In Situ Electrostatic Confinement for Enhanced CO 2 -to-Ethylene Conversion in Neutral Medium295Advanced in-situ electrochemical scanning probe microscopies in electrocatalysis34Morphology Changes of Cu 2 O Catalysts During Nitrate Electroreduction to Ammonia**32An Explicit-Implicit Hybrid Solvent Model for Grand Canonical Simulations of the Electrochemical Environment7Interfacial Chemistry in the Electrocatalytic Hydrogenation of CO2 over C-Supported Cu-Based Systems13Chemical and Structural Evolution of AgCu Catalysts in Electrochemical CO 2 Reduction186Hurry Up and Wait: Managing the Inherent Mismatches in Time Scales in Natural and Artificial Photosynthetic Systems15In Situ EC-AFM Study of the Initial Stages of Cathodic Corrosion of Pt(111) and Polycrystalline Pt in Acid Solution15Dual-site catalysts featuring platinum-group-metal atoms on copper shapes boost hydrocarbon formations in electrocatalytic CO2 reduction115New paradigm of in situ characterization for next-generation CO2 electroreduction towards multi-carbon products over Cu-based catalysts12High-rate and selective conversion of CO2 from aqueous solutions to hydrocarbons102Understanding the restructuring and degradation of oxide-derived copper during electrochemical CO2 reduction36Porous Organic Polymers‐Based Single‐Atom Catalysts for Sustainable Energy‐Related Electrocatalysis94Insights into the dynamic evolution of catalytic active centers of the electrocatalytic carbon dioxide reduction reaction20Inverted Region in Electrochemical Reduction of CO 2 Induced by Potential-Dependent Pauli Repulsion76Assessment of the Degradation Mechanisms of Cu Electrodes during the CO 2 Reduction Reaction40Machine Learning Based Electronic Structure Predictors in Single-Atom Alloys: A Model Study of CO Kink-Site Adsorption across Transition Metal Substrates8Spatiotemporal Mapping of Local Heterogeneities during Electrochemical Carbon Dioxide Reduction25Nafion-Assisted Electrochemical Detection of Copper(I) Oxide Nanoparticles Under Neutral Conditions2Scanning tunneling microscopy under chemical reaction at solid–liquid and solid–gas interfaces8Dynamic Surface Reconstruction of Amphoteric Metal (Zn, Al) Doped Cu 2 O for Efficient Electrochemical CO 2 Reduction to C 2+ Products114Experimental evidence of distinct sites for CO2-to-CO and CO conversion on Cu in the electrochemical CO2 reduction reaction222Atomic-scale surface restructuring of copper electrodes under CO2 electroreduction conditions330Multiscale CO 2 Electrocatalysis to C 2+ Products: Reaction Mechanisms, Catalyst Design, and Device Fabrication328Gaining Deep Understanding of Electrochemical CO2RR with In Situ/Operando Techniques41Cu+ transient species mediate Cu catalyst reconstruction during CO2 electroreduction3CuGaO2 delafossite as a high-surface area model catalyst for Cu+-activated reactions6Steering the Dynamics of Reaction Intermediates and Catalyst Surface during Electrochemical Pulsed CO 2 Reduction for Enhanced C 2+ Selectivity106Progress and Perspectives of Pulse Electrolysis for Stable Electrochemical Carbon Dioxide Reduction43A CO2 electrolyzer tandem cell system for CO2-CO co-feed valorization in a Ni-N-C/Cu-catalyzed reaction cascade91The dynamic behaviors of heterogeneous interfaces in electrocatalytic CO2 reduction17A Bibliometric Analysis on Pulsed Electrolysis: Electronic Effect, Double Layer Effect, and Mass Transport19Self-Limited Reconstruction Realized via Copper-Ligand Interaction for Stabilizing High-Selective CO2 Electromethanation25Polymer Modification Strategy to Modulate Reaction Microenvironment for Enhanced CO2 Electroreduction to Ethylene82Polymer Modification Strategy to Modulate Reaction Microenvironment for Enhanced CO2 Electroreduction to Ethylene9Tailoring the facet distribution on copper with chloride18Design and regulation of defective electrocatalysts206Exploring the stability and catalytic activity of monoethanolamine functionalized CuO electrode in electrochemical CO 2 reduction3Facile synthesis of electrocatalytically active Cu/graphite using the negative electrode of spent Li-ion batteries5Fractal growth of a fern-like nanostructured Cu 2 O film electrode for electrochemical reduction of CO 2 to ethanol3Modeling diurnal and annual ethylene generation from solar-driven electrochemical CO 2 reduction devices21Studying the cation dependence of CO 2 reduction intermediates at Cu by in situ VSFG spectroscopy16Solution-based Cu+ transient species mediate the reconstruction of copper electrocatalysts for CO2 reduction243The Relevance of the Interfacial Water Reactivity for Electrochemical CO Reduction on Copper Single Crystals22Organic Thin Films Enable Retaining the Oxidation State of Copper Catalysts during CO2 Electroreduction21Spontaneous Reconstruction of Copper Active Sites during the Alkaline CORR: Degradation and Recovery of the Performance70Dynamic evolution of copper-based catalysts during CO2 electroreduction14A surface strategy boosting the ethylene selectivity for CO2 reduction and in situ mechanistic insights146Facilitating electrocatalytic CO2 reduction through electrolyte additives accompanied by activation of copper electrode with cyclic voltammetry4Complementary probes for the electrochemical interface107Theoretical Investigation of the Adsorbate and Potential‐Induced Stability of Cu Facets During Electrochemical CO2 and CO Reduction11Electrochemical CO2 Activation and Valorization on Metallic Copper and Carbon‐Embedded N‐Coordinated Single Metal MNC Catalysts43Electrochemical CO2 Activation and Valorization on Metallic Copper and Carbon‐Embedded N‐Coordinated Single Metal MNC Catalysts7Self-Reconstruction of Core–Shell Structured Electrocatalysts for Tailoring Reaction Pathways Revealed by Electrochemical Surface-Enhanced Raman Spectroscopy9Anionic Coordination Control in Building Cu‐Based Electrocatalytic Materials for CO2 Reduction Reaction14In situ/Operando Synchrotron Radiation Analytical Techniques for CO 2 /CO Reduction Reaction: From Atomic Scales to Mesoscales1In situ/Operando Synchrotron Radiation Analytical Techniques for CO2/CO Reduction Reaction: From Atomic Scales to Mesoscales52Electrochemical Characterization of Electrodeposited Copper in Amine CO2 Capture Media1Structure-sensitive reactivities of O/Cu(1 0 0) studied by in situ NAP-STM3Visualizing Electrochemical CO 2 Conversion via the Emerging Scanning Electrochemical Microscope: Fundamentals, Applications and Perspectives7Recent advances in dynamic reconstruction of electrocatalysts for carbon dioxide reduction46Scanning Probe Microscopies for Characterizations of 2D Materials26H and CO Co-Induced Roughening of Cu Surface in CO 2 Electroreduction Conditions85Toward Durable CO 2 Electroreduction with Cu‐Based Catalysts via Understanding Their Deactivation Modes68Ethylene Electrosynthesis via Selective CO 2 Reduction: Fundamental Considerations, Strategies, and Challenges46Alkali cation-induced cathodic corrosion in Cu electrocatalysts86Dynamic recycling behavior of Cu/Zn-based electrodes in electrochemical CO2 reduction11Some remaining puzzles in hydrogen electrocatalysis mechanisms on platinum surfaces30Interrogation of Oxidative Pulsed Methods for the Stabilization of Copper Electrodes for CO2 Electrolysis88Origin of Metal–Support Interactions for Selective Electrochemical CO2 Reduction into C1 and C2+ Products27Electrolyte–Electrocatalyst Interfacial Effects of Polymeric Materials for Tandem CO2 Capture and Conversion Elucidated Using In Situ Electrochemical AFM13Electrolyte manipulation on Cu-based electrocatalysts for electrochemical CO2 reduction47The rise of electrochemical surface science: From in situ interface structure to operando dynamics12

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    Transactions of Tianjin University · 2022-08-01

    Guangyi Jiang, Daliang Han, Zishan Han, Jiachen Gao, Xinyu Wang, Zhe Weng, Quan‐Hong Yang

    Read original paper ↗ ·
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