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RESEARCH PAPER · Materials Horizons · 2020

Design strategies for ceria nanomaterials: untangling key mechanistic concepts

Yuwen Xu, Sajjad S. Mofarah, Rashid Mehmood, Claudio Cazorla, Pramod Koshy, Charles Christopher Sorrell

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Design strategies for ceria nanomaterials: untangling key mechanistic conceptsOriginalImpact of morphology and collagen-functionalization on the redox equilibria of nanoceria for cancer therapies7Defect engineering of oxide perovskites for catalysis and energy storage: synthesis of chemistry and materials science335Dual functionality of mixed Cu-based two-dimensional (2D) heterostructures derived from electronic waste8Highly catalytically active CeO 2−x -based heterojunction nanostructures with mixed micro/meso-porous architectures22Mo-doped, Cr-Doped, and Mo–Cr codoped TiO2 thin-film photocatalysts by comparative sol-gel spin coating and ion implantation24Synthesis and Structure-Chirality Relationship Analysis of Steroidal Quinoxalines to Design and Develop New Chiral Drugs4DFT Investigation of pH-Driven Oxygen Vacancy Formation-Annihilation in CeO21Solvothermal Synthesis Routes to Substituted Cerium Dioxide Materials21Decoupling the Impacts of Engineering Defects and Band Gap Alignment Mechanism on the Catalytic Performance of Holey 2D CeO 2− x ‐Based Heterojunctions53Preclinical Cancer Theranostics—From Nanomaterials to Clinic: The Missing Link57Band-Gap Engineering: A New Tool for Tailoring the Activity of Semiconducting Oxide Catalysts for CO Oxidation39Green Stealth Engineering of Lifetime-Biocatalytic Nanocatalyst for Neuroblastoma Therapy5Role of Oxygen Vacancy Ordering and Channel Formation in Tuning Intercalation Pseudocapacitance in Mo Single-Ion-Implanted CeO 2– x Nanoflakes25Anticancer therapeutic effect of cerium-based nanoparticles: known and unknown molecular mechanisms48Confinement of nano-gold in 3D hierarchically structured gadolinium-doped ceria mesocrystal: synergistic effect of chemical composition and structural hierarchy in CO and propane oxidation3First-principles high-throughput screening of bulk piezo-photocatalytic materials for sunlight-driven hydrogen production37Synthesis, characterization, and photocatalysis of a rare-earth cerium/silver/zinc oxide inorganic nanocomposite6Density Functional Theory Investigation of the Biocatalytic Mechanisms of pH-Driven Biomimetic Behavior in CeO 261Reaction Atmospheres and Surface Ligation Control Surface Reactivity and Morphology of Cerium Oxide Nanocrystals during Continuous Addition Synthesis63D hierarchically structured Ce1-xGdxO2-x/2 mixed oxide particles: the role of microstructure, porosity and multi-level architecture stability in soot and propane oxidation.6Preparation of ceria by combined sol–gel and hydrothermal method: insights from the effects of different bases on the particle size distribution6Morphological Mapping of Hydrothermally Synthesised Nanoceria at High Ce Concentrations4Development of functional layers for direct ethanol solid oxide fuel cells0Tuning of Shape, Defects, and Disorder in Lanthanum-Doped Ceria Nanoparticles: Implications for High-Temperature Catalysis53Synthesis of Nanoceria with Varied Ratios of Ce3+/Ce4+ Utilizing Soluble Borate Glass19Insights on catalytic mechanism of CeO2 as multiple nanozymes227Bimodal mesoporous CeO2–ZrO2-based materials prepared by PMMA nanosphere assisted co-precipitation and its thermal stability6Void space and secondary oriented attachment mechanisms in cerium oxide nanorods6Solvothermal and hydrothermal methods for preparative solid-state chemistry5Recent progress of CeO2-based catalysts with special morphologies applied in air pollutants abatement: A review57Toward a Consistent Prediction of Defect Chemistry in CeO262Nanostructured CeO 2 ultrathin film deposited by the Langmuir Blodgett technique for highly sensitive and specific detection of sub ppm level NO 2 gas at room temperature6The Influence of Cerium to Manganese Ratio and Preparation Method on the Activity of Ceria-Manganese Mixed Metal Oxide Catalysts for VOC Total Oxidation15Recent Advances on Fine-Tuning Engineering Strategies of CeO2-Based Nanostructured Catalysts Exemplified by CO2 Hydrogenation Processes38Unveiling the Role of In Situ Sulfidation and H2O Excess on H2S Decomposition to Carbon-Free H2 over Cobalt/Ceria Catalysts8Phytomediated-Assisted Preparation of Cerium Oxide Nanoparticles Using Plant Extracts and Assessment of Their Structural and Optical Properties19From Ce(OH) 3 to Nanoscaled CeO 2 : Identification and Crystal Structure of a Cerium Oxyhydroxide Intermediate Phase48Aging mechanisms of nanoceria and pathways for preserving optimum morphology11Efficient and stable piezo-photocatalytic splitting of water and seawater by interfacial engineering of Na0.5Bi0.5TiO3/Na0.5Bi4.5Ti4O15 self-generated heterojunctions45Ceria-based ceramics surface investigation5ROS‐mediated anticancer effects of EGFR‐targeted nanoceria8Engineering a hollow bowl-like porous carbon-confined Ru–MgO hetero-structured nanopair as a high-performance catalyst for ammonia borane hydrolysis60Two decades of ceria nanoparticle research: structure, properties and emerging applications125Tailoring the Structural and Optical Properties of Cerium Oxide Nanoparticles Prepared by an Ecofriendly Green Route Using Plant Extracts30A neoteric antibacterial ceria-silver nanozyme for abiotic surfaces40Chemical isolation of rare earth elements (as pure rare earth oxides) from Nd-Fe-B magnets and Ni-MH batteries8Evolution of Ce4+ Lewis acidity during dehydroxylation of ceria nanoparticles with different morphology: An integrated FTIR, DFT and HRTEM study17Operando Monitoring of Homolytic Cleavage of H2 into Surface Hydrides on Defective Cerium Dioxide Nanoparticles2Cerium oxide nanoparticles in wound care: a review of mechanisms and therapeutic applications81Co3O4 supported on CeO2 with specific morphologies for high efficient CO-PROX reaction9Implications of size dispersion on X-ray scattering of crystalline nanoparticles: CeO 2 as a case study12Comparative first-principles analysis of crystalline versus amorphous CeO2 particles: implications for chemical mechanical planarization14Multifunctional scaffolds for bone repair following age-related biological decline: Promising prospects for smart biomaterial-driven technologies30SILAR deposited antiviral silver-doped ceria nano-films1Atomic-level insights into CeO2 performance: Chemical interactions in CMP explored through CeO2-SiO2 studies28Ce(III) formate-derived hierarchical cerium oxide particles with icosahedral symmetry-based architectures: Effect of third level of structural hierarchy in soot and propane oxidation3Development of Technology for the Synthesis of Nanocrystalline Cerium Oxide Under Production Conditions with the Best Regenerative Activity and Biocompatibility for Further Creation of Wound-Healing Agents12Constructing mesoporous CeO2 single-crystal particles in ionic liquids for enhancing the conversion of CO2 and alcohols to carbonates7Des-Guided Engineering of N-Doped Carbon for Mussel-Inspired, Oxygen-Vacancy-Rich Ceo2 Nanozymes Toward Ultrasensitive H2o2 Sensing0Flow synthesis of CeO2 nanoparticles by forced thin-film type reactor with addition of Al(NO3)30Review of phase equilibria of the system BaO–TiO 23Theranostic performance of EGFR-targeted ceria-based nanoparticles on EGFR-positive cancers1Interplay between iridium doping and oxygen vacancies in ceria: Experimental and theoretical investigation of optical and electronic properties10A cerium-based ferroptosis/PANoptosis nano-inducer for photothermal-enhanced combination therapy of breast cancer6Cerium-doped calcium phosphate materials for bone tissue engineering2DES-guided engineering of N-doped carbon for mussel-inspired, oxygen-vacancy-rich CeO2 nanozymes toward H2O2 sensing1Structure and Methods of Obtaining CeO2-x Nanocrystals0Transforming disorder in the design of advanced high-entropy oxide electrocatalysts for zinc-air batteries7Multifunctional CeO2 nanostructures: Recent advances in catalysis to environmental frontiers5Ambient-Pressure Near-Edge X-ray Absorption Fine Structure Study of the Photothermal Water Splitting Process on the Cu:CeO 2 Nanostructure Surface0Unstable Oxygen Vacancy Thermodynamics and Transport in CeO2: Multiscale Defect Dynamics and Catalytic Implications1Morphology‐Engineered Ceria Nanoparticles Ameliorate Periodontitis via Enhanced Antioxidant and Anti‐Inflammatory Activities0Surface Expansion of Nano-Ceria Induced by Hexamethylenetetramine (HMT) and Formate Binding.0

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  1. Impact of morphology and collagen-functionalization on the redox equilibria of nanoceria for cancer therapies

    Materials Science and Engineering C · 2020-10-22

    Wen‐Fan Chen, Chantelle Marie De Sa Malacco, Rashid Mehmood, Kochurani K. Johnson, Jia‐Lin Yang, Charles Christopher Sorrell, Pramod Koshy

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  2. Defect engineering of oxide perovskites for catalysis and energy storage: synthesis of chemistry and materials science

    Chemical Society Reviews · 2021-01-01

    Hamidreza Arandiyan, Sajjad S. Mofarah, Charles Christopher Sorrell, Esmail Doustkhah, Baharak Sajjadi, Derek Hao, Yuan Wang, Hongyu Sun, Bing‐Jie Ni, Mehran Rezaei, Zongping Shao, Thomas Maschmeyer

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  3. Dual functionality of mixed Cu-based two-dimensional (2D) heterostructures derived from electronic waste

    Green Chemistry · 2021-01-01

    Rasoul Khayyam Nekouei, Ignacio Tudela, Sajjad S. Mofarah, Ehsan Vahidi, Samane Maroufi, Ke Wang, Farshid Pahlevani, Veena Sahajwalla

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  4. Highly catalytically active CeO 2−x -based heterojunction nanostructures with mixed micro/meso-porous architectures

    Nanoscale · 2021-01-01

    Sajjad S. Mofarah, Luisa Schreck, Claudio Cazorla, Xiaoran Zheng, Esmaeil Adabifiroozjaei, Constantine Tsounis, Jason Anthony Scott, Reza Shahmiri, Yin Yao, Roozbeh Abbasi, Yuan Wang, Hamidreza Arandiyan, L. R. Sheppard, Vienna Wong, Esmail Doustkhah, Pramod Koshy, Charles Christopher Sorrell

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  5. Mo-doped, Cr-Doped, and Mo–Cr codoped TiO2 thin-film photocatalysts by comparative sol-gel spin coating and ion implantation

    International Journal of Hydrogen Energy · 2021-02-19

    Amanda Chen, Wen‐Fan Chen, Tina Majidi, Bernadette Pudadera, Armand J. Atanacio, Madhura Manohar, L. R. Sheppard, Rong Liu, Charles Christopher Sorrell, Pramod Koshy

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  6. Synthesis and Structure-Chirality Relationship Analysis of Steroidal Quinoxalines to Design and Develop New Chiral Drugs

    Chemistry · 2021-03-15

    Rashid Mehmood, Naghmana Rashid, Shakir Ullah, Maria John Newton Amaldoss, Charles Christopher Sorrell

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  7. DFT Investigation of pH-Driven Oxygen Vacancy Formation-Annihilation in CeO2

    arXiv (Cornell University) · 2021-04-22

    Hongyang Ma, Hangjuan Ren, Zhao Liu, Pramod Koshy, Charles Christopher Sorrell, Judy Nancy Hart

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  8. Solvothermal Synthesis Routes to Substituted Cerium Dioxide Materials

    Inorganics · 2021-05-21

    James W. Annis, Janet M. Fisher, David Thompsett, Richard I. Walton

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  9. Decoupling the Impacts of Engineering Defects and Band Gap Alignment Mechanism on the Catalytic Performance of Holey 2D CeO 2− x ‐Based Heterojunctions

    Advanced Functional Materials · 2021-07-03

    Xiaoran Zheng, Sajjad S. Mofarah, Claudio Cazorla, Rahman Daiyan, Ali Asghar Esmailpour, Jason Anthony Scott, Yin Yao, Sean Lim, Vienna Wong, Ewing Y. Chen, Hamidreza Arandiyan, Pramod Koshy, Charles Christopher Sorrell

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  10. Preclinical Cancer Theranostics—From Nanomaterials to Clinic: The Missing Link

    Advanced Functional Materials · 2021-07-24

    Kochurani K. Johnson, Pramod Koshy, Jia‐Lin Yang, Charles Christopher Sorrell

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  11. Band-Gap Engineering: A New Tool for Tailoring the Activity of Semiconducting Oxide Catalysts for CO Oxidation

    The Journal of Physical Chemistry Letters · 2021-09-16

    Hongmin Zhang, Zhiqiang Zhang, Yameng Liu, Xiuzhong Fang, Junwei Xu, Xiang Wang, Xianglan Xu

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  12. Green Stealth Engineering of Lifetime-Biocatalytic Nanocatalyst for Neuroblastoma Therapy

    Applied Surface Science · 2021-10-04

    Rashid Mehmood, Maria John Newton Amaldoss, Sajjad S. Mofarah, Qinxiang Zheng, Natasha Kapoor‐Kaushik, Nicholas Ariotti, Aditya Rawal, Jia‐Lin Yang, Pramod Koshy, Charles Christopher Sorrell

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  13. Role of Oxygen Vacancy Ordering and Channel Formation in Tuning Intercalation Pseudocapacitance in Mo Single-Ion-Implanted CeO 2– x Nanoflakes

    ACS Applied Materials & Interfaces · 2021-12-07

    Xiaoran Zheng, Sajjad S. Mofarah, Alan Cen, Claudio Cazorla, Enamul Haque, Ewing Y. Chen, Armand J. Atanacio, Madhura Manohar, Corey Venkata Vutukuri, Joel Luke Abraham, Pramod Koshy, Charles Christopher Sorrell

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  14. Anticancer therapeutic effect of cerium-based nanoparticles: known and unknown molecular mechanisms

    Biomaterials Science · 2022-01-01

    Maria John Newton Amaldoss, Rashid Mehmood, Jia‐Lin Yang, Pramod Koshy, Naresh Kumar, Ashwin Unnikrishnan, Charles Christopher Sorrell

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  15. Confinement of nano-gold in 3D hierarchically structured gadolinium-doped ceria mesocrystal: synergistic effect of chemical composition and structural hierarchy in CO and propane oxidation

    Catalysis Science & Technology · 2022-01-01

    Piotr Woźniak, Małgorzata A. Małecka, Piotr Kraszkiewicz, W. Miśta, Oleksii S. Bezkrovnyi, Lidia Esther Chinchilla, Susana Trasobares

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  16. First-principles high-throughput screening of bulk piezo-photocatalytic materials for sunlight-driven hydrogen production

    Journal of Materials Chemistry A · 2022-01-01

    Zhao Liu, Biao Wang, Dewei Chu, Claudio Cazorla

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  17. Synthesis, characterization, and photocatalysis of a rare-earth cerium/silver/zinc oxide inorganic nanocomposite

    Green Processing and Synthesis · 2022-01-01

    Jiang Wu, Qiao Li, Guoliang Zhang, Yuguang Lv

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  18. Density Functional Theory Investigation of the Biocatalytic Mechanisms of pH-Driven Biomimetic Behavior in CeO 2

    ACS Applied Materials & Interfaces · 2022-03-01

    Hongyang Ma, Zhao Liu, Pramod Koshy, Charles Christopher Sorrell, Judy Nancy Hart

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  19. Reaction Atmospheres and Surface Ligation Control Surface Reactivity and Morphology of Cerium Oxide Nanocrystals during Continuous Addition Synthesis

    Inorganic Chemistry · 2022-03-06

    Tawney A. Knecht, James Evan Hutchison

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  20. 3D hierarchically structured Ce1-xGdxO2-x/2 mixed oxide particles: the role of microstructure, porosity and multi-level architecture stability in soot and propane oxidation.

    Materials Research Bulletin · 2022-03-11

    Piotr Woźniak, Małgorzata A. Małecka, Lidia Esther Chinchilla, Susana Trasobares

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  21. Preparation of ceria by combined sol–gel and hydrothermal method: insights from the effects of different bases on the particle size distribution

    Chemical Papers · 2022-04-26

    Zerin Yeşil Acar, Meltem Asiltürk, Ertuğrul Arpaç

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  22. Morphological Mapping of Hydrothermally Synthesised Nanoceria at High Ce Concentrations

    ChemNanoMat · 2022-05-09

    Yuwen Xu, Pramod Koshy, Sajjad S. Mofarah, Charles Christopher Sorrell

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  23. Development of functional layers for direct ethanol solid oxide fuel cells

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  24. Tuning of Shape, Defects, and Disorder in Lanthanum-Doped Ceria Nanoparticles: Implications for High-Temperature Catalysis

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  25. Synthesis of Nanoceria with Varied Ratios of Ce3+/Ce4+ Utilizing Soluble Borate Glass

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  26. Insights on catalytic mechanism of CeO2 as multiple nanozymes

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  27. Bimodal mesoporous CeO2–ZrO2-based materials prepared by PMMA nanosphere assisted co-precipitation and its thermal stability

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  28. Void space and secondary oriented attachment mechanisms in cerium oxide nanorods

    Journal of Nanoparticle Research · 2022-11-01

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  29. Solvothermal and hydrothermal methods for preparative solid-state chemistry

    Elsevier eBooks · 2022-11-25

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  30. Recent progress of CeO2-based catalysts with special morphologies applied in air pollutants abatement: A review

    Journal of environmental chemical engineering · 2022-12-15

    Tong S. Wu, Rui‐tang Guo, Chu‐fan Li, Wei-guo Pan

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  31. Toward a Consistent Prediction of Defect Chemistry in CeO2

    Chemistry of Materials · 2022-12-21

    Xingfan Zhang, Lei Zhu, Qing Lin Hou, Jingcheng Guan, You Lü, Thomas W. Keal, John Buckeridge, C. Richard A. Catlow, Alexey A. Sokol

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  32. Nanostructured CeO 2 ultrathin film deposited by the Langmuir Blodgett technique for highly sensitive and specific detection of sub ppm level NO 2 gas at room temperature

    Journal of Materials Chemistry C · 2023-01-01

    Sipra Choudhury, Supriya Kanth, Vibha Saxena, Jagannath Gupta, Chirayath Antony Betty

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  33. The Influence of Cerium to Manganese Ratio and Preparation Method on the Activity of Ceria-Manganese Mixed Metal Oxide Catalysts for VOC Total Oxidation

    Catalysts · 2023-01-04

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  34. Recent Advances on Fine-Tuning Engineering Strategies of CeO2-Based Nanostructured Catalysts Exemplified by CO2 Hydrogenation Processes

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  35. Unveiling the Role of In Situ Sulfidation and H2O Excess on H2S Decomposition to Carbon-Free H2 over Cobalt/Ceria Catalysts

    Catalysts · 2023-02-28

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  36. Phytomediated-Assisted Preparation of Cerium Oxide Nanoparticles Using Plant Extracts and Assessment of Their Structural and Optical Properties

    International Journal of Molecular Sciences · 2023-05-17

    Nicușor Fifere, Anton Airinei, Florica Doroftei, Tudor Stefan Ardeleanu, Marius Dobromir, Daniel Ilie Timpu, Elena‐Laura Ursu

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  37. From Ce(OH) 3 to Nanoscaled CeO 2 : Identification and Crystal Structure of a Cerium Oxyhydroxide Intermediate Phase

    Chemistry of Materials · 2023-06-21

    Rémi F. André, Gwenaëlle Rousse, Capucine Sassoye, Maxim Avdeev, Benedikt Lassalle‐Kaiser, Benoı̂t Baptiste, Sophie Carenco

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  38. Aging mechanisms of nanoceria and pathways for preserving optimum morphology

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  39. Efficient and stable piezo-photocatalytic splitting of water and seawater by interfacial engineering of Na0.5Bi0.5TiO3/Na0.5Bi4.5Ti4O15 self-generated heterojunctions

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  40. Ceria-based ceramics surface investigation

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  41. ROS‐mediated anticancer effects of EGFR‐targeted nanoceria

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  42. Engineering a hollow bowl-like porous carbon-confined Ru–MgO hetero-structured nanopair as a high-performance catalyst for ammonia borane hydrolysis

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  43. Two decades of ceria nanoparticle research: structure, properties and emerging applications

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  44. Tailoring the Structural and Optical Properties of Cerium Oxide Nanoparticles Prepared by an Ecofriendly Green Route Using Plant Extracts

    International Journal of Molecular Sciences · 2024-01-04

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  45. A neoteric antibacterial ceria-silver nanozyme for abiotic surfaces

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    Abinaya Sindu Pugazhendhi, Craig J. Neal, Khoa Minh Ta, Marco Molinari, Udit Kumar, Fei Wei, Elayaraja Kolanthai, Andrew Ady, Christina Drake, Megan Hughes, Shibu Yooseph, Sudipta Seal, Melanie Jean Coathup

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  46. Chemical isolation of rare earth elements (as pure rare earth oxides) from Nd-Fe-B magnets and Ni-MH batteries

    Journal of environmental chemical engineering · 2024-03-24

    Rasoul Khayyam Nekouei, Samane Maroufi, Hossein Salehi, Veena Sahajwalla

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  47. Evolution of Ce4+ Lewis acidity during dehydroxylation of ceria nanoparticles with different morphology: An integrated FTIR, DFT and HRTEM study

    Journal of Catalysis · 2024-03-25

    Kristina K. Chakarova, Videlina R. Zdravkova, Bayan S. Karapenchev, D. Nihtianova, Elena Z. Ivanova, Hristiyan A. Aleksandrov, Iskra Z. Koleva, Dimitar A. Panayotov, Mihail Mihaylov, Georgi N. Vayssilov, Konstantin Hadjiivanov

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  48. Operando Monitoring of Homolytic Cleavage of H2 into Surface Hydrides on Defective Cerium Dioxide Nanoparticles

    ChemCatChem · 2024-03-25

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  49. Cerium oxide nanoparticles in wound care: a review of mechanisms and therapeutic applications

    Frontiers in Bioengineering and Biotechnology · 2024-05-20

    Shouying Chen, Yiren Wang, Shuilan Bao, Yao Li, Xiao Fu, Yang Yu, Hongbin Lyu, Haowen Pang, Shengmin Guo, Hongwei Zhang, Ping Zhou, Yun Zhou

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  50. Co3O4 supported on CeO2 with specific morphologies for high efficient CO-PROX reaction

    Chemical Physics · 2024-05-21

    Yaqi Wang, Chunhua Yang, Shuang Lv, Wei Min Gao, Sumin Li, Jinxiao Li, Rensheng Song, Hexiang Zhong, Jing Zhang, Liwei Pan

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