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RESEARCH PAPER · ACS Central Science · 2020

Novel Heterogeneous Catalysts for CO 2 Hydrogenation to Liquid Fuels

Peng Gao, Lina Zhang, Shenggang Li, Zixuan Zhou, Yuhan Sun

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Novel Heterogeneous Catalysts for CO 2 Hydrogenation to Liquid FuelsOriginalEffect of EDTA-2Na modification on Fe-Co/Al2O3 for hydrogenation of carbon dioxide to lower olefins and gasoline20The performance of Cu/Zn/Zr catalysts of different Zr/(Cu+Zn) ratio for CO2 hydrogenation to methanol39Correlation of Photocatalytic CO 2 Conversion and Electronic Structure of UiO-66 and Cu-UiO-66-NH 2 Under Irradiation Studied by In-Situ X-Ray Absorption Spectroscopy0Mechanistic studies toward the rational design of oxide catalysts for carbon dioxide hydrogenation2Recent Advances in Self-Powered Electrochemical Systems50Reverse water-gas shift reaction over Pt/MoO x /TiO 2 : reverse Mars–van Krevelen mechanism via redox of supported MoO x60Towards the development of the emerging process of CO 2 heterogenous hydrogenation into high-value unsaturated heavy hydrocarbons400Tuning product selectivity in CO 2 hydrogenation over metal-based catalysts103ZnZrOx integrated with chain-like nanocrystal HZSM-5 as efficient catalysts for aromatics synthesis from CO2 hydrogenation166A novel in situ grown Cu-ZnO-ZrO2/HZSM-5 hybrid catalyst for CO2 hydrogenation to liquid fuels of methanol and DME43Catalysts design for higher alcohols synthesis by CO2 hydrogenation: Trends and future perspectives203Recent advances in CO2 hydrogenation to value-added products — Current challenges and future directions327Synthesis of C 2+ Chemicals from CO 2 and H 2 via C–C Bond Formation101Design and Synthesis of Bioinspired ZnZrOx&Bio-ZSM-5 Integrated Nanocatalysts to Boost CO2 Hydrogenation to Light Olefins51Highly Selective Synthesis of Ethanol via CO 2 Hydrogenation over CoMoC x Catalysts44Cu-Based Nanocatalysts for CO 2 Hydrogenation to Methanol160Perspectives on Multifunctional Catalysts Derived from Layered Double Hydroxides toward Upgrading Reactions of Biomass Resources86Highly selective synthesis of LPG from CO2 hydrogenation over In2O3/SSZ-13 binfunctional catalyst23Effect of In2O3 particle size on CO2 hydrogenation to lower olefins over bifunctional catalysts92Understanding and Application of Strong Metal–Support Interactions in Conversion of CO 2 to Methanol: A Review88Direct conversion of CO2 to a jet fuel over CoFe alloy catalysts91Zn and Na promoted Fe catalysts for sustainable production of high-valued olefins by CO2 hydrogenation121Supported Metal Oxide Catalysts for CO2 Fischer–Tropsch Conversion to Liquid Fuels─A Review57Cobalt Catalysts Enable Selective Hydrogenation of CO2 toward Diverse Products: Recent Progress and Perspective128Selective Hydrogenation of CO 2 to Ethanol over Sodium-Modified Rhodium Nanoparticles Embedded in Zeolite Silicalite-195Tracking the phase changes in micelle-based NiGa nanocatalysts for methanol synthesis under activation and working conditions24A review on CO2 hydrogenation to ethanol: Reaction mechanism and experimental studies81Green Carbon Science: Efficient Carbon Resource Processing, Utilization, and Recycling towards Carbon Neutrality101Green Carbon Science: Efficient Carbon Resource Processing, Utilization, and Recycling towards Carbon Neutrality449Catalytic Methylation of Benzene over Pt/MoOx/TiO2 and Zeolite Catalyst Using CO2 and H26Fabrication of Pd/In2O3 Nanocatalysts Derived from MIL-68(In) Loaded with Molecular Metalloporphyrin (TCPP(Pd)) Toward CO2 Hydrogenation to Methanol81Chain-like ZSM-5 zeolite coupled with Cu-Fe3O4 for CO2 hydrogenation to light aromatics8Effects of Indium Promoter on Iron-Based Catalysts for Co2 Hydrogenation to Hydrocarbons16Evaluation of Alternative Processes of Methanol Production from Co2: Design, Optimization, Control, Techno-Economic, and Environmental Analysis61Highly CO-Selective Ni–MgO–CexZr1–xO2 Catalyst for Efficient Low-Temperature Reverse Water–Gas Shift Reaction18Highly Selective Hydrogenation of Co2 to C5+ Hydrocarbons Over Fe Catalysts Jointly Promoted by K with Pd0Highly Selective Hydrogenation of Co2 to C5+ Hydrocarbons Via Fe Catalysts Jointly Promoted by K with Pd0Hydrogenation of carbon dioxide (CO 2 ) to fuels in microreactors: a review of set-ups and value-added chemicals production29Research Progress of Catalytic Hydrogenation of Carbon Dioxide to Ethanol1Selective C 2+ alcohol synthesis by CO 2 hydrogenation via a reaction-coupling strategy24Understanding the geometric and basicity effects of organic polymer modifiers on Ru/TiO 2 catalysts for CO 2 hydrogenation to hydrocarbons3Kinetic Analysis of CO2 Hydrogenation to Long-Chain Hydrocarbons on a Supported Iron Catalyst38Recent advances in application of iron-based catalysts for CO hydrogenation to value-added hydrocarbons89Dynamic structural evolution of iron catalysts involving competitive oxidation and carburization during CO 2 hydrogenation317Efficient production of renewable hydrocarbon fuels using waste CO2 and green H2 by integrating Fe-based Fischer-Tropsch synthesis and olefin oligomerization23Computational identification of facet-dependent CO2 initial activation and hydrogenation over iron carbide catalyst18Optimization of the continuous coprecipitation in a microfluidic reactor: Cu-based catalysts for CO2 hydrogenation into methanol7Zeolite-based catalyst for direct conversion of CO2 to C2+ hydrocarbon: A review80Correlation of photocatalytic CO2 conversion and electronic structure of UiO-66 and Cu-UiO-66-NH2 under irradiation studied by in-situ X-ray absorption spectroscopy16Valorization of steel-work off-gases: Influence of impurities on the performance of Cu-based methanol synthesis catalyst13Co-Promoted In2O3/ZrO2 Integrated with Ultrathin Nanosheet HZSM-5 as Efficient Catalysts for CO2 Hydrogenation to Gasoline21Thermodynamic Analysis of CO2 Hydrogenation to Higher Alcohols (C2–4OH): Effects of Isomers and Methane44Tandem Reactions over Zeolite-Based Catalysts in Syngas Conversion51Frustrated Lewis pairs in situ formation in B-based porous aromatic frameworks for efficient o-phenylenediamine cyclization23Photocatalytic Oxidative Coupling of Benzylamine to Schiff Base over 0D/2D CdS/CdIn2S4 Heterojunction18Conversion of carbon dioxide into fuels—A review115Regulating iron species compositions by Fe-Al interaction in CO2 hydrogenation55Direct carbon dioxide hydrogenation to produce bulk chemicals and liquid fuels via heterogeneous catalysis89Sulfate-Promoted Higher Alcohol Synthesis from CO 2 Hydrogenation40Mechanisms of CO2 hydrogenative conversion on supported Ni/ZrO2 catalyst9Distance for Communication between Metal and Acid Sites for Syngas Conversion108A mini review on recent advances in thermocatalytic hydrogenation of carbon dioxide to value-added chemicals and fuels30Challenges and Opportunities of Fe‐based Core‐Shell Catalysts for Fischer‐Tropsch Synthesis7Highly dispersed Pd nanoparticles supported on dendritic mesoporous CeZrZnOx for efficient CO2 hydrogenation to methanol31Hydrogenation of Carbon Dioxide to Value-Added Liquid Fuels and Aromatics over Fe-Based Catalysts Based on the Fischer–Tropsch Synthesis Route23Highly selective hydrogenation of CO2 to C5+ hydrocarbons over Fe catalysts copromoted by K with Pd42Enhancing CO2 methanation over Ni catalysts supported on sol-gel derived Pr2O3-CeO2: An experimental and theoretical investigation80Green Carbon Science: Keeping the Pace in Practice100Green Carbon Science: Keeping the Pace in Practice10Recent Advances in Carbon Dioxide Adsorption, Activation and Hydrogenation to Methanol using Transition Metal Carbides36Strain-Enhanced Phase Transformation of Iron Oxide for Higher Alcohol Production from CO244Inverse Oxide/Metal Catalysts for CO2 Hydrogenation to Methanol31Role of ZrO2 and CeO2 support on the In2O3 catalyst activity for CO2 hydrogenation48Multifunctional heterogeneous catalysts for the tandem CO2 hydrogenation-Fischer Tropsch synthesis of gasoline42Advances in Selectivity Control for Fischer–Tropsch Synthesis to Fuels and Chemicals with High Carbon Efficiency184Electrochemical Promotion of Catalysis for CO2 Valorization0Selective synthesis of olefins via CO2 hydrogenation over transition-metal-doped iron-based catalysts176A review of catalytic hydrogenation of carbon dioxide: From waste to hydrocarbons61The Activity of Ultrafine Cu Clusters Encapsulated in Nano-Zeolite for Selective Hydrogenation of CO2 to Methanol9ZrO2–ZnO–CeO2 integrated with nano-sized SAPO-34 zeolite for CO2 hydrogenation to light olefins16Synthesis of Alkene and Ethanol in CO 2 Hydrogenation on a Highly Active Sputtering CuNaFe Catalyst57Lactic acid production by catalytic conversion of glucose: An experimental and techno-economic evaluation22Physico-Chemical Modifications Affecting the Activity and Stability of Cu-Based Hybrid Catalysts during the Direct Hydrogenation of Carbon Dioxide into Dimethyl-Ether13Recent advances in thermocatalytic hydrogenation of carbon dioxide to light olefins and liquid fuels via modified Fischer-Tropsch pathway107Hybrid MOF Template‐Directed Construction of Hollow‐Structured In2O3@ZrO2 Heterostructure for Enhancing Hydrogenation of CO2 to Methanol75Hetero-site cobalt catalysts for higher alcohols synthesis by CO2 hydrogenation: A review88THE PROMOTIONAL EFFECT OF POTASSIUM ON IRON-BASED SILICA SUPPORTED CATALYST FOR CO2 HYDROGENATION0Switching of CO2 hydrogenation selectivity via chlorine poisoning over Ru/TiO2 catalyst37Synthesis of ethanol, methanol and carboxylic acids using copper-based catalysts0Thermocatalytic CO 2 conversion by siliceous matter: a review48Estudo de catalisadores metálicos para a produção de metanol a partir da conversão de CO20Direct conversion of carbon dioxide into liquid fuels and chemicals by coupling green hydrogen at high temperature89Influence of Recycle Operation on the Catalytic Hydrogenation of CO2 to Long-Chain Hydrocarbons1Bimetallic Fe–Co catalysts for the one step selective hydrogenation of CO 2 to liquid hydrocarbons35CO2 Conversion via Catalytic Hydrogenation to Methanol, DME and Syngas5Consecutive sol-gel synthesis of Cu-Zn/Al2O3 catalyst for CO2 Hydrogenation0Dual functional nano zeolites for CO2 capture and conversion3Insights into the influence of Pd loading on CeO2 catalysts for CO2 hydrogenation to methanol14Recent advances of single-atom catalysts in CO 2 conversion297Research Progress on the Design, Preparation and Properties of Catalysts for CO2 Hydrogenation to Alcohols6Porous framework materials for energy & environment relevant applications: A systematic review137The synergy of Ni doping and oxygen vacancies over CeO2 in visible light-assisted thermal catalytic methanation reaction46CO2 utilization in syngas conversion to dimethyl ether and aromatics: Roles and challenges of zeolites-based catalysts59The synthesis of higher alcohols from CO2 hydrogenation over Mn-Cu-K modified Fe5C2 and CuZnAlZr tandem catalysts12Conversion of Recovered Ammonia and Carbon Dioxide into Urea in the Presence of Catalytically Active Copper Species in Nanospaces of Porous Silica Hollow Spheres17Nature of Catalytic Behavior of Cobalt Oxides for CO2 Hydrogenation42CO2 hydrogenation to methanol over hydrothermally synthesized Inx-Zry catalysts20Elucidating the structural evolution of highly efficient Co–Fe bimetallic catalysts for the hydrogenation of CO2 into olefins123Is ChatGPT a Reliable Source for Writing Review Articles in Catalysis Research? A Case Study on CO2 Hydrogenation to Higher Alcohols11Confinement Effects in Well-Defined Metal–Organic Frameworks (MOFs) for Selective CO2 Hydrogenation: A Review28Roadmap to the sustainable synthesis of polymers: From the perspective of CO2 upcycling45Molecular Views on Fischer–Tropsch Synthesis326Green Conversion of Carbon Dioxide and Sustainable Fuel Synthesis69Role of Catalyst Domain Size in the Hydrogenation of CO2 to Aromatics over ZnZrOx/ZSM-5 Catalysts19Decoupling the Interfacial Catalysis of CeO2-Supported Rh Catalysts Tuned by CeO2 Morphology and Rh Particle Size in CO2 Hydrogenation121Oxide Supported Cobalt Catalysts for CO2 Hydrogenation to Hydrocarbons: Recent Progress33Effect of Cu and Zn on the performance of Cu-Mn-Zn/ZrO2 catalysts for CO2 hydrogenation to methanol30One-step CO2 hydrogenation to C2+ products over TiO2- supported catalysts0Emerging spinel ferrite catalysts for driving CO2 hydrogenation to high-value chemicals56Nanoreactor Engineering Can Unlock New Possibilities for CO2 Tandem Catalytic Conversion to CC Coupled Products9CO2 hydrogenation for the production of higher alcohols: Trends in catalyst developments, challenges and opportunities57Direct hydrogenation of CO2 into valuable aromatics over K/Fe-Cu-Al @HZSM-5 tandem catalysts: Effects of zeolite surface acidity on aromatics formation33Understanding surface structures of In2O3 catalysts during CO2 hydrogenation reaction using time-resolved IR, XPS with in situ treatment, and DFT calculations69Three-Dimensional Assemblages of Metal Silicate for Catalytic CO2 Conversion to Methanol and Adsorptive Pollutant Removal5Assessing the efficiency of CO2 hydrogenation for emission reduction: Simulating ethanol synthesis process as a case study14Unlocking the potential of CO2 hydrogenation into valuable products using noble metal catalysts: A comprehensive review60Hydrogenation of Carbon Dioxide to Formate by Noble Metal Catalysts Supported on a Chemically Stable Lanthanum Rod-Metal–Organic Framework14Noble Metals in Recent Developments of Heterogeneous Catalysts for CO 2 Conversion Processes86Understanding of the Fate of α-Fe2O3 in CO2 Hydrogenation through Combined Time-Resolved In Situ Characterization and Microkinetic Analysis40Impacts of Interaction between Active Components on Catalyst Deactivation over KFe/ZSM-5 Bifunctional Catalyst29Selective Valorization of CO2 towards Valuable Hydrocarbons through Methanol‐mediated Tandem Catalysis30Unique biological amino acids turn CO2 emission into novel nanomaterials with three switchable product pathways9Recent Advances in the Technologies and Catalytic Processes of Ethanol Production34The role of Na for efficient CO2 hydrogenation to higher hydrocarbons over Fe-based catalysts under externally forced dynamic conditions27Reduction of CO2 to chemicals and Fuels: Thermocatalysis versus electrocatalysis166Recent Progress in Thermocatalytic Liquid Phase CO 2 Conversion to Bulk Chemicals and Fuels17The critical role of intrinsic physicochemical properties of catalysts for CO2 hydrogenation to methanol: A state of the art review30Catalytic Cracking of Fischer-Tropsch Wax on Different Zeolite Catalysts5Translating clean liquid fuels synthesis with low aromatics over NaFe@C/HZSM-22 directly in CO2 hydrogenation25Effect of Conversion, Temperature and Feed Ratio on In 2 O 3 /In(OH) 3 Phase Transitions in Methanol Synthesis Catalysts: A Combined Experimental and Computational Study11Modeling and Simulation Based Parametric Analysis for Monolithic CO2 Hydrogenation Reactors Using Experimental Data1Unveiling the promoting effect of potassium on the structural evolution of iron catalysts during CO2 hydrogenation49Double-Edged Sword Effect of Classical Strong Metal–Support Interaction in Catalysts for CO2 Hydrogenation to CO, Methane, and Methanol43Catalytic hydrogenation of CO2 as a method for obtaining valuable chemical products4Research progress of hydrogenation of carbon dioxide to ethanol49Illuminating the impact of the proximity communication modes between redox metallic and acidic zeolite sites during hydro-conversion of n-heptane5Engineering metal/metal oxide nanoparticles for photocatalytic carbon dioxide reduction0Reaction Pathways for Synthesis of Four Carbon Chemicals from Sugars and Sugar Derived Platform Chemicals15Synthesis of Liquid Hydrocarbon via Direct Hydrogenation of CO2 over FeCu-Based Bifunctional Catalyst Derived from Layered Double Hydroxides6Novel Porous Organic Polymer Catalyst with Phosphate and Sulfonic Acid Sites for Facile Esterification of Levulinic Acid24

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  2. The performance of Cu/Zn/Zr catalysts of different Zr/(Cu+Zn) ratio for CO2 hydrogenation to methanol

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  3. Correlation of Photocatalytic CO 2 Conversion and Electronic Structure of UiO-66 and Cu-UiO-66-NH 2 Under Irradiation Studied by In-Situ X-Ray Absorption Spectroscopy

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  9. ZnZrOx integrated with chain-like nanocrystal HZSM-5 as efficient catalysts for aromatics synthesis from CO2 hydrogenation

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  12. Recent advances in CO2 hydrogenation to value-added products — Current challenges and future directions

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  14. Design and Synthesis of Bioinspired ZnZrOx&Bio-ZSM-5 Integrated Nanocatalysts to Boost CO2 Hydrogenation to Light Olefins

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  15. Highly Selective Synthesis of Ethanol via CO 2 Hydrogenation over CoMoC x Catalysts

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  16. Cu-Based Nanocatalysts for CO 2 Hydrogenation to Methanol

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  17. Perspectives on Multifunctional Catalysts Derived from Layered Double Hydroxides toward Upgrading Reactions of Biomass Resources

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  18. Highly selective synthesis of LPG from CO2 hydrogenation over In2O3/SSZ-13 binfunctional catalyst

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  19. Effect of In2O3 particle size on CO2 hydrogenation to lower olefins over bifunctional catalysts

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  20. Understanding and Application of Strong Metal–Support Interactions in Conversion of CO 2 to Methanol: A Review

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  21. Direct conversion of CO2 to a jet fuel over CoFe alloy catalysts

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  22. Zn and Na promoted Fe catalysts for sustainable production of high-valued olefins by CO2 hydrogenation

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  24. Cobalt Catalysts Enable Selective Hydrogenation of CO2 toward Diverse Products: Recent Progress and Perspective

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  33. Effects of Indium Promoter on Iron-Based Catalysts for Co2 Hydrogenation to Hydrocarbons

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  34. Evaluation of Alternative Processes of Methanol Production from Co2: Design, Optimization, Control, Techno-Economic, and Environmental Analysis

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  36. Highly Selective Hydrogenation of Co2 to C5+ Hydrocarbons Over Fe Catalysts Jointly Promoted by K with Pd

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  37. Highly Selective Hydrogenation of Co2 to C5+ Hydrocarbons Via Fe Catalysts Jointly Promoted by K with Pd

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  39. Research Progress of Catalytic Hydrogenation of Carbon Dioxide to Ethanol

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  41. Understanding the geometric and basicity effects of organic polymer modifiers on Ru/TiO 2 catalysts for CO 2 hydrogenation to hydrocarbons

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  42. Kinetic Analysis of CO2 Hydrogenation to Long-Chain Hydrocarbons on a Supported Iron Catalyst

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  43. Recent advances in application of iron-based catalysts for CO hydrogenation to value-added hydrocarbons

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  44. Dynamic structural evolution of iron catalysts involving competitive oxidation and carburization during CO 2 hydrogenation

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  45. Efficient production of renewable hydrocarbon fuels using waste CO2 and green H2 by integrating Fe-based Fischer-Tropsch synthesis and olefin oligomerization

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  46. Computational identification of facet-dependent CO2 initial activation and hydrogenation over iron carbide catalyst

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